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Visible - Near Infrared Spectral Indices for Mapping Mineralogy and Chemistry with OSIRIS-REx

The primary objective of the Origins, Spectral Interpretation, Resource Identification, SecurityRegolith Explorer (OSIRIS-REx) mission is to return to Earth a pristine sample of carbonaceous material from the primitive asteroid (101955) Bennu. To support compositional mapping as part of sample site selection and characterization, we tested 95 spectral parameters on visible to near infrared laboratory reflectance data of minerals and carbonaceous meteorites to find which of these parameters reliably identified spectral features of interest. Most spectral parameters had high positive detection rates when used on spectra of pure, single component materials. The meteorite spectra have fewer and weaker absorption features and, as a result, fewer detections with the spectral parameters. Parameters targeting absorptions at 0.7 and 2.7 – 3 µm, which arise due to hydrated minerals, were most successful for the meteorites. Based on these results, we have identified a set of 17 parameters that are most likely to be useful at Bennu and spectral analogs. These parameters detect olivines, pyroxenes, carbonates, water/OH-bearing minerals, serpentines, ferric minerals, and organics. Particle size and albedo are known to affect band depth but had a negligible impact on parameter accuracy. The effect of instrument-like noise added to the laboratory spectra can result in more false positive detections, but these exhibit large errors. Our study has determined the prioritization of spectral parameters used for OSIRISREx spectral analysis and mapping and informs the reliability of all parameter-derived data products.

Hannah H Kaplan↗

Interim Measures Report for the Headquarters Building Area Location of Concern (LOC) 2E East SWMU 104 John F. Kennedy Space Center, Florida

The Hazardous and Solid Waste Amendment portion of the National Aeronautics and Space Administration (NASA) Resource Conservation and Recovery Act (RCRA) Permit issued by the Florida Department of Environmental Protection (FDEP), requires identification and evaluation of all known Solid Waste Management Units (SWMUs) and Locations of Concern (LOCs) located on Kennedy Space Center (KSC) property. The KSC Headquarters Building Area (KHQA) has been identified as SWMU 104 under KSC's RCRA Program. This report summarizes the Interim Measure (IM) conducted by Geosyntec Consultants (Geosyntec) for NASA under Indefinite Delivery Indefinite Quantity Contract NNK12CA13B at the KHQA to mitigate potential exposure to polychlorinated biphenyl (PCB)-affected media at the eastern side of LOC 2E. The IM activities were conducted in June and July 2015 to remediate PCBs above the FDEP Residential Direct-Exposure (R-) Soil Cleanup Target Level (SCTL) of 0.5 milligram per kilogram (mg/kg) established by Chapter 62-777, Florida Administrative Code. The IM was performed in accordance with the IM Work Plan (IMWP) approved by the FDEP, dated August 2012. IM activities were conducted in accordance with the KSC Generic PCB Work Plan (NASA 2007).

Sager, Eric D.↗

Search for Pulsations from a Nearby Millisecond Pulsar and Wasilewski 49: Mirror for a Hidden Seyfert 1 Nucleus

