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At least 379 records · Page 21

Absolute rate of the reaction of O/3-P/ with hydrogen sulfide over the temperature range 263 to 495 K

The technique of flash photolysis coupled with time resolved detection of O via resonance fluorescence has been used to obtain rate constants for the reaction of O(3-P) with H2S at temperatures from 263 to 495 K and at pressures in the range 10-400 torr. Under conditions where secondary reactions are avoided, the measured rate constants for the primary step obey the Arrhenius equation k = (7.24 plus or minus 1.07) x 10 to the -12th exp(-3300 plus or minus 100/1.987 T) cu cm/molecules/s. Experiments with D2S show that the reaction exhibits a primary isotope effect, in support of a hydrogen abstraction mechanism.

Whytock, D. A.↗

XMM-Newton Observations of Four Millisecond Pulsars

I present an analysis of the XMM-Newton observations of four millisecond pulsars, J0437-4715, J2124-3358, J1024-0719, and J0034-0534. The new data provide strong evidence of thermal emission in the X-ray flux detected from the first three objects. This thermal component is best interpreted as radiation from pulsar polar caps covered with a nonmagnetic hydrogen atmosphere. A nonthermal power-law component, dominating at energies E greater than or equal to 3 keV, can also be present in the detected X-ray emission. For PSR J0437-4715, the timing analysis reveals that the shape and pulsed fraction of the pulsar light curves are energy dependent. This, together with the results obtained from the phase-resolved spectroscopy, supports the two-component (thermal plus nonthermal) interpretation of the pulsar's X-ray radiation. Highly significant pulsations have been found in the X-ray flux of PSRs 52124-3358 and 51024-0719. For PSR 50034-0534, a possible X-ray counterpart of the radio pulsar has been suggested. The inferred properties of the detected thermal emission are compared with predictions of radio pulsar models.

Zavlin, Vyacheslav E.↗

ASASSN-15LH: A Superluminous Ultraviolet Rebrightening Observed by Swift and Hubble

We present and discuss ultraviolet and optical photometry from the Ultraviolet/Optical Telescope, X-ray limits from the X-Ray Telescope on Swift, and imaging polarimetry and ultraviolet/optical spectroscopy with the Hubble Space Telescope, all from observations of ASASSN-15lh. It has been classified as a hydrogen-poor superluminous supernova (SLSN I), making it more luminous than any other supernova observed. ASASSN-15lh is not detected in the X-rays in individual or co-added observations. From the polarimetry we determine that the explosion was only mildly asymmetric. We find the flux of ASASSN-15lh to increase strongly into the ultraviolet, with an ultraviolet luminosity 100 times greater than the hydrogen-rich, ultraviolet-bright SLSN II SN2008es. We find that objects as bright as ASASSN-15lh are easily detectable beyond redshifts of ∼4 with the single-visit depths planned for the Large Synoptic Survey Telescope. Deep near-infrared surveys could detect such objects past a redshift of ∼20, enabling a probe of the earliest star formation. A late rebrightening-most prominent at shorter wavelengths -is seen about two months after the peak brightness, which is itself as bright as an SLSN. The ultraviolet spectra during the rebrightening are dominated by the continuum without the broad absorption or emission lines seen in SLSNe or tidal disruption events (TDEs) and the early optical spectra of ASASSN-15lh. Our spectra show no strong hydrogen emission, showing only Lyα absorption near the redshift previously found by optical absorption lines of the presumed host. The properties of ASASSN-15lh are extreme when compared to either SLSNe or TDEs.

Brown, Peter J.↗

Technology Development for Hydrogen Propellant Storage and Transfer at the Kennedy Space Center (KSC)

The National Aeronautics and Space Administration (NASA) is a major user of liquid hydrogen. In particular, NASA's John F. Kennedy (KSC) Space Center has operated facilities for handling and storing very large quantities of liquid hydrogen (LH2) since the early 1960s. Safe operations pose unique challenges and as a result NASA has invested in technology development to improve operational efficiency and safety. This paper reviews recent innovations including methods of leak and fire detection and aspects of large storage tank health and integrity. We also discuss the use of liquid hydrogen in space and issues we are addressing to ensure safe and efficient operations should hydrogen be used as a propellant derived from in-situ volatiles.

cryogenics↗

Momentum transfer interaction of a laser-produced plasma with a low-pressure background.

