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At least 379 records · Page 21

Electrolytic Oxide Reduction of Plutonium Oxide Surrogates

Our research team has investigated electrolytic oxide reduction (EOR) as an improved metal production process versus the currently employed multiple cycle direct oxide reduction (MCDOR) process for the conversion of plutonium oxide to plutonium metal. Inherent advantages in safety, waste generation, efficiency, and operational ease make EOR an attractive alternative to traditional metal production practices. Phase I of the project consisted of the construction of a prototype electrochemical cell, and proof of concept experiments towards the reduction of SnO 2 and CeO 2 compounds. Phase II of the project was focused on the optimization of the cerium system in preparation for future plutonium EOR experiments. We observed the electrolytic reduction of cerium oxide resulting in mixed degrees of success, and discovered this was a result of parasitic side reactions and partial reduction. We employed cyclic voltammetry (CV) to identify the products of these side reactions and characterize partially reduced species. We also observed that, when metal was successfully produced by EOR, a large amount of passed charge was required. We concluded that this observation was due to several inefficiencies of the process relating to the reduction mechanism (e.g. inefficient use of cathodically produced calcium). We used our CV results to guide our optimization of the EOR of CeO 2 by refining our electrochemical method, cell geometry, and materials of construction. Finally, we developed a next generation cell, worked to establish a new molten salt electrochemical capability in the Plutonium Facility, and completed a strategy for plutonium experiments. Our electrochemical method to produce plutonium metal clearly supports the core mission of the laboratory. Furthermore, this project has allowed for the development of capabilities that will provide valuable data to programs interested in characterization and detection, as well as science of signatures. Additionally, establishing this capability in the plutonium facility will facilitate future safeguard studies that can assist with safeguard development in molten salt reprocessing flowsheets, and molten salt reactor designs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A functional description of the Buffered Telemetry Demodulator (BTD)

This article gives a functional description of the buffered telemetry demodulator (BTD), which operates on recorded digital samples to extract the symbols from the received signal. The key advantages of the BTD are as follows: (1) its ability to reprocess the signal to reduce acquisition time; (2) its ability to use future information about the signal and to perform smoothing on past samples; and (3) its minimum transmission bandwidth requirement as each sub carrier harmonic is processed individually. The first application of the BTD would be the Galileo S-band contingency mission, where the signal is so weak that reprocessing to reduce the acquisition time is crucial. Moreover, in the event of employing antenna arraying with full spectrum combining, only the sub carrier harmonics need to be transmitted between sites, resulting in significant reduction in data rate transmission requirements. Software implementation of the BTD is described for various general-purpose computers.

Tsou, H.↗

Abatement of radioiodine in aqueous reprocessing off-gas

The reprocessing used nuclear fuel (UNF) releases volatile fission and activation products, including 129 I, into the off-gas of a processing plant. Mitigation of the release of vapor phase radionuclides is necessary for meeting regulatory requirements in the United States and other countries. In an aqueous reprocessing plant, volatile radioiodine could be present in several forms, depending on the chemistry of the process used. Inorganic iodine will be the predominate species in any shearing or voloxidation pretreatment off-gas and dissolver off-gas (DOG). Organic iodides such as CH 3 I, C 4 H 9 I, and C 12 H 25 I have been proposed to be generated during solvent extraction; thus, these species must be captured from the vessel off-gas (VOG). The abatement of inorganic and organic iodide species to meet United States regulatory requirements has been demonstrated in laboratory experiments using Ag-based solid sorbents. The data presented in this paper includes the effect of gas composition (e.g., the presence of water vapor and NO x ), iodine speciation (I 2 , CH 3 I, C 4 H 9 I, C 12 H 25 I), and sorbent bed parameters (e.g., temperature, sorbent age) on complete iodine capture on Ag-mordenite in an aqueous reprocessing plant.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Simultaneous U, B, V, and X-ray measurements of a burst from 4U/MXB 1636-53

