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At least 379 records · Page 21

Applications for Gradient Metal Alloys Fabricated Using Additive Manufacturing

Recently, additive manufacturing (AM) techniques have been developed that may shift the paradigm of traditional metal production by allowing complex net-shaped hardware to be built up layer-by-layer, rather than being machined from a billet. The AM process is ubiquitous with polymers due to their low melting temperatures, fast curing, and controllable viscosity, and 3D printers are widely available as commercial or consumer products. 3D printing with metals is inherently more complicated than with polymers due to their higher melting temperatures and reactivity with air, particularly when heated or molten. The process generally requires a high-power laser or other focused heat source, like an electron beam, for precise melting and deposition. Several promising metal AM techniques have been developed, including laser deposition (also called laser engineered net shaping or LENS® and laser deposition technology (LDT)), direct metal laser sintering (DMLS), and electron beam free-form (EBF). These machines typically use powders or wire feedstock that are melted and deposited using a laser or electron beam. Complex net-shape parts have been widely demonstrated using these (and other) AM techniques and the process appears to be a promising alternative to machining in some cases. Rather than simply competing with traditional machining for cost and time savings, the true advantage of AM involves the fabrication of hardware that cannot be produced using other techniques. This could include parts with "blind" features (like foams or trusses), parts that are difficult to machine conventionally, or parts made from materials that do not exist in bulk forms. In this work, the inventors identify that several AM techniques can be used to develop metal parts that change composition from one location in the part to another, allowing for complete control over the mechanical or physical properties. This changes the paradigm for conventional metal fabrication, which relies on an assortment of "post-processing" methods to locally alter properties (such as coating, heat treating, work hardening, shot peening, etching, anodizing, among others). Building the final part in an additive process allows for the development of an entirely new class of metals, so-called "functionally graded metals" or "gradient alloys." By carefully blending feedstock materials with different properties in an AM process, hardware can be developed with properties that cannot be obtained using other techniques but with the added benefit of the net-shaped fabrication that AM allows.

Hofmann, Douglas C.↗

Silicon Effects on Properties of Melt Infiltrated SiC/SiC Composites

Silicon effects on tensile and creep properties, and thermal conductivity of Hi-Nicalon SiC/SiC composites have been investigated. The composites consist of 8 layers of 5HS 2-D woven preforms of BN/SiC coated Hi-Nicalon fiber mats and a silicon matrix, or a mixture of silicon matrix and SiC particles. The Hi-Nicalon SiC/silicon and Hi-Nicalon SiC/SiC composites contained about 24 and 13 vol% silicon, respectively. Results indicate residual silicon up to 24 vol% has no significant effect on creep and thermal conductivity, but does decrease the primary elastic modulus and stress corresponding to deviation from linear stress-strain behavior.

Bhatt, Ramakrishna T.↗

Summary of Results from Analyses of Deposits of the Deep-Ocean Impact of the Eltanin Asteroid