Five studies are reported in this final report. The recently discovered 5.3 ms pulsar J1012+5307 at a distance of 520 pc is in an area of the sky which is particularly deficient in absorbing gas. The column density along the line of sight is less than 7.5 x 10(exp 19) CM(exp -2) which facilitates soft X-ray observations. Halpern reported a possible ROSAT Position Sensitive Proportional Counter (PSPC) detection of the pulsar in a serendipitous, off-axis observation. We have now confirmed the X-ray emission of PSR J1012+,5307 in a 23 ksec observation with the ROSAT High Resolution Imager (HRI). A point source is detected within 3" of the radio position. Its count rate of 1.6 +/- 0.3 x 10(exp -3) s(exp -1) corresponds to an unabsorbed 0. 1-2.4 keV flux of 6.4 x 10(exp -14) ergs cm(exp -2) s(exp -1), similar to that reported previously. This counts-to-flux conversion is valid for N(sub H) = 5 x 10(exp 19) cm(exp -2), and either a power-law spectrum of photon index 2.5 or a blackbody of kT = 0.1 keV. The implied X-ray luminosity of 2.0 x 10(exp 30) ergs s(exp -1) is 5 X 10(exp -4) of the pulsar's spin-down power dot-E, and similar to that of the nearest millisecond pulsar J0437-4715, which is nearly a twin of J1012+5307 in P dot-E. We subjected the 37 photons (and 13 background counts) within the source region to a pulsar search, but no evidence for pulsation was found. The pulsar apparently emits over a large fraction of its rotation cycle, and the absence of sharp modulation can be taken as evidence for surface thermal emission, as is favored for PSR J0437-4715, rather than magnetospheric X-ray emission which is apparent in the sharp pulses of the much more energetic millisecond pulsar B1821-24. A further test of this interpretation will be made with a longer ROSAT observation, which will increase the number of photons collected by a factor of 5, and permit a more sensitive examination of the light curve for modulation due to emission from heated polar caps. If found, such modulation will be further evidence that surface reheating by the impact of particles accelerated along open fiel;d lines operates in these approximately 10(exp -9) year old pulsars. In a second study, a new AM Her star serendipitously in a 25 day observation was detected with the EUVE satellite. A coherent period of 85.82 min is present in the EUVE Deep Survey imager light curve of this source. A spectroscopic optical identification is made with a 19th magnitude blue star that has H and He emission lines, and broad cyclotron humps typical of a magnetic cataclysmic variable. A lower limit to the polar magnetic field of 50 MG is estimated from the spacing of the cyclotron harmonics. EUVE J0425.6-5714 is also detected in archival ROSAT HRI observations spanning two months, and its stable and highly structured light curve permits us to fit a coherent ephemeris linking the ROSAT and EUVE data over a 1.3 yr gap. The derived period is 85.82107 +/- 0.00020 min, and the ephemeris should be accurate to 0.1 cycles until the year 2005. A narrow but partial X-ray eclipse suggests that this object belongs to the group of AM Her stars whose viewing geometry is such that the accretion stream periodically occults the soft X-ray emitting accretion spot on the surface of the white dwarf. A non-detection of hard X-rays from ASCA observations that are contemporaneous with the ROSAT HRI shows that the soft X-rays must dominate by at least an order of magnitude, which is consistent with a known trend among AM Her stars with large magnetic field. This object should not be confused with the Seyfert galaxy IH 0419-577 (= LB 1727), another X-ray/EUV source which lies only 3'95 away, and was the principal target of these monitoring observations. In a third report; the identity of the persistent high-energy (> 100 MeV) gamma-ray sources in the Galaxy, still largely a mystery is investigated. The second installment of the EGRET (2EG) lists a total of 128 sources, of which 51 are likely or possibly identified with AGNs, five with rotation-powered pulsars, and one is the LMC. There are 71 unidentified sources, of which 33, or almost half, lie in the narrow band of absolute value of b < 10 degrees along the Galactic plane. This excess of low-latitude sources must, therefore, constitute a Galactic population that is either similar to the already identified gamma-ray pulsars, or an entirely new class of gamma-ray emitters associated with the disk population. We are continuing our program, begun in A06, that is aimed at intermediate-latitude sources, arguing that X-ray detection of them is the most plausible method of identifying the Galactic population. The sources at high latitude must statistically be mostly AGNS, and are more straightforwardly identified through radio and optical means. For the fourth report, identification of the EGRET Source the identity of the persistent, high-energy gamma-ray sources in the Galactic plane is a mystery. The most likely scenario is a population of middle-aged pulsars, many of which could be radio quiet like Geminga. We have an ongoing program of ROSAT, VLA, and optical observations of selected EGRET error circles at intermediate Galactic latitude. For one of these fields, at (l, b) = (106 degrees, +3), our complete census of X-ray and radio sources, reveals a remarkable association between a radio shell with unique properties, and a complete census of X-ray and radio sources reveals a remarkable association between a radio shell with unique properties, and a compact X-ray source. Further observations are needed to determine whether or not this source has a hard X-ray spectrum like that of other gamma ray pulsars and, ideally, to find its pulsations. A fifth report reviews, Wasilewski 49, an interacting pair of Seyfert galaxies at z = 0.063, one of which contains a hidden Seyfert I nucleus as evidenced by broad wings on its Balmer lines.

