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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS2002

Effects of proton irradiation on luminescence and carrier dynamics of self-assembled III-V quatum dots

The effects of proton irradiation (1.5 MeV) on photoluminescence intensities and carrier dynamics were compared between III-V quantum dots and similar quantum well structures. A significant enhancement in radiation tolerance is seen with three-dimensional quantum confinement. Measurements were carried out in different quantum dot (QD) structures, varying in material (InGaAs/GaAs and InAlAs/AlGaAs), QD surface density (4x10^8 to 3x10'^10 cm^-2), and substrate orientation [(100) and (311) B]. Similar trends were observed for all QD samples. A slight increase in PL emission after low to intermediate proton doses, are also observed in InGaAs/GaAs (100) QD structures. The latter is explained in terms of more efficient carrier transfer from the wetting layer via radiation-induced defects.

nanotechnology DLTS optical properties pn diodes q↗
DOE OSTI2020

A Study of a Monitoring Program for Intermediate Depth Disposal of Low- Level Radioactive Waste - 20167

This study investigated a monitoring program for intermediate depth disposal of low-level radioactive waste. At first, it extracted monitoring targets, such as the status of cracks in the low diffusion layer after closure of the facility. Secondly, it focused on distributed optical fiber sensors which can minimize the amount of cable, and measurement positions and methods were specifically determined to propose the monitoring method. Finally, conformity to regulatory requirements was verified to clarify key points and issues to be addressed in performing monitoring. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Topological response of the anomalous Hall effect in MnBi 2 Te 4 due to magnetic canting

Three-dimensional (3D) compensated MnBi 2 Te 4 is antiferromagnetic, but undergoes a spin-flop transition at intermediate fields, resulting in a canted phase before saturation. In this work, we experimentally show that the anomalous Hall effect (AHE) in MnBi 2 Te 4 originates from a topological response that is sensitive to the perpendicular magnetic moment and to its canting angle. Synthesis by molecular beam epitaxy allows us to obtain a large-area quasi-3D 24-layer MnBi 2 Te 4 with near-perfect compensation that hosts the phase diagram observed in bulk which we utilize to probe the AHE. This AHE is seen to exhibit an antiferromagnetic response at low magnetic fields, and a clear evolution at intermediate fields through surface and bulk spin-flop transitions into saturation. Throughout this evolution, the AHE is super-linear versus magnetization rather than the expected linear relationship. We reveal that this discrepancy is related to the canting angle, consistent with the symmetry of the crystal. Our findings bring to light a topological anomalous Hall response that can be found in non-collinear ferromagnetic, and antiferromagnetic phases.

36 MATERIALS SCIENCE↗
NASA NTRS2002

Functional recovery of anterior semicircular canal afferents following hair cell regeneration in birds

Streptomycin sulfate (1.2 g/kg i.m.) was administered for 5 consecutive days to 5-7-day-old white Leghorn chicks; this causes damage to semicircular canal hair cells that ultimately regenerate to reform the sensory epithelium. During the recovery period, electrophysiological recordings were taken sequentially from anterior semicircular canal primary afferents using an indentation stimulus of the canal that has been shown to mimic rotational stimulation. Chicks were assigned to an early (14-18 days; n = 8), intermediate (28-34 days; n = 5), and late (38-58 days; n = 4) period based on days after treatment. Seven untreated chicks, 15-67 days old, provided control data. An absence of background and indent-induced discharge was the prominent feature of afferents in the early period: only "silent" afferents were encountered in 5/8 experiments. In several of these chicks, fascicles of afferent fibers were seen extending up to the epithelium that was void of hair cells, and intra- and extracellular biocytin labeling revealed afferent processes penetrating into the supporting cell layer of the crista. In 3/8 chicks 74 afferents could be characterized, and they significantly differed from controls (n = 130) by having a lower discharge rate and a negligible response to canal stimulation. In the intermediate period there was considerable variability in discharge properties of 121 afferents, but as a whole the number of "silent" fibers in the canal nerve diminished, the background rate increased, and a response to canal stimulation detected. Individually biocytin-labeled afferents had normal-appearing terminal specializations in the sensory epithelium by 28 days poststreptomycin. In the late period, afferents (n = 58) remained significantly different from controls in background discharge properties and response gain. The evidence suggests that a considerable amount of variability exists between chicks in the return of vestibular afferent function following ototoxic injury and that the secretory function of regenerating hair cells might become functional before their transducer function.

