Gas Permeability, Pore Habit, and Salinity Evolution during Methane Hydrate Dissociation in Sandy Sediments
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The surface modification of poly[1-(trimethylsilyl)- propyne] (PTMSP) film via a thiol-ene click reaction with sodium 3-mercapto-1-propanesulfonate has yielded membranes having a CO 2 permeance as high as 530 GPU with a CO 2 /N 2 selectivity of 21. This level of performance, together with the simplicity of this surface modification, indicates that such materials could become viable alternatives to some of the most enticing membrane materials that are currently being explored for the practical capture of CO 2 from flue gas.
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Two-dimensional membranes have gained enormous interest due to their potential to deliver precision filtration of species with performance that can challenge current desalination membrane platforms. Molybdenum disulfide (MoS 2 ) laminar membranes have recently demonstrated superior stability in aqueous environment to their extensively-studied analogs graphene-based membranes; however, challenges such as low ion rejection for high salinity water, low water flux, and low stability over time delay their potential adoption as a viable technology. Here, we report composite laminate multilayer MoS 2 membranes with stacked heterodimensional one- to two-layer-thick porous nanosheets and nanodisks. These membranes have a multimodal porous network structure with tunable surface charge, pore size, and interlayer spacing. In forward osmosis, our membranes reject more than 99% of salts at high salinities and, in reverse osmosis, small-molecule organic dyes and salts are efficiently filtered. Finally, our membranes stably operate for over a month, implying their potential for use in commercial water purification applications.
Synthetic mesoporous silica nanoparticle (MSN) is an architected geomaterial that provides confinement-mediated flow and transport properties of fluids needed for environmental research such as subsurface energy storage or carbon capture.
This final report on Laboratory Directed Research and Development (LDRD) project 209234 presents background material for electrokinetics at the pore and porous media scales. We present some theoretical developments related to uncoupling electrokinetic flow solutions, from a manuscript recently accepted into Mathematical Geosciences for publication. We present a summary of two pore-scale modeling efforts undertaken as part of the academic alliance with University of Illinois, resulting in one already submitted journal publication to Transport in Porous Media and another in preparation for submission to a journal. We finally show the laboratory apparatus built in Laboratory B59 in Building 823 and discuss some of the issues that occurred with it.
Understand failure conditions of rock in the confined extension region
This report summarizes the activities and key findings of the project team occurring during Phase 1 (August 2014 – October 2015) of the Tularosa Basin Geothermal Play Fairway Analysis Project.