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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21

Spacecraft-to-Earth Communications for Juno and Mars Science Laboratory Critical Events

Deep Space communications typically utilize closed loop receivers and Binary Phase Shift Keying (BPSK) or Quadrature Phase Shift Keying (QPSK). Critical spacecraft events include orbit insertion and entry, descent, and landing.---Low gain antennas--> low signal -to-noise-ratio.---High dynamics such as parachute deployment or spin --> Doppler shift. During critical events, open loop receivers and Multiple Frequency Shift Keying (MFSK) used. Entry, Descent, Landing (EDL) Data Analysis (EDA) system detects tones in real-time.

radio science↗

Mission Implementation Constraints on Planetary Muon Radiography

Cost: Use heritage hardware, especially use a tested landing system to reduce cost (Phoenix or MSL EDL stage). The sky crane technology delivers higher mass to the surface and enables reaching targets at higher elevation, but at a higher mission cost. Rover vs. Stationary Lander: Rover-mounted instrument enables tomography, but the increased weight of the rover reduces the allowable payload weight. Mass is the critical design constraint for an instrument for a planetary mission. Many factors that are minor factors or do not enter into design considerations for terrestrial operation are important for a planetary application. (Landing site, diurnal temperature variation, instrument portability, shock/vibration)

entry, descent, and landing (EDL)↗

Mid-Lift-to-Drag Ratio Rigid Vehicle Control System Design and Simulation for Human Mars Entry

The Mid-Lift-to-Drag Ratio Rigid Vehicle (MRV) is a proposed candidate in the NASA Evolvable Mars Campaign's (EMC) Pathfinder Entry, Descent, and Landing (EDL) architecture study. The purpose of the study is to design a mission and vehicle capable of transporting a 20mt payload to the surface of Mars. The MRV is unique in its rigid, asymmetrical lifting-body shape which enables a higher lift-to-drag ratio (L/D) than the typical robotic Mars entry capsule vehicles that carry much less mass. This paper presents the formulation and six-degree-of-freedom (6DOF) performance of the MRV's control system, which uses both aerosurfaces and a propulsive reaction control system (RCS) to affect longitudinal and lateral directional behavior.

mars↗

Model Correlation for Mars Pathfinder Entry, Descent and Landing Simulation

Two multi-body drop tests were conducted to provide data to calibrate and verify a multi-body dynamics computer model, which was the major analytical tool used to study the entry, descent and landing (EDL) of the Mars Pathfinder mission. A general summary of the tests and important features of the simulation model are presented in this paper. Good correlation between between test results and analytical predictions were achieved.

Mars↗

OVERFLOW Analysis of Supersonic Retropropulsion Testing on a Blunt Mars Entry Vehicle Concept

Supersonic retropropulsion (SRP) flow over a Hypersonic Inflatable Aerodynamic Decelerator (HIAD) blunt-body vehicle was simulated using the Overflow Computational Fluid Dynamics (CFD) solver. Two nozzle configurations were tested (1E and 1F) as a subset of the seven total configurations in the Descent System Study (DSS) testing campaign. A generalized, Adaptive Mesh Refinement (AMR) shock capturing and plume refinement technique was developed and calibrated for producing automatic and unique grid systems optimized for any given testing condition. Solution independence from grid resolution was determined by successively increasing grid refinement until asymptotic convergence of the mean aerodynamic loads was observed. Overflow Reynolds-averaged Navier-Stokes (RANS) solutions produced realistic SRP flow phenomena, including Mach disk normal shocks contained in high-thrust plumes and bow shock triple-points. Solutions for the 1E nozzle configuration were steady. Conversely, a subset of the 1F test conditions were unsteady and exhibited periodic, non-sinusoidal expansions and contractions of the streamwise-oriented plume, resulting in unsteady aerodynamic loads on the vehicle. Initial investigations into the effect of turbulence modeling fidelity demonstrated significant differences between the aerodynamic loads simulated with RANS and Detached Eddy Simulation (DES). Multiple flow mechanisms were identified as root causes of these differences, including bow shock shape augmentation and reduced entrainment due to reduced turbulence in the DES simulations. Initial comparisons of pitching moment control authority and aerodynamic drag performance between the tested nozzle configurations demonstrated that the 1E configuration may be more advantageous for the Mars Entry, Descent, and Landing (EDL) task.