The expansion of a laser-produced metallic plasma into a photoionized hydrogen background has been experimentally studied. Langmuir probe and microwave diagnostics have detected an interaction front which decelerates with a dependence on background density and time consistent with a momentum coupling between the laser plasma and the ionized fraction of the background. An ion percursor has also been observed. Calculations of scattering cross sections indicate that multiple-encounter Coulomb scattering will dominate collisional momentum transfer. The leading edge of the laser plasma contains multiply charged ions of charge state z greater than or equal to 5, and collisional effects appear adequate to explain the principal features of the momentum coupling. The ion precursor may have a collisionless origin.

Koopman, D. W.↗

Distribution of energetic positive ion species above a diffuse midnight aurora

The present paper deals with species-identifying distribution function measurements of auroral primary particles, made during a magnetically quiet presubstorm period above a hydrogen-associated diffuse aurora. Only ions identified as H(+) and He(++) were detected. In the mass spectrum data, the He(++) was not clearly above background. At energies between 2.5 and 12 keV, the He(++)/H(+) intensity ratio had an upper limit of 2 to 4 percent. The same upper limit applies to all other ions, such as He(+) and O(+). Though this would suggest a solar wind source for these ions, an admixture including an appreciable fraction of polar wind protons is not precluded. This situation contrasts sharply with a number of recently reported observations of large intensities of precipitating O(+) ions during magnetic storms, and may be characteristic of undisturbed periods.

Moore, T. E.↗

Observations of the high latitude far ultraviolet background in the 1040-1080 A band

Observations of the far ultraviolet background at high galactic latitudes in a band from 1040-1080 A were carried out with a rocket-borne 1 meter telescope and a 0.23 square degree field of view photometer. The photometer had a sharp cutoff shortward of 1040 A and a sensitivity at hydrogen Lyman alpha of a factor of 0.0001 below its sensitivity at 1060 A. A second photometer monitored geocoronal hydrogen Lyman alpha emission enabling an accurate evaluation of counts due to this background. The hydrogen Lyman alpha flux contributed only 17 percent of the total counts detected in the cosmic background detector. An upper limit to the emission in the 1040-1080 A band of 9700 photons per sq cm-s-sr-A is obtained. This upper limit is compared with previous measurements and theoretical predictions.

Bixler, J.↗

Observations of several new transitions of interstellar HCO

Four new transitions of the interstellar formyl radical, HCO have been detected. Five transitions are now known for interstellar HCO, and thus its identification is secure. The column density found by assuming NGC 2024 is an extended source is N subT(HCO) = (8.5 + or - 4.0) x 10 to the 12th/sq cm. This gives a fractional abundance (abundance relative to hydrogen) for NGC 2024 which agrees quite well with some theoretical predictions. Several unidentified lines were detected and are reported here. Tentative identification for some of the unidentified lines are suggested.

Snyder, L. E.↗

The microwave and far-infrared spectra of the O-(18)H radical

Far-infrared laser magnetic resonance (LMR) spectroscopy was used to calculate the frequencies, wavelengths, and line strengths for transitions of O-(18)H molecules at microwave and far-infrared frequencies. In this experiment, a molecular transition frequency is tuned into coincidence with that of a fixed frequency laser by the application of a variable magnetic field. The O-(18)H radicals, detected in natural abundance (0.20 percent), were produced by the reaction of hydrogen atoms with nitrogen dioxide. These data together with microwave frequencies ascertained by Gottlieb, Redford, and Smith (1974) were used to determine the parameters of an effective Hamiltonian. Rotational levels up to J = 5.5 were involved. Results are indicated schematically and the low-lying energy levels of O-(18)H are shown. It is concluded that the frequencies of transitions between levels studied directly in the LMR experiment are reliable.

Comben, E. R.↗

Forecasting the arrival of fast coronal mass ejecta at Earth by the detection of 2-20 keV neutral atoms

Studies have shown that Earth passages of fast coronal mass ejections (CMEs) trigger geomagnetic storms. Early identification of fast earth-directed CME can help provide storm warnings, but detection of such by coronagraphs is extremely difficult. We suggest that energetic hydrogen atoms (EHA) between 2 and 10 keV produced during the transit phase of an Earth-directed CME by recombination between protons and electrons in the CME can travel ahead of the CME and act as harbingers of a magnetic storm. This forecasting scheme should work if enough EHA are produced, because while CMEs decelerate continuously after their ejection, the EHA fluxes produced in the initial phase of fast CMEs propagate at their initial high speeds. Model simulations support this proposed mechanism.