Data are presented on the first simultaneous X-ray and optical burst to be measured in more than one optical color. Various analyses agree that, to a first approximation, the optical burst is produced through blackbody reprocessing of the X-ray burst, with a short delay. Depending on the technique used, the value of the delay is 2 or 3 s. The smearing of the optical signal is determined to be less than 3 s. The temperature of the optical reprocessor ranges from approximately 25,000 K at quiescence to approximately 50,000 K at burst maximum. An extinction toward the source is derived from the color-color diagram, suggesting a distance greater than or approximately equal to 2 kpc. The projected effective area of the blackbody reprocessor is approximately 5 x 10 to the 21st (D/5 kpc)-squared sq cm. The fraction of the total X-ray burst energy converted into optical energy at all wavelengths is, within an order of magnitude, approximately 3 percent. These parameters are discussed in relation to the 4 hr orbital periodicity in the system reported by Pedersen et al. (1981).

Lawrence, A.↗

High-Resolution X-Ray Spectroscopy of the Seyfert 2 Galaxy Circinus with Chandra

Results from a 60 ks Chandra High Energy Transmission Grating Spectrometer (HETGS) observation of the nearby Seyfert 2 Circinus are presented. The spectrum shows a wealth of emission lines at both soft and hard X-rays, including lines of Ne, Mg, Si, S, Ar, Ca, and Fe, and a prominent Fe K(alpha) line at 6.4 keV. We identify several of the He-like components and measure several of the Lyman lines of the N-like ions. The lines' profiles are unresolved at the limited signal-to-noise ratio of the data. Our analysis of the zeroth-order image in a companion paper constrains the size of the emission region to be 20-60 pc, suggesting that emission within this volume is almost entirely due to the reprocessing of the obscured central source. Here we show that a model containing two distinct components can reproduce almost all the observed properties of this gas. The ionized component can explain the observed intensities of the ionized species, assuming twice-solar composition and an N is proportional r(exp -1.5) density distribution. The neutral component is highly concentrated, well within the 0.8" point source, and is responsible for almost all of the observed K(alpha) (6.4 keV) emission. Circinus seems to be different than Mkn 3 in terms of its gas distribution.

Sambruna, Rita M.↗

Effect of the HITRAN 92 spectral data on the retrieval of NO2 mixing ratios from Nimbus 7 LIMS

To ensure spectral consistency when comparing Nimbus 7 Limb Infrared Monitor of the Stratosphere Experiment (LIMS) NO2 distributions with those from Atmosphere Trace Molecule Spectroscopy (ATMOS) and Upper Atmosphere Research Satellite Experiments (UARS), 1 day (May 5, 1979) of LIMS measurements were reprocessed using the NO2 line list on the HITRAN 92 tape compiled by the Airforce Geophysics Laboratory (AFGL). The revised NO2 mixing ratios are smaller by up to 20%. The decrease is not constant with height, latitude, or time of day but depends on the absolute amount of NO2 in the profile, as a result of a change in the degree of saturation for the strong NO2 spectral lines. The revised NO2 agrees better with correlative measurements and with NO2 distributions from the Stratospheric Aerosol and Gas Experiment (SAGE) and Halogen Occultation Experiment (HALOE) satellite experiments but not with those from ATMOS 85. Profiles of the day/night ratio of revised NO2 are now larger near 5 hPa. There is also some improvement between observed and modeled ozone in the upper stratosphere, when the revised nighttime NO2 profile is used as the estimate of NO(y) for the model calculations.