Supersonic Retropropulsion↗

OVERFLOW Analysis of Supersonic Retropropulsion Testing on a Blunt Mars Entry Vehicle Concept

Supersonic retropropulsion (SRP) flow over a Hypersonic Inflatable Aerodynamic Decelerator (HIAD) blunt-body vehicle was simulated using the Overflow Computational Fluid Dynamics (CFD) solver. Two nozzle configurations were tested (1E and 1F) as a subset of the seven total configurations in the Descent System Study (DSS) testing campaign. A generalized, Adaptive Mesh Refinement (AMR) shock capturing and plume refinement technique was developed and calibrated for producing automatic and unique grid systems optimized for any given testing condition. Solution independence from grid resolution was determined by successively increasing grid refinement until asymptotic convergence of the mean aerodynamic loads was observed. Overflow Reynolds-averaged Navier-Stokes (RANS) solutions produced realistic SRP flow phenomena, including Mach disk normal shocks contained in high-thrust plumes and bow shock triple-points. Solutions for the 1E nozzle configuration were steady. Conversely, a subset of the 1F test conditions were unsteady and exhibited periodic, non-sinusoidal expansions and contractions of the streamwise-oriented plume, resulting in unsteady aerodynamic loads on the vehicle. Initial investigations into the effect of turbulence modeling fidelity demonstrated significant differences between the aerodynamic loads simulated with RANS and Detached Eddy Simulation (DES). Multiple flow mechanisms were identified as root causes of these differences, including bow shock shape augmentation and reduced entrainment due to reduced turbulence in the DES simulations. Initial comparisons of pitching moment control authority and aerodynamic drag performance between the tested nozzle configurations demonstrated that the 1E configuration may be more advantageous for the Mars Entry, Descent, and Landing (EDL) task.

Supersonic Retropropulsion↗

Demonstration of Linear Covariance Analysis Techniques to Evaluate Entry Descent and Landing Guidance Algorithms, Vehicle Configurations, Analysis Techniques, and Trajectory Profiles

Linear covariance analysis techniques have been previously developed to analyze closed-loop entry, descent, and landing (EDL) scenarios and the initial validation efforts are under-way confirming the generated GN&C system performance results. Given both the theoretical foundation and previous conceptual demonstration, this work begins to flex the potential of linear covariance analysis for atmospheric flight and highlight its versatility and reliability by evaluating multiple entry guidance algorithms, vehicle configurations, trajectory profiles, environment conditions, and analysis techniques for a variety of trade studies. To demonstrate the benefit linear covariance analysis can provide in producing rapid yet accurate performance data, two entry profiles are adopted including the NASA Mars Science Laboratory (MSL) and Exploration Flight Test-1 (EFT-1) while utilizing two different guidance algorithms, the Apollo Final Phase (AFP) and the Fully Numeric Predictor-Corrector Entry Guidance (FNPEG) with different navigation sensor suites in a 6 degree-of-freedom (6-DOF) simulation environment. Results are shown using both linear covariance and Monte Carlo analysis techniques to high-light the consistency between the two methodologies and continue the validation maturation of linear covariance analysis for entry, descent, and landing.

EDL↗

Assessing Huygens Probe Entry, Descent, and Landing at Titan Simulation using Dragonfly Atmosphere Model

Dragonfly is a New Frontiers Program mission that will deliver a rotorcraft to Saturn's moon, Titan. This mission follows Huygens as the previous mission that successfully landed a vehicle on Titan. A flight mechanics simulation of Dragonfly's Entry, Descent, and Landing sequence has been developed using the Program to Optimize Simulated Trajectories II. The simulation incorporates several subsystem models, including aerodynamics, gravity, and mass properties, to fully capture the multi-body six degree of freedom dynamics. Among all the subsystem models that inform the Entry, Descent, and Landing dynamics, the atmosphere model of Titan is a critical component. The atmosphere model characterizes the density, temperature, pressure, and winds that the entry vehicle experiences during the descent. This impacts several aspects of the descent such as the peak heating, aerodynamics, parachute release conditions, the dynamics of the vehicle and parachutes, and the landing ellipse. In the course of developing Dragonfly, an updated model of the Titan atmosphere has been created corresponding to Dragonfly's arrival in the mid-2030s, approximately one Titan year after the Huygens mission successfully landed a probe on Titan. This work leverages previous work done to investigate Huygens EDL sequence to assess the atmosphere model developed for Dragonfly. This is done by utilizing the updated Titan atmosphere model, the Dragonfly atmosphere model, within the Huygens POST2-based flight simulation with the goal of characterizing the differences between the atmospheric models and assessing how the Dragonfly atmosphere model impacts Huygens entry dynamics.