Deposits of the late Pliocene (2.5 Ma) Eltanin impact are unique in the known geological record. The only known example of a km-sized asteroid to impact a deep-ocean (5 km) basin, is the most meterorite-rich locality known. This was discovered as an Ir anomaly in sediments from three cores collected in 1965 by the USNS Eltanin. These cores contained mm-sized shock-melted asteroid materials and unmelted meteorite fragments. Mineral chemistry of meteorite fragments, and siderophole concentrations in melt rocks, indicate that the parent asteroid was a low-metal (4\%) mesosiderite. A geological exploration of the impact in 1995 by Polarstern expedition ANT-XIV4 was near the Freeden Seamounts (57.3S, 90.5 W), and successfully collected three cores with impact deposits. Analyses showed that sediments as old as Eocene were eroded by the impact disturbance and redeposited in three distinct units. The lowermost is a chaotic assemblage of sediment fragments up to 50 cm in size. Above this is a laminated sand-rich unit that deposited as a turbulent flow, and this is overlain by a more fine-grained deposit of silts and clays that settled from a cloud of sediment suspended in the water column. Meteoritic ejecta particles were concentrated near the base of the uppermost unit, where coarse ejecta caught up with the disturbed sediment. Here we will present results from a new suite of cores collected on Polarstern expedition ANT-XVIIU5a. In 2001, the Polarstern returned to the impact area and explored a region of 80,000 sq-km., collecting at least 16 sediment cores with meteoritic ejecta. The known strewn field extends over a region 660 by 200 km. The meteoritic ejecta is most concentrated in cores on the Freeden seamounts, and in the basins to the north, where the amount of meteoritic material deposited on the ocean floor was as much as 3 g/sq-cm. These concentrations drop off to the north and the east to levels as low as approximately 0.1 g/sq-cm. We were unable to sample the impact south and west of the seamounts, as the deposit was buried beyond the reach of our 25 m piston corer. We estimate that ground zero was in the region just north, or northwest, of the seamounts. There is no evidence that the impactor penetrated the ocean floor or formed a crater. The composition of the melted ejecta is inconsistent with mixing between projectile and terrestrial materials other than seawater salts. X-ray radiographs of sediments reveal details not seen in earlier cores. The uppermost impact unit is well-preserved in several cores, found as much as 50 km from the seamounts to the east, north, and west of the seamounts, where at least 25 cm of this unit is preserved. At greater distances burrowing organisms have mixed the sediments so if this unit did exist, it was too thin to survive bioturbation. These finegrained sediments are clearly laminated, and show alternating layers of low- and high-density (meteoritic) sediments, consistent with ripple formation in an energetic flow regime. We have extracted 35 g of meteoritic melt rock and 3 g of meteorite fragments from sieved sediments. Additionally a 9 g, 2.2 cm meteorite was recovered during opening of one core. The fact that 9\% of the coarse ejecta is unmelted meteorites may be characteristic of deep-ocean impacts. This may have significance for delivery of organic matter to the early Earth by small impacts into primordial oceans, where actual meteorite fragments can survive in significant amounts. However, a large portion of the meteoritic debris is buried rapidly by the sediments disturbed by the impact.

Kyte, Frank T.↗

Improved silicon/carbon interface for solar cells

Resistance measurements showing that vitreous graphite remains almost wholly intact even after 1 hour of contact with silicon melt indicates that vitreous carbon may be superior to rubbed-on graphite as interface between ceramic substrate and silicon layer of solar cell.

Zook, D. J.↗

Doppler radar study of a warm frontal region

The paper presents a case study of the structure of a warm frontal region as deduced from Doppler radar observations. The precipitation occurring ahead of the surface warm front was banded. The dominant precipitation bands were oriented transverse to the mid-level winds, and they were spaced 110 km apart. It is suggested that these bands were formed by highly organized vertical circulations in a 2.5 km thick layer just above the warm frontal zone. The precipitation bands extended from this layer down to the surface. Near the surface additional circulations were produced by pressure perturbations resulting from cooling associated with melting snow. Some diagnostic calculations of ageostrophic winds, frontogenesis and vorticity production are presented. The frontogenesis calculation gives approximately a 2-4 h doubling time of the horizontal potential temperature gradient associated with the warm front, at mid-levels. The highly organized band-associated circulations suggest the importance of their inclusion in diagnostic calculations.

Heymsfield, G. M.↗

Internal structures of the Galilean satellites

Models for the interior structures of Io, Ganymede and Callisto are proposed based on recent discoveries of volcanism and high heat flow on Io, a primordial, heavily cratered surface on Callisto, and a surface modified by endogenic processes on Ganymede. The model for Io consists of a thin, high-rigidity outer shell overlying a thin, partially molten or molten layer maintained by tidal dissipation in the outer shell, which in turn surrounds a solid interior. Ganymede is modeled as an ice outer layer surrounding a shell of undifferentiated, primordial ice-silicate mixture and a rock core, with accretional heating responsible for melting the ice in an originally homogeneous ice-silicate interior. Finally, the old, heavily cratered surface of Callisto is interpreted as suggesting a primordial ice-silicate mixture with little, if any, ice-rock differentiation in the interior.

Schubert, G.↗

Macrosegregation during plane front directional solidification of Csl-1 wt. percent Tll alloy

Macrosegregation produced during vertical Bridgeman directional solidification of Csl-1 wt. pct. Tll in crucibles of varying diameter, from 0.5 to 2.0 cm, was examined. Gravity driven convection is present in the melt even in the smallest crucible diameter of 0.5 cm. Observed solutal profiles are in agreement with the analytical boundary layer model of Favier which describes macrosegregation in the presence of convection. The scintillation efficiency of Csl decreases along the specimen length as the thallium iodide content of the alloy increases.

