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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 379 records · Page 21
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

The density evolution of IRAS galaxies

A maximum likelihood test for density evolution is applied to a full-sky redshift survey of 5297 galaxies selected from the IRAS data base and flux-limited at 1.2 Jy. No evidence for evolution is found. Attention is given to important systematic errors which decrease the certainty with which evolution can be measured, namely, limited knowledge of the cosmological model, the unknown intrinsic spectral energy distribution of IRAS galaxies from 16 to 140 microns, the effect of density fluctuations, a Malmquist-like bias arising from flux errors in the IRAS Point Source Catalog, and possible incompleteness of the sample at high redshifts and low Galactic latitudes. It is shown that the Malmquist bias could result in a significant overestimation of the evolution rate, especially if the catalog has a flux limit near the completion limit of the Point Source Catalog.

Fisher, Karl B.↗
DOE OSTI2020

Assessing Uncertainties and Approximations in Solar Heating of the Climate System

In calculating solar radiation, climate models make many simplifications, in part to reduce computational cost and enable climate modeling, and in part from lack of understanding of critical atmospheric information. Whether known errors or unknown errors, the community's concern is how these could impact the modeled climate. The simplifications are well known and most have published studies evaluating them, but with individual studies it is difficult to compare. Here, we collect a wide range of such simplifications in either radiative transfer modeling or atmospheric conditions and assess potential errors within a consistent framework on climate-relevant scales. We build benchmarking capability around a solar heating code (Solar-J) that doubles as a photolysis code for chemistry and can be readily adapted to consider other errors and uncertainties. The broad classes here include: use of broad wavelength bands to integrate over spectral features; scattering approximations that alter phase function and optical depths for clouds and gases; uncertainty in ice-cloud optics; treatment of fractional cloud cover including overlap; and variability of ocean surface albedo. We geographically map the errors in W m -2 using a full climate re-creation for January 2015 from a weather forecasting model. For many approximations assessed here, mean errors are ~2 W m -2 with greater latitudinal biases and are likely to affect a model’s ability to match the current climate state. Combining this work with previous studies, we make priority recommendations for fixing these simplifications based on both the magnitude of error and the ease or computational cost of the fix.

58 GEOSCIENCES↗
NASA NTRS1973

A multi-spectral method for estimating cirrus cloud top heights

A two-channel method has been developed to estimate the altitude of cirrus clouds over ocean areas with an expected altitude error less than or equal to plus or minus 50 mb. Reflected radiation is used to estimate cirrus emissivity in the 10- to 11-micron spectral interval. The cirrus altitude is determined from the emissivity estimate, a registered 10- to 11-micron measurement, and a vertical temperature profile. Nimbus 3 medium-resolution infrared radiometer measurements were used to establish the relationship between reflectance and 11-micron cirrus emissivity.

Shenk, W. E.↗
NASA NTRS2006

Processing Raman Spectra of High-Pressure Hydrogen Flames

The Raman Code automates the analysis of laser-Raman-spectroscopy data for diagnosis of combustion at high pressure. On the basis of the theory of molecular spectroscopy, the software calculates the rovibrational and pure rotational Raman spectra of H2, O2, N2, and H2O in hydrogen/air flames at given temperatures and pressures. Given a set of Raman spectral data from measurements on a given flame and results from the aforementioned calculations, the software calculates the thermodynamic temperature and number densities of the aforementioned species. The software accounts for collisional spectral-line-broadening effects at pressures up to 60 bar (6 MPa). The line-broadening effects increase with pressure and thereby complicate the analysis. The software also corrects for spectral interference ("cross-talk") among the various chemical species. In the absence of such correction, the cross-talk is a significant source of error in temperatures and number densities. This is the first known comprehensive computer code that, when used in conjunction with a spectral calibration database, can process Raman-scattering spectral data from high-pressure hydrogen/air flames to obtain temperatures accurate to within 10 K and chemical-species number densities accurate to within 2 percent.

