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At least 397 records · Page 22

Solubilities of carbon dioxide and water in rhyolitic melt at 850 C and 750 bars

Concentrations of carbon dioxide and water dissolved in glasses quenched from rhyolitic melts equilibrated with H2O-CO2 fluids at 850 C and 750 bar were measured using IR spectroscopy; concentrations of H2O and CO2 in the quenched fluids were measured manometrically. The mole fraction of CO2 in the quenched fluid ranged from 0.06 to 0.91. Concentrations of CO2 in the coexisting rhyolitic melt increased from 23(+/-6) ppm for the sample equilibrated with the most CO2-poor fluid to 515(+/-16) ppm for that equilibrated with the most CO2-rich fluid. The water content of the melt varied from 0.51(+/-0.06) to 3.34(+/-0.08) wt pct. Our results show that concentrations of molecular CO2 and H2O in the glasses obey Henry's Law; the mole fractions of molecular CO2 and molecular H2O in the quenched melts are proportional to their fugacities in the coexisting vapor. CO2 contents of vapor-saturated melts are not enhanced by addition of water to CO2-rich vapor, contrary to previous reports for silicate melts at higher pressures. The Henrian behavior of CO2 and H2O at low pressure considerably simplifies modeling of the degassing of silicic magmas.

Blank, J. G.↗

BOREAS TGB-12 Isotropic Carbon Dioxide Data over the NSA

The BOREAS TGB-12 team made measurements of soil carbon inventories, carbon concentration in soil gases, and rates of soil respiration at several sites to estimate the rates of carbon accumulation and turnover in each of the major vegetation types. This data set contains information on the carbon isotopic content of carbon dioxide sampled from soils in the NSA-OBS, NSA-YJP, and NSA-OJP sites. Data were collected from 14-Nov-1993 to 10-Oct-1996. The data are stored in tabular ASCII files.

Trumbore, Susan↗

Exploratory Analysis of Carbon Dioxide Levels, Ultrasound and Optical Coherence Tomography Measures of the Eye During ISS Missions

Carbon dioxide (CO2) levels on board the International Space Station (ISS) have typically averaged 2.3 to 5.3 mmHg, with large fluctuations occurring over periods of hours and days. CO2 has effects on cerebral vascular tone, resulting in vasodilation and alteration of cerebral blood flow (CBF). Increased CBF leads to elevated intracranial pressure (ICP), a factor leading to visual disturbances, headaches, and other central nervous system symptoms. Ultrasound of the optic nerve and optical coherence tomography (OCT) provide surrogate measurements of ICP; in-flight measurements of both were implemented as enhanced screening tools for the Visual Impairment/Intracranial Pressure (VIIP) syndrome. This analysis examines the relationships between ambient CO2 levels on ISS, ultrasound and OCT measures of the eye in an effort to understand how CO2 may possibly be associated with VIIP and to inform future analysis of in-flight VIIP data.

Schaefer, C.↗

Effect of Carbon Dioxide Exposure on Physical and Cognitive Performance in A Simulated Spaceflight Contingency Scenario

INTRODUCTION: Carbon dioxide (CO2) produced by astronauts inside space suits can accumulate to levels that may affect health and performance. The human health and performance risks associated with different levels of CO2 exposure in the flight environment remain an area of debate. The purpose of this study is to characterize the limit of acceptable performance (cognitive and physical) decrements and symptom severity for mission operations when subjected to elevated inspired CO2 levels in simulated contingency lunar extravehicular activity (EVA) scenarios. METHODS: This study will create a simulation of a 1-hour, ~2km contingency EVA walk back to a habitat, incorporating a passive treadmill and a fully immersive virtual reality (VR) simulation of a lunar EVA environment. Subjects will be asked to walk on a treadmill while breathing partial pressures of CO2 of 0, 5, 10, 15, 20, 25, 30mmHg for 1 hour at a time. Cognitive performance will be quantified using validated cognitive tests and measures of functional task performance embedded within the VR environment. Test subject symptoms and self-assessment of performance will be evaluated via survey. RESULTS: This study currently has approval from NASA’s Institutional Review Board and has completed the Test Readiness Review process. Next steps for this research study include test subject recruitment, data collection, and analysis. Data collection is planned for calendar year 2023 and 2024. DISCUSSION: This study will provide valuable information regarding how various partial pressures of CO2 exposure impact acute health, as well as cognitive and physical performance during simulated contingency lunar EVA. This information will enable assessment of health and performance risk associated with spacesuit systems and operations concepts for future exploration missions as well as informing definition of future standards and requirements.

