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NASA NTRS2000

Acoustics and Trust of Separate-Flow Exhaust Nozzles With Mixing Devices for High-Bypass-Ratio Engines

The NASA Glenn Research Center recently completed an experimental study to reduce the jet noise from modern turbofan engines. The study concentrated on exhaust nozzle designs for high-bypass-ratio engines. These designs modified the core and fan nozzles individually and simultaneously. Several designs provided an ideal jet noise reduction of over 2.5 EPNdB for the effective perceived noise level (EPNL) metric. Noise data, after correcting for takeoff thrust losses, indicated over a 2.0-EPNdB reduction for nine designs. Individually modifying the fan nozzle did not provide attractive EPNL reductions. Designs in which only the core nozzle was modified provided greater EPNL reductions. Designs in which core and fan nozzles were modified simultaneously provided the greatest EPNL reduction. The best nozzle design had a 2.7-EPNdB reduction (corrected for takeoff thrust loss) with a 0.06-point cruise thrust loss. This design simultaneously employed chevrons on the core and fan nozzles. In comparison with chevrons, tabs appeared to be an inefficient method for reducing jet noise. Data trends indicate that the sum of the thrust losses from individually modifying core and fan nozzles did not generally equal the thrust loss from modifying them simultaneously. Flow blockage from tabs did not scale directly with cruise thrust loss and the interaction between fan flow and the core nozzle seemed to strongly affect noise and cruise performance. Finally, the nozzle configuration candidates for full-scale engine demonstrations are identified.

Naseem H Saiyed↗

NASA NTRS2005

A Kinetic and Product Study of the Cl + HO2 Reaction

Absolute rate data and product branching ratios for the reactions Cl + HO2 to HCl + O2 (k1a) and Cl + HO2 to OH + ClO (k1b) have been measured from 226 to 336 K at a total pressure of 1 Torr of helium using the discharge flow resonance fluorescence technique coupled with infrared diode laser spectroscopy. For kinetic measurements, pseudo-first-order conditions were used with both reagents in excess in separate experiments. HO2 was produced by two methods: through the termolecular reaction of H atoms with O2 and also by the reaction of F atoms with H2O2. Cl atoms were produced by a microwave discharge of Cl2 in He. HO2 radicals were converted to OH radicals prior to detection by resonance fluorescence at 308 nm. Cl atoms were detected directly at 138 nm also by resonance fluorescence. Measurement of the consumption of HO2 in excess Cl yielded k1a and measurement of the consumption of Cl in excess HO2 yielded the total rate coefficient, k1. Values of k1a and k1 derived from kinetic experiments expressed in Arrhenius form are (1.6 +/- 0.2) x 10-11 exp[(249 +/- 34)/T] and (2.8 +/- 0.1) x 10-11 exp[(123 +/- 15)/T] cm3 molecule-1 s-1, respectively. As the expression for k1 is only weakly temperature dependent, we report a temperature-independent value of k1 = (4.5 +/- 0.4) x 10-11 cm3 molecule-1 s-1. Additionally, an Arrhenius expression for k1b can also be derived: k1b = (7.7 +/- 0.8) x 10-11 exp[-(708 +/- 29)/T] cm3 molecule-1 s-1. These expressions for k1a and k1b are valid for 226 K T 336 and 256 K T 296 K, respectively. The cited errors are at the level of a single standard deviation. For the product measurements, an excess of Cl was added to known concentrations of HO2 and the reaction was allowed to reach completion. HCl product concentrations were determined by IR absorption yielding the ratio k1a/k1 over the temperature range 236 K T 296 K. OH product concentrations were determined by resonance fluorescence giving rise to the ratio k1b/k1 over the temperature range 226 K T 336 K. Both of these ratios were subsequently converted to absolute numbers. Values of k1a and k1b from the product experiments expressed in Arrhenius form are (1.5 +/- 0.1) x 10-11 exp[(222 +/- 17)/T] and (10.6 +/- 1.5) x 10-11 exp[-(733 +/- 41)/T] cm3 molecule-1 s-1, respectively. These expressions for k1a and k1b are valid for 256 K T 296 and 226 K T 336 K, respectively. A combination of the kinetic and product data results in the following Arrhenius expressions for k1a and k1b of (1.4 +/- 0.3) x 10-11 exp[(269 +/- 58)/T] and (12.7 +/- 4.1) x 10-11 exp[-(801 +/- 94)/T] cm3 molecule-1 s-1, respectively. Numerical simulations were used to check for interferences from secondary chemistry in both the kinetic and product experiments and also to quantify the losses incurred during the conversion process HO2 to OH for detection purposes.

