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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1986

Comparison of regional clear-sky albedos inferred from satellite observations and model computations

A comparison of model- and satellite-inferred clear sky top-of-atmosphere (TOA) albedos is presented. The clear sky albedos were inferred from GOES-2 observations for November 1978 over South America and most of North America and adjacent ocean regions. The model albedos were computed on a 1 deg X 1 deg latitude-longitude grid, allowing for variations in surface vegetation type, solar zenith angle, orography, and spectral absorption/scattering. Over the ocean areas, the observed and calculated TOA albedos agree within + or - 1 percent, while the albedos over land mostly agree within + or - 2 percent for the entire range of significant geographical variation of albedo from 13 percent over the Amazon Basin to 24 percent over mountains of western North America. Both the ocean and land agreements lie within the theoretical and observational uncertainties.

Briegleb, B. P.↗
NASA NTRS1986

Seasonal behavior of NO2 in the winter stratosphere - Inferred NO(x)

An analysis is performed of Solar Mesosphere Explorer (SME) data for the first 90 days of 1982, when a trend of increasing NO2 content in the stratosphere near the 10 mbar pressure level was detected. A photochemical-dynamical model is developed to account for the observed densities, which were also detected with ground-based instrumentation. The model calculations indicated that partitioning of the NO(x) family from N2O5 to NO2 was responsible for the trend. The new partitioning requires a lowering of the mixing ratio of NO(x), which was also observed. Finally, the SME data also confirmed that the enhanced NO2 concentrations were dependent on the solar zenith angle.

Zawodny, J. M.↗
NASA NTRS1985

Ozone-temperature relationships in the stratosphere

Utilizing independent estimates of ozone and temperature fields from the SBUV (Nimbus 7) and NOAA operational satellites, respectively, for the period 1978-1981, the coefficient of variation between the two parameters is determined. This coefficient is defined as A = Delta-O3 x (T)/Delta T x (O3) wehre Delta is an incremental change in either temperature or ozone and the bracket is a mean state. In practice, A is determined on a daily basis by regression of ozone mixing ratio versus temperature around a latitude circle during the winter season and the bracket value is the daily zonal average. This has the advantage of keeping the solar zenith angle fixed for a daily value while allowing it to change during the season. This is done at 30, 10, 5, 2, and 1 mb from 20 deg to 60 deg latitude in both hemispheres. The results are summarized and compared with those determined from a one-dimensional photochemical model applied to different latitudes.

Miller, A. J.↗
NASA NTRS1986

An analysis at mesospheric coherent-scatter power enhancements during solar flare events

Solar flares produce increases in coherent-scatter power from the mesosphere due to the increase in free electrons produced by X-ray photoionization. Thirteen such power enhancements were observed at Urbana. When such an enhancement occurs at an altitude containing a turbulence layer with constant strength, the relative enhancement of electon density is estimated from the enhancement in power. Such estimates of enchanced electron density are compared with estimates of the X-ray photoionization at that altitude, deduced from geostationary satellite measurements. It is found that possible types ion-chemical reaction scheme may be distinguished, and the nonflare ion-pair production function may be estimated. The type of ion-chemical scheme and the nonflare ion-production function are shown to depend on the solar zenith angle.

Parker, J.↗
NASA NTRS1986

Near-midnight observations of nitric oxide delta- and gamma-band chemiluminescence

Chemiluminescent nightglow emission of the nitric oxide delta and gamma bands was measured from a sounding rocket launched on April 27, 1981, near local midnight. The integrated band emission rates for this near zenith observation above 205 km were less than 10 Rayleighs. The solar zenith angle was 127 deg. The branching ratio from the C2Pi state to the A2Sigma(+) state of NO was determined from comparison of the total emission rate of the delta band system to that of the gamma band system and found to be 0.30 + or - 0.06. The branching ratios within each of the band systems were found to be consistent with previous theoretical and experimental determinations. The vertical atomic nitrogen distribution, derived with the use of a model atmosphere, was found to have a peak density of 2.0 x 10 to the 7th atoms/cu cm at an altitude of 205 km. The analysis of these data indicate the presence of residual NO emission above 270 km at local midnight on the order of 1 Rayleigh of total band emission.

Tennyson, P. D.↗
NASA NTRS1986

Angular dependence of reflectance of land cover surfaces

Preliminary results are discussed from an investigation into the effects of the solar zenith angle on the surface reflectances of cloud types being categorized in the International Satellite Cloud Climatology Project. The analysis is based on AVHRR channel one data at 0.6 micron over the period July 1983-July 1984. Subsatellite scenes of eight geographically separated targets distinguished by their predominant vegetation type were examined pixel-by-pixel. Attempts were made to discover any spatial variability index in each pixel to classify pixels representing clouds by the recorded brightness temperature.