D. M. Nusbaum↗

Influence of variable rates of neritic carbonate deposition on atmospheric carbon dioxide and pelagic sediments

Short-term imbalances in the global cycle of shallow water calcium carbonate deposition and dissolution may be responsible for much of the observed Pleistocene change in atmospheric carbon dioxide content. However, any proposed changes in the alkalinity balance of the ocean must be reconciled with the sedimentary record of deep-sea carbonates. The possible magnitude of the effect of shallow water carbonate deposition on the dissolution of pelagic carbonate can be tested using numerical simulations of the global carbon cycle. Boundary conditions can be defined by using extant shallow water carbonate accumulation data and pelagic carbonate deposition/dissolution data. On timescales of thousands of years carbonate deposition versus dissolution is rarely out of equilibrium by more than 1.5 x 10(13) mole yr-1. Results indicate that the carbonate chemistry of the ocean is rarely at equilibrium on timescales less than 10 ka. This disequilibrium is probably due to sea level-induced changes in shallow water calcium carbonate deposition/dissolution, an interpretation that does not conflict with pelagic sedimentary data from the central Pacific.

NASA Discipline Exobiology↗

A 4 U Laser Heterodyne Radiometer for Methane (CH4) and Carbon Dioxide (CO2) Measurements from an Occultation-Viewing CubeSat

We present a design for a 4 U (20 cm 20 cm 10 cm) occultation-viewing laser heterodyne radiometer (LHR) that measures methane (CH4), carbon dioxide (CO2) and water vapor(H2O) in the limb that is designed for deployment on a 6 U CubeSat. The LHR design collects sunlight that has undergone absorption by the trace gas and mixes it with a distributive feedback (DFB) laser centered at 1640 nm that scans across CO2, CH4, and H2O absorption features. Upper troposphere lower stratosphere measurements of these gases provide key inputs to stratospheric circulation models: measuring stratospheric circulation and its variability is essential for projecting how climate change will affect stratospheric ozone.

occultation↗

Carbon Dioxide Active Remote Sensing Using Pulsed 2-µm Lidar

A pulsed 2-µm Integrate Path Differential Absorption (IPDA) lidar was developed at NASA Langley Research Center for high-accuracy and high-precision measurements of atmospheric carbon dioxide (CO 2 ). The instrument targets the R30 CO 2 absorption line and implements high-energy tunable on-line transmitter and advanced HgCdTe avalanche photodiode receiver. During 2019 airborne validation campaign, the IPDA was tested over the ocean for retrieving the weighted-average column dry-air volume mixing ratio of CO 2 (XCO 2 ) from 4.5 km altitude. XCO 2 measurement resulted in 404.43 ± 1.23 ppm using 10 s average, as compared to 405.49 ppm from prediction models. This translates to 0.26% and 0.30% relative accuracy and precision, respectively. Performance models were updated to scale the IPDA technology assuming operation from space platform. Results present XCO 2 measurements using the instrument capabilities considering different target scenarios for Earth’s surface. This demonstrates the potential for the IPDA technique and technology to achieve sustained global CO 2 measurement.

Active Remote Sensing↗

Carbon Dioxide Active Remote Sensing Using Pulsed 2-µm Lidar

A pulsed 2-µm Integrate Path Differential Absorption (IPDA) lidar was developed at NASA Langley Research Center for high-accuracy and high-precision measurements of atmospheric carbon dioxide (CO 2 ). The instrument targets the R30 CO 2 absorption line and implements high-energy tunable on-line transmitter and advanced HgCdTe avalanche photodiode receiver. During 2019 airborne validation campaign, the IPDA was tested over the ocean for retrieving the weighted-average column dry-air volume mixing ratio of CO 2 (XCO 2 ) from 4.5 km altitude. XCO 2 measurement resulted in 404.43 ± 1.23 ppm using 10 s average, as compared to 405.49 ppm from prediction models. This translates to 0.26% and 0.30% relative accuracy and precision, respectively. Performance models were updated to scale the IPDA technology assuming operation from space platform. Results present XCO 2 measurements using the instrument capabilities considering different target scenarios for Earth’s surface. This demonstrates the potential for the IPDA technique and technology to achieve sustained global CO 2 measurement.

