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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Superconductivity in d- and f- band metals; Proceedings of the Conference, University of Rochester, Rochester, N.Y., October 29, 30, 1971.

High critical field measurements are discussed together with the lattice dynamics of transition metals, energy bands for transition metals and compounds, the importance of transverse acoustic phonons in A-15 superconductors, and aspects of electron-phonon coupling in transition metals. Other subjects considered include the superconductivity of Nb3Ga, the transition temperature of transition-metal superconductors, the relation of normal and superconducting properties to the electronic density of states, and questions of the superconductivity of various ternary thorium compounds. Individual items are abstracted in this issue.

Douglass, D. H.↗
NASA NTRS1985

Theoretical research program to study transition metal trimers and embedded clusters

Small transition metal clusters at a high level of approximation i.e. including all the valence electrons in the calculation and also including extensive electron correlation were studied. Perhaps the most useful end result of these studies is the qualitative information about the electronic structure of these small metal clusters, including the nature of the bonding. The electronic structure studies of the small clusters are directly applicable to problems in catalysis. From comparison of dimers, trimers and possibly higher clusters, it is possible to extrapolate the information obtained to provide insights into the electronic structure of bulk transition metals and their interaction with other atoms and molecules at both surface and interior locations.

Walch, S. P.↗
NASA NTRS1995

The transition regions of Capella

We have used the Goddard High Resolution Spectrometer (GHRS) to observe the spectoscopic binary system Capella (G8 III + G1 III). Exposures with the G140L, G140M, G160M, G200M, and echelle gratings provide emission line profiles with unprecedented signal-to-noise and spectral resolving power (lambda/Delta-lambda) up to 92,000. Multi-Gaussin fits to the line profiles show that the hotter star contributes 60%-70% of the total flux in the chromospheric O I and Mg II resonance lines, but about 90% of the flux in the Si III, Si IV, and C IV lines formed in the transition region at T less than or = 10(exp 5) K. We find clear evidence that the emission lines from the hotter star are systemtically redshifted relative to the photosphere with Doppler shifts of 5 +/- 1 km/s for the +9 +/- 3 km/s in the chromospheric Mg II and O I lines, respectively, increasing to +24 +/- 5 km/s for the transition region Si IV 1393.8A line. The multi-Gaussian fits to permitted transition region lines of SI III, Si IV, C IV, and N V indicate the presence of three components: moderately broad lines formed in the transition region of the hotter star (component H), narrow lines formed in the transition region of the cooler star (component C), and very broad lines that we think are formed in microflares on the hotter star (component B). The He II 1640.4 A feature has an broad profile, which indicates that it is formed by collisional excitation primarily from the hotter star, and a weak narrow component that we interpret as due to radiative recombination on the cooler star. We observed spin-forbidden emission lines of C III), O III), Si III), O IV), O V), and S IV) that are sensitive to electron density. Fainter members of the O IV) multiplet and all of the S IV) lines have never before been seen in any star than the Sun. We determine electron densities in the transition regions of the Capella stars using lines ratios of O IV) lines and emission measure analysis. The emission measures are self-consistent only when the fluxes from each emitting component are considered separately. In particular, the transition region abundance distributions appear to be different on the two stars, and the spin-forbidden lines were not detected in the B component. The emission measures for component H (the G1 star) are consistent with a constant electron pressure (or hydrostatic equilibrium) transition region with P(sub e) = 10(exp 15 + 0.1)/cu cm K and possibly solar 'coronal' abundances.

Linsky, Jeffrey L.↗
NASA NTRS1985

Differential electron scattering cross sections for the 3 (2)S to 3 (2)P0 h, k transitions in Mg II - Comparison of experiment and theory

Angular differential electron scattering cross sections are reported for the unresolved inelastic 3s (2)S to 3p (2)P0 h, k transitions in Mg II for the first time. Relative differential cross sections have been measured at 35 eV and 50 eV in the angular range of Theta between 6 and 17 deg using the newly developed electron energy loss technique in a crossed electron-ion beam geometry. Theoretical values have been calculated in a five-state close-coupling approximation in which 3s, 3p, 3d, 4s, and 4p states were included, and to which measurements were normalized at Theta = 12 deg.

