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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

HRTEM and EFTEM Studies of Phyllosilicate-Organic Matter Associations in Matrix and Dark Inclusions in the EET92042 CR2 Carbonaceous Chondrite

Based on petrologic and isotopic observations, the CR chondrites represent one of the most primitive carbonaceous chondrite groups. The organic matter in CR chondrite matrices is considered to be among the most ancient carbonaceous matter known, potentially providing a link between organic matter in the interstellar medium and our solar system [1]. However, the organic chemistry of CR chondrites may be complicated by the fact that these meteorites have undergone moderate secondary alteration, which potentially overprints primordial features [2]. Although the general effects of this alteration have been documented [2], the details of the fine-grained mineralogy and alteration styles of CR matrices are not fully understood. Here we present TEM observations of matrix in EET 92042, a CR chondrite that contains particularly primitive insoluble organic matter [1]. Preliminary studies [3] determined that EET 92042 matrix is heterogeneous in terms of mineralogy, texture, and petrographic fabric on the micron scale. EET 92042 contains magnetite-rich regions, foliated matrix and dark inclusions (DIs). Some chondrules show fine-grained rims, similar to those described by [4].

Abreu, Neyda M.↗

Computational diagnostics and characterization of combustion recession in diesel sprays

While low-temperature combustion (LTC) strategies have been found to mitigate nitrogen oxides and particulate matter emissions in diesel engines, studies have also associated LTC with an increase in unburnt hydrocarbons. With more recent studies on diesel after end-of-injection (AEOI), combustion recession is identified as a phenomenon where at near nozzle region, high-temperature ignition (HTI) combustion can propagate back to the nozzle tip consuming the unburnt hydrocarbons AEOI. Current literature has suggested that combustion recession is controlled by auto-ignition. However, high-fidelity simulations and detailed analysis of such a mechanism are missing. In this study, comprehensive Large Eddy Simulations of a reacting spray at “Spray A” conditions are performed, where detailed analysis of combustion recession concerning flame morphology and propagation modes are included. In particular, this study demonstrated for the first time that while combustion recession is mainly auto-ignition dominated (consistent with the literature), a cool flame was found to deflagrate towards the richer regions of the mixture, promoting mixing and increasing the mixture temperature. This leads to HTI kernels, which then grow and develop as deflagrative waves, therefore sustaining the combustion recession process. The study also detailed the extinction mechanism of combustion: the entrainment wave will overlean the near-nozzle mixtures, rendering it unable to support HTI, which leads to the extinction of the upstream flame AEOI in lower reactivity mixtures. Combustion recession is also observed to be contingent on the chemical and diffusion processes, even at low scalar dissipation rates. Finally, a new criterion for combustion recession based on chemical explosive mode is proposed and validated with previous combustion recession index to quantify the extent of HTI in near-nozzle mixtures AEOI. The newly developed metric combined with a previous experimentally-based metric can provide simple but valuable measurements of the degree and propensity of the upstream flame AEOI.

CEMA↗

Structural polymorphism of amyloid fibrils in ATTR amyloidosis revealed by cryo-electron microscopy

ATTR amyloidosis is caused by the deposition of transthyretin in the form of amyloid fibrils in virtually every organ of the body, including the heart. This systemic deposition leads to a phenotypic variability that has not been molecularly explained yet. In brain amyloid conditions, previous studies suggest an association between clinical phenotype and the molecular structures of their amyloid fibrils. Here we investigate whether there is such an association in ATTRv amyloidosis patients carrying the mutation I84S. Using cryo-electron microscopy, we determined the structures of cardiac fibrils extracted from three ATTR amyloidosis patients carrying the ATTRv-I84S mutation, associated with a consistent clinical phenotype. We found that in each ATTRv-I84S patient, the cardiac fibrils exhibited different local conformations, and these variations can co-exist within the same fibril. Our finding suggests that one amyloid disease may associate with multiple fibril structures in systemic amyloidoses, calling for further studies.

