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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

The Direction of Fluid Dynamics for Liquid Propulsion at NASA Marshall Space Flight Center

Marshall Space Flight Center (MSFC) is the National Aeronautics and Space Administration (NASA)-designated center for the development of space launch systems. MSFC is particularly known for propulsion system development. Many engineering skills and technical disciplines are needed to accomplish this mission. This presentation will focus on the work of the Fluid Dynamics Branch (ER42). ER42 resides in the Propulsion Systems Department at MSFC. The branch is responsible for all aspects of the discipline of fluid dynamics applied to propulsion or propulsion-induced loads and environments. This work begins with design trades and parametric studies, and continues through development, risk assessment, anomaly investigation and resolution, and failure investigations. Applications include the propellant delivery system including the main propulsion system (MPS) and turbomachinery; combustion devices for liquid engines and solid rocket motors; coupled systems; and launch environments. An advantage of the branch is that it is neither analysis nor test centric, but discipline centric. Fluid dynamics assessments are made by analysis, from lumped parameter modeling through unsteady computational fluid dynamics (CFD); testing, which can be cold flow or hot fire; or a combination of analysis and testing. Integration of all discipline methods into one branch enables efficient and accurate support to the projects. To accomplish this work, the branch currently employs approximately fifty engineers divided into four teams -- Propellant Delivery CFD, Combustion Driven Flows CFD, Unsteady and Experimental Flows, and Acoustics and Stability. This discussion will highlight some of the work performed in the branch and the direction in which the branch is headed.

Griffin, Lisa W.↗

A Review Towards the Design Optimization of High Performance Additively Manufactured Rotating Detonation Rocket Engine Injectors

Rotating Detonation Rocket Engines (RDRE) have been marketed primarily for their higher specific impulse potential over constant pressure (CP) liquid rocket engines. However, several other performance advantages exist with RDREs over CP engines such as heat transfer advantages for gas expander cycle, increased completeness of combustion at low chamber L*, compact engine design, reduced coolant channel pressure drop potential, and improved injector C* performance. NASA has paved the way for liquid engine system performance enhancement since the Apollo program and continues to do so with metal additive manufacturing (AM), super-alloy materials, and advanced propulsion concepts. A team of propulsion development engineers at NASA are in the process of developing high-performance 7K lbf class RDRE hardware for their potential use in lander, upper stage, and even launch vehicle applications. Clear advantages have been demonstrated with AM including program cost and schedule reductions of up to 50%. It is well known that injector performance is integrally linked to the global performance of a combustion device. This is especially the case for RDREs since detonation stability is heavily dependent on the mixedness of propellants. A major program goal is to rapidly produce ultra-high-performance AM injectors. This paper reviews the available literature on liquid rocket injector design optimization as well as the experimental work conducted to date on injectors tested in RDREs. Major lessons learned are document and suggestions given towards the design of high-performance liquid RDRE injectors. In addition, the integration of metal AM into the design of liquid RDRE injector schemes is discussed. Finally, several candidate AM RDRE injector elements were produced to obtain their diodicity and cold flow characteristics.

rotating detonation engine↗

Structure of Flame Balls at Low Lewis-Number

The Structure of Flame Balls at Low Lewis-Number (SOFBALL) experiment explored the behavior of a newly discovered flame phenomena called "flame balls." These spherical, stable, stationary flame structures, observed only in microgravity, provide a unique opportunity to study the interactions of the two most important processes necessary for combustion (chemical reaction and heat and mass transport) in the simplest possible configuration. The previously unobtainable experimental data provided a comparison with models of flame stability and flame propagation limits that are crucial both in assessing fire safety and in designing efficient, clean-burning combustion engines.

Weiland, Karen J.↗

Combustion in a turbulent mixing layer formed at a rearward-facing step

A premixed propane/air flame was stabilized in a turbulent mixing layer formed at a rearward-facing step. The mean and rms averages of the turbulent velocity flowfield were determined by laser velocimetry for both reacting (phi = 0.57) and nonreacting flows (Re = 15,000-37,000 based on step height). The reacting-flow was visualized by high-speed schlieren photography. Large-scale structures dominate the reacting mixing layer. The growth of the large-scale structures was tied to the propagation of the flame. The linear growth rate of the reacting mixing layer defined by the mean velocity profiles was unchanged by combustion but the virtual origin moves downstream. The reacting mixing layer boundaries based on the mean velocity profiles were shifted toward the recirculation zone and reattachment lengths were shortened by 30 percent. The edge of the flame controlled by the large-scale structure development propagated faster into the incoming reactants than the boundary of the mixing layer given by the mean velocity flowfield. Thus, the region of high velocity gradient did not coincide with the region of high reaction and heat transfer.