Remsburg, Ellis E.↗

High Resolution Spectroscopy And Timing Of The Isolated Neutron Star RBS 1774

The 2004 May 31 XMM-Newton observation was reprocessed using SASv6.0.0 and times of high background were filtered out. The net exposure time remaining was 23 ks. The source was clearly detected in MOS1, MOS2 and PN chips. We performed both timing and spectroscopic analysis on the data. We performed a spectral analysis by fitting data from the three EPIC detectors simultaneously, finding that the broadband spectrum can be represented by a single absorbed blackbody, with kT = 0.10 keV. The fitting revealed the presence of an absorption feature at 0:7 keV, but the data did have enough resolution to allow us to discriminate between an absorption line and an edge. We also tested magnetized models of Pavlov et a1 and Zavlin et al, but found that fits with these models were considerably worse than with a blackbody. For the timing analysis, we extracted the counts within a 3000 radius aperture in both PN and MOS 1 and MOS2 but with the aperture truncated by a chord where it approached the edge of the CCD window in each case: this maximized the counts while avoiding any edge effects. We analyzed PN, MOSl and MOS2 data both individually and combined using the Maximum Likelihood Periodogram technique of Zane et al. (2002) and Cropper et al. (2004). Periods from 10000 s to 30 ms were searched, ensuring that in each case the period grid was 2.5 times better sampled than the Nyquist frequency. The search revealed a significant period at 9.437s. Taken overall, we found the characteristics of RBS 1774 to be remarkably similar to those of another X-ray faint isolated neutron stars. These results were written up for the Astrophysical Journal, and the paper has recently been accepted for publication.

Mushotzky, Richard↗

Performance Criteria for Capture and/or Immobilization Technologies (Revision 1)

The capture and subsequent immobilization of regulated volatile radionuclides from the off-gas streams of a used nuclear fuel (UNF) reprocessing facility has been a topic of substantial research interest for the US Department of Energy and its international counterparts. Removal of specific radionuclides from the plant effluent streams before discharge to the environment is required to meet regulations set forth by the US Environmental Protection Agency. Upon removal, the radionuclides, as well as associated sorbents that cannot be regenerated in a cost-effective manner, are destined for conversion to a waste form. Research in separation and capture methodologies has included a wide range of technology types, and studies of waste forms are correspondingly diverse. In considering the future development and implementation of both sorbents and waste forms, it is necessary to identify benchmark measures of performance to objectively evaluate each sorbent system or waste form. Sets of performance criteria and associated metrics have been developed for sorbent and waste form evaluation. These criteria address physical, radiological, and chemical characteristics, technical practicality, technical maturity, cost, and, for sorbents, system performance. The criteria and metrics appear to be robust and should be applicable despite the eventual waste classification (as either high- or low-level waste). They are flexible enough to address both aqueous reprocessing and electrochemical reprocessing of UNF. These criteria sets can serve as tools to evaluate performance at multiple stages within the development process, and in this revision (Revision 1) they have been used to assess technologies relating to krypton/xenon separations and iodine capture from off-gas streams arising from UNF reprocessing. Assessment of krypton/xenon separations using engineered forms of two zeolite minerals (silver mordenite and hydrogen mordenite in a polyacrylonitrile-based binder [AgZ-PAN/HZ-PAN]) found that the zeolite-based separation is relatively advanced in its development, but several key issues require resolution. First, desorption processes for both krypton and xenon require refinement to provide an understanding of the product purity that can be achieved. Second, adsorption rate data is needed in order to calculate the bed depth required for effective separation. Finally, it is strongly recommended that a technical review of krypton/xenon separation by AgZ-PAN/HZ-PAN be performed to synergize available data and assess the cost savings and operational benefits that may be realized from implementation of this technology. Assessment of metal organic frameworks (MOFs) for their use in the separation of krypton/xenon found that the ideal separation would be performed using a single-column system with a MOF selective for krypton over xenon. A robust research effort should work to identify a krypton-selective MOF designed to operate at temperatures of approximately 0°C or higher, which could be preferred over cryogenic krypton/xenon capture for used fuel reprocessing off-gas streams. In the case of the CaSDB-MOF (the most well-understood xenon sorbent to date), two issues are judged of high importance. First, xenon breakthrough capacity for the CaSDB-MOF in prototypical conditions should be determined. Preliminary research indicates that breakthrough may be near immediate, presenting a substantial obstacle in separative system design. Second, development of desorption methodology should be performed to determine regeneration time, energy requirements, and the product stream composition. Silver-based sorbents (AgZ and AgAero) for use in iodine capture from the dissolver off-gas were evaluated against the established criteria. These sorbents are significantly better understood for this application as a result of research efforts over the past decade. The potential implementation of AgAero at a large scale is hindered by its physical degradation by components of the dissolver off-gas stream. Less is known about the adsorption of iodine by these sorbents from other off-gas streams in the plant. Initial experimental efforts have been closely coordinated in an effort to understand organic iodine (such as would be found in the vessel off-gas) adsorption by AgZ and AgAero. Future work should expand this experimental program, and analysis of other reprocessing facility off-gas streams such as the vitrification off-gas stream should be conducted to better understand other potential applications for iodine sorbents. A review of iodine waste form development shows that this area is diverse and that multiple promising waste forms have been identified for the immobilization of radioactive iodine. Efforts related to the direct conversion of iodine sorbents (including AgZ and AgAero) should be continued because of the advantages of direct conversion in a waste management strategy and other sorbents should continue to be advanced as merited.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Atomic Processes in X-ray Photoioinzed Gas