Halpern, Jules P.↗

Perceptual learning through optimization of attentional weighting: human versus optimal Bayesian learner

Human performance in visual detection, discrimination, identification, and search tasks typically improves with practice. Psychophysical studies suggest that perceptual learning is mediated by an enhancement in the coding of the signal, and physiological studies suggest that it might be related to the plasticity in the weighting or selection of sensory units coding task relevant information (learning through attention optimization). We propose an experimental paradigm (optimal perceptual learning paradigm) to systematically study the dynamics of perceptual learning in humans by allowing comparisons to that of an optimal Bayesian algorithm and a number of suboptimal learning models. We measured improvement in human localization (eight-alternative forced-choice with feedback) performance of a target randomly sampled from four elongated Gaussian targets with different orientations and polarities and kept as a target for a block of four trials. The results suggest that the human perceptual learning can occur within a lapse of four trials (<1 min) but that human learning is slower and incomplete with respect to the optimal algorithm (23.3% reduction in human efficiency from the 1st-to-4th learning trials). The greatest improvement in human performance, occurring from the 1st-to-2nd learning trial, was also present in the optimal observer, and, thus reflects a property inherent to the visual task and not a property particular to the human perceptual learning mechanism. One notable source of human inefficiency is that, unlike the ideal observer, human learning relies more heavily on previous decisions than on the provided feedback, resulting in no human learning on trials following a previous incorrect localization decision. Finally, the proposed theory and paradigm provide a flexible framework for future studies to evaluate the optimality of human learning of other visual cues and/or sensory modalities.

Non-NASA Center↗

[Characterization of Black and Dichothrix Cyanobacteria Based on the 16S Ribosomal RNA Gene Sequence]

My project focuses on characterizing different cyanobacteria in thrombolitic mats found on the island of Highborn Cay, Bahamas. Thrombolites are interesting ecosystems because of the ability of bacteria in these mats to remove carbon dioxide from the atmosphere and mineralize it as calcium carbonate. In the future they may be used as models to develop carbon sequestration technologies, which could be used as part of regenerative life systems in space. These thrombolitic communities are also significant because of their similarities to early communities of life on Earth. I targeted two cyanobacteria in my research, Dichothrix spp. and whatever black is, since they are believed to be important to carbon sequestration in these thrombolitic mats. The goal of my summer research project was to molecularly identify these two cyanobacteria. DNA was isolated from each organism through mat dissections and DNA extractions. I ran Polymerase Chain Reactions (PCR) to amplify the 16S ribosomal RNA (rRNA) gene in each cyanobacteria. This specific gene is found in almost all bacteria and is highly conserved, meaning any changes in the sequence are most likely due to evolution. As a result, the 16S rRNA gene can be used for bacterial identification of different species based on the sequence of their 16S rRNA gene. Since the exact sequence of the Dichothrix gene was unknown, I designed different primers that flanked the gene based on the known sequences from other taxonomically similar cyanobacteria. Once the 16S rRNA gene was amplified, I cloned the gene into specialized Escherichia coli cells and sent the gene products for sequencing. Once the sequence is obtained, it will be added to a genetic database for future reference to and classification of other Dichothrix sp.

Ortega, Maya↗

OSIRIS-REx Touch-And-Go (TAG) Mission Design and Analysis

The Origins Spectral Interpretation Resource Identification Security Regolith Explorer (OSIRIS-REx) mission is a NASA New Frontiers mission launching in 2016 to rendezvous with the near-Earth asteroid (101955) 1999 RQ36 in late 2018. After several months in formation with and orbit about the asteroid, OSIRIS-REx will fly a Touch-And-Go (TAG) trajectory to the asteroid s surface to obtain a regolith sample. This paper describes the mission design of the TAG sequence and the propulsive maneuvers required to achieve the trajectory. This paper also shows preliminary results of orbit covariance analysis and Monte-Carlo analysis that demonstrate the ability to arrive at a targeted location on the surface of RQ36 within a 25 meter radius with 98.3% confidence.