Active Remote Sensing↗

Development of system design information for carbon dioxide using an amine type sorber

Development work on system design information for amine type carbon dioxide sorber is reported. Amberlite IR-45, an aminated styrene divinyl benzene matrix, was investigated to determine the influence of design parameters of sorber particle size, process flow rate, CO2 partial pressure, total pressure, and bed designs. CO2 capacity and energy requirements for a 4-man size system were related mathematically to important operational parameters. Some fundamental studies in CO2 sorber capacity, energy requirements, and process operation were also performed.

Rankin, R. L.↗

High-dispersion spectroscopic observations of Venus during 1968 and 1969 II. The carbon-dioxide band at 8689A

Thirty well-exposed photographic plates showing the spectrum of the carbon dioxide band at 8689A in the atmosphere of Venus were obtained during 1968 and 1969. All spectra were obtained at a dispersion of 2 A/mm for Venus phase angles varying from 10 deg. to 126 deg. Rotational temperatures ranging from 236 K to 274 K were found. The average value of the rotational temperature is 246 + or - 1 K (one standard deviation); for 1967 observations, the rotational temperatures ranged from 222 to 248 K, with an average value of 238 + or - 4 K. The variation of the equivalent width of the 8689A band, with Venus phase angle, was very similar for the two sets of observations (53 plates). The temporal variations, of approximately 30 percent, were comparable with the phase variations over this limited range of phase angle.

Schorn, R. A. J.↗

Tables and charts of equilibrium thermodynamic properties of carbon dioxide for temperatures from 100 K to 25,000 K

Equilibrium thermodynamic properties for pure carbon dioxide are presented in tabulated and graphical form for temperatures from 100 K to 25,000 K and pressures from 40 mN/sq m to 1 GN/sq m. Properties include pressure, temperature, density, enthalpy, speed of sound, entropy, molecular weight ratio, specific heat at constant pressure, specific heat at constant volume, isentropic exponent, and species mole fractions.

Miller, C. G., III↗

Biochemical Capture and Removal of Carbon Dioxide

We devised an enzyme-based facilitated transport membrane bioreactor system to selectively remove carbon dioxide (CO2) from the space station environment. We developed and expressed site-directed enzyme mutants for CO2 capture. Enzyme kinetics showed the mutants to be almost identical to the wild type save at higher pH. Both native enzyme and mutant enzymes were immobilized to different supports including nylons, glasses, sepharose, methacrylate, titanium and nickel. Mutant enzyme could be attached and removed from metal ligand supports and the supports reused at least five times. Membrane systems were constructed to test CO2 selectivity. These included proteic membranes, thin liquid films and enzyme-immobilized teflon membranes. Selectivity ratios of more than 200:1 were obtained for CO2 versus oxygen with CO2 at 0.1%. The data indicate that a membrane based bioreactor can be constructed which could bring CO2 levels close to Earth.

Trachtenberg, Michael C.↗

Testing of an Amine-Based Pressure-Swing System for Carbon Dioxide and Humidity Control

Hamilton Sundstrand has developed a stable and efficient amine-based carbon dioxide (CO2) and water vapor (H2O) sorbent, SA9T, that is well-suited for use in a spacecraft environment. The sorbent is efficiently packaged in pressure-swing regenerable beds that are thermally linked to improve removal efficiency and minimize vehicle thermal loads, and the flows are all controlled with a single spool valve. The SA9T sorbent technology has already been baselined for the new Orion spacecraft. However, more data was needed on the operational characteristics of the package in a simulated spacecraft environment. This amine-based technology, referred to as the CO2 And Moisture Removal Amine Swing-bed (CAMRAS) by the Exploration Life Support Air Team at Johnson Space Center (JSC), was tested at JSC during the last third of 2006. Two series of tests on the CAMRAS were performed at simulated metabolic loads of four and/or six crewmen in a closed chamber. Tests were run at a variety of cabin temperatures and with a range of operating conditions varying cycle time, available vacuum pressure, blower speed, and crew activity levels. Results of this testing are presented and potential flight operational strategies discussed.

Lin, Amy B.↗