It has long been known that photoionization and photoabsorption play a dominant role in determining the state of gas in nebulae surrounding hot stars and in active galaxies. Recent observations of X-ray spectra demonstrate that these processes are also dominant in highly ionized gas near compact objects, and also affect the transmission of X-rays from the majority of astronomical sources. This has led to new insights into the understanding of what is going on in these sources. It has also pointed out the need for accurate atomic cross sections for photoionization and absorption, notably for processes involving inner shells. The xstar code can be used for calculating the heating, ionization and reprocessing of X-rays by gas in a range of ionization states and temperatures. It has recently been updated to include an improved treatment of inner shell transitions in iron. I will review the capabilities of xstar, the atomic data, and illustrate some applications to recent X-ray spectral observations.

Kallman, Timothy↗

Accretion onto magnetized neutron stars - X-ray pulsars with intermediate rotation rates

Assuming that the accreting material originates in a wind or envelope and therefore carried no net angular momentum, the Kevin-Helmholtz instability is applied to the transport of accreting plasma across the magnetopause of a rotating and magnetized neutron star for the case in which this surface is interchange-stable. Magnetopause location is determined, and the blackbody emission temperature is estimated. A possible period-dependence is noted in the X-ray temperature data which is in approximate agreement with the present model calculations. The magnetopause is found to be insufficiently stable to support an optically thick sheath of plasma surrounding the source, so that neither shrouding of the X-ray source nor significant reprocessing of the radiation field is possible in the model presented. It is concluded that while the flow structure at the magnetopause can control accretion column geometry, the emerging pulse profile and spectra are only indirectly altered, through a dynamical influence on emission region geometry.

Burnard, D. J.↗

A spectrophotometric atlas of white dwarfs compiled from the IUE archives

Ultraviolet spectrophotometric data are presented for 182 subluminous stars, mostly white dwarfs, that have been observed with the low-resolution mode of the IUE satellite since 1978 and for which archived data became available on April 1, 1989. Tables of 20 A binned data are given for all stars. Of these, 133 cover the entire wavelength range of the IUE, while the remainder have partial coverage. Plots of the original unbinned spectra are given. Many targets had multiple spectra combined, and the older spectra were reprocessed and corrected for reduction procedure changes made over the past 10 years.

