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At least 397 records · Page 22

The extreme wings of atomic emission and absorption lines

Consideration of the extreme wings of atomic and molecular emission and absorption lines in low pressure gases. Classical and semiclassical results are compared with accurate quantal calculations of the self-broadening of Lyman-alpha in the hydrogen absorption spectrum that arises from quasimolecular transition. The results of classical, quantal, and semiclassical calculations of the absorption coefficient in the red wing are shown for temperatures of 500, 200, and 100 K. The semiclassical and quantal spectra agree well in shape at 500 K. Various other findings are discused.

Dalgarno, A.↗

Titan - Unidentified strong absorptions in the photometric infrared

The morphology of Titan's infrared spectral features reveals a pattern of differences with respect to Saturn's bands. Titan's bands exhibit a progressive washing out with increasing wavelength relative to the corresponding bands in Saturn's spectrum. Unidentified absorption features of apparently gaseous origin appear in the long-wavelength wing of Titan's 1-micron CH4 band complex with considerably greater strength. Greater absorption is also observed in the 1.1 micron region. Not all of the phenomena can be explained by enhanced CH4 absorption, so Titan's spectrum implies the existence of another spectroscopically active gas. Several candidates for this gas are briefly considered.

Trafton, L.↗

Absorption of trapped particles by Jupiter's moons

Inclusion of absorption effects of the four innermost moons in the radial transport equations for electrons and protons in Jupiter's magnetosphere. It is found that the phase space density n at 2 Jupiter radii for electrons with equatorial pitch angles less than 69 deg is reduced by a factor of 42,000 when lunar absorption is included in the calculation. For protons with equatorial pitch angles less than 69 deg the corresponding reduction factor is 2,300,000. The effect of the satellites becomes progressively weaker for both electrons and protons as equatorial pitch angles of 90 deg are approached, because the likelihood of impacting a satellite becomes progressively smaller. The large density decreases found at the orbits of Io, Europa, and Ganymede result in corresponding particle flux decreases that should be observed by spacecraft making particle measurements in Jupiter's magnetosphere. The characteristic signature of satellite absorption should be a downward-pointing vertex in the flux versus radius curve at the L value corresponding to each satellite.

Hess, W. N.↗

Remote atmospheric sensing with an airborne laser absorption spectrometer

A laser absorption spectrometer, using an infrared laser transmitter and a heterodyne radiometer, can be used from an aircraft or spacecraft to measure altitude profiles of air pollutants and other atmospheric constituents. The technique involves measurement of differential absorption at several wavelengths, using the diffusely reflecting earth's surface to provide a return signal. The pressure broadening of absorption lines allows one to discriminate between high and low altitude absorbers. Application of the technique to measurements of ozone, nitric oxide, and water vapor are presented. CO2 and CO lasers are considered as transmitters. The discussion includes altitude resolution limitations, atmospheric temperature dependence, and frequency stability requirements of the instrument.

Menzies, R. T.↗

Thermodynamic derivatives of infrared absorptance

Calculation of the concentration, pressure, and temperature dependence of the spectral absorptance of a vibrational absorption band. A smooth thermodynamic dependence was found for wavelength intervals where the average absorptance is less than 0.65. Individual rotational lines, whose parameters are often well known, were used as bases in the calculation of medium resolution spectra. Two modes of calculation were combined: well-separated rotational lines plus interaction terms, or strongly overlapping lines that were represented by a compound line of similar shape plus corrections. The 1.9- and 6.3-micron bands of H2O and the 4.3-micron band of CO2 were examined in detail and compared with experiment.

Broersma, S.↗

The nu sub 9 fundamental of ethane - Integrated intensity and band absorption measurements with application to the atmospheres of the major planets

Measurements of the absolute intensity and integrated band absorption have been performed for the nu sub 9 fundamental band of ethane. The intensity is found to be about 34 per sq cm per atm at STP, and this is significantly higher than previous estimates. It is shown that a Gaussian profile provides an empirical representation of the apparent spectral absorption coefficient. Employing this empirical profile, a simple expression is derived for the integrated band absorption, which is in excellent agreement with experimental values. The band model is then employed to investigate the possible role of ethane as a source of thermal infrared opacity within the atmospheres of Jupiter and Saturn, and to interpret qualitatively observed brightness temperatures for Saturn.