Brest, C. L.↗
NASA NTRS1986

The dayglow of the O2 atmospheric band system

The dayglow of the O2 atmospheric O2(1Sigma) band system has been simulated by taking into account the three main production mechanisms of the O2(1Sigma) state resonance fluorescence, a photochemical term due to quenching of O(1D), and a pure chemical process. Values of the emission rate, which are involved in the resonant scattering of the O2 atmospheric bands (A, B, and gamma), have been obtained as a function of altitude (0-120 km) and solar zenith angle using a line-by-line calculation. The values of the emission rate, along with updated rate coefficients, have been used in the calculation of the production rate of O2(1Sigma) and the volume emission rate of the (O2 1Sigma, v prime = 0)-(O2 3Sigma, v double prime = 0) transition. The results of these calculations are compared to observational measurements and are found to be in excellent agreement.

Bucholtz, A.↗
NASA NTRS1987

Observations of energetic ions on the nightside of Venus

Ions with energy greater than 40 eV have been measured on the nightside of Venus by the Pioneer Venus orbiter neutral mass spectrometer (ONMS). For periapsis altitudes beyond 1500 km, they are confined to solar zenith angles greater than 120 deg. The nightside energetic ion composition at 2000 km resembles the nightside thermal ion composition occurring at 1000 km with the dominant species being O(+). Postflight laboratory calibrations performed on the ONMS backup unit have been used to estimate the energetic O(+) ambient flux and density. The direction from which the energetic ions appear to be coming can be determined because the ONMS is mounted at an angle with respect to the spin axis of the spacecraft. Both tailward and antitailward components of the apparent ion flow are exhibited when projected into the ecliptic plane. The major component of the apparent ion flow is observed perpendicular to the ecliptic plane.

Kasprzak, W. T.↗
NASA NTRS1987

Model ozone photochemistry on the basis of Solar Mesosphere Explorer mesospheric observations

Morning and afternoon mesospheric ozone profiles (50-90 km) measured by the Solar Mesosphere Explorer (SME) satellite are analyzed with one-dimensional photochemical models. The observed ozone abundances are 40 percent and 100 percent greater than the model ozone abundances at 50 and 80 km, respectively. Diurnal model calculations are compared with SME observations of ozone profiles at about 0400 and 1400 LT for high northern summer latitudes. Analysis of the ratios of these early morning and midafternoon ozone profiles provides the additional constraint that larger odd-oxygen production rates are required if lower odd-hydrogen activity is invoked to increase model O3 abundances. The increase in odd-oxygen production must be solar zenith angle independent in the mesosphere, ruling out significant changes in the Schumann-Runge band O2 opacities from Allen and Frederrick (1982).

Clancy, R. T.↗
NASA NTRS1987

A simple spectral model of the dynamics of the Venus ionosphere

A two-dimensional model of the ionosphere of Venus has been constructed by expanding pertinent quantities in Legendre polynomials. The model is simplified by including only a single ion species, O(+). Horizontal plasma flow velocity and plasma density have been calculated as a coupled system. The calculated plasma flow velocity is found to be in good agreement with observations and the results of earlier studies. Solar zenith angle dependence of plasma density, particularly on the nightside, shows some features which differ from results of earlier studies and observed values. Effects of raising or lowering the ionopause height and changing the nightside neutral atmosphere have been discussed.

Singhal, R. P.↗
NASA NTRS1987

Scene shadow effects on multispectral response

Spectral responses measured from nonuniform balsam fir canopies with varying amounts and locations of shadows are examined in order to study the effects of scene shadows on spectral response. The behavior of canopy reflectance and spectral band transformations, normalized difference (ND), and greenness for a variety of solar zenith angles and background types are analyzed. The use of vegetation indices for monitoring vegetation is studied in terms of shadowing. It is observed that the red and near-IR reflectance factors decrease as the amount of scene shadows increase; the ND increases with increasing scene shadows; changing shadow amounts have little effect on greenness; and the ND from 'pure' pixels increases as the shadows cast by adjacent vegetation canopies increases.

Ranson, K. Jon↗
NASA NTRS1987

Frequency functions of Venus nightside ion densities

The variability of the total and major ion densities in the nightside Venus ionosphere are studied by deriving an experimental frequency function for these quantities. The frequency function N(i) derived for the total ion density is found to be insensitive to division of the parent set into two approximately equal subsets representing dawn and dusk hemispheres, an upper and lower altitude interval, or two solar zenith angle intervals. The N(i) function is reasonably well peaked near the median value, and 78 percent of the normalized values fall within a factor of 2.8 of the median value. The frequency of occurrence decreases more rapidly on the high side of the median than on the low side. The frequency functions for the constituent ions are similar to that for N(i).