Nguyen, Quang-Viet↗
DOE OSTI2021

Organic contamination detection for isotopic analysis of water by laser spectroscopy

Hydrogen and oxygen stable isotope ratios (δ 2 H, δ 17 O, and δ 18 O values) are commonly used tracers of water. These ratios can be measured by isotope ratio infrared spectroscopy (IRIS). However, IRIS approaches are prone to errors induced by organic compounds present in plant, soil, and natural water samples. A novel approach using 17 O-excess values has shown promise for flagging spectrally contaminated plant samples during IRIS analysis. A systematic assessment of this flagging system is needed to prove it useful. Errors induced by methanol and ethanol water mixtures on measured IRIS and isotope ratio mass spectrometry (IRMS) results were evaluated. For IRIS analyses both liquid- and vapour-mode (via direct vapour equilibration) methods are used. The δ 2 H, δ 17 O, and δ 18 O values were measured and compared with known reference values to determine the errors induced by methanol and ethanol contamination. In addition, the 17 O-excess contamination detection approach was tested. This is a post-processing detection tool for both liquid and vapour IRIS triple-isotope analyses, utilizing calculated 17 O-excess values to flag contaminated samples. Organic contamination induced significant errors in IRIS results, not seen in IRMS results. Methanol caused larger errors than ethanol. Results from vapour-IRIS analyses had larger errors than those from liquid-IRIS analyses. The 17 O-excess approach identified methanol driven error in liquid- and vapour-mode IRIS samples at levels where isotope results became unacceptably erroneous. For ethanol contaminated samples, a mix of erroneous and correct flagging occurred with the 17 O-excess method. Here our results indicate that methanol is the more problematic contaminant for data corruption. The 17 O-excess method was therefore useful for data quality control. Organic contamination caused significant errors in IRIS stable isotope results. These errors were larger during vapour analyses than during liquid IRIS analyses, and larger for methanol than ethanol contamination. The 17 O-excess method is highly sensitive for detecting narrowband (methanol) contamination error in vapour and liquid analysis modes in IRIS.

60 APPLIED LIFE SCIENCES↗
NASA NTRS2006

Implementation of Cloud Retrievals for Tropospheric Emission Spectrometer (TES) Atmospheric Retrievals: Part 1. Description and Characterization of Errors on Trace Gas Retrievals

We develop an approach to estimate and characterize trace gas retrievals in the presence of clouds in high spectral measurements of upwelling radiance in the infrared spectral region (650-2260/cm). The radiance contribution of clouds is parameterized in terms of a set of frequency-dependent nonscattering optical depths and a cloud height. These cloud parameters are retrieved jointly with surface temperature, emissivity, atmospheric temperature, and trace gases such as ozone from spectral data. We demonstrate the application of this approach using data from the Tropospheric Emission Spectrometer (TES) and test data simulated with a scattering radiative transfer model. We show the value of this approach in that it results in accurate estimates of errors for trace gas retrievals, and the retrieved values improve over the initial guess for a wide range of cloud conditions. Comparisons are made between TES retrievals of ozone, temperature, and water to model fields from the Global Modeling and Assimilation Office (GMAO), temperature retrievals from the Atmospheric Infrared Sounder (AIRS), tropospheric ozone columns from the Goddard Earth Observing System (GEOS) GEOS-Chem, and ozone retrievals from the Total Ozone Mapping Spectrometer (TOMS). In each of these cases, this cloud retrieval approach does not introduce observable biases into TES retrievals.

aerosols↗
DOE OSTI2023

Single-shot X-ray absorption spectroscopy at X-ray free electron lasers

X-ray Absorption Spectroscopy (XAS) is a widely used X-ray diagnostic method for studying electronic and structural properties of matter. At first glance, the relatively narrow bandwidth and the highly fluctuating spectral structure of X-ray Free Electron Lasers (XFEL) sources seem to require accumulation over many shots to achieve high data quality. To date the best approach to implementing XAS at XFEL facilities has been using monochromators to scan the photon energy across the desired spectral range. While this is possible for easily reproducible samples such as liquids, it is incompatible with many important systems. Here, we demonstrate collection of single-shot XAS spectra over 10s of eV using an XFEL source, with error bars of only a few percent. We additionally show how to extend this technique over wider spectral ranges towards Extended X-ray Absorption Fine Structure measurements, by concatenating a few tens of single-shot measurements. Our results pave the way for future XAS studies at XFELs, in particular those in the femtosecond regime. This advance is envisioned to be especially important for many transient processes that can only be initiated at lower repetition rates, for difficult to reproduce excitation conditions, or for rare samples, such as those encountered in high-energy density physics.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1994