59 BASIC BIOLOGICAL SCIENCES↗

Evaluation of Protein Extraction Methods for Metaproteomic Analyses of Root-Associated Microbes

Metaproteomics is a powerful tool for the characterization of metabolism, physiology, and functional interactions in microbial communities, including plant-associated microbiota. However, the metaproteomic methods that have been used to study plant-associated microbiota are very laborious and require large amounts of plant tissue, hindering wider application of these methods. We optimized and evaluated different protein extraction methods for metaproteomics of plant-associated microbiota in two different plant species (Arabidopsis and maize). Our main goal was to identify a method that would work with low amounts of input material (40 to 70 mg) and that would maximize the number of identified microbial proteins. We tested eight protocols, each comprising a different combination of physical lysis method, extraction buffer, and cell-enrichment method on roots from plants grown with synthetic microbial communities. We assessed the performance of the extraction protocols by liquid chromatography-tandem mass spectrometry–based metaproteomics and found that the optimal extraction method differed between the two species. For Arabidopsis roots, protein extraction by beating whole roots with small beads provided the greatest number of identified microbial proteins and improved the identification of proteins from gram-positive bacteria. For maize, vortexing root pieces in the presence of large glass beads yielded the greatest number of microbial proteins identified. Based on these data, we recommend the use of these two methods for metaproteomics with Arabidopsis and maize. Furthermore, detailed descriptions of the eight tested protocols will enable future optimization of protein extraction for metaproteomics in other dicot and monocot plants.

59 BASIC BIOLOGICAL SCIENCES↗

Evaluation of Containment and Geomechanical Risks at Integrated Mid-Content Stacked Carbon Storage Hub Sites

The U.S. Department of Energy is leading the development of CCS through collaborative projects and programs to not only develop and demonstrate the technology but to also quantify the risks and provide tools that site operators can use to develop a site-specific understanding of their risk to enable successful project operations. This report summarizes results and findings from the application of risk-assessment tools to an industrial-scale Geologic Carbon Storage (GCS) project. Specifically, we applied the National Risk Assessment Partnership’s (NRAP) Open Integrated Assessment Model (NRAP-Open-IAM) and State of Stress Assessment Tool (SOSAT) to two candidate sites being considered for storage by the Integrated Midcontinent Stacked Carbon Storage Hub (IMSCS-Hub) project team. These sites, Sleepy Hollow Field in Nebraska and Patterson Field in Kansas, have historical oil and gas production and thus are attractive candidates to store the 50 million metric tons (Mt), which is the CarbonSAFE objective. Because these sites have historical operations, they have a significant number of existing wells that pose a risk for well leakage. Additionally, the storage formations will undergo significant pore pressure perturbation (i.e., increase due to CO 2 injection). Hence, we have selected the two NRAP tools best suited to study the risks associated with well leakage and geomechanical risks. The objective of the study was not only to assess the risk at the site, but to also improve the NRAP tools through application using real site data on an ongoing project.

54 ENVIRONMENTAL SCIENCES↗

Ultraviolet photometry of OB associations in M31

The study obtains near-UV and FUV magnitudes for 76 massive stars in 24 OB associations in the central and southern portions of M31 from images obtained by the Ultraviolet Imaging Telescope (UIT) during the Astro 1 spacelab mission. A comparison is made with the previous UIT photometry of 30 stars in the giant association NGC 206. Extinctions are estimated from the relation between E(B - V) and the distance from the center of M31 derived by Hodge and Lee (1988) from topical CCD stellar photometry. From evolutionary models, lower limits to the maximum stellar mass are estimated at about 60-100 solar masses in NGC 206, A29, A61, A63, A130, and A132. For other associations, the limits are in the range of about 20-55 solar masses.