Williams, I. D.↗
NASA NTRS1983

Electron collisional rate coefficients for low-level transitions in hydrogen

There exists presently no general agreement concerning the collisional excitation rates of atomic hydrogen. The present investigation is concerned with the results reported by various investigators, taking into account the semiempirical rates of Johnson (1972), a study conducted by Aggarwal (1983), empirically based rates of Crandall et al. (1974), and the rates tabulated in Osterbrock (1974), based on the close-coupling calculations of Burke et al. (1967). It is found that there is a major conflict between the 'best' theoretical and Johnson values on the one hand, and the empirical data on the other. A study of the data shows that the Johnson value for the 1 to 2 rate agrees well with other theoretical calculations, and within 25 percent of empirical measurements, but that the Johnson 1 to 3 rate is 40-75 percent of the 'best' theoretical calculations.

Drake, S. A.↗
NASA NTRS1977

Characteristics of first order shock induced magnetic transitions in iron and discrimination from TRM

Reflected light microscopy provides information on first-order shock transitions in iron and iron-nickel and permits discrimination of microstructures due to shock transitions from those imparted by thermal transitions. In addition, thin-foil electron microscopy is used to characterize magnetic transitions in fine-particle iron. First-order magnetic phase changes, such as that from the antiferromagnetic face centered cubic state to the ferromagnetic body centered cubic state, are studied with the aim of calibrating the shock and thermal mechanisms of magnetization in iron with a particle size range between 250 and 1200 A. The efficiency of remanence due to shock transition is also estimated.

Wasilewski, P.↗
NASA NTRS1983

Theoretical studies of solar-pumped lasers

Metallic vapor lasers of Na2 and Li2 are examined as solar energy converters. The absorbed photons cause transitions to vibrational-rotational levels in an upper electronic state. With broad band absorption the resultant levels can have quantum numbers considerably higher than the upper lasing level. The excited molecule then relaxes to the upper lasing level which is one of the lower vibrational levels in the upper electronic state. The relaxation occurs from collisions, provided the molecule is not quenched into the ground level electronic state. Lasing occurs with a transition to a vibrational level in the lower electronic state. Rough estimates of solar power efficiencies are 1 percent for Na2 and probably a similar figure for Li2. The nondissociative lasers from a family distinct from materials which dissociate to yield an excited atom.

Harries, W. L.↗
NASA NTRS1993

Excitation cross sections for the ns 2S yields np 2P resonance transitions in Mg(+) (n = 3) and Zn(+) (n = 4) using electron-energy-loss and merged-beams methods

Electron-excitation cross sections are reported for the 3s 2S yields 3p 2P(h, k) resonance transition in Mg(+) at energies from threshold (4.43 eV) to approximately 9 times threshold (40.0 eV). The electron-energy-loss merged-beams technique used in these measurements is described in detail. In addition, the method of separating contributions of the elastically scattered (Coulomb) and the inelastically scattered electrons in the present Mg(+) case and previously reported Zn(+) results is described. Comparisons in the experimental energy range are made for Mg(+) with the two five-state close-coupling theoretical calculations carried out herein, and with other published close-coupling, distorted-wave, and semiempirical calculations. The present Mg(+) cross sections and Zn(+) cross sections from earlier measurements are tabulated.

Smith, Steven J.↗
NASA NTRS2009

Paper to Electronic Questionnaires: Effects on Structured Questionnaire Forms

With the use of computers, paper questionnaires are being replaced by electronic questionnaires. The formats of traditional paper questionnaires have been found to effect a subject's rating. Consequently, the transition from paper to electronic format can subtly change results. The research presented begins to determine how electronic questionnaire formats change subjective ratings. For formats where subjects used a flow chart to arrive at their rating, starting at the worst and middle ratings of the flow charts were the most accurate but subjects took slightly more time to arrive at their answers. Except for the electronic paper format, starting at the worst rating was the most preferred. The paper and electronic paper versions had the worst accuracy. Therefore, for flowchart type of questionnaires, flowcharts should start at the worst rating and work their way up to better ratings.