Use of multiple gauges and microwave attenuation of precipitation for satellite verification

In this paper both a microwave attenuation measurement along a horizontal line and multiple point gauge measurements are analyzed as possible ground-truth designs to validate satellite precipitation retrieval algorithms at the field of view spatial level (typically about 20 km). The design consists of comparing a sequence of pairs of contemporaneous measurements taken from the ground and from space. The authors examine theoretically the variance of expected differences between the two systems. The line average measurement leads to a smaller mean-square error compared to the case of a single point gauge, since some of the small-scale variability of the rain field is smoothed away by the line integration. The multiple point gauge measurements also give smaller mean-square error than that of a single point gauge. The centroid of the line and point gauge configurations are considered to be located randomly inside the field of view for different overpasses. A space-time spectral formalism is used with a noise-forced diffusive rain field to find the mean-square error. By considering instantaneous ground and satellite measurement pairs over about 50 visits when raining, we can reduce the expected error to approximately 10% of the standard deviation of climatological variability. This is considered to be a useful level of tolerance for identifying biases in the retrieval algorithms. It is found that the multiple point gauges (especially two gauges) are the economical ground-truth design compared to the microwave attenuation based on the mean-square error comparison. The major finding of this study is that a significant improvement over the point gauge is obtained by adding a single additional piece of information; adding more gauges or extending the line of attenuation is not an important improvement.

Ha, Eunho↗
NASA NTRS2009

Spatial Modulation Improves Performance in CTIS

Suitably formulated spatial modulation of a scene imaged by a computed-tomography imaging spectrometer (CTIS) has been found to be useful as a means of improving the imaging performance of the CTIS. As used here, "spatial modulation" signifies the imposition of additional, artificial structure on a scene from within the CTIS optics. The basic principles of a CTIS were described in "Improvements in Computed- Tomography Imaging Spectrometry" (NPO-20561) NASA Tech Briefs, Vol. 24, No. 12 (December 2000), page 38 and "All-Reflective Computed-Tomography Imaging Spectrometers" (NPO-20836), NASA Tech Briefs, Vol. 26, No. 11 (November 2002), page 7a. To recapitulate: A CTIS offers capabilities for imaging a scene with spatial, spectral, and temporal resolution. The spectral disperser in a CTIS is a two-dimensional diffraction grating. It is positioned between two relay lenses (or on one of two relay mirrors) in a video imaging system. If the disperser were removed, the system would produce ordinary images of the scene in its field of view. In the presence of the grating, the image on the focal plane of the system contains both spectral and spatial information because the multiple diffraction orders of the grating give rise to multiple, spectrally dispersed images of the scene. By use of algorithms adapted from computed tomography, the image on the focal plane can be processed into an image cube a three-dimensional collection of data on the image intensity as a function of the two spatial dimensions (x and y) in the scene and of wavelength (lambda). Thus, both spectrally and spatially resolved information on the scene at a given instant of time can be obtained, without scanning, from a single snapshot; this is what makes the CTIS such a potentially powerful tool for spatially, spectrally, and temporally resolved imaging. A CTIS performs poorly in imaging some types of scenes in particular, scenes that contain little spatial or spectral variation. The computed spectra of such scenes tend to approximate correct values to within acceptably small errors near the edges of the field of view but to be poor approximations away from the edges. The additional structure imposed on a scene according to the present method enables the CTIS algorithms to reconstruct acceptable approximations of the spectral data throughout the scene.

Bearman, Gregory H.↗
NASA NTRS2018

Enhancements to the Open Access Spectral Band Adjustment Factor Online Calculation Tool for Visible Channels