Huygens↗

Assessing Huygens Probe Entry, Descent, and Landing at Titan Simulation using Dragonfly Atmosphere Model

Dragonfly is a New Frontiers Program mission that will deliver a rotorcraft to Saturn's moon, Titan. This mission follows Huygens as the previous mission that successfully landed a vehicle on Titan. A flight mechanics simulation of Dragonfly's Entry, Descent, and Landing sequence has been developed using the Program to Optimize Simulated Trajectories II. The simulation incorporates several subsystem models, including aerodynamics, gravity, and mass properties, to fully capture the multi-body six degree of freedom dynamics. Among all the subsystem models that inform the Entry, Descent, and Landing dynamics, the atmosphere model of Titan is a critical component. The atmosphere model characterizes the density, temperature, pressure, and winds that the entry vehicle experiences during the descent. This impacts several aspects of the descent such as the peak heating, aerodynamics, parachute release conditions, the dynamics of the vehicle and parachutes, and the landing ellipse. In the course of developing Dragonfly, an updated model of the Titan atmosphere has been created corresponding to Dragonfly's arrival in the mid-2030s, approximately one Titan year after the Huygens mission successfully landed a probe on Titan. This work leverages previous work done to investigate Huygens EDL sequence to assess the atmosphere model developed for Dragonfly. This is done by utilizing the updated Titan atmosphere model, the Dragonfly atmosphere model, within the Huygens POST2-based flight simulation with the goal of characterizing the differences between the atmospheric models and assessing how the Dragonfly atmosphere model impacts Huygens entry dynamics.

Entry Descent Landing↗

A coarse-grained model of clay colloidal aggregation and consolidation with explicit representation of the electrical double layer

The aggregation of clay minerals in liquid water exemplifies colloidal self-assembly in nature. These negatively charged aluminosilicate platelets interact through multiple mechanisms with different sensitivities to particle shape, surface charge, aqueous chemistry, and interparticle distance and exhibit complex aggregation structures. Experiments have difficulty resolving the associated colloidal assemblages at the scale of individual particles. Conversely, all-atom molecular dynamics (MD) simulations provide detailed insight on clay colloidal interaction mechanisms, but they are limited to systems containing a few particles. We develop a new coarse-grained (CG) model capable of representing assemblages of hundreds of clay particles with accuracy approaching that of MD simulations, at a fraction of the computational cost. Our CG model is parameterized based on MD simulations of a pair of smectite clay particles in liquid water. A distinctive feature of our model is that it explicitly represents the electrical double layer (EDL), i.e., the cloud of charge-compensating cations that surrounds the clay particles. Our model captures the simultaneous importance of long-range colloidal interactions (i.e., interactions consistent with simplified analytical models, already included in extant clay CG models) and short-range interactions such as ion correlation and surface and ion hydration effects. The resulting simulations correctly predict, at low solid-water ratios, the existence of ordered arrangements of parallel particles separated by water films with a thickness up to ~10 nm and, at high solid-water ratios, the coexistence of crystalline and osmotic swelling states, in agreement with experimental observations.

54 ENVIRONMENTAL SCIENCES↗

Theoretical Modeling of Electrochemical Proton-Coupled Electron Transfer

Proton-coupled electron transfer (PCET) plays an essential role in a wide range of electrocatalytic processes. Here, a vast array of theoretical and computational methods have been developed to study electrochemical PCET. These methods can be used to calculate redox potentials and pKa values for molecular electrocatalysts, proton-coupled redox potentials and bond dissociation free energies for PCET at metal and semiconductor interfaces, and reorganization energies associated with electrochemical PCET. Periodic density functional theory can also be used to compute PCET activation energies and perform molecular dynamics simulations of electrochemical interfaces. Various approaches for maintaining a constant electrode potential in electronic structure calculations and modeling complex interactions in the electric double layer (EDL) have been developed. Theoretical formulations for both homogeneous and heterogeneous electrochemical PCET spanning the adiabatic, nonadiabatic, and solvent-controlled regimes have been developed and provide analytical expressions for the rate constants and current densities as functions of applied potential. The quantum mechanical treatment of the proton and inclusion of excited vibronic states have been shown to be critical for describing experimental data, such as Tafel slopes and potential dependent kinetic isotope effects. The calculated rate constants can be used as input to microkinetic models and voltammogram simulations to elucidate complex electrocatalytic processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Four-Terminal Electrochemistry: A Back-Gate Controls the Electrochemical Potential of a 2D Working Electrode