Hill, Jesse K.↗

Dried Plum Protects From Radiation-Induced Bone Loss by Attenuating Pro-Osteoclastic and Oxidative Stress Responses

Future space explorations beyond the earths magnetosphere will increase human exposure to space radiation and associated risks to skeletal health. We hypothesize that oxidative stress resulting from radiation exposure plays a major role in progressive bone loss and dysfunction in associated tissue. In animal studies, increased free radical formation is associated with pathological changes in bone structure, enhanced bone resorption, reduced bone formation and decreased bone mineral density, which can lead to skeletal fragility. Our long-term goals are to define the mechanisms and risk of bone loss in the spaceflight environment and to facilitate the development of effective countermeasures. We had previously reported that exposure to low or high-LET radiation correlates with an acute increase in the expression of pro-osteoclastic and oxidative stress genes in bone during the early response to radiation followed by pathological changes in skeletal structure. We then conducted systematic screening for potential countermeasures against bone loss where we tested the ability of various antioxidants to mitigate the radiation-induced increase in expression of these markers. For the screen, 16-week old C57Bl6J mice were treated with a dietary antioxidant cocktail, injectable DHLA or a dried plum-enriched diet (DP). Mice were then exposed to 2Gy 137Cs radiation and one day later, marrow cells were collected and the relevant genes analyzed for expression levels. Among the candidate countermeasures tested, DP was most effective in reducing the expression of genes associated with bone loss. Furthermore, analysis of skeletal structure by microcomputed tomography (microCT) revealed that DP also prevents the radiation-induced deterioration in skeletal microarchitecture as indicated by parameters such as percent bone volume (BVTV), trabecular spacing and trabecular number. We also found that DP has similar protective effects on skeletal structure in a follow-up study using 1 Gy of sequential proton and iron, radiation species relevant to spaceflight. When cultured ex vivo under osteogenic conditions, bone marrow-derived cells from DP-fed animals exhibited increased colony numbers compared to control diet-fed animals. These findings suggest that DP exerts pro-osteogenic effects apart from its previously demonstrated anti-resorptive action, which may be one of the mechanisms underlying its radioprotective effect on bone. In conclusion, a diet enriched in certain types of antioxidants may be useful as an intervention for radiation-induced bone loss.

Bone-loss↗

Atmospheric reentry of the in-core thermionic SP-100 reactor system

Presumed end-of-life atmospheric reentry of the GA SP-100 system was studied to assess dispersal feasibility and associated hazards. Reentry was studied by sequential use of an orbital trajectory and a heat analysis computer program. Two heating models were used. The first model assumed a thermal equilibrium condition between the stagnation point aerodynamic heating and the radiative cooling of the skin material surface. The second model allowed for infinite conductivity of the skin material. Four reentering configurations were studied representing stages of increased SP-100 breakup: (1) radiator, shield and reactor, (2) shield and reactor, (3) reactor with control drums, and (4) reactor without control drums. Each reentering configuration was started from a circular orbit at 116 km having an inertial velocity near Mach 25. The assumed failing criterion was the attainment of melting temperature of a critical system component. The reentry analysis revealed breakup of the vessel in the neighborhood of 61 km altitude and scattering of the fuel elements. Subsequent breakup of the fuel elements was not predicted. Oxidation of the niobium skin material was calculated to cause an increase in surface temperature of less than ten percent. The concept of thermite analogs for enhancing reactor reentry dispersal was assessed and found to be feasible in principle. A conservative worst-case hazards analysis was performed for radioactive and nonradioactive toxic SP-100 materials assumed to be dispersed during end-of-life reentry. The hazards associated with this phase of the SP-100 mission were calculated to be insignificant.