Pitz, R. W.↗

Unsteady numerical simulations of the stability and dynamics of flames

In this report we describe the research performed at the Naval Research Laboratory in support of the NASA Microgravity Science and Applications Program over the past three years (from Feb. 1992) with emphasis on the work performed since the last microgravity combustion workshop. The primary objective of our research is to develop an understanding of the differences in the structure, stability, dynamics and extinction of flames in earth gravity and in microgravity environments. Numerical simulations, in which the various physical and chemical processes can be independently controlled, can significantly advance our understanding of these differences. Therefore, our approach is to use detailed time-dependent, multi-dimensional, multispecies numerical models to perform carefully designed computational experiments. The basic issues we have addressed, a general description of the numerical approach, and a summary of the results are described in this report. More detailed discussions are available in the papers published which are referenced herein. Some of the basic issues we have addressed recently are (1) the relative importance of wall losses and gravity on the extinguishment of downward-propagating flames; (2) the role of hydrodynamic instabilities in the formation of cellular flames; (3) effects of gravity on burner-stabilized flames, and (4) effects of radiative losses and chemical-kinetics on flames near flammability limits. We have also expanded our efforts to include hydrocarbon flames in addition to hydrogen flames and to perform simulations in support of other on-going efforts in the microgravity combustion sciences program. Modeling hydrocarbon flames typically involves a larger number of species and a much larger number of reactions when compared to hydrogen. In addition, more complex radiation models may also be needed. In order to efficiently compute such complex flames recent developments in parallel computing have been utilized to develop a state-of-the-art parallel flame code. This is discussed below in some detail after a brief discussion of the numerical models.

Kailasanath, K.↗

A Combined Crossed Molecular Beam and Theoretical Investigation of the Elementary Reaction of Tricarbon (C 3 (X 1 Σ g + )) with Diacetylene (C 4 H 2 (X 1 Σ g + )): Gas Phase Formation of the Heptatriynylidyne Radical ( l -C 7 H(X 2 Π))

An elucidation of the underlying formation pathways to acyclic hydrocarbons such as polyynes (C n H 2 ), cumulenes (C n H 2 ), and linear resonantly stabilized linear radicals (l-C n H) is indispensable to understand the hydrocarbon chemistry in extreme low and high temperature environments. In this study, we exploited the crossed molecular beam technique to investigate the reaction of tricarbon C 3 (X 1 Σ g + ) with diacetylene (butadiyne; HCCCCH; X 1 Σ g + ) at a collision energy of 47 ± 1 kJ mol ⁻1 . The experimental data were merged with ab initio calculations of the singlet C 7 H 2 potential energy surface (PES) revealing that the reaction is initiated via the formation of an initial van der Waals reactant complex in the entrance channel. Subsequent rearrangements lead to various carbene-type and cyclic intermediates via ring-opening, ring-closure, and hydrogen migration processes eventually forming acyclic C 7 H 2 isomers prior to their barrierless unimolecular decomposition to the most stable linear isomer, heptatriynylidyne (C 7 H, X 2 Π) in an overall endoergic reaction (+57 kJ mol ⁻1 ). The reaction exhibits strong similarities to the tricarbon – acetylene (C 3 – C 2 H 2 ). Furthermore, the significant energy threshold suggests that the tricarbon reaction with (poly)acetylenes forming resonantly stabilized linear radicals are open in high-temperature environments such as combustion flames and circumstellar envelopes of carbon stars and planetary nebulae as their descendants; however, these reactions are closed in low-temperature environments as in cold molecular clouds and hydrocarbon-rich atmospheres of planets and their moons such as in Titan.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Reduction of gaseous pollutant emissions from gas turbine combustors using hydrogen-enriched jet fuel

Recent progress in an evaluation of the applicability of the hydrogen enrichment concept to achieve ultralow gaseous pollutant emission from gas turbine combustion systems is described. The target emission indexes for the program are 1.0 for oxides of nitrogen and carbon monoxide, and 0.5 for unburned hydrocarbons. The basic concept utilizes premixed molecular hydrogen, conventional jet fuel, and air to depress the lean flammability limit of the mixed fuel. This is shown to permit very lean combustion with its low NOx production while simulataneously providing an increased flame stability margin with which to maintain low CO and HC emission. Experimental emission characteristics and selected analytical results are presented for a cylindrical research combustor designed for operation with inlet-air state conditions typical for a 30:1 compression ratio, high bypass ratio, turbofan commercial engine.