Berry, Kevin↗

Volume of Impact Melt Generated by the Formation of the South Pole-Aitken Basin

The South Pole-Aitken Basin (SPA) is the largest, deepest, and oldest identified basin on the Moon and as such contains surfaces that are unique due to their age, composition, and depth of origin in the lunar crust [1-5] (Figure 1). SPA has been a target of intense interest as an area for robotic sample return in order to determine the age of the basin and the composition and origin of its interior [6-8]. In response to this interest there have been several efforts to estimate the likely provenance of regolith material within central SPA [9-12]. These model estimates suggest that, despite the formation of basins and craters following SPA, the regolith within SPA is dominated by locally derived material. An assumption of these models has been that the locally derived material is primarily SPA impact-melt as opposed to local basement material (e.g. unmelted lower crust). However, the definitive identification of SPA derived impact melt on the basin floor, either by remote sensing [5, 13] or via photogeology [2, 14] is extremely difficult due to the number of subsequent impacts and volcanic activity [4].

Petro, Noah E.↗

Visible-near Infrared Spectral Indices for Mapping Mineralogy and Chemistry with OSIRIS-Rex

The primary objective of the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission is to return to Eartha pristine sample of carbonaceous material from the primitive asteroid (101955) Bennu. To support compositional mapping of Bennu as part of sample site selection and characterization, we tested 95 spectral indices on visible to near infrared laboratory reflectance data from minerals and carbonaceous meteorites. Our aim was to determine which indices reliably identify spectral features of interest. Most spectral indices had high positive detection rates when applied to spectra of pure, single-component materials. The meteorite spectra have fewer and weaker absorption features and, as a result, fewer detections with the spectral indices. Indices targeting absorptions at 0.7 and 2.7–3lm, which are attributable to hydrated minerals, were most successful for the meteorites. Based on these results, we identified a set of 17 indices that are most likely to be useful at Bennu. These indices detect olivines, pyroxenes, carbonates, water/OH-bearing minerals, serpentines, ferric minerals, and organics. Particle size and albedo are known to affect band depth but had a negligible impact on interpretive success with spectral indices. Preliminary analysis of the disk-integrated Bennu spectrum with these indices is consistent with expectations given the observed absorption near 3lm. Our study prioritizes spectral indices to be used for OSIRIS-REx spectral analysis and mapping and informs the reliability of all index-derived data products, including a science value map for sample site selection.

Hannah H. Kaplan↗

Mars - Remote spectral identification of H2O frost and mineral hydrate

A reflectance spectrum (0.62-2.6 microns) of Mars (integral disk) is obtained using a newly developed IR spectrometer at the 2.25 m telescope on Mauna Kea, Hawaii. Details of the instrument, observations, and data reduction are presented. Several distinct absorption features are evident that were apparently caused by H2O, but the positions and intensities of the features are quite unusual. In summary, the regolith is probably not as desiccated and dehydrated as the full disk reflectance spectrum and Viking soil analyses would suggest. The surface materials become desiccated and dehydrated as a result of solar UV effects and because of the relative adsorption and desorption rates during the strong diurnal cycling. There may be significant amounts of H2O at depth, and in the Solis Lacus region the H2O reservoir may extend to within a few centimeters of the surface. The Solis Lacus region may therefore be an important target for future Mars landing or sample return mission.