Varanasi, P.↗

Sound absorption of low-temperature reusable surface insulation candidate materials

Sound absorption data from tests of four candidate low-temperature reusable surface insulation materials are presented. Limitations on the use of the data are discussed, conclusions concerning the effective absorption of the materials are drawn, and the relative significance to Vibration and Acoustic Test Facility test planning of the absorption of each material is assessed.

Johnston, J. D.↗

Monitoring spacecraft atmosphere contaminants by laser absorption spectroscopy

Data were obtained which will provide a test of the accuracy of the differential absorption method for trace contaminant detection in many-component gas mixtures. The necessary accurate absorption coefficient determinations were carried out for several gases; acetonitrile, 1,2-dichloroethane, Freon-113, furan, methyl ethyl ketone, and t-butyl alcohol. The absorption coefficients are displayed graphically. An opto-acoustic method was tested for measuring absorbance, similar to the system described by Dewey.

Steinfeld, J. I.↗

Remote atmospheric sensing with an airborne laser absorption spectrometer

A laser absorption spectrometer, using an IR laser transmitter and a heterodyne radiometer, can be used from an aircraft or spacecraft to measure altitude profiles of air pollutants and other atmospheric constituents. The technique involves measurement of differential absorption at several wavelengths, using the diffusely reflecting earth's surface to provide a return signal. The pressure broadening of absorption lines allows one to discriminate between high and low altitude absorbers. Application of the technique to measurements of ozone, nitric oxide, and water vapor are presented. CO2 and CO lasers are considered as transmitters. The discussion includes altitude resolution limitations, atmospheric temperature dependence, and frequency stability requirements of the instrument.

Menzies, R. T.↗

The absorption-line spectrum of the quasi-stellar object PHL 957

Six high-dispersion spectra of the quasar PHL 957 are analyzed which were obtained with an integrating television system at the Coude focus of the 200-inch Hale telescope. One hundred seventy-nine absorption lines are found, and seven absorption-line redshift systems are identified. The system at z equals 2.3099 is shown to be most prominent, with 26 lines including a very strong L-alpha line. A system close to the emission redshift is found to be double, and many lines in all the systems are identified as Lyman alpha-beta pairs. Column densities and velocity dispersions are obtained from curves of growth for the major systems and the Lyman pairs. The system at z equals 2.3099 is found to resemble interstellar material in ionization and abundance ratios and constitutes strong evidence for absorption originating in a galaxy along the line of sight to the quasar. The double system is found to have higher ion states and is probably associated with the quasar.

Wingert, D. W.↗

A correlation test of the intrinsic interpretation of QSO absorption redshifts

It is noted that the general intrinsic interpretation of QSO absorption redshifts predicts a high probability of clustering for the expulsion velocities of clouds ejected from a QSO core and that a correlation function has been defined which depends on the probability of clustering of three or more expulsion velocities. A test of this correlation is formulated which utilizes data on pairs of QSOs with similar emission redshifts and at least three well established absorption redshifts with corresponding expulsion velocities greater than 0.02c. It is shown that the correlation should be positive (maximum value +100%) if the absorption systems are intrinsic and correlated, zero if there is no physical connection among these systems, and negative if a strong anticorrelation exists or QSOs tend to eject one or two clouds at well separated characteristic velocities. Data on five QSOs are analyzed, and large positive values are obtained for the correlations.

Opher, R.↗

Infrared band absorptance correlations and applications to nongray radiation

Various mathematical models for infrared radiation absorption spectra for atmospheric gases are reviewed, and continuous correlations for the total absorptance of a wide band are presented. Different band absorptance correlations were employed in two physically realistic problems (radiative transfer in gases with internal heat source, and heat transfer in laminar flow of absorbing-emitting gases between parallel plates) to study their influence on final radiative transfer results. This information will be applied to the study of atmospheric pollutants by infrared radiation measurement.

