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At least 397 records · Page 22

The effect of finite field size on classification and atmospheric correction

The atmospheric effect on the upward radiance of sunlight scattered from the Earth-atmosphere system is strongly influenced by the contrasts between fields and their sizes. For a given atmospheric turbidity, the atmospheric effect on classification of surface features is much stronger for nonuniform surfaces than for uniform surfaces. Therefore, the classification accuracy of agricultural fields and urban areas is dependent not only on the optical characteristics of the atmosphere, but also on the size of the surface do not account for the nonuniformity of the surface have only a slight effect on the classification accuracy; in other cases the classification accuracy descreases. The radiances above finite fields were computed to simulate radiances measured by a satellite. A simulation case including 11 agricultural fields and four natural fields (water, soil, savanah, and forest) was used to test the effect of the size of the background reflectance and the optical thickness of the atmosphere on classification accuracy. It is concluded that new atmospheric correction methods, which take into account the finite size of the fields, have to be developed to improve significantly the classification accuracy.

Kaufman, Y. J.↗

Chemistry and evolution of Titan's atmosphere

The chemistry and evolution of Titan's atmosphere are reviewed, in light of the scientific findings from the Voyager mission. It is argued that the present N2 atmosphere may be Titan's initial atmosphere, rather than one photochemically derived from an original NH3 atmosphere. The escape rate of hydrogen from Titan is controlled by photochemical production from hydrocarbons. CH4 is irreversibly converted to less hydrogen-rich hydrocarbons, which over geologic time accumulate on the surface to a layer thickness of about 0.5 km. Magnetospheric electrons interacting with Titan's exosphere may dissociate enough N2 into hot, escaping N atoms to remove about 0.2 of Titan's present atmosphere over geologic time. The energy dissipation of magnetospheric electrons exceeds solar EUV energy deposition in Titan's atmosphere by an order of magnitude, and is the principal driver of nitrogen photochemistry. The environmental conditions in Titan's upper atmosphere are favorable to building up complex molecules, particularly in the north polar cap region.

Strobel, D. F.↗

Different atmospheric effects in remote sensing of uniform and nonuniform surfaces

The atmospheric effect on the radiance of sunlight scattered from the earth-atmosphere system is greatly dependent on the surface reflectance pattern, the contrast between adjacent fields, and the optical properties of the atmosphere. In addition, the atmospheric effect is described by the range and magnitude of the adjacency effects, the atmospheric modulation transfer function, and the apparent spatial resolution of remotely sensed imagery. This paper discusses the atmospheric effect on classification of surface features and shows that surface nonuniformity can be used for developing procedures to remove the atmospheric effect from the satellite imagery.

Kaufman, Y. J.↗

Constraints on bulk composition, seasonal variation, and global dynamics of Pluto's atmosphere

The potential seasonal variation of Pluto's atmosphere is investigated by considering the behavior of the candidate atmospheric constituents Ne, N2, CO, O2, and Ar when individually mixed with CH4. The effects of diurnal and latitudinal variation of insolation and eclipses on the atmosphere are also studied. Seasonal effects are shown to dominate. It is shown that the atmospheric bulk may not be a minimum near aphelion but rather at intermediate distances from the sun during summer/winter where inadequate ice deposits may allow the atmosphere to collapse by freezing out over winter latitudes. The likely global circulation regimes for each model atmosphere are investigated as a function of temperature, and it is concluded that if CH4, O2, or CO dominates the atmosphere, Pluto will exhibit cyclic variations between an axially symmetric circulation system at perihelion and a baroclinic wave regime at aphelion. If N2 dominates the wave regime should hold continuously.

Stern, S. A.↗

Atmospheric effect on classification of finite fields

The atmospheric effect on the upward radiance of sunlight scattered from the earth-atmosphere system is strongly influenced by the contrasts between fields and their sizes. In this paper, the radiances above finite fields are computed to simulate radiances measured by a satellite. A simulation case including 11 agricultural fields and four natural fields (water, soil, savanah, and forest) is used to test the effect of field size, background reflectance, and optical thickness of the atmosphere on the classification accuracy. For a given atmospheric turbidity, the atmospheric effect on classification of surface features may be much stronger for nonuniform surfaces than for uniform surfaces. Therefore, the classification accuracy of agricultural fields and urban areas is dependent not only on the optical characteristics of the atmosphere, but also on the size of the surface elements to be classified and their contrasts. It is concluded that new atmospheric correction methods, which take into account the finite size of the fields, are needed.