We demonstrate that ultrathin semiconductor working electrodes integrated into metal–insulator–semiconductor (MIS) stacks are an enabling platform for understanding non-Faradaic semiconductor electrochemistry. Furthermore, 5 nm thick ZnO electrodes were deposited on 30 nm HfO 2 dielectric on a Pd “gate” electrode. Application of a bias V G between the Pd gate and the ZnO electrode causes electrons to accumulate in the ZnO layer as measured by recording the in-plane sheet conductance. By contacting the top surface of the ZnO layer with the electrolyte in a conventional three-electrode electrochemical cell, we show that the gate voltage V G modulates the electrochemical potential V ZnO of the ZnO film with respect to a reference electrode. Electrochemical potential changes ΔV ZnO up to –1 V vs Ag/Ag + are achieved for V G = +7 V. Furthermore, by measuring V ZnO vs V G , we extract the quantum capacitance CQ of the ZnO film as a function of the Fermi-level position, which provides a direct measure of the ZnO electronic density of states (DOS). Finally, we demonstrate that the gated ZnO working electrodes can disentangle the two principal components of electrochemical potential, namely, the Fermi-level shift Δδ and the double-layer charging energy eΔΦ EDL . This disentanglement hinges on a fundamental difference between back-gating and normal electrochemical control, namely, that electrochemical control requires double-layer charging, while back-gate control does not. Collectively, the results show that the backside gate electrode is an effective fourth terminal that enables measurements that are difficult to achieve in conventional three-terminal electrochemical setups.

36 MATERIALS SCIENCE↗

Simultaneous Energy Generation and Flow Enhancement (Electroslippage Effect) in Polyelectrolyte Brush Functionalized Nanochannels

Energy generation through nanofluidics is a topic of great nanotechnological relevance. In this work, we conduct all-atom molecular dynamics (MD) simulations of the transport of water and ions in a pressure-driven flow in nanochannels grafted with charged polyelectrolyte (PE) brushes and discover the possibility of simultaneous electrokinetic energy generation and flow enhancement (henceforth denoted as the electroslippage effect). Such PE-brush-functionalized nanochannels have been recently shown to demonstrate an overscreening (OS) effect (characterized by the presence of a greater number of screening counterions within the PE brush layer than needed to screen the PE brush charges), a consequent presence of excess coions within the PE brush-free bulk, and a coion-driven electroosmotic (EOS) transport in the presence of small to moderate applied axial electric fields. Here, however, we find that the streaming current, which represents the current generated by the flow-driven downstream advection of the charge imbalance present within the electric double layer (EDL) that screen the PE brush charges, is governed by the migration of the counterions. This stems from the fact that the highest contribution to the overall streaming current arises from the region near the PE brush-water interface (where there is an excess of counterions), while the brush-free bulk yields a hitherto unreported, but small, coion-dictated streaming current. This downstream advection of the charge imbalance (and the resultant counterion-driven streaming current) eventually leads to the development of an electric field (streaming electric field) in the direction that is opposite to the direction of the counterion-driven streaming current. The streaming current and the streaming electric field interact to generate the electrokinetic energy. Equally importantly, this streaming electric field induces an EOS transport, which becomes coion-driven, due to the presence of excess coions in the brush-free bulk. For the case of nanochannels grafted with negatively charged PE brushes, the streaming electric field will be in a direction that is opposite to the pressure-driven transport, and hence the coion (or anion) driven EOS flow, will be in the same direction as the pressure-driven transport. On the other hand, for the case of nanochannels grafted with positively charged PE brushes, the streaming electric field will be in the same direction as the pressure-driven flow, and hence the coion (or cation) driven EOS flow, will again be in the same direction as the pressure-driven flow. Therefore, whenever there occurs the presence of the OS and the resulting coion-driven EOS transport in PE brush grafted nanochannels, regardless of the sign of the charges of the PE brushes, this EOS transport will always aid the pressure-driven transport and will cause the most fascinating increase in the net volume flow rate across the nanochannel cross section, which is the electroslippage effect.

overscreening↗