Trujillo, Anna C.↗
NASA NTRS1978

On dielectronic recombination and resonances in excitation cross sections

It is found that the contribution to the dielectronic recombination rate of stabilizing transitions of the outer electron is within the 30% accuracy of the Burgess rates calculated by neglecting this process even for Delta n = 0 transitions for astrophysically important ions. Autoionization to excited levels, ignored in the Burgess procedure and shown by Jacobs et al. (1977) to be important for some ions in the calculation of the dielectronic recombination rate, is discussed with reference to the resonance excitation of some astrophysically important X-ray lines. In particular, the contribution of resonances to the excitation of several lines in the helium and neon isosequences is estimated.

Raymond, J. C.↗
NASA NTRS1989

Theoretical study of metal noble-gas positive ions

Theoretical calculations have been performed to determine the spectroscopic constant for the ground and selected low-lying electronic states of the transition-metal noble-gas ions Var(+), FeAr(+), CoAr(+), CuHe(+), CuAr(+), and CuKr(+). Analogous calculations have been performed for the ground states of the alkali noble-gas ions LiAr(+), LiKr(+), NaAr(+), and KAr(+) and the alkaline-earth noble-gas ion MgAr(+) to contrast the difference in binding energies between the simple and transition-metal noble-gas ions. The binding energies increase with increasing polarizability of the noble-gas ions, as expected for a charge-induced dipole bonding mechanism. It is found that the spectroscopic constants of the X 1Sigma(+) states of the alkali noble-gas ions are well described at the self-consistent field level. In contrast, the binding energies of the transition-metal noble-gas ions are substantially increased by electron correlation.

Bauschlicher, Charles W., Jr.↗
NASA NTRS1983

Complex time dependent wave packet technique for thermal equilibrium systems - Electronic spectra

A time dependent wave packet method is presented for the rapid calculation of the properties of systems in thermal equilibrium and is applied, as an illustration, to electronic spectra. The thawed Gaussian approximation to quantum wave packet dynamics combined with evaluation of the density matrix operator by imaginary time propagation is shown to give exact electronic spectra for harmonic potentials and excellent results for both a Morse potential and for the band contours of the three transitions of the visible electronic absorption spectrum of the iodine molecule. The method, in principle, can be extended to many atoms (e.g., condensed phases) and to other properties (e.g., infrared and Raman spectra and thermodynamic variables).

Reimers, J. R.↗
NASA NTRS1975

Scattering of 4.5 eV electrons by ground /x 3 Sigma g minus/ state and metastable /a 1 Delta g/ oxygen molecules

The paper reports on differential and integral cross sections for scattering of 4.5 eV electrons by ground state (x 3 Sigma g minus) and metastable (a 1 Delta g) oxygen molecules in the -2.0 eV to plus 2.0 eV energy loss range. The cross section for the (a 1 Delta g to b 1 Sigma g plus) transition was found to be more than an order of magnitude larger than that of the excitation of the b state from the ground state. It was found that the principle of detailed balance can be applied to the rotationally unresolved inelastic and superelastic electronic transitions between the (x 3 Sigma g minus) and (a 1 Delta g) states, which indicates that for this transition one may neglect the very different rotational level structure of the two states in estimating superelastic cross section from inelastic data to an accuracy of about 15 per cent.

Hall, R. I.↗
NASA NTRS1994

The structural changes of water ice I during warmup

The polymorph transitions of vapor deposited water ice I during warmup from 15 K to 210 K was mapped by means of selected area electron diffraction. The polymorph transitions account for many phenomena observed in laboratory analog studies of cometary outgassing and radial diffusion in UV photolyzed interstellar ices.

Jenniskens, Peter↗