Clayton, R. M.↗

Future fundamental combustion research for aeropropulsion systems

Physical fluid mechanics, heat transfer, and chemical kinetic processes which occur in the combustion chamber of aeropropulsion systems were investigated. With the component requirements becoming more severe for future engines, the current design methodology needs the new tools to obtain the optimum configuration in a reasonable design and development cycle. Research efforts in the last few years were encouraging but to achieve these benefits research is required into the fundamental aerothermodynamic processes of combustion. It is recommended that research continues in the areas of flame stabilization, combustor aerodynamics, heat transfer, multiphase flow and atomization, turbulent reacting flows, and chemical kinetics. Associated with each of these engineering sciences is the need for research into computational methods to accurately describe and predict these complex physical processes. Research needs in each of these areas are highlighted.

Mularz, E. J.↗

Future fundamental combustion research for aeropropulsion systems

Physical fluid mechanics, heat transfer, and chemical kinetic processes which occur in the combustion chamber of aeropropulsion systems were investigated. With the component requirements becoming more severe for future engines, the current design methodology needs the new tools to obtain the optimum configuration in a reasonable design and development cycle. Research efforts in the last few years were encouraging but to achieve these benefits research is required into the fundamental aerothermodynamic processes of combustion. It is recommended that research continues in the areas of flame stabilization, combustor aerodynamics, heat transfer, multiphase flow and atomization, turbulent reacting flows, and chemical kinetics. Associated with each of these engineering sciences is the need for research into computational methods to accurately describe and predict these complex physical processes. Research needs in each of these areas are highlighted.

Mularz, E. J.↗

The challenges and opportunities of supersonic transport propulsion technology

The major challenges confronting the propulsion community for civil supersonic transport applications are identified: high propulsion system efficiency at both supersonic and subsonic cruise conditions, low-cost fuel with adequate thermal stability at high temperatures, low noise cycles and exhaust systems, low emission combustion systems, and low drag installations. Both past progress and future opportunities are discussed in relation to perceived technology shortfalls for an economically successful airplane that satisfies environmental constraints.

Strack, William C.↗

The challenges and opportunities of supersonic transport propulsion technology

The major challenges confronting the propulsion community for civil supersonic transport applications are identified: high propulsion system efficiency at both supersonic and subsonic cruise conditions, low-cost fuel with adequate thermal stability at high temperatures, low noise cycles and exhaust systems, low emission combustion systems, and low drag installations. Both past progress and future opportunities are discussed in relation to perceived technology shortfalls for an economically successful airplane that satisfies environmental constraints.

Strack, William C.↗

Structure of the Compressible Reacting Mixing Layer: A Linear Stability Analysis

Previous investigations have demonstrated that a mixing layer in compressible reacting conditions can develop two instability modes in addition to the more common central mode, which exists unaccompanied in incompressible non-reacting flows. These 'outer' modes were shown in the investigations of Planche and Reynolds to have a detrimental effect on mixing and combustion efficiency and therefore their presence has important consequences for applications of supersonic combustion. Results from a parametric study of the compressible reacting mixing layer's regime space using a linear stability technique will be discussed. The purpose is to develop a more complete understanding behind the effects of compressibility, heat release and the density, equivalence and velocity ratios on the amplification rate and structure of each instability mode.

Day, M. J.↗

Characterizing the Chemical Stability of High Temperature Materials for Application in Extreme Environments

