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At least 379 records · Page 21

Recent solar extreme ultraviolet irradiance observations and modeling: A review

For more than 90 years, solar extreme ultraviolet (EUV) irradiance modeling has progressed from empirical blackbody radiation formulations, through fudge factors, to typically measured irradiances and reference spectra was well as time-dependent empirical models representing continua and line emissions. A summary of recent EUV measurements by five rockets and three satellites during the 1980s is presented along with the major modeling efforts. The most significant reference spectra are reviewed and threee independently derived empirical models are described. These include Hinteregger's 1981 SERF1, Nusinov's 1984 two-component, and Tobiska's 1990/1991/SERF2/EUV91 flux models. They each provide daily full-disk broad spectrum flux values from 2 to 105 nm at 1 AU. All the models depend to one degree or another on the long time series of the Atmosphere Explorer E (AE-E) EUV database. Each model uses ground- and/or space-based proxies to create emissions from solar atmospheric regions. Future challenges in EUV modeling are summarized including the basic requirements of models, the task of incorporating new observations and theory into the models, the task of comparing models with solar-terrestrial data sets, and long-term goals and modeling objectives. By the late 1990s, empirical models will potentially be improved through the use of proposed solar EUV irradiance measurements and images at selected wavelengths that will greatly enhance modeling and predictive capabilities.

Tobiska, W. Kent↗

Gale Crater - Why are We There and What do We Hope to Learn?

The Mars Science Laboratory Rover Curiosity is commencing a two-year investigation of Gale crater and Mt. Sharp, the craters prominent central mound. Gale is a 155 km, late Noachian/early Hesperian impact crater located near the dichotomy boundary separating the southern highlands from the northern plains. The central mound is composed of layered sedimentary rock, with upper and lower mound units separated by a prominent erosional unconformity. The lower mound is of particular interest, as it contains secondary minerals indicative of a striking shift from water-rich to water-poor conditions on early Mars. A key unknown in the history of Gale is the relationship between the sedimentary units in the mound and sedimentary sequences in the surrounding region. We employed orbital remote sensing data to determine if areas within a 1,000 km radius of Gale match the characteristics of sedimentary units in Mt. Sharp. Regions of interest were defined based on: the mound s inferred age, altitude range, and THEMIS nighttime brightness (a proxy for thermal inertia). Using orbital CTX, MOC and HiRISE images we examined all areas within our regions of interest for analogous geomorphic units in the same altitude ranges as the corresponding units in Mt. Sharp. The results are consistent with the hypothesis that sedimentary units in both the upper and lower sections of the Gale mound are related to nearby regional units located along the dichotomy boundary. This relationship supports an inferred geologic history that includes several episodes of widespread sedimentary deposition and erosion in the martian mid-latitudes. In this model Mt. Sharp is the remnant of regional sedimentary deposits that partially or completely filled the crater, became lithified, and were subsequently deeply eroded. Key questions that will be addressed by Curiosity include the compositions of the sediments, the modes of deposition, the mechanisms of lithification, and the nature of the erosion.

Allen, Carlton C.↗

Data for Expression of a Bacterial Trehalose 6-Phosphate Synthase Gene otsA in Camelina sativa Seeds Promotes the Channelling of Carbon Towards Oil Accumulation

Improving seed oil yield is essential for developing Camelina sativa as a sustainable biofuel crop. Fatty acid synthesis depends on the production of acetyl-CoA from photosynthetically derived sugars. Trehalose 6-phosphate (T6P), a proxy for sucrose availability, can link sugar status to plant growth and development. Synthesised by trehalose 6-phosphate synthase (TPS) from UDP-glucose and glucose-6-phosphate, T6P plays a regulatory role in metabolism. Our previous studies on Arabidopsis transgenic lines constitutively expressing the E. coli otsA (encoding TPS) showed increased T6P levels and seed triacylglycerol, along with stunted growth. In the present study we express otsA in camelina under the control of a seed-specific Phaseolin promoter. Seeds of the resulting transgenic lines accumulated high levels of T6P, and a 15%–20% increase in total fatty acids and triacylglycerol compared to wild-type. Molecular analysis showed the transgenic seeds had reduced SnRK1 activity, elevated WRI1 protein levels, and increased the levels of WRI1 and its target genes, along with enhanced rates of fatty acid synthesis that increased seed weights relative to wild type. Notably, the increase in oil did not affect seed protein levels but did reduce the soluble metabolite fraction. Crucially, seed-specific expression of otsA mitigated the growth defects associated with constitutive otsA expression, and the transgenic lines showed normal seed development and germination. These findings demonstrate that targeted T6P modulation via seed-specific otsA expression is an effective metabolic engineering strategy to boost oil production in camelina and potentially in other oilseed crops and bioenergy crops such as energycane, sorghum and miscanthus.