rate constants↗

NASA NTRS1983

Halocarbon concentration patterns associated with frontal passages

The atmospheric mixing ratios of CCl2F2 (F-12) and CCl3F (F-11) increase abruptly up to 14 ppt (F-12) and 8 ppt (F-11) after strong cold fronts pass and decrease abruptly after warm fronts pass at a semicontinuous monitoring station near Pullman, WA (46 deg 42 min N, 117 deg 10 min W). It is concluded that air masses from higher latitudes (above 60 deg N) can have F-12 and/or F-11 concentrations as much as 5 percent higher than mid-latitude air masses. Conversely, nitrous oxide shows no significant changes during frontal passages and is uniformly distributed between air masses.

Carter, M. W.↗

NASA NTRS1980

Adhesion, friction, and wear of binary alloys in contact with single-crystal silicon carbide

Sliding friction experiments, conducted with various iron base alloys (alloying elements are Ti, Cr, Mn, Ni, Rh and W) in contact with a single crystal silicon carbide /0001/ surface in vacuum are discussed. Results indicate atomic size misfit and concentration of alloying elements play a dominant role in controlling adhesion, friction, and wear properties of iron-base binary alloys. The controlling mechanism of the alloy properties is as an intrinsic effect involving the resistance to shear fracture of cohesive bonding in the alloy. The coefficient of friction generally increases with an increase in solute concentration. The coefficient of friction increases as the solute-to-iron atomic radius ratio increases or decreases from unity. Alloys having higher solute concentration produce more transfer to silicon carbide than do alloys having low solute concentrations. The chemical activity of the alloying element is also an important parameter in controlling adhesion and friction of alloys.

Miyoshi, K.↗

NASA NTRS1980

The adhesion, friction, and wear of binary alloys in contact with single-crystal silicon carbide

Sliding friction experiments were conducted with various iron-base alloys (alloying elements were Ti, Cr, Ni, Rh, and W) in contact with a single-crystal silicon carbide (0001) surface in vacuum. Results indicate atomic size misfit and concentration of alloying elements play a dominant role in controlling adhesion, friction, and wear properties of iron-base binary alloys. The controlling mechanism of the alloy properties is an intrinsic effect involving the resistance to shear fracture of cohesive bonding in the alloy. The coefficient of friction generally increases with an increase in solute concentration. The coefficient of friction increases as the solute-to-iron atomic radius ratio increases or decreases from unity. Alloys having higher solute concentration produce more transfer to silicon carbide than do alloys having low solute concentrations. The chemical activity of the alloying element is also an important parameter in controlling adhesion and friction of alloys.

Miyoshi, K.↗

NASA NTRS2000

BOREAS TE-5 CO2 Concentration and Stable Isotope Composition

The BOREAS TE-5 team collected measurements in the NSA and SSA on gas exchange, gas composition, and tree growth. This data set contains measurements of the concentration and stable carbon (C-13/C-12 and oxygen (O-18/O-16) isotope ratios of atmospheric CO2 in air samples collected at different heights within forest canopies. The data were collected to determine the influence of photosynthesis and respiration by the forest ecosystems on the concentration and stable isotope ratio of atmospheric CO2 These measurements were collected at the SSA during each 1994 IFC at OJP, OBS, and OA sites. Measurements were also collected at the NSA during each 1994 IFC at the OJP, T6R5S TE UBS, and T2Q6A TE OA sites. The stable isotope ratios are expressed using standard delta notation and in units of per mil. The isotope ratios are expressed relative to the international standard, PDB, for both carbon and oxygen samples. The data are stored in tabular ASCII files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Activity Archive Center (DAAC).