Kaufman, Y. J.↗

Modeling the middle atmosphere circulation

Some of the motivations for constructing models of the middle atmosphere circulation are given. These are as follows: (1) to provide a better understanding of middle atmosphere dynamics; (2) to study the coupling of middle atmosphere dynamics with radiation and chemistry; (3) to study the sensitivity of tropospheric climate modeling and/or weather forecasting to changes in the middle atmosphere; (4) to better understand the limitations of more simplified models; (5) to supply a proxy for atmospheric data for diagnostic analysis; and finally, (6) for forecast-analysis of data. Different types of models are discussed in relation to their anticipated use. Various model simplifications, such as using the quasi-geostrophic set of equations and simplified radiative transfer, are discussed as are some of the consequences of these simplifications. Some of the accomplishments of middle atmosphere circulation modeling are presented as are some of the difficulties in existing models. Finally, some of the problems in constructing and verifying middle atmosphere circulation models are discussed.

Geller, M. A.↗

Atmospheric effects on remote sensing of surface reflectance

This paper reviews the atmospheric effects on remote sensing of surface reflectance. The scattering and absorption of sunlight by atmospheric molecules and aerosols affects the quality of images of the surface remotely sensed from satellites and aircrafts. The concentration and characteristics of the atmospheric aerosols vary from place to place and vary with time. The effect of atmospheric aerosols on the upward radiance depends on their optical thickness, scattering phase function and absorption. These parameters result from the aerosol concentration, composition, and the relative humidity. For high resolution images the aerosol scale height is also of importance. The radiative transfer theory that predicts the atmospheric radiances for a given surface and atmosphere is a well established theory for the case of uniform surfaces (or low resolution data). Some radiative transfer models exist for nonuniform surfaces and others are being developed. Recent field experiment and laboratory simulation data confirm the need for these models and can be used for their testing. It is shown that the atmospheric effect reduces the apparent resolution of satellite imagery and causes errors in the classification of surface fields. Suggestions for correction procedures are given. Such corrections can be based on ground observations, on satellite radiances above dark areas, or on climatologic information, depending on the accuracy of the corrections needed. The chosen correction algorithm depends also on the image resolution and the specific remote sensing application.

Kaufman, Y. J.↗

Atmospheric-water absorption features near 2.2 micrometers and their importance in high spectral resolution remote sensing

Selective absorption of electromagnetic radiation by atmospheric gases and water vapor is an accepted fact in terrestrial remote sensing. Until recently, only a general knowledge of atmospheric effects was required for analysis of remote sensing data; however, with the advent of high spectral resolution imaging devices, detailed knowledge of atmospheric absorption bands has become increasingly important for accurate analysis. Detailed study of high spectral resolution aircraft data at the U.S. Geological Survey has disclosed narrow absorption features centered at approximately 2.17 and 2.20 micrometers not caused by surface mineralogy. Published atmospheric transmission spectra and atmospheric spectra derived using the LOWTRAN-5 computer model indicate that these absorption features are probably water vapor. Spectral modeling indicates that the effects of atmospheric absorption in this region are most pronounced in spectrally flat materials with only weak absorption bands. Without correction and detailed knowledge of the atmospheric effects, accurate mapping of surface mineralogy (particularly at low mineral concentrations) is not possible.

Kruse, F. A.↗

Estimation of absolute water surface temperature based on atmospherically corrected thermal infrared multispectral scanner digital data

Airborne remote sensing systems, as well as those on board Earth orbiting satellites, sample electromagnetic energy in discrete wavelength regions and convert the total energy sampled into data suitable for processing by digital computers. In general, however, the total amount of energy reaching a sensor system located at some distance from the target is composed not only of target related energy, but, in addition, contains a contribution originating from the atmosphere itself. Thus, some method must be devised for removing or at least minimizing the effects of the atmosphere. The LOWTRAN-6 Program was designed to estimate atmospheric transmittance and radiance for a given atmospheric path at moderate spectral resolution over an operational wavelength region from 0.25 to 28.5 microns. In order to compute the Thermal Infrared Multispectral Scanner (TIMS) digital values which were recorded in the absence of the atmosphere, the parameters derived from LOWTRAN-6 are used in a correction equation. The TIMS data were collected at 1:00 a.m. local time on November 21, 1983, over a recirculating cooling pond for a power plant in southeastern Mississippi. The TIMS data were analyzed before and after atmospheric corrections were applied using a band ratioing model to compute the absolute surface temperature of various points on the power plant cooling pond. The summarized results clearly demonstrate the desirability of applying atmospheric corrections.

Anderson, James E.↗

Dissipative tides - Application to Venus' lower atmosphere

A linearized planetary scale wave model is used to investigate the effects of thermal and mechanical damping on atmospheric tides. When the damping rate is comparable to the frequency of solar diurnal forcing the circulation consists of three parts: a classical vertically propagating 'atmospheric tide' in the upper atmosphere, a simple thermally direct subsolar-to-antisolar circulation or 'Halley cell' in most of the lower atmosphere, and finally, a reversed 'anti-Halley cell' near the surface. The near-surface circulation produces horizontal divergence near the subsolar point. While tides are a frequently encountered phenomenon (Venus, earth, and Mars), there is so far no observational evidence of a Halley circulation in any planetary atmosphere. A subsolar-antisolar circulation might be possible in Venus' slowly rotating lower atmosphere if the mechanical dissipation time scale is of the order of or less than a Venusian day. Such a circulation could be a factor in maintaining the superrotation of Venus' upper atmosphere.