NASA Discipline Neuroscience↗
NASA NTRS1996

Mullite fiber reinforced reaction bonded Si3N4 composites

Fracture toughnesses of brittle ceramic materials have been improved by introducing reinforcements and carefully tailored interface layers. Silicon carbide and Si3N4 have been emphasized as matrices of structural composites intended for high temperature service because they combine excellent mechanical, chemical, thermal and physical properties. Both matrices have been successfully toughened with SiC fibers, whiskers and particles for ceramic matrix composite (CMC) parts made by sintering, hot pressing or reaction forming processes. These SiC reinforced CMCs have exhibited significantly improved toughnesses at low and intermediate temperature levels, as well as retention of properties at high temperatures for selected exposures; however, they are vulnerable to attack from elevated temperature dry and wet oxidizing atmospheres after the matrix has cracked. Property degradation results from oxidation of interface layers and/or reinforcements. The problem is particularly acute for small diameter (-20 tim) polymer derived SiC fibers used for weavable toes. This research explored opportunities for reinforcing Si3N4 matrices with fibers having improved environmental stability; the findings should also be applicable to SiC matrix CMCs.

Saleh, T.↗
DOE OSTI2021

Layer spacing gradient (NaLi) 1–x CoO 2 for electrochemical Li extraction

Designing materials with high Li to Na selectivity is the key for direct extraction of Li from unconventional sources, such as seawater, without complex separations. However, material discovery is hindered by an insufficient understanding on how a material's composition and structure relate to Li selectivity during electrochemical co-intercalation. Here, we synthesized a core-shell structured (NaLi) 1-x CoO 2 with a core Li phase (Li 0.94 CoO 2 ), a shell Na phase (Na 0.51 CoO 2 ), and a transition intermediate phase via Na ion-exchange of parent Li 1-x CoO 2 . We reveal that the chemical compositions and spatial relation of these phases play critical roles in governing high Li to Na selectivity. The core Li phase restricts large layer spacing expansion and inhibits Na intercalation. The shell Na phase serves to maintain the electrode stability against further Na ion exchange. With the layer spacing gradient design, we achieved a high Li selectivity of 1.5 x 10 5 with a recovery of similar to 7.6:1 Li to Na from 1:20,000 initial ratio.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Scalable Synthesis of 2D Mo 2 C and Thickness‐Dependent Hydrogen Evolution on Its Basal Plane and Edges

Abstract 2D transition metal carbides (2D TMCs and MXenes) are promising candidates for applications of energy storage and catalysis. However, producing high‐quality, large 2D flakes of Mo2C MXene has been challenging. Here, a new salt‐assisted templating approach is reported that enables the direct synthesis of 2D Mo 2 C with low defect concentrations. KCl acts as a template to form an intermediate 2D product, facilitating Mo 2 C formation without coarsening upon melting. The thickness of the flakes produced can range from monolayer (0.36 nm) to 10 layers (4.55 nm), and the electrocatalytical hydrogen evolution reaction (HER) activity of 2D Mo 2 C is inversely proportional to its thickness. The monolayer Mo 2 C shows remarkable HER performance with a current density of ≈6800 mA cm − 2 at 470 mV versus reversible hydrogen electrode and an ultrahigh turnover frequency of ≈17 500 s − 1 . This salt‐assisted synthesis approach can also produce WC and V 8 C 7 nanosheets, expanding the family of 2D carbides. The new pathway eliminates the need for layered ceramic precursors, making it a versatile approach to direct synthesis of MXene‐like 2D carbides.

Chemistry↗
DOE OSTI2025

Visualizing Size-Dependent Dynamics of CeO 2-δ {100}-Supported CoO x Nanoparticles Under CO 2 Hydrogenation Conditions