Lipids↗

The impact of kinetic and global effects on ideal ballooning 2nd stable pedestals of conventional and low aspect-ratio tokamaks

The EPED model (Snyder et al 2011 Nucl. Fusion 51 103016) has had success in describing the pedestal structure of Type-I ELM and QH-mode plasmas in tokamaks, by combining kinetic ballooning mode (KBM) and peeling–ballooning (PB) constraints. Within EPED, the KBM constraint is often approximated by a technique using calculated ideal ballooning mode (IBM) thresholds, fit to a functional form designed to capture non-local effects. It has been noted that quantitative differences between local ideal MHD and gyro-kinetic (GK) ballooning stability can be larger at low aspect ratio. KBM critical pedestals are consistent with observations in initial studies on conventional and spherical tokamaks. In this work, the application of a reduced model for the calculation of the kinetic ballooning stability boundary is presented based on a novel and newly developed gyro-fluid system (GFS) code (Staebler et al 2023 Phys. Plasmas 30 102501). GFS is observed to capture KBMs in DIII-D as well as the NSTX pedestals, opening a route to integrating this model into EPED. Finally, high but finite $n$ global ballooning modes are observed to limit the access to the local 2nd stability and thus provide a transport mechanism that constrains the pedestal evolution with $β_{p,\textrm{ped}}$. The high $n$ global ballooning stability is approximated by its ideal MHD analog using ELITE. It is shown that nearly-local high $n$ modes with $k_yρ_s$ ~ $0.25 - 0.5$ can provide a proxy for the critical $β_{p,\textrm{ped}}$ when a 2nd stable access exists on DIII-D plasmas. The use of GFS and ELITE scaling in EPED provides improved agreement to EPED1 in an initial comparison with DIII-D pedestal data.

Anastopoulos Tzanis, Michail Savvas [Oak Ridge Nat↗

Analysis of TRMM-LIS Lightning and Related Microphysics Using a Cell-Scale Database

Previous studies of tropical lightning activity using Tropical Rainfall Measurement Mission (TRMM) Lightning Imaging Sensor (LIS) data performed analyses of lightning behavior over mesoscale "feature" scales or over uniform grids. In order to study lightning and the governing ice microphysics intrinsic to thunderstorms at a more process-specific scale (i.e., the scale over which electrification processes and lightning occur in a "unit" thunderstorm), a new convective cell-scale database was developed by analyzing and refining the University of Utah's Precipitation Features database and retaining precipitation data parameters computed from the TRMM precipitation radar (PR), microwave imager (TMI) and LIS instruments. The resulting data base was to conduct a limited four-year study of tropical continental convection occurring over the Amazon Basin, Congo, Maritime Continent and the western Pacific Ocean. The analysis reveals expected strong correlations between lightning flash counts per cell and ice proxies, such as ice water path, minimum and average 85GHz brightness temperatures, and 18dBz echo top heights above the freezing level in all regimes, as well as regime-specific relationships between lighting flash counts and PR-derived surface rainfall rates. Additionally, radar CFADs were used to partition the 3D structure of cells in each regime at different flash counts. The resulting cell-scale analyses are compared to previous mesoscale feature and gridded studies wherever possible.

Leroy, Anita↗

Midwest Water Resources: Developing an Evapotranspiration Climatology to Analyze Spatiotemporal Water Budget Patterns for Agriculture and Natural Resources Managers in the Midwest