Covey, Curt↗

A component decomposition model for evaluating atmospheric effects in remote sensing

A radiance value of a target pixel recorded by a remote sensor can be decomposed into three components: (1) attenuated target signature, (2) pure atmospheric radiation, and (3) the contribution made by the ground through the atmospheric scattering process. Given the meteorological and optical parameters of a layer-structured atmosphere, its transmittance and radiance distribution can be accurately calculated with a plane-parallel radiative transfer model. For a uniform surface, the ground contribution can be obtained by comparing radiances for an atmosphere over a black but nonemitting surface and the same atmosphere with an underlying ground of given albedo or temperature. For an inhomogeneous surface, the first two components remain the same as long as the surface is a plane. The third may be estimated using the locally averaged top-of-atmosphere radiance. An atmospheric point spread function is calculated by a Monte Carlo approach and is used for retrieving the ground signature through a deconvolution procedure.

Li, S.↗

Mechanisms and observations for isotope fractionation of molecular species in planetary atmospheres

Chemcial and physical processes which may give rise to isotope fractionation of molecular species in the atmospheres of both earth and other planets are reviewed, along with observations of isotopically substituted molecules in planetary atmospheres. Mechanisms for production of isotope fractionation considered include atmospheric escape and the effect of isotope substitution on equilibrium constants (including those of phase changes), photolysis rates, and chemical reaction rates. The isotopes considered for compounds in the terrestrial atmosphere include D, T, C-13, C-14, N-15, O-18, and S-34. Compounds for which data about isotopic composition in the terrestrial atmosphere are summarized include CO, CO2, O3, N2O, NH3, SO2, H2S, H2O, H, H2, and CH4. Planetary atmospheres discussed include those of Venus, Mars, Jupiter, Saturn, Uranus, and Titan; isotopes reviewed are D, C-13, N-15, and O-18. Suggestions for additional research in the area of isotopically substituted molecules in atmospheres are offered.

Kaye, Jack A.↗

A cloud model simulation of space shuttle exhaust clouds in different atmospheric conditions

A three-dimensional cloud model was used to characterize the dominant influence of the environment on the Space Shuttle exhaust cloud. The model was modified to accept the actual heat and moisture from rocket exhausts and deluge water as initial conditions. An upper-air sounding determined the ambient atmosphere in which the cloud could grow. The model was validated by comparing simulated clouds with observed clouds from four actual Shuttle launches. The model successfully produced clouds with dimensions, rise, decay, liquid water contents and vertical motion fields very similar to observed clouds whose dimensions were calculated from 16 mm film frames. Once validated, the model was used in a number of different atmospheric conditions ranging from very unstable to very stable. In moist, unstable atmospheres simulated clouds rose to about 3.5 km in the first 4 to 8 minutes then decayed. Liquid water contents ranged from 0.3 to 1.0 g kg-1 mixing ratios and vertical motions were from 2 to 10 ms-1. An inversion served both to reduce entrainment (and erosion) at the top and to prevent continued cloud rise. Even in the most unstable atmospheres, the ground cloud did not rise beyond 4 km and in stable atmospheres with strong low level inversions the cloud could be trapped below 500 m. Wind shear strongly affected the appearance of both the ground cloud and vertical column cloud. The ambient low-level atmospheric moisture governed the amount of cloud water in model clouds. Some dry atmospheres produced little or no cloud water. One case of a simulated TITAN rocket explosion is also discussed.

Chen, C.↗

Atmospheric Trace Molecule Spectroscopy (ATMOS)

The Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment is a space-borne investigation designed to obtain fundamental information related to the chemistry and physics of the earth's upper atmosphere (20 to 120 km altitude). The instrument, a high resolution (0.01/cm) interferometric spectrometer, measures the atmospheric absorption of solar radiation over the wavelength range from 2 to 16 micrometers, a spectral band which encompasses active transitions of all of the molecular species of current importance in upper atmospheric studies. There are two major aspects to the experiment: (1) the determination of the detailed compositional structure of the stratosphere and mesosphere, and its global, seasonal, and long-term variability; and (2) the study of the partitioning of absorbed solar energy at levels in the atmosphere characterized by dissociation of many of the constituents and by the breakdown of thermodynamic equilibrium. Characteristics of ATMOS are given. This experiment will be part of the atmospheric science research payload flown on the Atmospheric Laboratory for Applications and Science (ATLAS 1) NASA mission planned for late 1990.