With close to 40 years of satellite observations, from which, cloud, land-use, and aerosol parameters can be measured, inter-consistent calibrations are needed to normalize retrievals across satellite records. Various visible-sensor inter-calibration techniques have been developed that utilize radiometrically stable Earth targets, e.g., deep convective clouds and desert/polar ice pseudo-invariant calibration sites. Other equally effective, direct techniques for intercalibration between satellite imagers are simultaneous nadir overpass comparisons and ray-matched radiance pairs. Combining independent calibration results from such varied techniques yields robust calibration coefficients, and is a form of self-validation. One potential source of significant error when cross-calibrating satellite sensors, however, are the often small but substantial spectral discrepancies between comparable bands, which must be accounted for. As such, visible calibration methods rely on a Spectral Band Adjustment Factor (SBAF) to account for the spectral-response function- induced radiance differences between analogous imagers. The SBAF is unique to each calibration method as it is a function of the Earth-reflected spectra. In recent years, NASA Langley pioneered the use of SCIAMACHY-, GOME-2-, and Hyperion-retrieved Earth spectra to compute SBAFs. By carefully selecting hyperspectral footprints that best represent the conditions inherent to an inter-calibration technique, the uncertainty in the SBAF is greatly reduced. NASA Langley initially provided the Global Space-based Inter-calibration System processing and research centers with online SBAF tools, with which users select conditions to best match their calibration criteria. This article highlights expanded SBAF tool capabilities for visible wavelengths, with emphasis on the use of the spectral range filtering for the purpose of separating scene conditions for the channel that the SBAF is needed based on the reflectance values of other bands. In other words, spectral filtering will enable better scene-type selection for bands where scene determination is difficult without information from other channels, which should prove valuable to users in the calibration community.

Scarino, Benjamin↗
DOE OSTI2024

AuriDESI: mock catalogues for the DESI Milky Way Survey

The Dark Energy Spectroscopic Instrument Milky Way Survey (DESI MWS) will explore the assembly history of the Milky Way by characterizing remnants of ancient dwarf galaxy accretion events and improving constraints on the distribution of dark matter in the outer halo. We present mock catalogues that reproduce the selection criteria of MWS and the format of the final MWS data set. These catalogues can be used to test methods for quantifying the properties of stellar halo substructure and reconstructing the Milky Way’s accretion history with the MWS data, including the effects of halo-to-halo variance. The mock catalogues are based on a phase-space kernel expansion technique applied to star particles in the Auriga suite of six high-resolution lambda-cold dark matter magnetohydrodynamic zoom-in simulations. They include photometric properties (and associated errors) used in DESI target selection and the outputs of the MWS spectral analysis pipeline (radial velocity, metallicity, surface gravity, and temperature). They also include information from the underlying simulation, such as the total gravitational potential and information on the progenitors of accreted halo stars. We discuss how the subset of halo stars observable by MWS in these simulations corresponds to their true content and properties. These mock Milky Ways have rich accretion histories, resulting in a large number of substructures that span the whole stellar halo out to large distances and have substantial overlap in the space of orbital energy and angular momentum.

dynamics↗
DOE OSTI2022

Characterization and Optimization of a Spectral Window for Direct Gaseous Uranium Hexafluoride Enrichment Assay Using Laser-Induced Breakdown Spectroscopy

Through a systematic scanning of 235 U and 238 U emission lines between 280 nm and 745 nm, the optimal emission line for direct gaseous uranium hexafluoride (UF 6 ) enrichment assay using laser-induced breakdown spectroscopy (LIBS) was found. Screening for spectral features that are potentially useful for U isotopic analysis was gauged from the magnitude of the 235 U– 238 U isotopic shift and the signal-to-background ratio of the emission line through a parameter termed ΔSBR 235U–238U . The ΔSBR spectrum shows peaks at wavelength positions where there are strong lines with significant 235 U– 238 U shifts. The screening identified 13 spectral-window candidates, which were down selected based on their overall accuracy in predicting the 235 U enrichment of three UF 6 samples of natural (0.720 atom% 235 U) and low-enriched (4.675 atom% and 9.157 atom% 235 U) grades. The U(I) 646.498 nm emission line, with a determined 235 U– 238 U isotopic shift of -17.7 pm, was found to be the optimal spectral window for direct UF 6 enrichment assay. The root mean square error for enrichment assays on the three natural and low-enriched UF 6 samples, with each sample measured in six replicates, was 0.31% in absolute 235 U content. Each measurement comprised LIBS signals accumulated from 3000 laser shots. In conclusion, the analytical bias and precision were better than 0.5% and 0.3%, respectively, in absolute [ 235 U/( 235 U + 238 U)] ratios. Specific for the two low-enriched UF 6 samples, the relative standard deviations from six replicated measurements were around 2%.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