Evapotranspiration (ET) is a climatic variable critical to the hydrologic cycle and is used to evaluate spatiotemporal trends in drought conditions. Although in-situ observations provide accurate ET information, these records are spatially sparse. The United States Department of Agriculture (USDA) Midwest Climate Hub, National Integrated Drought Information System, Minnesota Department of Agriculture, Michigan State University, and the USDA Foreign Agricultural Service have partnered with DEVELOP to gain new insights on spatiotemporal patterns of ET with NASA satellite data. This project evaluates the feasibility of using remotely sensed ET data products to understand trends from 2001 through 2020. Actual ET (aET) data were sourced from NASA’s Terra Moderate Resolution Imaging Spectroradiometer (MODIS), and reference ET (refET) and precipitation data were sourced from the Gridded Surface Meteorological Dataset (gridMET). Spatial and temporal differences in the MODIS and gridMET data sets were resolved such that gridded data could be compared. These data sets were then used to produce monthly Normals maps of mm/8-day of precipitation, aET, and refET. Using precipitation and ET Normals maps, hydrologic state maps were produced by subtracting either refET or aET from precipitation. These hydrologic state maps provide a proxy water balance by summarizing the difference between water entering and leaving the ground surface. Additionally, the ET products were compared in timeseries plots. The ET products from this project provided partners with comparable datasets to assess potential drought and flooding conditions to support Midwest agricultural and natural resource managers in decision-making.

Emma Myrick↗

Chapter 10 - Remote Sensing Measurements of Aerosol Properties

Satellite instruments have proven especially capable at monitoring the quantity of airborne particles in columns of atmosphere, globally. This chapter describes the principles of satellite measurements and retrieval algorithms, and surveys current instruments and their capabilities. We outline the issues associated with retrieval algorithms, such as surface characterization and aerosol proximity to clouds, and the challenges with interpretation of the results. The relationship between measured aerosol properties and climate-relevant aerosol properties simulated in models is outlined, as well as how measurements are used to evaluate models. Most space-based aerosol instruments are passive sensors that measure reflected sunlight at multiple wavelengths, some at multiple viewing angles. A few are active sensors that send out their own laser light and measure the returned signal. Except when clouds are present, the excess amount of light scattered back to space, beyond that expected from the surface and atmospheric gas, is attributed to aerosol. Satellite measurements are used in many ways in aerosol research. They often provide the only method for monitoring hazardous phenomena such as major wildfire and volcanic eruption plumes, especially in remote areas. Stable, long-term, near-global-scale satellite data records make it possible to identify regional and global aerosol trends. Aerosol radiative effects on climate can be quantified on a near-global scale and used to estimate the strength of aerosol–radiation and aerosol–cloud interactions as well as to evaluate climate model simulations of these interactions. Aerosol-type mapping from satellite imagery is helpful for source attribution, model validation, and to constrain particle light-absorption properties that are essential for radiative forcing calculations. The range of aerosol properties retrieved from satellite observations has grown considerably since the first global estimates of aerosol optical depth (τ a) over ocean were made in the late 1970s. Methods for retrieving particle size and light-absorption properties were explored in the 1990s using multispectral, multi-angle observations, and polarization in visible and near-infrared wavelengths. Sensitivity to particle light absorption, primarily from black or brown carbon content, improved with the inclusion of UV channels, and sensitivity to very thin aerosol layers in the upper troposphere and lower stratosphere was advanced with the use of limb-sounding instruments and active sensors. There are limitations to every measurement technique, including satellite aerosol remote sensing. For wide-swath, passive instruments, aerosol retrievals near clouds can present substantial challenges as far as 15 km away due to cloud-scattered light contaminating the signal. In nearly all cases, retrievals over bright snow and ice surfaces are precluded because surface reflectance uncertainties can overwhelm the aerosol signal. Similarly, meteorological cloud is identified and masked out where possible. Data from passive sensors also lack vertical resolution except those that view toward the limb or where multi-angle imagery is acquired over plumes from wildfires, erupting volcanoes, and wind-blown dust. Yet, passive sensors provide vastly more coverage than the active instruments that mitigate these issues. Particle microphysical information is qualitative from all remote sensing techniques, relying on proxies to infer particle composition, hygroscopicity, and the amount of light-absorbing material. Further, particles smaller than about 200 nm diameter cannot be distinguished from atmospheric gas molecules with remote sensing, which hinders studies of cloud condensation nuclei and their effects on clouds. Most satellite instruments dedicated to aerosol observations are in low-Earth, near-polar, sun-synchronous orbits, which means they cross the equator at the same local time each day. Most are set on cycles that repeat approximately every 16 days, which makes it difficult to monitor aerosol evolution locally. Geostationary satellites make it possible to observe changes occurring from minutes to hours over regions up to 8000 km in size, but lack coverage of high latitudes, and often provide more limited constraints on aerosol properties. Ground-truth data are vital for satellite aerosol-retrieval validation. The AErosol RObotic NETwork (AERONET) of sun photometers was created in 1993 and has become an established global network of over 350 instruments for validating satellite measurements. The network, as well as global networks of ground-based lidars, solar flux radiometers and other sun photometers, are widely used for evaluating global satellite retrievals and model simulations. NASA's Earth Observing System (EOS) program beginning in 1999 led to improvements in reliability, spatial resolution, and spectral resolution (and hence, to improved particle size discrimination and light absorption properties). Satellite payloads include advanced broad-swath and multi-angle imagers, along with the first space-based active sensor focused largely on long-term aerosol monitoring. Since about 2002, Europe's SENTINEL and operational meteorological satellite fleets are also providing sustained aerosol observations, with planned continuation until at least 2030. Satellite remote sensing instruments offer valuable data for evaluating aerosol representations in global climate models. They have been used to assess aerosol optical and physical properties, trends and distributions, and are applied increasingly as direct model constraints in data assimilation to create global aerosol reanalysis products. Aerosol optical depth is the most common quantity adopted for routine model evaluation, including multiwavelength data to loosely constrain particle-size distributions. These evaluations of multiple models have revealed general biases in their regional aerosol amounts and seasonal patterns of transport and removal. Although satellite measurements have near-global coverage, substantial errors can be introduced into the model observation comparison unless attention is paid to spatial and temporal collocation, cloud screening, subgrid-scale variability, and measurement uncertainties that vary with retrieval conditions.

