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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21

Physical aging and its influence on the reliability of network epoxies and epoxy-matrix composites

The matrix-dominated physical and mechanical properties of a carbon fiber reinforced epoxy composite and a neat epoxy resin were found to be affected by sub-Tg annealing in nitrogen and dark atmosphere. Postcured specimens of Thornel 300 carbon-fiber/Fiberite 934 epoxy as well as Fiberite 934 epoxy resin were quenched from above Tg and given annealing at 140 C, 110 C, or 80 C, for time up to one-hundred thousand minutes. No weight loss was observed during annealing at these temperatures. Significant variations were found in density, modulus, hardness, damping, moisture absorption ability, thermal expansivity. Moisture-epoxy interactious were also studied. The kinetics of aging as well as the molecular aggregation during this densification process were monitored by differential scanning calorimetry, dynamic mechanical analysis, density gradient column, microhardness tester, Instron, and solid-state nuclear magnetic resonance spectroscopy.

Heinemann, K.↗

Multispectral linear array

The Multispectral Linear Array (MLA) is a solid-state earth imagery radiometer operating in the 'push-broom' mode and using a focal plane containing multiple spectral band linear detector arrays. The MLA sensor offers the capability for increased spatial and spectral resolution with multiple selectable bands and in-orbit operation flexibility. Both free-flyer (satellite) and Shuttle-attached instrument designs have been studied. Four Shuttle-attached MLA instrument design studies were initiated in 1982, and the concepts resulting from these studies are described.

Richard, H. L.↗

Fire- and heat-resistant laminating resins based on maleimido-substituted aromatic cyclotriphosphazenes

A novel class of flame- and heat-resistant polymers has been synthesized by the thermal polymerization of maleimido-substituted aromatic cyclotriphosphazenes. The polymer obtained from tris-(aminophenoxy)tris(maleimidophenoxy)cyclotriphosphazene has good thermal stability and is noteworthy for its high char yield, viz., 82 percent at 800 C in nitrogen and 81 percent at 700 C in air. Graphite-fabric laminates prepared with this polymer did not burn in pure oxygen, even at 300 C, and were tested for mechanical properties. Hexakis(4-maleimidophenoxy)cyclotriphosphazene and some fluorine-containing monomers have also been synthesized. The structures of these cyclic phosphazene precursors and polymers were characterized by FT IR spectrophotometry, H-1 NMR, F-19 NMR, and P-31 solid-state magic angle spinning NMR spectroscopy, and mass spectrometry. The curing behavior of the polymer precursors and the thermal stabilities of the polymers were evaluated by differential scanning calorimetry (DSC) and thermogravimetric analyses (TGA).

Kumar, D.↗

Physical aging in graphite/epoxy composites

Sub-Tg annealing has been found to affect the properties of graphite/epoxy composites. The network epoxy studied was based on the chemistry of tetraglycidyl 4,4'-diamino-diphenyl methane (TGDDM) crosslinked by 4,4'-diamino-diphenyl sulfone (DDS). Differential scanning calorimetry, thermal mechanical analysis, and solid-state cross-polarized magic-angle-spinning nuclear magnetic resonance spectroscopy have been utilized in order to characterize this process of recovery towards thermodynamic equilibrium. The volume and enthalpy recovery as well as the 'thermoreversibility' aspects of the physical aging are discussed. This nonequilibrium and time-dependent behavior of network epoxies are considered in view of the increasingly wide applications of TGDDM-DDS epoxies as matrix materials of structural composites in the aerospace industry.

Kong, E. S. W.↗

Observations of spectroscopic binaries at ultraviolet and red wavelengths

The use of IUE-satellite and ground-based-Reticon observations for the study of spectroscopic binaries is examined, and sample data from the Reticon are presented. IUE radial-velocity determinations with uncertainties as low as 2-5 km/sec should be possible for binaries with early-type secondary components, using UV spectral lines where contamination by the later-type primary is reduced. The Reticon solid-state photodiode-array detector has been used at the coudefocus of the 2.7-m telescope at McDonald Observatory for observation of complex multiple systems in the 400-950-nm range with a quantum efficiency of 40-80 percent and resolution of 20-30 pm at 440 pm/mm. The fundamental parameters of 15 systems observed with this apparatus are listed in a table, and two sample spectra are shown.

Fekel, F. C., Jr.↗

Lasers, their development, and applications at M.I.T. Lincoln Laboratory

A historical account of the work on lasers at MIT Lincoln Laboratory is presented. Highlighted are the efforts that led to the coinvention of the semiconductor laser and the Laboratory's later role in establishing the feasibility of GaInAsP/InP semiconductor lasers for use in fiber telecommunications at 1.3-1.5 micron wavelengths. Descriptions of other important developments include tunable lead-salt semiconductor and solid-state lasers for spectroscopy and LIDAR applications, respectively, as well as ultrastable CO2 lasers for coherent infrared radar.