Knudsen, William C.↗
NASA NTRS1987

Hemispherical reflectance variations of vegetation canopies and implications for global and regional budget studies

The hemispherical reflectance (HR) variations of vegetation canopies are studied as a function of solar zenith angle, wavelength, and canopy characteristics (leaf area index, leaf orientation distribution, and leaf and soil optical properties). The radiative transfer model of Kimes (1984) is used to explain the radiative transfers that give rise to variations in the HR for various vegetation canopies as a function of sun angle. The results of this model are compared with those calculated from Sellers' (1985) analytical two-stream approximation. It is noted that the findings have significant implications for a wide range of global and regional energy budget studies.

Kimes, D. S.↗
NASA NTRS1987

A canopy reflectance model based on an analytical solution to the multiple scattering equation

An approximation to the radiative transfer equation for solar radiation in relatively full, homogeneous plant canopies is presented and solved analytically for solar zenith angles less than 60 deg. The model predicts reflectance at any depth in the canopy and in any direction and may be inverted with bidirectional reflectance measurements. The model was fit to data at two sun angles and two wavebands (visible and NIR) to within the assumed errors on the reflectance data. The calculated albedos are insensitive to achievable measurement errors. Some of the parameter values themselves found by the inversion agree reasonably well with independent measurements, but the uncertainties introduced by the data noise are rather large. However, the agreement is good enough to demonstrate that the model is physically realistic.

Camillo, Peter↗
NASA NTRS1987

Extraction of spectral hemispherical reflectance (albedo) of surfaces from nadir and directional reflectance data

A radiative transfer model is used to investigate how the error of spectral hemispherical reflectance data obtained from nadir reflectance values varies with wavelength, solar zenith angle, leaf area index, and leaf orientation distribution. Several techniques employing multiple off-nadir view angles taken in azimuth planes are found to accurately infer spectral hemispherical reflectances, and to be well suited to sensor systems that scan in a known azimuth plane or view fore and aft in a known azimuth plane. The effects of errors in hemispherical reflectance on terrestrial energy budget and productivity calculations is also considered.

Kimes, D. S.↗
NASA NTRS1988

The budget of biologically active ultraviolet radiation in the earth-atmosphere system

This study applies the concept of a budget to describe the interaction of solar ultraviolet (UV) radiation with the earth-atmosphere system. The wavelength ranges of interest are the biologically relevant UV-B between 280 and 320 nm and the UV-A from 32000 to 400 nm. The Nimbus 7 solar backscattered ultraviolet (SBUV) instrument provides measurements of total column ozone and information concerning cloud cover which, in combination with a simple model of radiation transfer, define the fractions of incident solar irradiance absorbed in the atmosphere, reflected to space, and absorbed at the ground. Results for the month of July quantify the contribution of fractional cloud cover and cloud optical thickness to the radiation budget's three components. Scattering within a thick cloud layer makes the downward radiation field at the cloud base more isotropic than is the case for clear skies. For small solar zenith angles, typical of summer midday conditions, the effective pathlength of this diffuse irradiance through tropospheric ozone is greater than that under clear-sky conditions. The result is an enhanced absorption of UV-B radiation in the troposphere during cloud-covered conditions. Major changes in global cloud cover or cloud optical thicknesses could alter the ultraviolet radiation received by the biosphere by an amount comparable to that predicted for long-term trends in ozone.

Frederick, John E.↗
NASA NTRS1988

Vertical column abundance measurements of atmospheric hydroxyl from 26 deg, 40 deg, and 65 deg N

The vertical column abundance of atmospheric hydroxyl was measured with Pepsios spectrometers from Boca Raton, Florida (26.4 N); Fritz Peak, Colorado (40 deg N); and Poker Flat, Alaska (65 deg N). The data show a global solar zenith angle dependence for the OH abundances, with the general features common in measurements from all three locations since 1980. However, while theoretical models agree well with the pre-1980 abundances, the post-1980 data do not. It appears that a significant change in the atmospheric photochemistry needs to be introduced.

Burnett, Clyde R.↗
NASA NTRS1988

Temperature dependence of the atmospheric photolysis rate coefficient for NO2

Accurate values for the photolysis rate coefficient of NO2 (j1) are required for studies related to the observed imbalance in the photostationary state of O3, NO, and NO2 in the troposphere. Direct measurements of the temperature dependence of j1 at temperatures from -70 to 30 C were made in sunlight for relatively cloudless summer days in Boulder, Colorado. The ratios of j1 (30 C)/j1 (T C) for T = -10 C and -70 C, respectively, were 1.046 + or - 0.040 and 1.070 + or - 0.031. The j1 ratios were independent of solar zenith angle. Theoretical estimates of the temperature-dependent j1 ratios based upon recently reported cross section (sigma) and quantum yield (phi) data are more consistent with these experimental measurements than those based upon the currently accepted sigma and phi data.

Shetter, Richard E.↗