Wegner, Gary↗

Overview of TRMM Data Products and Services

November 27, 2007 marks the l0th anniversary of the launch of the Tropical Rainfall Measuring Mission (TRMM) satellite. In anticipation of this anniversary, this paper will present an overview of the various TRMM data products currently available including the standard products, near real-time products, special products, and prototype products. It also will present an easy way to obtain these data. TRMM standard products have been publicly available since a few months after launch in November 1997. TRMM is currently on version 6 of the data product. Version 3 was the "at launch" version. The approval for each of these versions came through the Joint TRMM Science Team. Standard products are divided into 3 categories: single TRMM instrument, Visible Infrared Scanner (VIRS), TRMM Microwave Imager (TMI), and Precipitation Radar (PR); combined TRMM products (PR and TMI); finally TRMM and other satellites (combined, TMI, SSMI, AMSRE, AMSU). The single TRMM instrument products are processed through 4 levels: Level lA, science data packets processed into orbital files; Level 1B and lC, geolocated data at the instrument field of view; Level 2, geolocated, geophysical parameters at the instrument field of view; Level 3, time aggregated, gridded geophysical parameters. These products are available with 24 hours of production through an anonymous ftp account on trmmopen.gsfc.nasa.gov. The TRMM data system started to produce near real-time products at the end of 1999. They are currently available only through a controlled user account. However, approval to get access to this account can be obtained by sending a note to Erich.F.Stoclter@nasa.gov providing the reason for access and contact information including a valid email. TRMM is not restricting access but needs the information to determine the usefulness of near-real time data to the general science community including applications agencies. TRMM near real-time products are swath products up to Level 2 of processing. The oldest data in the swath is generally no older than 120 minutes when it becomes available to the community. The real-time products including a VIRS level lB, a TMI parameter reduced 1B, a TMI level 2 parameter reduced rain product, a PR level 2 surface rain product, and a PR level 2 rain product with 25 vertical levels. Currently, TRMM also produces a gridded 3 hour global merged product from several radiometers including AMSU and from radiometercalibrated IR data. The paper also describes several simple-format gridded text products available fiom the trmmopen.gsfc.nasa.gov anonymous fip server denoted as 3668 products. These products were produced to provide rain estimates from the three TRMM instruments in a universal format (ASCII) that requires very little data format knowledge. The paper goes on to describe prototype L1 radiometer products that apply an early intercalibration approach that provides a starting point to be used for Global Precipitation Measurement mission radiometer products. The paper also provides a brief overview of a precipitation features data product being produced using TRMM products including the Lighting Imaging Sensor (LIS) using an algorithm developed at the University of Utah and distributed by that organization. The paper concludes with some possible changes to products that are planned for the next reprocessing cycle and special services such as geographical subsetting available to the science community.

Stocker, Erich Franz↗

Assessment of Long-term Trends in the Collection 4 Total Ozone Record from the Ozone Monitoring Instrument

Long-term changes in total ozone affect the amount of harmful UV radiation reaching Earth’s surface and reflect progress made towards recovery of stratospheric ozone. Satellite total ozone data are also used to estimate long-term trends in tropospheric ozone, a reactive and potent greenhouse gas, by subtracting the stratospheric column timeseries from that of total ozone. For these scientific applications, the long-term stability should be better than 1%. Left unchecked, instrument calibration drift can produce a trend of this magnitude or greater. NASA has produced nearly twenty years of total ozone data from the Ozone Monitoring Instrument (OMI) using the Total Ozone Mapping Spectrometer (TOMS) algorithm. The drift in the OMI instrument as monitored by ice radiance calibration has been relatively slow, but it has reached a level of ~3% over the mission lifetime. This drift was corrected in the recently released Collection 4 OMI calibrated radiances, updating the Collection 3 calibration released in 2006. We have reprocessed the OMI total ozone record using the Collection 4 calibration and updates to the TOMS algorithm. We summarize these changes and evaluate their impact by comparing to the previous Collection 3 OMI dataset, the Suomi NPP Ozone Mapping and Profiler Suite Nadir Mapper (OMPS-NM) and Solar Backscatter UV (SBUV) Merged Ozone Dataset (MOD) total ozone records and other independent satellite total ozone datasets. Climatological radiance residuals from OMI and OMPS-NM are calculated and compared to investigate differences in spectral calibration that can cause drifts in long-term total ozone trends. We also analyze the tropospheric ozone record produced using the Collection 4 OMI total ozone and stratospheric column ozone from MLS. Collection 3 OMI data processed with the TOMS algorithm show a positive drift relative to other satellite and ground-based data of 1-2 DU per decade. Initial results show that this drift is reduced in Collection 4 OMI, due to the updated OMI calibration. In this work we will quantify the improvements in Collection 4 OMI relative to independent data sources at both the ozone and radiance level