Sidawi, I. M. S.↗

Snow Physics and Meltwater Hydrology of the SSiB Model Employed for Climate Simulation Studies with GEOS 2 GCM

Present-day climate models produce large climate drifts that interfere with the climate signals simulated in modelling studies. The simplifying assumptions of the physical parameterization of snow and ice processes lead to large biases in the annual cycles of surface temperature, evapotranspiration, and the water budget, which in turn causes erroneous land-atmosphere interactions. Since land processes are vital for climate prediction, and snow and snowmelt processes have been shown to affect Indian monsoons and North American rainfall and hydrology, special attention is now being given to cold land processes and their influence on the simulated annual cycle in GCMs. The snow model of the SSiB land-surface model being used at Goddard has evolved from a unified single snow-soil layer interacting with a deep soil layer through a force-restore procedure to a two-layer snow model atop a ground layer separated by a snow-ground interface. When the snow cover is deep, force-restore occurs within the snow layers. However, several other simplifying assumptions such as homogeneous snow cover, an empirical depth related surface albedo, snowmelt and melt-freeze in the diurnal cycles, and neglect of latent heat of soil freezing and thawing still remain as nagging problems. Several important influences of these assumptions will be discussed with the goal of improving them to better simulate the snowmelt and meltwater hydrology. Nevertheless, the current snow model (Mocko and Sud, 2000, submitted) better simulates cold land processes as compared to the original SSiB. This was confirmed against observations of soil moisture, runoff, and snow cover in global GSWP (Sud and Mocko, 1999) and point-scale Valdai simulations over seasonal snow regions. New results from the current snow model SSiB from the 10-year PILPS 2e intercomparison in northern Scandinavia will be presented.

Mocko, David M.↗

Depths and Geologic Setting of Northern Hemisphere Gullies (and Comparison to Their Southern Counterparts)

Gullies are recognized as having an incised (often sinuous) channel, alcove, and apron morphology as defined. Previous detailed work has focused on the characteristics of southern hemisphere gullies; here we examine the distribution, morphology and depth of northern hemisphere gullies. Gully locations (both hemispheres) were compiled from the literature, not a global search, and thus the gullies studied here are the subset of the whole for which corresponding MOLA tracks are available. We find that the heads of the majority of N. hemisphere gullies commence in a specific cliff-forming layer, and average 250 m below the local surface. This observation suggests that the rock layer has a genetic relationship to gullies and is difficult at present to reconcile with gully formation from snowmelt, which predicts no correlation to rock layers. Gully locations and depths correspond to specific geologic units. We propose that in addition to ground ice and a melting mechanism, gully formation requires groundwater flow along or within specific rock units.

Gilmore, Martha S.↗

Sudbury project (University of Muenster-Ontario Geological Survey): Origin of the polymict, allochthonous breccias of the Onaping Formation

The Sudbury structure has been interpreted as a deeply eroded remnant of a peak-ring basin. The polymict, allochthonous breccias of the Onaping Formation (OF) occur in the central part of the Sudbury structure, which is surrounded by the 1.85-Ga-old 'Sudbury Igneous Complex' (SIC). From bottom to top the OF can be divided into Basal, Gray, Green, and lower and upper Black members. The breccias were mapped in detail in the east range of the structure. The SIC and the lower part of the OF (Basal Member) are interpreted as the impact melt system. The overlying Gray Member is a breccia unit with a clastic matrix and has a sharp contact to the Basal Member. The Green Member is considered as a continuous uniform breccia layer on top of the Gray Member and comprises the former 'chlorite shard horizon'. The uppermost unit of the OF (Black Member) can be subdivided into a lower and an upper Black Member unit. The lower part (100-150 m thick) still shows petrographic features of suevitic breccias, small fragments of basement rocks, melt particles, chloritized particles, and breccia fragments in a dark, clastic matrix.