aerosol properties↗

Post-fire time series of sensor and geochemistry sample data from surface water, groundwater, precipitation, soil, and vegetation across Oak Creek watershed, Washington

This dataset supports a broader study examining wildfire impacts on hydrologic connectivity across 5 sites within the Oak Creek watershed and the resulting biogeochemical impacts. Stream sites were selected using the Advanced Terrestrial Simulator (ATS) hydrologic model to identify locations with varying groundwater contributions and hydrologic responses across different burn severity scenarios. The Retreat Fire burned from July 23 to August 2 in 2024, affecting the five study sites at varying burn severities. Each site is equipped with YSI EXO2 sondes logging sub-hourly throughout the year, and grab samples are collected approximately every six weeks. YSI sondes are used to measure temporally resolved proxies for groundwater inputs (specific conductivity) and organic matter (fluorescent dissolved organic matter; fDOM) along with basic water quality and depth. Grab samples of surface water, groundwater, and precipitation are analyzed for water stable isotopes and conductivity to understand endmembers for hydrologic mixing Grab samples of surface water, groundwater, soil water, and litter/vegetation/soil leachates are analyzed for organic matter composition measured by Fourier-Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS) to understand organic matter dynamics. Game camera photos are provided in a separate data package available at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/3018598. Future versions of this dataset will include time series data from YSI EXO2 sondes (fDOM, dissolved oxygen, temperature, depth, specific conductance, turbidity, pH), BaroTROLL sensors (air temperature and barometric pressure), rain gauges (precipitation), and data from the soil and vegetation samples. Because this study is ongoing, this data package will be updated regularly to include newly collected data and the additional data types. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions. This dataset is comprised of (1) a folder of field photos; (2) a folder of surface water sample data; (3) a folder of raw Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) data; (4) a data checks report; (5) file-level metadata; (6) data dictionary; (7) field metadata; (8) readme; (9) international generic sample number (IGSN) mapping file; and (10) field protocols. The sample data subfolder contains (1) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) data and averages; (2) total dissolved nitrogen data and averages; (3) stable water isotopes and averages; (4) methods codes; (5) FTICR-MS methods; and (15) a subfolder of 9.4 Tesla (9.4T) FTICR-MS data. This folder contains the processed data and three subfolders, one containing the .xml files, one containing the water CoreMS output files, and the other containing instructions and scripts for processing the files in CoreMS (https://github.com/EMSL-Computing/CoreMS). All files are .csv, .pdf, .R, .xml, .d, .html, .Rmd, .py, .cal, .json, .jpg, .jpeg, .png, .mov, or .mp4.