The Stability of Fiber Spectrographs in the Faint-source Regime

The use of optical fibers in astronomical instrumentation offers high-multiplex and light-gathering flexibility. However, with most previous fiber spectrographs optimized for large fields of view on modest-aperture telescopes, the performance of fibers in the context of faint targets on large telescopes remains largely untested. In this paper, we evaluate aspects of fiber stability, especially as they apply in the context of precision sky subtraction of faint sources at modest spectral resolution ($R$ ~ 3000). After introducing a framework for describing potential systematic errors, we use publicly available data from existing instruments, including instrumentation used by the fourth-generation Sloan Digital Sky Survey’s MaNGA project (MaNGA: Mapping Nearby Galaxies at Apache Point Observatory) and the Very Large Telescope’s FLAMES: Fiber Large Array Multi Element Spectrograph. We isolate sources of fiber systematics and estimate the observed amplitude of persistent residuals as well as stochastic noise contributions resulting from changing fiber stresses. Comparing these levels against their impact on various sky subtraction schemes demonstrates that 0.1% precision sky subtraction with fiber instruments is possible. As a demonstration, we show that the MaNGA instrument can deliver 0.2% residuals on bright near-IR sky lines with nonlocal sky subtraction, if pseudo-slit limitations are addressed by allocating 50% of its fibers to sky. We further highlight recently published deep exposures that achieved a 1$σ$ background level of 27.6 AB per square arc second, equivalent to a precision of 0.2% of the sky background continuum.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1975

Balance between resolution and signal-to-noise ratio in scanner design for earth resources systems

An outline is presented of a method in which a sensor under design can be evaluated by comparison with an existing sensor of similar spectral response, providing certain performance characteristics are known. An approach for calculating errors in radiance measurements is discussed, giving attention to calibration, error caused by resolution factors, noise effects on accuracy, and combined radiance level accuracies for several scanner designs. The derivation of error caused by the modulation transfer function is also considered.

Norwood, V. T.↗
NASA NTRS1980

Search and rescue emergency locating transmitter detection/location procedure via TIROS satellite

A procedure is described which works effectively to detect and locate emergency locating transmitters (ELTs) and emergency position indicating radio beacons (EPIRBs) in a multisignal environment. Using data generated from several manufactured ELTs with diverse superimposed Doppler curves, as many as 9 simultaneous ELTs can be detected and located at a variety of signal strengths. It is noted that average position errors of 10 km are attainable today at signal power to noise spectral density ratios as low as 17 dB-Hz.

Wren, P. E.↗
NASA NTRS1982

The use of Landsat-3 thermal data to help differentiate land covers

Landsat-3 Multispectral Scanner Subsystem (MSS) digital data of the Baltimore, Maryland area gathered on May 24, 1978, are examined to show the usefulness of thermal data in providing better discrimination between agricultural and residential areas, certain types of urban/industrial areas and water, cloud shadows and water, and bare-extractive areas and bright urban cover types. High altitude aircraft imagery taken on May 3, 1978, provides ground truth and training site verification. Two classifications are made for each training site: the initial one using bands 4, 5, and 7 and a second in which the thermal data are included with the visible and near infrared data. This permits a direct comparison of areas spectrally similar with and without the inclusion of the thermal data. Commission errors determined from selected subsets of the data show reductions of 95% for the urban/industrial versus water themes, 84% for the residential versus agriculture themes, 64.0% for the bare-extractive versus bright urban themes, and 24% for the cloud shadow versus water themes when the thermal data are included in the signature.

Ormsby, J. P.↗
NASA NTRS1980

Analytical design of multispectral sensors

An optimal design based on the criterion of minimum mean square representation error using the Karhunen-Loeve expansion was developed to represent the spectral response functions from a stratum based upon a stochastic process scene model. From the overall pattern recognition system perspective, the effect of the representation accuracy on a typical performance criterion (the probability of correct classification) is investigated. The optimum sensor design provides a standard against which practical (suboptimum) operational sensors can be compared. An example design is provided and its performance is illustrated. Although developed primarily for the purpose of sensor design, the procedure has potential for making important contributions to scene understanding. Spectral channels which have narrow bandwidths relative to current sensor systems may be necessary to provide adequate spectral representation and improved classification performance.

Wiersma, D. J.↗