Hsieh, K. C.↗

Ground-Based Investigations with the Cryogenic Hydrogen Maser

The cryogenic hydrogen maser (CHM) developed at the Smithsonian Astrophysical Observatory (SAO) was designed to be functionally similar to SAO room temperature hydrogen masers with appropriate modifications made for operation at cryogenic temperatures. A schematic of the SAO CHM is shown in Figure 1, and a description of this device and its operation follows. A beam of molecular hydrogen is dissociated into atoms at room temperature. The resultant beam of atomic hydrogen is then cooled, magnetically state selected, and focused into a quartz storage bulb centered inside of a microwave cavity resonant with the hydrogen hyperfine transition at 1420 MHz. The quartz storage bulb is coated with a superfluid He-4 film, and both the bulb and cavity are maintained near 0.5 K. The maser signal is coupled out inductively and carried to room temperature via semi-rigid coaxial cable. After passing through a room temperature isolator and preamp, the maser signal is detected with a low-noise heterodyne receiver as used in the room temperature SAO hydrogen masers. The maser temperature is lowered to 0.5 K using a recirculating He-3 refrigerator. This refrigerator consists of several cooling stages: a liquid nitrogen stage at 77 K, a liquid 4He bath at 4.2 K, a pumped He-4 pot at approximately 1.7 K, and the pumped, recirculating He-3 stage at 0.5 K. The atomic hydrogen beam, state selector, storage bulb and cavity are all connected inside a single, maser vacuum chamber (MVC). This space is pumped out from below by a turbo pump. Above the MVC, an inlet to the space allows for the input of flowing superfluid 4He film. External to the MVC is a second, outer vacuum chamber (OVC), maintained for operation of the cryostat and also pumped by a turbo pump. Inside the OVC, there is radiation shielding at 77 K and 1.7 K.

Walsworth, Ronald L.↗

Electrochemically Grown Single Nanowire Sensors

We report a fabrication technique that is potentially capable of producing arrays of individually addressable nanowire sensors with controlled dimensions, positions, alignments, and chemical compositions. The concept has been demonstrated with electrodeposition of palladium wires with 75 nm to 350 nm widths. We have also fabricated single and double conducting polymer nanowires (polyaniline and polypyrrole) with 100nm and 200nm widths using electrochemical direct growth. Using single Pd nanowires, we have also demonstrated hydrogen sensing. It is envisioned that these are the first steps towards nanowire sensor arrays capable of simultaneously detecting multiple chemical species.

conducting polymer nanowires↗

ROSAT HRI observations of hot stars in the Orion Nebula

ROSAT High Resolution Interferometer (HRI) observations of hot (O6-A5) stars in the Orion Nebula region are presented. Fourteen of 21 O6-B5 stars were detected and all of them appear to have X-ray luminosities and L(sub x)/L(sub bol) ratios similar to field O6-B5 stars. The brightest star in the Trapezium, the O7 V star theta(sup 1) C Ori, has notable variation in its X-ray emission; the variation seems to have the same phase dependence as recently found for the star's hydrogen alpha emission. A maximum of six of 27 B6-A5 stars observed were detected; we argue that the most likely explanation for their X-ray emission is that it arises from unseen, low-mass binary companions.

Caillault, Jean-Pierre↗

Lipid Decontamination Procedures for Life Detection Missions

Molecular biosignatures are key targets for current, proposed, and future life detection missions. With the high accuracy and low limit of detection (LOD) that new and future instruments will require, decontamination of life detection hardware is necessary to prevent false positives. Lipids are a molecular biosignature of interest, as they are ubiquitous to all life as we know it, can survive unaltered in the geologic record for longer than any other biomolecule (i.e. billions of years), and form through both biotic and abiotic processes. Lipids display origin-diagnostic molecular patterns that can reveal biotic or abiotic synthesis, so finding them and ascertaining their molecular features is important for potentially detecting evidence of life elsewhere. Traditional methods of decontamination, or contamination control (CC), primarily clean hardware through fabrication in sterile (cleanroom) environments, killing microbes, and removing/flushing contaminants off instrument and spacecraft components. However, research suggests that some standard cleaning methods are either unlikely to remove lipid contaminants or are incompatible with life detection instrument materials. To solve this problem, I propose to find, test, and verify a decontamination method that thoroughly cleans instruments by destroying lipid molecules, but is simultaneously compatible with major materials used in these instruments. I will study the effects of traditional CC methods (including Dry Heat Microbial Reduction and Vapor phase Hydrogen Peroxide) and experimental CC methods (Electron Beam Irradiation) on lipid molecules for application to life detection instrumentation. I will then develop a CC plan for a novel lipid detector (ExCALiBR, Extractor for Chemical Analysis of Lipid Biomarkers in Regolith) searching for lipids in either soil or icy world scenarios. This plan will uphold planetary protection regulation requirements and validate experimental analyses of in-situ life detection tests.