Carbon dioxide is a major greenhouse gas. In order to optimize processes focused on its chemical valorization, one needs detailed information about the effects of CO 2 and/or CO 2 /H 2 mixtures on the structure and morphology of metal/oxide catalysts. Here, in this study, the evolution of a catalyst with cobalt supported on CeO 2 -cube nanostructures under CO 2 hydrogenation conditions was investigated by using a set of in situ characterization techniques (X-ray absorption fine structure, X-ray diffraction, diffuse reflectance infrared Fourier transform spectroscopy, and environmental transmission electron microscopy (TEM)). The {100} facets of the ceria support displayed an unexpectedly high stability due to strong interactions with the aggregates of cobalt oxide. A significant influence of interfacial bonding between CoO x and CeO 2-δ {100} is evident through a clear preference in the orientation of CoO x nanoparticles (NPs) with respect to the substrate. For initially reduced Co/CeO 2 -cube nanostructures, a kinetically controlled oxidation of cobalt upon the introduction of CO 2 was observed during the early stages of CO 2 hydrogenation. Environmental TEM revealed the size-dependent morphological behavior of cobalt oxide NPs due to strong interactions with the CeO 2 {100} surface. When the environment was switched from H 2 to a mixture of H 2 and CO 2 at 250 °C, small CoO x NPs (in the largest dimension < 2.5 nm) rapidly transformed from a pyramidal three-dimensional (3D) form to a planar, monatomic layer attached to the concurrently oxidized CeO 2-δ {100} surface. This maximizes the number of sites available for the binding of CO 2 or reaction intermediates. The shape transformation reflected the oxophilic character of cobalt and strong metal–support interactions. The removal of CO 2 from the gas phase led to a reduction of the cobalt oxide NPs by hydrogen and a reversible two-dimensional → 3D transformation. In contrast, no significant morphological changes, apart from further oxidation, were observed for big CoO x NPs (in the largest dimension > 3 nm). These trends are not seen for nanoparticles of noble metals. The observed morphological and structural changes in the small CoO x NPs affected the stability of reaction intermediates and modified the selectivity of the CoO x /CeO 2 catalyst system for methane production.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Identification of a quasi-liquid phase at solid–liquid interface

Abstract An understanding of solid–liquid interfaces is of great importance for fundamental research as well as industrial applications. However, it has been very challenging to directly image solid–liquid interfaces with high resolution, thus their structure and properties are often unknown. Here, we report a quasi-liquid phase between metal (In, Sn) nanoparticle surfaces and an aqueous solution observed using liquid cell transmission electron microscopy. Our real-time high-resolution imaging reveals a thin layer of liquid-like materials at the interfaces with the frequent appearance of small In nanoclusters. Such a quasi-liquid phase serves as an intermediate for the mass transport from the metal nanoparticle to the liquid. Density functional theory-molecular dynamics simulations demonstrate that the positive charges of In ions greatly contribute to the stabilization of the quasi-liquid phase on the metal surface.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1990

The periodicities in the infrared excess of G29-38 - An oscillating brown dwarf?

The oscillatory behavior of brown dwarfs has been investigated. The observed periodicities in the infrared excess of the white dwarf Giclas 29-38 are consistent with low-degree, intermediate radial order p-mode oscillations of a brown dwarf companion to the white dwarf. These oscillation modes have the correct frequencies, act on observable layers of the atmosphere, and may be excited to sufficient amplitudes to explain the observations.

Marley, Mark S.↗
NASA NTRS1993

Boundary-layer receptivity due to distributed surface imperfections of a deterministic or random nature

Acoustic receptivity of a Blasius boundary layer in the presence of distributed, 2D surface irregularities is investigated analytically. It is shown that, out of the entire spatial spectrum of the surface irregularities, only a narrow band of Fourier components can lead to an efficient conversion of the acoustic input at any given frequency to an unstable eigenmode of the boundary-layer flow. Random irregularities which are spatially homogeneous in nature, and also possess a continuous spectrum in the streamwise direction, lead to instability amplitudes that are intermediate to those caused by the periodic and isolated irregularities, respectively, being, in fact, of the same order as the geometrical mean of the amplitudes in the latter two cases. A physical explanation for these asymptotic scalings is given, in addition to providing an analytical expression for the expected value of the instability amplitude for an ensemble of statistically irregular surfaces with random phase distributions.

Choudhari, Meelan↗
NASA NTRS2005

A GCM Recent History of Northern Martian Polar Layered Deposits: Contribution from Past Equatorial Ice Reservoirs

Polar layered deposits are exposed in the walls of the troughs cutting the north polar cap of Mars. They consist of alternating ice and dust layers or layers of an ice-dust mixture with varying proportions and are found throughout the cap. Layers thickness ranges from meters to several tens of meters with an approximately 30 meter dominant wavelength. Although their formation processes is not known, they are presumed to reflect changes in ice and dust stability over orbital and axial variations. Intensive 3-D LMD GCM simulations of the martian water cycle have been thus performed to determine the annual rates of exchange of surface ice between the northern cap and tropical areas for a wide range of obliquity and orbital parameters values.These rates have been employed to reconstruct an history of the northern cap and test simple models of dust-ice layers formation over the last 10 Ma orbital variations. We use the 3-D water cycle model simulated by the 3-D LMD GCM with an intermediate grid resolution (7.5 longitude x 5.625 latitude) and 25 vertical levels. The dust opacity is constant and set to 0,15. No exchange of ice with regolith is allowed. The evolution of the northern cap over obliquity and orbital changes (eccentricity, Longitude of perihelion) has been recently described with this model. High summer insolation favors transfer of ice from the northern pole to the Tharsis and Olympus Montes, while at low obliquity, unstable equatorial ice is redeposited in high-latitude and polar areas of both hemisphere. The disappearance of the equatorial ice reservoir leads to a poleward recession of icy high latitude reservoirs, providing an additional source for the cap accumulation during each obliquity or orbital cycle. Furthering the efforts, a quantitative evolution of ice reservoirs is here investigated for various astronomical conditions.