Biogeochemistry↗

Vehicle Design Data Format and Process for a Complete TARIS and OLTARIS Radiation Analysis for Designers and Engineers

Protecting astronauts from space radiation is a complex task when it comes to modeling and simulation. This document shows what information is needed from a spacecraft designer using CAD (Computer-Assisted Design) at each phase of the design to enable the engineers to evaluate the design phase against space radiation limits to determine the suitability of the design for space flight. The current personal exposure limits are listed in NASA STD-3001. A proxy to determine the REID (Radiation Exposure Induced Death) in NASA STD-3001 is the whole body effective dose equivalent (E or effective dose). For short-term tissue effects, organ-averaged gray equivalent (G (sub T)) is used. The TARIS (Tool for the Assessment of Radiation In Space - for LaRC (Langley Research Center) engineers) and OLTARIS (On-Line TARIS) - for designers) systems are used to generate these response functions. The E can use ICRP60 or NASA Q-values. A possible space radiation design basis environment for short-term tissue effects is described and used in all analyses. A single space vehicle was designed with three astronaut configurations and two of those configurations were used in a storm shelter thickness perturbation analysis. Conversion of the data from the CAD model to input necessary for TARIS and OLTARIS is also discussed in detail with relevant examples.

Singleterry, Robert C.↗

Simplifying the creation of thermal decomposition mechanisms for designing mixed fibre composites

Among the most challenging aspects of simulating thermal decomposition of fibre reinforced polymers is the determination of appropriate reaction parameters. Thermogravimetric analysis is typically used to generate decomposition data, to which the reaction parameters are then fit. When designing mixed fibre materials (e.g. combinations of glass and carbon fibres), the number of TGA experiments needed to explore the entire design space may be intractable. Here, we demonstrate the creation of two candidate proxy mixed fibre mechanisms and compare them to a mechanism created by fitting parameters from TGA on the mixed fibre composite. These mechanisms are then demonstrated in a 2D axisymmetric numerical decomposition, heat transfer, and porous flow model. We find a maximum 11% uncertainty in mass and 4% in temperature difference when using a proxy mechanism.

Scott, Sarah N. [Sandia National Lab. (SNL-CA), Li↗

Data Transfer for Multiple Sensor Networks Over a Broad Temperature Range

At extreme temperatures, cryogenic and over 300 C, few electronic components are available to support intelligent data transfer over a common, linear combining medium. This innovation allows many sensors to operate on the same wire bus (or on the same airwaves or optical channel: any linearly combining medium), transmitting simultaneously, but individually recoverable at a node in a cooler part of the test area. This innovation has been demonstrated using room-temperature silicon microcircuits as proxy. The microcircuits have analog functionality comparable to componentry designed using silicon carbide. Given a common, linearly combining medium, multiple sending units may transmit information simultaneously. A listening node, using various techniques, can pick out the signal from a single sender, if it has unique qualities, e.g. a voice. The problem being solved is commonly referred to as the cocktail party problem. The human brain uses the cocktail party effect when it is able to recognize and follow a single conversation in a party full of talkers and other noise sources. High-temperature sensors have been used in silicon carbide electronic oscillator circuits. The frequency of the oscillator changes as a function of the changes in the sensed parameter, such as pressure. This change is analogous to changes in the pitch of a person s voice. The output of this oscillator and many others may be superimposed onto a single medium. This medium may be the power lines supplying current to the sensors, a third wire dedicated to data transmission, the airwaves through radio transmission, an optical medium, etc. However, with nothing to distinguish the identities of each source that is, the source separation this system is useless. Using digital electronic functions, unique codes or patterns are created and used to modulate the output of the sensor.

Krasowski, Michael↗

In-Situ and Remote-Sensing Data Fusion Using Machine Learning Techniques to Infer Urban and Fire Related Pollution Plumes

Airmass type characterization is key in understanding the relative contribution of various emission sources to atmospheric composition and air quality and can be useful in bottom-up model validation and emission inventories. However, classification of pollution plumes from space is often not trivial. Sub-orbital campaigns, such as SEAC4RS (Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys) give us a unique opportunity to study atmospheric composition in detail, by using a vast suite of in-situ instruments for the detection of trace gases and aerosols. These measurements allow identification of spatial and temporal atmospheric composition changes due to various pollution plumes resulting from urban, biogenic and smoke emissions. Nevertheless, to transfer the knowledge gathered from such campaigns into a global spatial and temporal context, there is a need to develop workflow that can be applicable to measurements from space. In this work we rely on sub-orbital in-situ and total column remote sensing measurements of various pollution plumes taken aboard the NASA DC-8 during 2013 SEAC4RS campaign, linking them through a neural-network (NN) algorithm to allow inference of pollution plume types by input of columnar aerosol and trace-gas measurements. In particular, we use the 4STAR (Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research) airborne measurements of wavelength dependent aerosol optical depth (AOD), particle size proxies, O3, NO2 and water vapor to classify different pollution plumes. Our method relies on assigning a-priori ground-truth labeling to the various plumes, which include urban pollution, different fire types (i.e. forest and agriculture) and fire stage (i.e. fresh and aged) using cluster analysis of aerosol and trace-gases in-situ and auxiliary (e.g. trajectory) data and the training of a NN scheme to fit the best prediction parameters using 4STAR measurements as input. We explore our misclassification rates as related to our ground-truth labels, and with multi-layered pollution plume cases. The next step in our analysis is to optimize parameter selection for a scheme that can be applied to space-borne aerosol and trace-gas observation platforms such as OMI, and future geostationary satellites such as TEMPO and GEO-CAPE.