Farmer, C. B.↗

Geochemical cycles of atmospheric gases

The processes that control the atmosphere and atmospheric changes are reviewed. The geochemical cycles of water vapor, nitrogen, carbon dioxide, oxygen, and minor atmospheric constituents are examined. Changes in atmospheric chemistry with time are discussed using evidence from the rock record and analysis of the present atmosphere. The role of biological evolution in the history of the atmosphere and projected changes in the future atmosphere are considered.

Walker, J. C. G.↗

Chemical kinetics and modeling of planetary atmospheres

A unified overview is presented for chemical kinetics and chemical modeling in planetary atmospheres. The recent major advances in the understanding of the chemistry of the terrestrial atmosphere make the study of planets more interesting and relevant. A deeper understanding suggests that the important chemical cycles have a universal character that connects the different planets and ultimately link together the origin and evolution of the solar system. The completeness (or incompleteness) of the data base for chemical kinetics in planetary atmospheres will always be judged by comparison with that for the terrestrial atmosphere. In the latter case, the chemistry of H, O, N, and Cl species is well understood. S chemistry is poorly understood. In the atmospheres of Jovian planets and Titan, the C-H chemistry of simple species (containing 2 or less C atoms) is fairly well understood. The chemistry of higher hydrocarbons and the C-N, P-N chemistry is much less understood. In the atmosphere of Venus, the dominant chemistry is that of chlorine and sulfur, and very little is known about C1-S coupled chemistry. A new frontier for chemical kinetics both in the Earth and planetary atmospheres is the study of heterogeneous reactions. The formation of the ozone hole on Earth, the ubiquitous photochemical haze on Venus and in the Jovian planets and Titan all testify to the importance of heterogeneous reactions. It remains a challenge to connect the gas phase chemistry to the production of aerosols.

Yung, Yuk L.↗

Fractionation of terrestrial neon by hydrodynamic hydrogen escape from ancient steam atmospheres

Atmospheric neon is isotopically heavier than mantle neon. By contrast, nonradiogenic mantle Ar, Kr, and Xe are not known to differ from the atmosphere. These observations are most easily explained by selective neon loss to space; however, neon is much too massive to escape from the modern atmosphere. Steam atmospheres are a likely, if intermittent, feature of the accreting Earth. They occur because, on average, the energy liberated during accretion places Earth above the runaway greenhouse threshold, so that liquid water is not stable at the surface. It is found that steam atmospheres should have lasted some ten to fifty million years. Hydrogen escape would have been vigorous, but abundant heavy constituents would have been retained. There is no lack of plausible candidates; CO2, N2, or CO could all suffice. Neon can escape because it is less massive than any of the likely pollutants. Neon fractionation would have been a natural byproduct. Assuming that the initial Ne-20/Ne-22 ratio was solar, it was found that it would have taken some ten million years to effect the observed neon fractionation in a 30 bar steam atmosphere fouled with 10 bars of CO. Thicker atmospheres would have taken longer; less CO, shorter. This mechanism for fractionating neon has about the right level of efficiency. Because the lighter isotope escapes much more readily, total neon loss is pretty minimal; less than half of the initial neon endowment escapes.

Zahnle, K.↗

Gas chromatographic concepts for the analysis of planetary atmospheres

Over the last few years, new gas chromatographic (GC) concepts were developed for use on board spacecraft or any other restricted environments for determining the chemical composition of the atmosphere and surface material of various planetary bodies. Future NASA Missions include an entry probe that will be sent to Titan and various spacecraft that will land on Mars. In order to be able to properly respond to the mission science requirements and physical restrictions imposed on the instruments by these missions, GC analytical techniques are being developed. Some of these techniques include hardware and mathematical techniques that will improve GC sensitivity and increase the sampling rate of a GC descending through a planetary atmosphere. The technique of Multiplex Gas Chromatography (MGC) is an example of a technique that was studied in a simulated Titan atmosphere. In such an environment, the atmospheric pressure at instrument deployment is estimated to be a few torr. Thus, at such pressures, the small amount of sample that is acquired might not be enough to satisfy the detection requirements of the gas chromatograph. In MGC, many samples are pseudo-randomly introduced to the chromatograph without regard to elution of preceding components. The resulting data is then reduced using mathematical techniques such as cross-correlation of Fourier Transforms. Advantages realized from this technique include: improvement in detection limits of several orders of magnitude and increase in the number of analyses that can be conducted in a given period of time. Results proving the application of MGC at very low pressures emulating the same atmospheric pressures that a Titan Probe will encounter when the instruments are deployed are presented. The sample used contained hydrocarbons that are expected to be found in Titan's atmosphere. In addition, a new selective modulator was developed to monitor water under Martian atmospheric conditions. Since this modulator is selective only to water, the need for a GC column is eliminated. This results in further simplification of the instrument.

Valentin, J. R.↗