Levrard, B.↗
DOE OSTI2024

Method of making thin films of sodium fluorides and their derivatives by ALD

A method of making thin films of sodium fluorides and their derivatives by atomic layer deposition (“ALD”). A sodium precursor is exposed to a substrate in an ALD reactor. The sodium precursor is purged, leaving the substrate with a sodium intermediate bound thereon. A fluorine precursor is exposed to the bound sodium intermediate in the ALD reactor. The fluorine precursor is purged and a sodium fluoride film is formed on the substrate.

Mane, Anil U.↗
DOE OSTI2024

Intrinsically sodiophilic, mesoporous metal-free wetting layers based on inexpensive carbon black for sodium-metal batteries

In this article, elevated temperature molten Na batteries are seeing a resurgence of interest for low-cost electrochemical energy storage for the grid. Of the many recent innovations in this battery concept, new methods focused on intermediate temperature operation (e.g. 110–190 °C) have gained prominence as a way to enable comparable performance with less thermal energy loss and lower-cost materials of construction. However, the poor wettability of molten Na on suitable solid-electrolyte separators such as sodium Beta Alumina Solid-Electrolyte (Na-β”-Al 2 O 3 , ‘BASE’) requires continued innovation in interface engineering to promote full utilization of the solid-electrolyte surface area and minimize cell resistance. There have been many successful approaches to improve Na-wettability to-date including heat treatment in an inert atmosphere to remove adsorbed surface species, deposition of alloying metals such as Pb, Sn, or Bi, and use of carbon-based interfacial layers. However, these approaches either lack the ability to provide good wetting at very low temperatures (near the melting point of Na) or rely on non-scalable processes and/or toxic/expensive metals. To solve these issues, a new carbon-based sodiophilic treatment is demonstrated, which utilizes inexpensive components to form a meso/macroporous sodiophilic layer, is easily applied via drop-casting or spray-coating, provides excellent wetting as low as 110 °C, and is completely metal-free. It is found that the good sodium wetting can be attributed to the wider range of pore sizes in the carbon layers demonstrated in this study. Na wetting may occur as surface tension is initially broken by larger pores, followed by the intrusion of molten Na into smaller pores due to the apparent intrinsic affinity of Na-metal for carbon surfaces, in conjunction with the capillarity effect. Low cell-level area specific resistances of 20–30 and 13–15 Ω·cm 2 are demonstrated at 110 and 140 °C respectively. Finally, the utility of this metal-free wetting layer for solid-Na anodes is explored, showing that the metal-free wetting layer can reach a critical current density of 1.88 mA·cm -2 at 30 °C.

25 ENERGY STORAGE↗
NASA NTRS1995

The mosaic structure of plasma bulk flows in the Earth's magnetotail

Moments of plasma distributions observed in the magnetotail vary with different time scales. In this paper we attempt to explain the observed variability on intermediate timescales of approximately 10-20 min that result from the simultaneous energization and spatial structuring of solar wind plasma in the distant magnetotail. These processes stimulate the formation of a system of spatially disjointed. highly accelerated filaments (beamlets) in the tail. We use the results from large-scale kinetic modeling of magnetotail formation from a plasma mantle source to calculate moments of ion distribution functions throughout the tail. Statistical restrictions related to the limited number of particles in our system naturally reduce the spatial resolution of our results, but we show that our model is valid on intermediate spatial scales Delta(x) x Delta(z) equal to approximately 1 R(sub E) x 1000 km. For these spatial scales the resulting pattern, which resembles a mosaic, appears to be quite variable. The complexity of the pattern is related to the spatial interference between beamlets accelerated at various locations within the distant tail which mirror in the strong near-Earth magnetic field. Global motion of the magnetotail results in the displacement of spacecraft with respect to this mosaic pattern and can produce variations in all of the moments (especially the x-component of the bulk velocity) on intermediate timescales. The results obtained enable us to view the magnetotail plasma as consisting of two different populations: a tailward-Earthward system of highly accelerated beamlets interfering with each other, and an energized quasithermal population which gradually builds as the Earth is approached. In the near-Earth tail, these populations merge into a hot quasi-isotropic ion population typical of the near-Earth plasma sheet. The transformation of plasma sheet boundary layer (PSBL) beam energy into central plasma sheet (CPS) quasi-thermal energy occurs in the absence of collisions or noise. This paper also clarifies the relationship between the global scale where an MHD description might be appropriate and the lower intermediate scales where MHD fails and large-scale kinetic theory should be used.