Rediker, R. H.↗

X-rays from Eta Carinae

X-ray observations of Eta Car obtained with the high-resolution imager and solid-state spectrometer of the Einstein observatory are reported and interpreted in terms of a two-shell model. A soft component with temperature 5 million K is located in the expanding outer shell, and the hard core component with temperature 80 million K is attributed to the interaction of a high-velocity stellar wind from the massive central object with the inner edge of a dust shell. Model calculations based on comparison with optical and IR data permit estimation of the mass of the outer shell (0.004 solar mass), the mass of the dust shell (3 solar mass), and the total shell expansion energy (less than 2 x 10 to the 49th ergs).

Chlebowski, T.↗

Spectral observation of the soft X-ray background and of the North Polar Spur with solid state spectrometers

Soft X-ray diffuse background observations in the 0.3-1.5 keV interval of two sky regions, near the north galactic pole and the North Polar Spur (NPS) are reported. Data were taken with a solid-state spectrometer carried by a rocket. The near-polar region exhibited O VII ion emissions at 530 eV. A second component was not identified but was attributed to the Galactic Halo. Fe XVIII, Ne IX, and O VIII contributions were detected in the NPS, along with an enhancement at 1.35 keV from Mg XI lines. A two-temperature contour was fit to the spectra and chi-square confidence levels of 90 and 68 percent were obtained.

Rocchia, R.↗

Recent developments in EHF Satcom technology

The state-of-the-art in EHF Satcom technology is assessed and hardware samples are described. Travelling wave tube amplifiers provide up to 30 percent efficiency for 20 GHz spaceborne operations and up to 20 percent efficiency at 30/44 GHz in ground operations. Solid-state power amplifiers incorporate FET and IMPATT diode technologies for 20-44 GHz transmissions using GaAs FETs and Si or GaAs diodes. Noise is reduced with loss image-enhanced mixers coupled to an IF FET amplifier, resulting ultimately in 6-7 dB noise levels compared to 19 dB gain. Finally, high power varactor upconverters have been developed to provide up to 50 mW RF output at at least 10 percent efficiency at frequencies up to 50 GHz.

Okean, H. C.↗

The ac power line protection for an IEEE 587 Class B environment

The 587B series of protectors are unique, low clamping voltage transient suppressors to protect ac-powered equipment from the 6000V peak open-circuit voltage and 3000A short circuit current as defined in IEEE standard 587 for Category B transients. The devices, which incorporate multiple-stage solid-state protector components, were specifically designed to operate under multiple exposures to maximum threat levels in this severe environment. The output voltage peaks are limited to 350V under maximum threat conditions for a 120V ac power line, thus providing adequate protection to vulnerable electronic equipment. The principle of operation and test performance data is discussed.

Roehr, W. D.↗

High-density Schottky barrier IRCCD sensors for remote sensing applications

It is pointed out that the ambitious goals envisaged for the next generation of space-borne sensors challenge the state-of-the-art in solid-state imaging technology. Studies are being conducted with the aim to provide focal plane array technology suitable for use in future Multispectral Linear Array (MLA) earth resource instruments. An important new technology for IR-image sensors involves the use of monolithic Schottky barrier infrared charge-coupled device arrays. This technology is suitable for earth sensing applications in which moderate quantum efficiency and intermediate operating temperatures are required. This IR sensor can be fabricated by using standard integrated circuit (IC) processing techniques, and it is possible to employ commercial IC grade silicon. For this reason, it is feasible to construct Schottky barrier area and line arrays with large numbers of elements and high-density designs. A Pd2Si Schottky barrier sensor for multispectral imaging in the 1 to 3.5 micron band is under development.

Elabd, H.↗

Kinetics of thermal donor generation in silicon

The generation kinetics of thermal donors at 450 C in Czochralski-grown silicon was found to be altered by high-temperature preannealing (e.g., 1100 C for 30 min). Thus, when compared with as-grown Si, high-temperature preannealed material exhibits a smaller concentration of generated thermal donors and a faster thermal donor saturation. A unified mechanism of nucleation and oxygen diffusion-controlled growth (based on solid-state plate transformation theory) is proposed to account for generation kinetics of thermal donors at 450 C, in as-grown and high-temperature preannealed Czochralski silicon crystals. This mechanism is consistent with the main features of the models which have been proposed to explain the formation of oxygen thermal donors in silicon.