Neural-network↗

Study of Magnetic Structure in the Solar Photosphere and Chromosphere

This grant funded an observational and theoretical program to study the structure and dynamics of the solar photosphere and low chromosphere, and the spectral signatures that result. The overall goal is to learn about mechanisms that cause heating of the overlying atmosphere, and produce variability of solar emission in spectral regions important for astrophysics and space physics. The program exploited two new ground-based observational capabilities: one using the Swedish Solar Telescope on La Palma for very high angular resolution observations of the photospheric intensity field (granulation) and proxies of the magnetic field (G-band images); and the other using the Near Infrared Magnetograph at the McMath-Pierce Solar Facility to map the spatial variation and dynamic behavior of the solar temperature minimum region using infrared CO lines. We have interpreted these data using a variety of theoretical and modelling approaches, some developed especially for this project. Previous annual reports cover the work done up to 31 May 1997. This final report summarizes our work for the entire period, including the period of no-cost extension from 1 June 1997 through September 30 1997. In Section 2 we discuss observations and modelling of the photospheric flowfields and their consequences for heating of the overlying atmosphere, and in Section 3 we discuss imaging spectroscopy of the CO lines at 4.67 mu.

Noyes, Robert W.↗

SCPS-TP: A Satellite-Enhanced TCP

This viewgraph presentation reviews the Space Communications Protocol Standard Transport Protocol (SCPS-TP) which is a satellite enhanced Transport Control Protocol (TCP). The contents include: 1) Purpose; 2) Background; 3) Stressed Communication Environments; 4) SCPS-TP Features; 5) SCPS-TP Performance; 6) Performance Enhancing Proxies (PEPs); and 7) Ongoing and Future SCPS-TP Work.

transmission control protocol(TCP)↗

Transition, Training, and Assessment of Multispectral Composite Imagery in Support of the NWS Aviation Forecast Mission

The NASA/Short‐term Prediction, Research, and Transition (SPoRT) Program works closely with NOAA/NWS weather forecasters to transition unique satellite data and capabilities into operations in order to assist with nowcasting and short‐term forecasting issues. Several multispectral composite imagery (i.e. RGB) products were introduced to users in the early 2000s to support hydrometeorology and aviation challenges as well as incident support. These activities lead to SPoRT collaboration with the GOES‐R Proving Ground efforts where instruments such as MODIS (Aqua, Terra) and S‐NPP/VIIRS imagers began to be used as near‐realtime proxies to future capabilities of the Advanced Baseline Imager (ABI). One of the composite imagery products introduced to users was the Night‐time Microphysics RGB, originally developed by EUMETSAT. SPoRT worked to transition this imagery to NWS users, provide region‐specific training, and assess the impact of the imagery to aviation forecast needs. This presentation discusses the method used to interact with users to address specific aviation forecast challenges, including training activities undertaken to prepare for a product assessment. Users who assessed the multispectral imagery ranged from southern U.S. inland and coastal NWS weather forecast offices (WFOs), to those in the Rocky Mountain Front Range region and West Coast, as well as highlatitude forecasters of Alaska. These user‐based assessments were documented and shared with the satellite community to support product developers and the broad users of new generation satellite data.