Huguenin, R. L.↗

Identification of a nuclear localization sequence in the polyomavirus capsid protein VP2

A nuclear localization signal (NLS) has been identified in the C-terminal (Glu307-Glu-Asp-Gly-Pro-Gln-Lys-Lys-Lys-Arg-Arg-Leu318) amino acid sequence of the polyomavirus minor capsid protein VP2. The importance of this amino acid sequence for nuclear transport of newly synthesized VP2 was demonstrated by a genetic "subtractive" study using the constructs pSG5VP2 (expressing full-length VP2) and pSG5 delta 3VP2 (expressing truncated VP2, lacking amino acids Glu307-Leu318). These constructs were transfected into COS-7 cells, and the intracellular localization of the VP2 protein was determined by indirect immunofluorescence. These studies revealed that the full-length VP2 was localized in the nucleus, while the truncated VP2 protein was localized in the cytoplasm and not transported to the nucleus. A biochemical "additive" approach was also used to determine whether this sequence could target nonnuclear proteins to the nucleus. A synthetic peptide identical to VP2 amino acids Glu307-Leu318 was cross-linked to the nonnuclear proteins bovine serum albumin (BSA) or immunoglobulin G (IgG). The conjugates were then labeled with fluorescein isothiocyanate and microinjected into the cytoplasm of NIH 3T6 cells. Both conjugates localized in the nucleus of the microinjected cells, whereas unconjugated BSA and IgG remained in the cytoplasm. Taken together, these genetic subtractive and biochemical additive approaches have identified the C-terminal sequence of polyoma-virus VP2 (containing amino acids Glu307-Leu318) as the NLS of this protein.

Non-NASA Center↗

Evaluation of 2-μm Pulsed Integrated Path Differential Absorption Lidar for Carbon Dioxide Measurement—Technology Developments, Measurements, and Path to Space

The societal benefits of understanding climate change through the identification of global carbon dioxide sources and sinks led to the recommendation for NASA's Active Sensing of Carbon Dioxide Emissions over Nights, Days, and Seasons space-based mission for global carbon dioxide measurements. For more than 15 years, the NASA Langley Research Center has developed several carbon dioxide active remote sensors using the differential absorption lidar technique operating at 2-μm wavelength. Recently, an airborne double-pulsed integrated path differential absorption lidar was developed, tested, and validated for atmospheric carbon dioxide measurement. Results indicated 1.02% column carbon dioxide measurement uncertainty and 0.28% bias over the ocean. Currently, this technology is progressing toward triple-pulse operation targeting both atmospheric carbon dioxide and water vapor-the dominant interfering molecule on carbon dioxide remote sensing. Measurements from the double-pulse lidar and the advancement of the triple-pulse lidar development are presented. In addition, measurement simulations with a space-based IPDA lidar, incorporating new technologies, are also presented to assess feasibility of carbon dioxide measurements from space.

Singh, Upendra N.↗

Visible–near infrared spectral indices for mapping mineralogy and chemistry with OSIRIS-REx

The primary objective of the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission is to return to Earth a pristine sample of carbonaceous material from the primitive asteroid (101955) Bennu. To support compositional mapping of Bennu as part of sample site selection and characterization, we tested 95 spectral indices on visible to near infrared laboratory reflectance data from minerals and carbonaceous meteorites. Our aim was to determine which indices reliably identify spectral features of interest. Most spectral indices had high positive detection rates when applied to spectra of pure, single-component materials. The meteorite spectra have fewer and weaker absorption features and, as a result, fewer detections with the spectral indices. Indices targeting absorptions at 0.7 and 2.7–3 µm, which are attributable to hydrated minerals, were most successful for the meteorites. Based on these results, we identified a set of 17 indices that are most likely to be useful at Bennu. These indices detect olivines, pyroxenes, carbonates, water/OH-bearing minerals, serpentines, ferric minerals, and organics. Particle size and albedo are known to affect band depth but had a negligible impact on interpretive success with spectral indices. Preliminary analysis of the disk-integrated Bennu spectrum with these indices is consistent with expectations given the observed absorption near 3 lm. Our study prioritizes spectral indices to be used for OSIRIS-REx spectral analysis and mapping and informs the reliability of all index-derived data products, including a science value map for sample site selection.