Avermann, M. E.↗

A Study of Precipitation Mean Particle Size with the GPM Combined Radar-Radiometer Algorithm

The Global Precipitation Measurement (GPM) mission provides quantitative estimates of the mass-weighted mean diameter, Dm, a characteristic parameter of the precipitation particle size distribution (PSD). This study investigates the three-dimensional distribution of Dm retrieved by the GPM Combined Radar-Radiometer Algorithm (CORRA) using observations from GPM’s dual-frequency precipitation radar and microwave imager. We examine Dm in individual precipitation systems in different climate regimes and investigate a six-year global climatology. The vertical structure of Dm is demonstrated with cases of deep convection, frontal rain and snow, and stratocumulus light rain. The Dm values, detectable by GPM, range from appx 0.7 mm in stratocumulus precipitation to >3.5 mm in the ice layers of intense convection. Within the constraint of the 12-dBZ detectability threshold, the smallest climatological mean Dm (~ 0.8 mm) are found in the eastern oceans, and the largest values (~ 2 mm) occur above the melting levels in convection over land in summer. The standard deviation is generally < 0.45 mm below 6 km. Climate regimes are characterized with Dm annual/seasonal variations, its convective/stratiform components, and vertical variabilities (2-10 km). The US Central Plains and Argentina are associated with the largest Dm in a deep layer. Tropical Africa has larger Dm and standard deviation than Amazon. Large convective Dm occurs at high latitudes of Eurasia and North America in summer; the southern hemisphere high latitudes have shallower systems with smaller Dm. Oceanic storm tracks in both hemispheres have relatively large Dm, particularly for convective Dm in winter.

Mei Han↗

Optimization of solar cells for air mass zero operation and a study of solar cells at high temperatures

The power to weight ratio of GaAs cells can be reduced by fabricating devices using thin GaAs films on low density substrate materials (silicon, glass, plastics). A graphoepitaxy technique was developed which uses fine geometric patterns in the substrate to affect growth. Initial substrates were processed by etching 25 microns deep grooves into 100 oriented wafers; fine-grained polycrystalline GaAs layers 25-50 microns thick were then deposited on these and recrystallization was performed, heating the substrates to above the GaAs melting point in ASH3 atmosphere, resulting in large grain regrowth oriented along the groove dimensions. Experiments with smaller groove depths and spacings were initially encouraging; single large GaAs grains would totally cover one and often two groove fields of 14 groove each spanning several hundred microns. Dielectric coatings on the grooved substrates were also used to modify the growth.

Hovel, H. J.↗

The nature and origin of type B1 and B2 Ca-Al-rich inclusions in the Allende meteorite

The Type B Ca-Al-rich inclusions in the Allende carbonaceous chondrite form a continuous range from the mineralogically concentrically zoned B1 subtype to the unzoned B2 subtype. These subtypes differ in (1) structure, texture, grain size and shape, (2) mineralogical proportions and compositions, (3) accessory mineralogy, (4) relative abundance of spinel framboids, (5) rim layering, (6) major element chemistry, and (7) degree of secondary alteration. These differences, together with observations on the crystallization of synthetic melts, suggest that the B1 inclusions crystallized relatively rapidly from molten parental material while B2 types crystallized relatively slowly close to the solidus from material that had not been completely melted. The same data are used to construct an evaporative residue model for the origin of the parental Type B materials. In the model, dust in the protosolar nebula was heated with removal of more volatile elements, leaving completely melted (Type B1) residues at the highest temperatures and incompletely melted, less highly evaporated (Type B2) residues at lower temperatures.

Wark, D. A.↗

An assessment of the crustal remelting hypothesis for volcanism in the Freyja Montes deformation zone

The linear mountain belts of Ishtar Terra on Venus are notable for their topographic relief and slope and for the intensity of surface deformation. The mountains surround the highland plain Lakshmi Planum, the site of two major paterae and numerous other volcanic features and deposits, and evidence is widespread for volcanism within the mountains and in terrain immediately outward of the mountain belt units. While two hypotheses for magmatism can be distinguished on the basis of the chemistry of the melts, chemical data are presently lacking for the Ishtar region. The competing hypotheses for magmatism in Western Ishtar Terra can also be tested with thermal models, given a kinematic or dynamic model for the evolution of the region. The crustal remelting hypothesis is assessed, using the kinematic scenario of Head for the evolution of Freyja Montes. In that scenario, Freyja Montes formed by a sequence of large scale underthrusts of the lithosphere of the North Polar Plains beneath Ishtar Terra, with successive blocks of underthrust crust sutured in imbricate fashion onto the thickened crust of Lakshmi Planum and the mantle portion of underthrusting lithosphere episodically detached. The numerical experiments thus show that volcanic activity associated with the formation of the Frejya Montes deformation zone can be explained by crustal melting, due either to direct contact of crustal material with the hot asthenosphere or to heat generation in a thickened crustal layer.