Collection 4 OMI Total Ozone↗

Thermodynamic modeling of KCl-PrCl 3 and KCl-LiCl-PrCl 3 systems

Molten salt electrolysis can recover the actinides from spent nuclear fuels, and it involves a eutectic LiCl-KCl in molten form as an electrolyte. During reprocessing, the concentration of fission products such as La, Nd, Pr, etc., increases and affects the recovery efficiency of the electrolyte. In this work, thermodynamic modeling of KCl-PrCl 3 and KCl-LiCl-PrCl 3 systems was carried out using the CALPHAD (Calculation of Phase Diagrams) approach for the first time. The thermodynamic functions for the pure salts were taken from the SGTE (Scientific Group Thermodata Europe) Substances (SSUB) database. The experimental thermochemical and phase equilibria data available in the literature were used as input for the assessment of KCl-PrCl 3 and KCl-LiCl-PrCl 3 systems. The model parameters for the KCl-LiCl system were adjusted to include the new Gibbs energy descriptions for the pure salts. In addition, the sublattice model for the liquid phase in the LiCl-PrCl 3 system was modified and reassessed to ensure the model compatibility for higher-order extrapolation. There is a good agreement between the experimental and calculated thermochemical and phase diagram data for all the optimized constituent binaries and the ternary system. Furthermore, this work will be beneficial for determining the solubility limit of PrCl 3 in molten LiCl-KCl electrolytes and their thermodynamic properties for improving the efficiency of the pyrochemical process.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Unattended Monitoring of Uranium Holdup with Scintillating Fibers

This work evaluated the use of scintillating fiber (SciFi) radiation sensors as a cost-effective, unattended monitoring technique for uranium holdup accumulation in reprocessing equipment. With ruggedized packaging and an outer diameter of less than 1 cm, scintillating fibers offer deployment flexibility. Additionally, plastic scintillating fibers coupled with standard optical fibers provide an affordable option to monitor locations kilometers away from a localized control room or data acquisition (DAQ) system. These combinations of characteristics along with their relatively low manufacturing costs make scintillating fibers ideal for installation at key measurement points such as pipes, valves, and filtration systems.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Validation Assessment for the Soil Moisture Active Passive (SMAP) Level 4 Carbon (L4_C) Data Product Version 5