Hannah H. Kaplan↗

Optimizing serendipitous detections of kilonovae: cadence and filter selection

The rise of multimessenger astronomy has brought with it the need to exploit all available data streams and learn more about the astrophysical objects that fall within its breadth. One possible avenue is the search for serendipitous optical/near-infrared counterparts of gamma-ray bursts (GRBs) and gravitational-wave (GW) signals, known as kilonovae. With surveys such as the Zwicky Transient Facility (ZTF), which observes the sky with a cadence of ∼3 d, the existing counterpart locations are likely to be observed; however, due to the significant amount of sky to explore, it is difficult to search for these fast-evolving candidates. Thus, it is beneficial to optimize the survey cadence for realtime kilonova identification and enable further photometric and spectroscopic observations. We explore how the cadence of wide field-of-view surveys like ZTF can be improved to facilitate such identifications. We show that with improved observational choices, e.g. the adoption of three epochs per night on a ∼ nightly basis, and the prioritization of redder photometric bands, detection efficiencies improve by about a factor of two relative to the nominal cadence. We also provide realistic hypothetical constraints on the kilonova rate as a form of comparison between strategies, assuming that no kilonovae are detected throughout the long-term execution of the respective observing plan. These results demonstrate how an optimal use of ZTF increases the likelihood of kilonova discovery independent of GWs or GRBs, thereby allowing for a sensitive search with less interruption of its nominal cadence through Target of Opportunity programs.

methods: observational↗

The Project “Analogs for Venus’ Geologically Recent Surfaces” (AVENGERS): A Comprehensive Database of Terrestrial Active Volcanoes for the Analysis of Ongoing Volcanism on Venus

The recently selected missions to Venus have opened a new era for the exploration of the Earth’s twin planet. As the Venus decade approaches, it is crucial to set the science goals for the future orbiting and in-situ investigations. One of the key science targets on Venus is certainly represented by the young topographic rises, which can be defined as the surface expression of underlying mantle plumes. These areas can be considered as the geologically youngest regions of Venus, being characterized by recent volcanic and tectonic activity. Studying areas of active volcanism and tectonism on Venus is crucial because it can reveal clues on the geologic past of the planet, as well as provide information about the volatile content of its interior and about the formation of its dense atmosphere. To this regard, the Project “Analogs for VENus’ GEologically Recent Surfaces” (AVENGERS) aims to build a database of Terrestrial analog sites for the analysis and identification of recent and possibly ongoing volcanic as well as tectonic activity on Venus to be investigated by the future missions. The Project AVENGERS will be a powerful tool for allowing a more efficient exploitation of the wealth of data to be provided by the future investigations of Venus during the upcoming decade.

P D Incecco↗

The terrestrial cratering record. I - Current status of observations

The location, size and principle characteristics of the currently known proven and probable terrestrial impact craters are compiled. A crater is classified as proven if the structure is associated with meteoritic fragments, and probable if shock metamorphic effects are observed in the target rocks. Proven impact structures have been found to be Pleistocene to Recent in age, while probable impact structures range from Precambrian to Pleistocene. Diameter and age relationships are used to show that a 20 km impact structure will be recognizable as a crater for up to 600 million years, and smaller structures will have shorter lifetimes. Depth-diameter relationships for terrestrial craters show them to be intrinsically shallower than their lunar counterparts, and a transition in crater morphology from simple, or bowl-shaped with an uplifted rim, to complex, with an uplifted center and a depressed rim, is observed with increasing diameter. Shock metamorphic studies have lead to the identification of the type of bolide at a number of probable impact craters, supporting meteoritic origins.