Ashour-Abdalla, M.↗
NASA NTRS1993

Asymptotic theory of intermediate- and high-degree solar acoustic oscillations

A second-order asymptotic approximation is developed for adiabatic nonradial p-modes of a spherically symmetric star. The exact solutions of adiabatic oscillations are assumed in the outermost layers, where the asymptotic description becomes invalid, which results in a eigenfrequency equation with model-dependent surface phase shift. For lower degree modes, the phase shift is a function of frequency alone; for high-degree modes, its dependence on the degree is explicitly taken into account.

Brodsky, M.↗
DOE OSTI2024

Tailoring Interfaces for Enhanced Methanol Production from Photoelectrochemical CO 2 Reduction

Efficient and stable photoelectrochemical reduction of CO 2 into highly reduced liquid fuels remains a formidable challenge, which requires an innovative semiconductor/catalyst interface to tackle. In this study, we introduce a strategy involving the fabrication of a silicon micropillar array structure coated with a superhydrophobic fluorinated carbon layer for the photoelectrochemical conversion of CO 2 into methanol. The pillars increase the electrode surface area, improve catalyst loading and adhesion without compromising light absorption, and help confine gaseous intermediates near the catalyst surface. The superhydrophobic coating passivates parasitic side reactions and further enhances local accumulation of reaction intermediates. Upon one-electron reduction of the molecular catalyst, the semiconductor–catalyst interface changes from adaptive to buried junctions, providing a sufficient thermodynamic driving force for CO 2 reduction. These structures together create a unique microenvironment for effective reduction of CO 2 to methanol, leading to a remarkable Faradaic efficiency reaching 20% together with a partial current density of 3.4 mA cm –2 , surpassing the previous record based on planar silicon photoelectrodes by a notable factor of 17. Furthermore, this work demonstrates a new pathway for enhancing photoelectrocatalytic CO 2 reduction through meticulous interface and microenvironment tailoring and sets a benchmark for both Faradaic efficiency and current density in solar liquid fuel production.

14 SOLAR ENERGY↗
NASA NTRSDate not supplied

TPSAS-NF1676L-20108-DND

This presentation describes several enhancements planned for the version 4 aerosol subtyping and lidar ratio selection algorithms of the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) instrument. The CALIOP subtyping algorithm determines the most likely aerosol type from CALIOP measurements (attenuated backscatter, estimated particulate depolarization ratios de, layer altitude), and surface type. The aerosol type, so determined, is associated with a lidar ratio (LR) from a discrete set of values. In the version 3 algorithms, there are 6 pairs of 532 and 1064 nm lidar ratios. Some of these lidar ratios will be updated in the version 4 algorithms. In particular, the dust and polluted dust will be adjusted to reflect the latest measurements and model studies of these types. The algorithms are being updated to eliminate the occasional confusion between smoke and clean marine aerosols seen in version 3 by modifications to the elevated layer flag definitions that are used to determine the presence of smoke aerosols over the ocean. In the subtyping algorithms pure dust is determined by high estimated particulate depolarization ratios [de > 0.20]. Mixtures of dust and other aerosol types are determined by intermediate values of the estimated depolarization ratio [0.075< de <0.2]. The version 3 algorithms are limited to mixtures of dust and smoke, the so-called polluted dust aerosol type. To differentiate between mixtures of dust and smoke, and dust and marine aerosols, a new aerosol type will be added in the version 4 data products. In the revised classification algorithms, polluted dust will still defined as dust + smoke/pollution but in the marine boundary layer instances of moderate depolarization will be typed as dusty marine aerosols with a lower lidar ratio [LR = 35 sr] than polluted dust [currently LR = 55 sr]. The dusty marine type introduced in version 4 is modeled as a mixture of dust + marine aerosol. In the v3 algorithms the frequency of dust and polluted dust aerosols at daytime is higher than at nighttime. We present possible reasons for this and present the v4 distributions resulting from both improved background slope corrections of the daytime depolarization ratios and changes to the daytime thresholds for the polluted dust and dusty marine types of version 4. To gauge the impact of the enhancements, we contrast the following between versions 3 and 4: aerosol type, parameter distributions of each type, layer heights of maximum frequency, and distributions of smoke in biomass burning regions. To illustrate specific impacts the presentation shows case studies of version 3 and version 4 vertical feature masks of the aerosol subtypes, where appropriate, for the above enhancements.

A Omar↗