Namiki, Noriyuki↗

Imperfect fractional crystallization of the lunar magma ocean and formation of the lunar mantle: A realistic chemical approach

It is generally considered that lunar mare basalts were generated by the melting of a cumulate mantle formed in an early Moon-wide magma ocean or magmasphere. However, the nature and chemistry of this cumulate mantle and the logistics of its origin have remained elusive. Extensive studies of terrestrial layered mafic intrusions over the past sixty years have emphasized the imperfection of fractional crystallization and attendant crystal-crystal and crystal-liquid separation in a convecting magma chamber. These separations were similarly inefficient during evolution of the lunar magmasphere, allowing for the trapping of interstitial melt and entrainment of a small proportion of less-dense plagioclase into the more-dense mafic cumulate mush. Indeed, petrography of lunar highlands samples demonstrates this well for anorthosites (with 1-10 percent olivine). Therefore, we propose a 'realistic' model for the evolution of the lunar mantle, which takes these observations into consideration, by the imperfect fractional crystallization of an early lunar magma ocean.

Snyder, Gregory A.↗

Understanding the Global Three-Dimensional Distribution of Precipitation Mean Particle Size with the Global Precipitation Measurement Mission

This study addresses the global distribution of precipitation mean particle size using data from the Global Precipitation Measurement (GPM) mission. The mass-weighted mean diameter Dm is a characteristic parameter of the precipitation particle size distribution (PSD), estimated from the GPM Combined Radar–Radiometer Algorithm (CORRA) using data from GPM’s dual-frequency precipitation radar and microwave imager. We examine Dm in individual precipitation systems in different climate regimes and investigate a 6-yr (2014–20) global climatology within 70°N–70°S. The vertical structure of Dm is demonstrated with cases of deep convection, frontal rain and snow, and stratocumulus light rain. The Dm values, detectable by GPM, range from ~0.7 mm in stratocumulus precipitation to >3.5 mm in the ice layers of intense convection. Within the constraint of the 12-dBZ detectability threshold, the smallest annual mean Dm (~0.8 mm) are found in the eastern oceans, and the largest values (~2 mm) occur above the melting levels in convection over land in summer. The standard deviation of the annual mean is generally <0.45 mm below 6 km. Climate regimes are characterized with Dm annual/seasonal variations, its convective/stratiform components, and vertical variabilities (2–10 km). The U.S. Central Plains and Argentina are associated with the largest Dm in a deep layer. Tropical Africa has larger Dm and standard deviation than Amazon. Large convective Dm occurs at high latitudes of Eurasia and North America in summer; the Southern Hemisphere high latitudes have shallower systems with smaller Dm. Oceanic storm tracks in both hemispheres have relatively large Dm, particularly for convective Dm in winter. Relatively small Dm occurs over tropical oceans, including ITCZ, requiring further investigation.

Mei Han↗

The Permanent and Inductive Magnetic Moments of Ganymede

Data acquired by the Galileo magnetometer on five passes by Ganymede have been used to characterize Ganymede's internal magnetic moments. Three of the five passes were useful for determination of the internal moments through quadrupole order. Models representing the internal field as the sum of dipole and quadrupole terms or as the sum of a permanent dipole field upon which is superimposed an induced magnetic dipole driven by the time varying component of the externally imposed magnetic field of Jupiter's magnetosphere give equally satisfactory fits to the data. The permanent dipole moment has an equatorial field magnitude 719 nT and is tilted by 176 degrees from the spin axis with the pole in the southern hemisphere rotated by 24 degrees from the Jupiter-facing meridian plane towards the trailing hemisphere. The data are consistent with an inductive response of a good electrical conductor of radius approximately 1 Ganymede radius. Although the data do not enable us to establish the presence of an inductive response beyond doubt, we favor the inductive response model because it gives a good fit to the data using only 4 parameters to describe the internal sources of fields, whereas the equally good dipole plus quadrupole fit requires 8 parameters. An inductive response is consistent with a buried conducting shell, probably liquid water with dissolved electrolytes, somewhere in the first few hundred km below Ganymede's surface. The depth at which the ocean is buried beneath the surface is somewhat uncertain, but our favored model suggests a depth of order 150 kilometers. As both temperature and pressure increase with depth and the melting temperature of pure ice decreases to a minimum at approximately 170 kilometer depth, it seems possible that near this location, a layer of water would be sandwiched between layers of ice.

Kivelson, M. G.↗