Fuell, Kevin↗

Super-Resolved Single-Molecule Tracking Studies of Rhodamine B Accumulation on Fresh and Aged Polyethylene Terephthalate

It is well-known that toxic organic micropollutants (OMs) accumulate on the surfaces of microplastics. However, much remains to be learned about the exact molecular level mechanisms of OM accumulation and how these evolve as the plastics age. In this work, super-resolved single-molecule tracking (SMT) is used for the first time to investigate the accumulation of Rhodamine B (RhB) dye on fresh and artificially aged polyethylene terephthalate (PET) surfaces. PET thin films serve as models for microplastics, while RhB serves as a proxy for the OMs they accumulate. Artificial aging of the films is accomplished by exposing them in a UV-ozone chamber. Water contact angle, spectroscopic ellipsometry, and carbonyl index measurements reveal a gradual decrease in film hydrophobicity, thickness, and carbonyl content with age. Atomic force microscopy (AFM) data reveal an increase in surface roughness and confirm that the films remain largely intact and continuous across the aging times explored. In SMT experiments, wide-field fluorescence videos acquired from the water/PET interface under 7.5 pM RhB reveal both mobile and immobile dye molecules. Measurements of the frame-to-frame displacements of the dye show that diffusion occurs by a desorption-mediated mechanism and that the diffusion rate varies with PET film age. The surface density of mobile dye molecules decreases with increasing PET age, while the population of immobile molecules becomes relatively larger, suggesting an age-dependent transformation of the mechanism(s) by which the dye is accumulated. SMT data reveal that both mobile and immobile molecules repeatedly adsorb over the same surface sites, consistent with the emergence of nanoscale PET surface heterogeneity also revealed by AFM. Estimates of the adsorption coefficients are obtained using a nearest-neighbor analysis, giving values from 9.9 × 10 5 to 2.1 × 10 6 M –1 for immobile molecules and from 1.8 × 10 5 to 2.5 × 10 5 M –1 for mobile molecules on fresh and 5 min aged PET, respectively. Here, anomalous age-dependent variations in the velocity of molecular motion on the PET surface and in the population of immobile molecules are shown to correlate with changes in the strength of RhB adsorption.

Adsorption↗

Measuring Black Hole Light Echoes with Very Long Baseline Interferometry

Light passing near a black hole can follow multiple paths from an emission source to an observer due to strong gravitational lensing. Photons following different paths take different amounts of time to reach the observer, which produces an echo signature in the image. The characteristic echo delay is determined primarily by the mass of the black hole, but it is also influenced by the black hole spin and inclination to the observer. In the Kerr geometry, echo images are demagnified, rotated, and sheared copies of the direct image and lie within a restricted region of the image. Echo images have exponentially suppressed flux, and temporal correlations within the flow make it challenging to directly detect light echoes from the total light curve. In this Letter, we propose a novel method to search for light echoes by correlating the total light curve with the interferometric signal at high spatial frequencies, which is a proxy for indirect emission. We explore the viability of our method using numerical general relativistic magnetohydrodynamic simulations of a near-face-on accretion system scaled to M87-like parameters. We demonstrate that our method can be used to directly infer the echo delay period in simulated data. An echo detection would be clear evidence that we have captured photons that have circled the black hole, and a high-fidelity echo measurement would provide an independent measure of fundamental black hole parameters. Our results suggest that detecting echoes may be achievable through interferometric observations with a modest space-based very long baseline interferometry mission.

79 ASTRONOMY AND ASTROPHYSICS↗

Phytoplankton production in the Sargasso Sea as determined using optical mooring data

Optical measurements from an untended mooring provide high-frequency observations of in-water optical properties and permit the estimation of important biological parameters continuously as a function of time. A 9-month time series, composed of three separate deployments, of optical data from the BIOWATT 1987 deep-sea mooring located in the oligotrophic waters of the Sargasso Sea at 34 deg N, 70 deg W are presented. These data have been tested using several bio-optical models for the purpose of providing a continuous estimate of phytoplankton productivity. The data are discussed in the context of contemporaneous shipboard observations and for future ocean color satellite observations. We present a continuous estimation of phytoplankton productivity for the 9-month time series. Results from the first 70-day deployment are emphasized to demonstrate the utility of optical observations as proxy measures of biological parameters, to present preliminary analysis, and to compare our bio-optical observations with concurrent physical observations. The bio-optical features show variation in response to physical forcings including diel variations of incident solar irradiance, episodic changes corresponding to wind forcing, variability caused by advective mesoscale eddy events in the vicinity of the mooring, and seasonal variability corresponding to changes in solar radiation, shoaling of the mixed layer depth, and succession of phytoplankton populations.

Waters, K. J.↗