Tiwari, S. N.↗

A parameterization for the absorption of solar radiation by water vapor in the earth's atmosphere

A parameterization for the absorption of solar radiation as a function of the amount of water vapor in the earth's atmosphere is obtained. Absorption computations are based on the Goody band model and the near-infrared absorption band data of Ludwig et al. A two-parameter Curtis-Godson approximation is used to treat the inhomogeneous atmosphere. Heating rates based on a frequently used one-parameter pressure-scaling approximation are also discussed and compared with the present parameterization.

Wang, W.-C.↗

Remote sensing of atmospheric SO2 using the differential absorption LIDAR technique

The paper reports an investigation of the capabilities of a UV differential absorption lidar (DIAL) system for remote measurements of sulfur dioxide emissions. Two features of the present DIAL system are an absorption cell permitting the determination of the difference in SO2 absorption coefficients for the two transmitted wavelengths and a calibration cell permitting the linearity and performance of the system to be evaluated. The DIAL technique is described along with the transmitter, receiver, data-adquisition, and data-processing components of the investigated system. Quantitative measurements of the average SO2 concentration in a region surrounding the exhaust stack of a steam-generating plant are discussed which show that the present system has measurement sensitivities of 10 ppb at a range of 0.8 km and 20 ppb at 1.9 km. Based on performance characteristics obtained during a calibration of this system, it is predicted that a measurement sensitivity of less than 4 ppb over a 1-km path will be attained.

Hoell, J. M., Jr.↗

Water vapor absorption of carbon dioxide laser radiation

An optoacoustic detector or spectrophone has been used to perform detailed measurements of the absorptivity of mixtures of water vapor in air. A (C-12) (O-16)2 laser was used as the source, and measurements were made at forty-nine different wavelengths from 9.2 to 10.7 microns. The details of the optoacoustic detector and its calibration are presented, along with a discussion of its performance characteristics. The results of the measurements of water vapor absorption show that the continuum absorption in the wavelength range covered is 5-10% lower than previous measurements.

Shumate, M. S.↗

A microscopic description of sound absorption in the atmosphere

The various mechanisms which contribute to sound absorption in the atmosphere are identified and a technique for computing the contribution from each is presented. The similarities between sound absorption, laser fluorescence measurements, and the opto-acoustic effect are discussed. Finally, experimental sound absorption results are compared to predictions to test the microscopic energy transfer approach.

Bass, H. E.↗

Shock tube measurements of the optical absorption of triatomic carbon, C3

The spectral absorption of C3 has been measured in a shock tube using a test gas mixture of acetylene diluted with argon. The absorption of a pulsed xenon light source was measured by means of eight photomultiplier channels to a spectrograph and an accompanying drum camera. The postshock test gas temperature and pressure were varied over the range 3300-4300 K and 0.36 to 2.13 atmospheres, respectively. The results showed appreciable absorption from C3 for the wavelength range 300 to 540 nanometers. The computed electronic oscillator strength varied from 0.12 to 0.06 as a function of temperature.

Jones, J. J.↗

Charged-particle absorption by Io

The electrostatic field associated with the rotation of Jupiter, relative to the rest frame of Io, would be distorted if the satellite were an electrical conductor. An idealized two-dimensional model of the distorted electric-field configuration, in the limit of a perfectly conducting satellite or satellite ionosphere, has been constructed and used to trace the adiabatic guiding-center trajectories of energetic protons and electrons across Jupiter's magnetic field lines, which are taken as rectilinear. The adiabatic trajectories of very low-energy particles (cold plasma) are found to avoid the satellite and escape absorption. In the limit of very high particle energies, the adiabatic trajectories are undistorted, and absorption proceeds as if Io were an insulator. The interpolation between these limits is monotonic for protons, such that Io sweeps out a drift shell half as wide as the satellite for first invariants of the order of 1 GeV per gauss. The situation for electrons is more complicated, and no absorption from adiabatic trajectories is found at first invariants not exceeding 46 GeV per gauss. Electrons having first invariants of at least 50 GeV per gauss are typically swept out of drift shells wider than the satellite itself. However, electrons can impact only a portion of Io's exposed hemisphere for first invariants of 50-200 GeV per gauss. Thus, the particle-absorbing characteristics of an electrically conducting Jovian satellite are found to depend on both the species and the energy of the incident particle, and the satellite's particle-absorbing cross section differs systematically from its geometric cross section.

Schulz, M.↗