Mao, B.-Y.↗

Integrated optics for fiber gyro's

Expected advantages of incorporating integrated optical waveguide components into fiber gyroscopes are summarized. The structural-simplicity benefits which can be achieved through the use of solid-state lasers, and integrated and fiber optics are examined; angular rate noise and random walk drift for the current technology in the 0.84-micron wavelength region are reported as 0.00001 deg/sec and 0.0002 deg/hr to the 1/2, respectively. The state-of-the-art in the pertinent materials research is reviewed; lithium niobate, suggested to be used as a waveguide substrate material, is noted to have a complex chemistry that is not yet fully understood. However, most of the optical and electrooptical components of a fiber gyro are conceptually understood and have been demonstrated.

Goss, W.↗

Observation of an Excess Current Noise Resulting from Oxygen Absorption onto Iron Films

This paper reports on measurements that demonstrate that oxygen absorbed on clean polycrystalline Fe films can produce an excess current noise. The noise is indicative of dynamic processes occurring in the surface region of the film. We propose that the noise results from the dynamics of a reversible reaction between absorbed states. The measurements are accurately modeled with a single correlation time implying that surface heterogeneity is not important to the reaction. In addition to offering promise for future states of solid-state surface reactions, these measurements also have implications for the origin of 1/f current noise in conductors.

Shanabarger, M. R.↗

Pressure Measurement

Pressure Systems, Inc.'s DPT 6400 is a system designed to increase productivity in industrial processes where there is a need for making multiple pressure measurements quickly and with high accuracy. It is applicable in controlling industrial processes in plants that are being upgraded to automated status. In order to automate such plants the pressures at the many loops must be measured, converted to digital information and transmitted to the plant's process control computer. The DPT 6400 serves that function. By employing solid-state pressure sensing transducers whose errors are automatically corrected by a microprocessor, it is capable of highly accurate pressure measurements. Basic DPT 6400 has 64 channels, but the system can be expanded to 256 channels by the addition of "slave" units.

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Emergency/Night Lightning

UDEC's highly efficient lighting system is finding wide acceptance among industrial and commercial firms as an energy savings means of providing emergency and night lighting. Originating from Skylab, the system consists of small high frequency fluorescent light fixtures powered by solar cells. Advantages of UDEC's lighting system stem from high reliability and high light output with very low energy drain. Principal components of system are long life fluorescent lamps operated by electronic circuitry, a sealed gelatine cell battery that needs no maintenance for eight years and a solid-state automatic battery charger. Installation of UDEC lighting in a company's six-and-a-half acre warehouse office cut the annual night lighting electric bill from $8,000 a year to $300 per year.

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Emergency Lighting

A lighting system originally developed for NASA's Apollo and Skylab manned spacecraft resulted in a industrial spinoff and creation of a whole new company to produce and market the product line. The company is UDEC Corp., Waltham, Mass. UDEC's "Multi-Mode" electronic lighting systems are designed for plant emergency and supplemental use, such as night lighting, "always-on" stairwell lights and illuminated exit signs. Their advantages stem from the qualities demanded for spacecraft installation: extremely high fight output with very low energy drain, compactness, light weight, and high reliability. The Multi-Mode system includes long-life fluorescent lamps operated by electronic circuitry, a sealed battery that needs no maintenance for 10 years, and a solid-state battery charger. A typical emergency installation consists of a master module with battery and an eight watt lamp, together with four remote "Satellight" modules powered by the master's battery. As a night lighting system for maintenance or I security, UDEC fixtures can bypass the battery and 1 operate on normal current at a fraction of the energy 1 demand of conventional night lighting. Industrial customers have realized savings of better than ninety percent with UDEC night lights. UDEC started as a basement industry in 1972 but the company has already sold more than 1,000 lighting systems to building operators.

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Breadboard Facility

In the sixties, Chrysler was NASA's prime contractor for the Saturn I and IB test launch vehicles. The company installed and operated at Huntsville what was known as the Saturn I/IB Development Breadboard Facility. "Breadboard," means an array of electrical and electronic equipment for performing a variety of development and test functions. This work gave Chrysler a broad capability in computerized testing to assure quality control in development of solid-state electronic systems. Today that division is manufacturing many products not destined for NASA, most of them being associated with the company's automotive line. A major project is production and quality-control testing of the "lean-burn" engine, one that has a built-in Computer to control emission timing, and allow the engine to run on a leaner mixture of fuel and air. Other environment-related products include vehicle emission analyzers. The newest of the line is an accurate, portable solid state instrument for testing auto exhaust gases. The exhaust analyzers, now being produced for company dealers and for service

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