The post-launch Cal/Val phase of the SMAP mission is guided by two primary objectives for each science product team: 1) to calibrate, verify, and improve the performance of the science algorithms, and 2) validate accuracies of the science data products as specified in the SMAP Level-1 mission science requirements. Algorithm science and product maintenance activities during the SMAP extended mission phase have also involved periodic algorithm calibration and product refinements to maintain or enhance product consistency and performance as well as science utility. This report provides an assessment of the latest (Version 5) SMAP Level 4 Carbon (L4_C) product. The L4_C Version 5 (v5) global record now spans more than six years (March 2015 – present) of SMAP operations and has benefited from five major reprocessing updates to the operational product. These reprocessing events and L4_C product release updates have incorporated various algorithm refinements and calibration adjustments to account for similar refinements to the upstream GEOS land model assimilation system, SMAP brightness temperatures, and MODIS vegetation inputs used for L4_C processing. The SMAP L4_C algorithms utilize a terrestrial carbon flux model informed by daily surface and root zone soil moisture information contributed from the SMAP Level 4 Soil Moisture (L4_SM) product along with optical remote sensing-based (e.g. MODIS-based) land cover and canopy fractional photosynthetic active radiation (fPAR), and other ancillary biophysical data. The carbon flux model estimates global daily net ecosystem CO2 exchange (NEE) and the component carbon fluxes, namely, vegetation gross primary production (GPP) and soil heterotrophic respiration (Rh). Other L4_C product elements include surface (~0-5 cm depth) soil organic carbon (SOC) stocks and associated environmental constraints to these processes, including soil moisture-related controls on GPP and ecosystem respiration (Kimball et al. 2014, Jones et al. 2017). The L4_C product addresses SMAP carbon cycle science objectives by: 1) providing a direct link between terrestrial carbon fluxes and underlying freeze/thaw and soil moisture-related constraints to these processes, 2) documenting primary connections between terrestrial water, energy and carbon cycles, and 3) improving understanding of terrestrial carbon sink activity. The SMAP L4_C algorithms and operational product are mature and at a CEOS Validation Stage 4 level (Jackson et al. 2012) based on extensive validation of the multi-year record against a diverse array of independent benchmarks, well characterized global performance, and systematic refinements gained from five major reprocessing events. There are no Level-1 mission science requirements for the L4_C product; however, self-imposed requirements have been established focusing on NEE as the primary product field for validation, and on demonstrating L4_C accuracy and success in meeting product science requirements (Jackson et al. 2012). The other L4_C product fields also have strong utility for carbon science applications (e.g., Liu et al. 2019, Endsley et al. 2020); however, analysis of these other fields is considered secondary relative to primary validation activities focusing on NEE. The L4_C targeted accuracy requirements are to meet or exceed a mean unbiased root-mean-square error (ubRMSE, or standard deviation of the error) for NEE of 1.6 g C m-2 d-1 and 30 g C m-2 yr-1, emphasizing northern (≥45°N) boreal and arctic ecosystems; this accuracy is similar to that of tower eddy covariance measurement-based observations (Baldocchi 2008). Methods used for the latest v5 L4_C product performance and validation assessment have been established from the SMAP Cal/Val plan and previous studies (Jackson et al. 2012, Jones et al. 2017) and include: 1) consistency evaluations of the product fields against earlier product releases (version 4 or earlier); 2) comparisons of daily carbon flux estimates with independent tower eddy 4covariance measurement-based daily carbon (CO2) flux observations from core tower validation sites (CVS); and 3) consistency checks against other global carbon products, including soil carbon inventory records, global GPP records derived from tower observation upscaling methods, and satellite-based observations of canopy solar induced chlorophyll fluorescence (SIF) as a surrogate for GPP. Metrics used to evaluate relative agreement between L4_C product fields and observational benchmarks include correlation (r-value), RMSE differences, bias and model sensitivity diagnostics. Following these validation criteria, the present report provides a validation assessment of the latest L4_C product release (v5). Detailed descriptions of the L4_C algorithm and additional global product accuracy and performance results are given elsewhere (Jones et al. 2017, Endsley et al. 2020). The v5 L4_C product replaces earlier product versions and continues to show: (i) accuracy and performance levels meeting or exceeding SMAP L4_C science requirements; (ii) improvement over the previous product version (version 4); and (iii) suitability for a diversity of science applications. Example L4_C applications from the recent literature include clarifying environmental trends and controls on the northern terrestrial carbon sink (Liu et al. 2019), diagnosing drought-related impacts on ecosystem productivity (Li et al. 2020), and regional monitoring of cropland conditions for projecting annual yields (Wurster et al. 2020). 2EXPECTED L4_C ALGORITHM AND PRODUCTPERFORMANCE The L4_C algorithm performance, including variance and uncertainty estimates of model outputs, was determined during the mission pre-launch phase through spatially explicit model sensitivity studies using available model inputs similar to those currently being used for operational production and evaluating the resulting model simulations over the observed range of northern (≥45 °N) and global conditions (Kimball et al. 2012, Entekhabi et al. 2014). The L4_C algorithm options were also evaluated during the mission prelaunch phase, including deriving canopy fPAR from lower order NDVI (Normalized Difference Vegetation Index) inputs in lieu of using MODIS (MOD15) fPAR; and including an explicit model representation of boreal fire disturbance recovery impacts. These results indicated that the L4_C accuracy requirements (i.e., NEE ubRMSE ≤ 30 g C m-2 yr-1or ≤ 1.6 g C m-2 d-1) could be met from the baseline algorithms over more than 82% and 89% of global and northern vegetated land areas, respectively (Yi et al. 2013, Kimball et al. 2014). The global L4_C algorithm error budget for NEE derived during the mission prelaunch phase indicated that the estimated NEE ubRMSE uncertainty is proportional to GPP and is therefore larger in higher biomass productivity areas, including forests and croplands (Kimball et al. 2014). Likewise, NEE ubRMSE uncertainty is expected to be lower in less-productive areas, including grasslands and shrublands. Expected model NEE ubRMSE levels were also generally within targeted accuracy levels for characteristically less-productive boreal and Arctic biomes, even though relative model error as a proportion of total productivity (NEE RMSE / GPP) may be large in these areas. The estimated NEE uncertainty was lower than expected in some warmer tropical high biomass productivity areas (e.g. Amazon rainforest) because of reduced low temperature and moisture constraints to the L4_C respiration calculations so that the bulk of model uncertainty is contributed by GPP in these areas. Model NEE uncertainty in the African Congo was estimated to