Stamatelatos, M. G.↗

Dynamic probabilistic risk assessment and game theory for cyber security risk analysis in nuclear power plants

Nuclear Power Plants and energy systems have become more prone to cyber-attacks with their digitalization and the increased use of smart equipment. Hence, it is important to quantify the risk associated with cyber-attacks in such systems. Dynamic Probabilistic Risk Assessment which involves studying the evolution of a system due to random events and operator and attacker actions during a cyber-attack by employing a physics-based model of the system is a suitable framework to quantify cybersecurity risk in nuclear power plants. In addition to the plant dynamics, it is also important to model the strategies of the attackers and plant operators for an effective cybersecurity risk assessment. Game theory provides a set of necessary tools to model such strategic interactions. In this research, a framework that integrates dynamic probabilistic risk assessment with game theory for cybersecurity risk analysis in nuclear power plants is presented. The mathematical formulation is derived based on the theory of continuous event trees. We propose a game theory based action model, that utilizes physics-based rewards to define the strategies of attackers and operators at every decision epoch. As a case study, the risk associated with cyber-attacks on the digital components in the secondary side of a pressurized water reactor is studied using a reduced order model. A set of attacker actions and a set of operator actions are defined for the system. The operator and attacker interactions were modelled using simultaneous game, their action policies were computed using the concept of mixed strategy Nash equilibrium and the evolution of the system was studied.

97 MATHEMATICS AND COMPUTING↗

Energetic particle observations at the Helios 1 spacecraft of shocks associated with coronal mass ejections

Energetic particle data from the Helios 1 spacecraft have been used to study the particles associated with 26 coronal mass ejection (CME)/shock pairs. The particle events are divided into four classes on the basis of the relative intensities of their prompt and shock-associated components. Events in group 1 have strong prompt and shock components and are associated with energetic CMEs originating, most commonly, with central meridian flares. Group 2 events characteristically have strong prompt components and weaker shock components and are associated with western hemisphere (i.e., favorably located) flares. Group 3 consists of events with absent prompt components and strong shock components; the CMEs probably originate in disappearing filament events near central meridian. Group 4 events show no particle enhancements and are associated with slow CMEs and slow shocks.

Cane, H. V.↗

Study of Electric Vehicle Range Loss Associated with Replacement Tires

The FuelEconomy.Gov website has become a trusted source for consumers to find information pertaining to fuel economy and fuel-efficient vehicles. As electric vehicles are an increasingly important part of the light-duty fleet in the U.S., there is a need to expand the website content that is targeted to electric vehicle (EV) owners. This report addresses a concern about which several anecdotal reports have come to the attention of the website support staff. Specifically, some EV owners have observed a sudden, noticeable decrease in their all-electric range when they replace the tires that came with their vehicle when it was new. This change has reportedly led some owners to take their vehicles to the dealership service department out of concern that something had gone wrong with the vehicle.

33 ADVANCED PROPULSION SYSTEMS↗

A photometric study of the Orion OB 1 association. 1: Observational data

An extensive catalog of observational data is presented for stars in the region of the young stellar association Orion OB 1. In addition to new photoelectric observations obtained on the uvbyB and UBV systems, photoelectric and spectroscopic data were compiled for the stars observed and for several bright members of the association having available photometric indices. Mean weighted values were computed for the uvbyB and UBV data and are tabulated in summary tables which include all references for individual values. These tables are expected to be reasonably complete for association members earlier than spectral type A0. From an analysis of currently available proper motion, radial velocity, and photometric data, membership criteria were derived and qualitative membership probabilities for 526 stars were summarized. A set of charts is included for assistance in identification of the program stars in all regions of the association.

Warren, W. H., Jr.↗

A photometric study of the Orion OB 1 association. 2: Photometric analysis

The procedures adopted for analysis of photometric data in terms of color excesses, intrinsic color indexes, absolute visual magnitudes, and rotational-velocity effects are discussed in detail for Orion association B-, intermediate (I)-, and AF-type stars. The effects of the nebular environment and a comparison of various calibrations of Balmer-line and four-color indexes are considered for the determination of individual absolute magnitudes for B-type stars. When absolute magnitudes of stars in the region of the Orion Nebula are determined from the beta index, emission mechanisms appear to spuriously brighten them. A detailed comparison of absolute magnitudes derived from Balmer-line indexes and MK spectral-type calibrations is presented. The data are also examined with regard to the effects of polarization and infrared excesses. The results suggest a complex combination of intracluster and circumstellar origins for these processes.

Warren, W. H., Jr.↗