Grieve, R. A. F.↗

NASA Earth Observations (NEO): Data Access for Informal Education and Outreach

The NEO (NASA Earth Observations) web space is currently under development with the goal of significantly increasing the demand for NASA remote sensing data while dramatically simplifying public access to georeferenced images. NEO will target the unsophisticated, nontraditional data users who are currently underserved by the existing data ordering systems. These users will include formal and informal educators, museum and science center personnel, professional communicators, and citizen scientists and amateur Earth observers. Users will be able to view and manipulate georeferenced browse imagery and, if they desire, download directly or order the source HDF data from the data provider (e.g., NASA DAAC or science team) via a single, integrated interface. NE0 will accomplish this goal by anticipating users expectations and knowledge level, thus providing an interface that presents material to users in a more simplified manner, without relying upon the jargon/technical terminology that make even the identification of the appropriate data set a significant hurdle. NEO will also act as a gateway that manages users expectations by providing specific details about images and data formats, developing tutorials regarding the manipulation of georeferenced imagery and raw data, links to software tools and ensuring that users are able to get the image they want in the format they want as easily as possible.

Ward, Kevin↗

Investigating the Impact of X-Ray Computed Tomography Imaging on Soluble Organic Matter in the Murchison Meteorite: Implications for Bennu Sample Analyses

X-ray computed tomography (XCT) is a valuable reconnaissance tool for three-dimensional imaging and identification of distinct lithologies in extraterrestrial samples. It will be used as part of the preliminary examination of samples returned from asteroid (101955) Bennu by the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission. However, it must first be established whether x-rays generated during XCT could degrade or alter the organic composition of the returned samples by radiolysis. To test this, we split a crushed sample of the Murchison CM2 meteorite, kept one portion as a control, and irradiated the other portion up to the maximum x-ray dosage (~180 Gy) that a Bennu sample would experience during an XCT imaging experiment. We then extracted organic compounds from both splits and conducted (i) nontargeted soluble organic analyses to compare the chemical distributions of C-, H-, O-, N-, and S-bearing species and (ii) targeted measurements to quantify the abundances of 96 individual soluble organic molecules that included protein amino acids, amines, carboxylic acids, hydroxy acids, carbonyl compounds, polycyclic aromatic hydrocarbons, alcohols, sugars, and N-heterocycles. We found that XCT imaging of the Murchison meteorite had no measurable impact on the relative abundances or enantiomeric compositions of most of the soluble organic compounds targeted in this study. Elevated total abundances of several soluble organic compound classes were observed in the XCT-scanned Murchison sample relative to the control. This is likely related to particle size heterogeneity and specific surface area differences between the sample aliquots used for the extractions, rather than a result of the x-ray exposure. Assuming the samples returned from asteroid Bennu by OSIRIS-REx have a similar composition to carbonaceous chondrites, these data provide confidence that XCT will not significantly alter their soluble organic compositions.

Daniel P Glavin↗

Formation of South Pole-Aitken Basin as the Result of an Oblique Impact: Implications for Melt Volume and Source of Exposed Materials

The South Pole-Aitken Basin (SPA) is the largest, deepest, and oldest identified basin on the Moon and contains surfaces that are unique due to their age, composition, and depth of origin in the lunar crust [1-3] (Figure 1). SPA has been a target of interest as an area for robotic sample return in order to determine the age of the basin and the composition and origin of its interior [3-6]. As part of the investigation into the origin of SPA materials there have been several efforts to estimate the likely provenance of regolith material in central SPA [5, 6]. These model estimates suggest that, despite the formation of basins and craters following SPA, the regolith within SPA is dominated by locally derived material. An assumption inherent in these models has been that the locally derived material is primarily SPA impact-melt as opposed to local basement material (e.g. unmelted lower crust). However, the definitive identification of SPA derived impact melt on the basin floor, either by remote sensing [2, 7] or via photogeology [8] is extremely difficult due to the number of subsequent impacts and volcanic activity [3, 4]. In order to identify where SPA produced impact melt may be located, it is important to constrain both how much melt would have been produced in a basin forming impact and the likely source of such melted material. Models of crater and basin formation [9, 10] present clear rationale for estimating the possible volumes and sources of impact melt produced during SPA formation. However, if SPA formed as the result of an oblique impact [11, 12], the volume and depth of origin of melted material could be distinct from similar material in a vertical impact [13].

Petro, N. E.↗