Decontamination↗

Sample Delivery and Computer Control Systems for Detecting Leaks in the Main Engines of the Space Shuttle

The main engines of the Space Shuttle use hydrogen and oxygen as the fuel and oxidant. The explosive and fire hazards associated with these two components pose a serious danger to personnel and equipment. Therefore prior to use the main engines undergo extensive leak tests. Instead of using hazardous gases there tests utilize helium as the tracer element. This results in a need to monitor helium in the ppm level continuously for hours. The major challenge in developing such a low level gas monitor is the sample delivery system. This paper discuss a system developed to meet the requirements while also being mobile. Also shown is the calibration technique, stability, and accuracy results for the system.

Griffin, Timothy P.↗

Aerogel-Positronium Technology for the Detection of Small Quantities of Organic and/or Toxic Materials

The Ps-aerogel system [Ps is positronium (an electron-positron-hydrogen-like atom)] has been evaluated and optimized as a potential tool for planetary exploration missions. Different configurations of use were assessed, and the results provide a quantitative measure of the expected performance. The aerogel density is first optimized to attain maximum production of Ps that reaches the pores of the aerogel. This has been accomplished, and the optimum aerogel density is .70 mg/cm3. The aerogel is used as a concentrator for target volatile moieties, which accumulate in its open porosity over an extended period of time. For the detection of the accumulated materials, the use of Ps as a probe for the environment at the pore surface, has been proposed. This concept is based on two steps: (1) using aerogel to produce Ps and (2) using the propensity of Ps to interact differently with organic and inorganic matter. The active area of such a detector will comprise aerogel with a certain density, specific surface area, and gas permeability optimized for Ps production and gas diffusion and adsorption. The aerogel is a natural adsorber of organic molecules, which adhere to its internal surface, where their presence is detected by the Ps probe. Initial estimates indicate that, e.g., trace organic molecules in the Martian atmosphere, can be detected at the ppm level, which rivals current methods having significantly higher complexity, volume, mass, and power consumption (e.g. Raman, IR).

Petkov, Mihail P.↗

Minimum-flux coronal models for hydrogen and helium white dwarf atmospheres

Families of zero-mass-loss coronal models based on the minimum-flux prescription of Hearn (1975), in which bound-bound, bound-free, and free-free radiative processes with their differing emissivity vs. temperature laws are included, have been computed. These models are applied to the case of white-dwarf envelopes of pure hydrogen or helium, and the results are expressed as relationships between the required total energy flux, the coronal base pressure, and its temperature. The soft X-ray detection of Sirius by the ANS group is discussed. If all the X-ray flux is ascribed to a minimum-flux hydrogen corona surrounding the white dwarf Sirius B, it must have a temperature of 1.6 + or -0.3 million K and a base pressure of 110,000 + or - 40,000 dyne/sq cm. The surface energy flux needed to heat such a corona is (9 + or - 5) x 10 to the 10th erg/sq cm per sec.

Lampton, M.↗

Hydrogen production rates from ground-based Fabry-Perot observations of comet Kohoutek

The only ground-based observations of a cometary hydrogen corona that have been obtained up to the present were carried out during the appearance of comet Kohoutek (1973 XII). Hydrogen Balmer alpha (H-alpha) emission from the gas cloud surrounding the comet was detected using a Fabry-Perot spectrometer at Kitt Peak National Observatory. These observations have been reexamined using (1) recently obtained solar full-disk Lyman beta emission line profiles, (2) a new calibration of the absolute sensitivity of the Fabry-Perot spectrometer based on comparison of NGC 7000 with standard stars and the planetary nebula NGC 7662, and (3) corrections for atmospheric extinction instead of the geocoronal H-alpha comparison method used previously to obtain comet H-alpha intensities. The new values for hydrogen production rates are in good agreement with results obtained from Lyman alpha observations of comet Kohoutek.

Scherb, F.↗