The chemical stability of high temperature materials must be known for use in the extreme environments of combustion applications. The characterization techniques available at NASA Glenn Research Center vary from fundamental thermodynamic property determination to material durability testing in actual engine environments. In this paper some of the unique techniques and facilities available at NASA Glenn will be reviewed. Multiple cell Knudsen effusion mass spectrometry is used to determine thermodynamic data by sampling gas species formed by reaction or equilibration in a Knudsen cell held in a vacuum. The transpiration technique can also be used to determine thermodynamic data of volatile species but at atmospheric pressures. Thermodynamic data in the Si-O-H(g) system were determined with this technique. Free Jet Sampling Mass Spectrometry can be used to study gas-solid interactions at a pressure of one atmosphere. Volatile Si(OH)4(g) was identified by this mass spectrometry technique. A High Pressure Burner Rig is used to expose high temperature materials in hydrocarbon-fueled combustion environments. Silicon carbide (SiC) volatility rates were measured in the burner rig as a function of total pressure, gas velocity and temperature. Finally, the Research Combustion Lab Rocket Test Cell is used to expose high temperature materials in hydrogen/oxygen rocket engine environments to assess material durability. SiC recession due to rocket engine exposures was measured as a function of oxidant/fuel ratio, temperature, and total pressure. The emphasis of the discussion for all techniques will be placed on experimental factors that must be controlled for accurate acquisition of results and reliable prediction of high temperature material chemical stability.

Opila, Elizabeth↗

Lean stability augmentation for premixing, prevaporizing combustors

An experimental program was conducted to investigate techniques for improving the lean combustion limits of premixing, prevaporizing combustors applicable to gas turbine engine main burners. Augmented flameholders employing recessed perforated plates, catalyzed tube bundles, and configurations in which pilot fuel was injected into the wakes of V-gutters or perforated plates were designed and tested. Stable operation of the piloted designs was achieved at equivalence ratios as low as 0.25; NOx emissions of less than 1.0 g/kg at simulated turbine engine cruise conditions were obtained. A piloted perforated plate employing four percent pilot fuel flow produced the best performance while meeting severe NOx constraints.

Mcvey, J. B.↗

Processing modifications for improved propellants - Coated oxidizers

The present investigation is concerned with a technique which makes it possible to improve greatly the performance of composite propellants by alleviating the combustion instability problem. The technique involves the coating of the oxidizer crystals (typically ammonium perchlorate) with a suitably selected chemical. For each application the chemical for the coating is chosen on the basis of a screening procedure including the employment of differential scanning calorimetry and the use of a thermogravimetric analyzer. It is particularly important that the coat chemicals have good thermochemical stability at temperatures up to the normal surface temperature of the propellant during time-independent combustion (typically 800 to 900 K). At higher temperatures, sudden degradation should occur over a vary narrow temperature range (10-20 C).

Helmy, A. K.↗

Flame characteristics of a NASA contra swirler module

Results are presented for an investigation of the structure of unconfined propane flames stabilized on a NASA contra-swirl can. General flame characterization, flame visualization by sodium chloride, temperature measurements, combustion products analysis, nitric oxide concentrations, and laser anemometer studies are considered. The results are discussed relative to sodium chloride visualization, temperature distributions, chemical composition of flames, nitric oxide distributions, and velocity distributions. It is shown that unconfined propane-air flames can be stabilized downstream of a NASA contra-swirl can under a wide range of airflow rates and fuel-air ratios. However, on increasing fuel input from the lowest at which flames can be stabilized, a compact recirculation zone-stabilized flame is formed. The effect of confinement on changes in flame shape and structure is determined.

Thompson, D.↗

Gas–Phase Preparation of the 14π Hückel Polycyclic Aromatic Anthracene and Phenanthrene Isomers (C 14 H 10 ) via the Propargyl Addition–BenzAnnulation (PABA) Mechanism

Polycyclic aromatic hydrocarbons (PAHs) imply the missing link between resonantly stabilized free radicals and carbonaceous nanoparticles, commonly referred to as soot particles in combustion systems and interstellar grains in deep space. Whereas gas phase formation pathways to the simplest PAH – naphthalene (C 10 H 8 ) – are beginning to emerge, reaction pathways leading to the synthesis of the 14π Hückel aromatic PAHs anthracene and phenanthrene (C 14 H 10 ) are still incomplete. Here, by utilizing a chemical microreactor in conjunction with vacuum ultraviolet (VUV) photoionization (PI) of the products followed by detection of the ions in a reflectron time-of-flight mass spectrometer (ReTOF-MS), the reaction between the 1'- and 2'-methylnaphthyl radicals (C 11 H 9 •) with the propargyl radical (C 3 H 3 •) accesses anthracene (C 14 H 10 ) and phenanthrene (C 14 H 10 ) via the Propargyl Addition–BenzAnnulation (PABA) mechanism in conjunction with a hydrogen assisted isomerization. Furthermore, the preferential formation of the thermodynamically less stable anthracene isomer compared to phenanthrene suggests a kinetic, rather than a thermodynamics control of the reaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