SMAP↗

Preprocessing Analysis of the Multi Isotope Process Monitor

The Multi-Isotope Process (MIP) Monitor is a nondestructive monitoring methodology to detect diversion and tampering of nuclear material at a reprocessing facility. The system measures the gamma-emitting isotopes in different stages of the reprocessing cycle through passive gamma spectroscopy. The indicators of isotopic distributions are measured and evaluated in near-real time by comparing measured spectra to expected, normal process spectra through multivariate analysis. The MIP monitor framework is compatible with medium resolution gamma detectors that can be easily deployed in an existing facility. In FY15, the MIP monitor was deployed at the H-Canyon Facility at Savannah River National Laboratory (SRNL) to develop and evaluate analysis algorithms for future in situ deployment. This paper discusses recent results from analysis of the data collected at SRNL. New results examine the preprocessing step of spectral alignment that is associated with the MIP monitor.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Radiation-Induced Chemical Yields of Carbon-Centered Radicals and Hydrogen Atoms from the Gamma Irradiation of n -Dodecane

Here, this study investigates the radiolytic yields of carbon-centered radicals and hydrogen atoms in n-dodecane under gamma irradiation. Utilizing molecular iodine (I 2 ) and 2,4,6-tri-tert-butylnitrosobenzene (3tBNB) as radical scavengers, we quantified the yields of molecular hydrogen and various carbon-centered radicals formed from bond scission of the solvent excited states. The yield of primary alkyl radicals was significantly lower than that of the secondary radicals, aligning with expected stabilities and bond dissociation energies. For the overall loss of n-dodecane, total yields of 0.598 ± 0.004 species/100 eV for C–C bond scission, 1.648 ± 0.012 species/100 eV for C–H bond scission, and 3.20 ± 0.10 species/100 eV for unimolecular H 2 elimination were determined. Notably, the I 2 scavenging data provided robust estimates, while the 3tBNB displayed lower efficiency in radical trapping. This research enhances our understanding of radiolytic processes in n-dodecane and offers insights for future studies on the behavior of hydrocarbons under ionizing radiation, with implications for improving UNF reprocessing strategies.

38 - RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCL↗