Hall, Forrest G.↗

NASA NTRS1978

Quantitative mapping by remote sensing of an ocean acid-waste dump

Results from quantitative analysis show that airplane remotely sensed spectral data can be used to quantify and map an acid-waste dump in terms of its particulate iron concentration. These same data, however, could not be used to map the dump in terms of total suspended solids, organic suspended solids, or inorganic suspended solids concentrations. A single-variable equation using the ratio of band 2 (440 to 490 nm) radiance to band 4 (540 to 580 nm) radiance was used to quantify the iron concentration in the acid-waste dump. The acid waste that was mapped varied in age from freshly dumped to 31/2 hr. Particulate iron concentrations in the acid waste were estimated to range up to 1.1 mg/l at a depth of 0.46 m. A classification technique was developed to identify pixels in the data set affected by sun glitter.

Ohlhorst, C. W.↗

NASA NTRS2020

Revisiting the Effectiveness Of HCHO/NO2 Ratios for Inferring Ozone Sensitivity to Its Precursors Using High Resolution Airborne Remote Sensing Observations in A High Ozone Episode During the KORUS-AQ Campaign

The nonlinear chemical processes involved in ozone production (P(O3)) have necessitated using proxy indicators to convey information about the primary dependence of P(O3) on volatile organic compounds (VOCs) or nitrogen oxides (NOx). In particular, the ratio of remotely sensed columns of formaldehyde (HCHO) to nitrogen dioxide (NO2) has been widely used for studying O3 sensitivity. Previous studies found that the errors in retrievals and the incoherent relationship between the column and the near-surface concentrations are a barrier in applying the ratio in a robust way. In addition to these obstacles, we provide calculational-observational evidence, using an ensemble of 0-D photochemical box models constrained by DC-8 aircraft measurements on an ozone event during the Korea-United States Air Quality (KORUS-AQ) campaign over Seoul, to demonstrate the chemical feedback of NO2 on the formation of HCHO is a controlling factor for the transition line between NOx-sensitive and NOx-saturated regimes. A fixed value (~2.7) of the ratio of the chemical loss of NOx (LNOx) to the chemical loss of HO2+RO2 (LROx) perceptibly differentiates the regimes. Following this value, data points with a ratio of HCHO/NO2 less than 1 can be safely classified as NOx-saturated regime, whereas points with ratios between 1 and 4 fall into one or the other regime. We attribute this mainly to the HCHO-NO2 chemical relationship causing the transition line to occur at larger (smaller) HCHO/NO2 ratios in VOC-rich (VOC-poor) environments. We then redefine the transition line to LNOx/LROx~2.7 that accounts for the HCHO-NO2 chemical relationship leading to HCHO = 3.7 × (NO2 – 1.14 × 1016 molec.cm-2). Although the revised formula is locally calibrated (i.e., requires for readjustment for other regions), its mathematical format removes the need for having a wide range of thresholds used in HCHO/NO2 ratios that is a result of the chemical feedback. Therefore, to be able to properly take the chemical feedback into consideration, the use of HCHO = a × (NO2 – b) formula should be preferred to the ratio in future works. We then use the Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) airborne instrument to study O3 sensitivity in Seoul. The unprecedented spatial (250 × 250 m2) and temporal (~every 2 h) resolutions of HCHO and NO2 observations form the sensor enhance our understanding of P(O3) in Seoul; rather than providing a crude label for the entire city, more in-depth variabilities in chemical regimes are observed that should be able to inform mitigation strategies correspondingly.

KORUS-AQ; formaldehyde; NOx; VOC; OMI; GeoTASO; oz↗

NASA NTRS2004

Thermal Structure of the TTL and Its Relation to Stratospheric-Tropospheric Exchange of Water

This document describes the annual cycle of the trajectory track line (TTL) fine scale thermal structure as captured by global positioning system (GPS) radio occultation and the pressure levels of the East Meets West Foundation (EMWF) weather analysis. This annual cycle is compared to the annual cycle in water concentrations measured by the HALogen Occultation Experiment (HALOE). A comparison between saturation mixing ratios at the temperatures captured by GPS radio occultation and HALOE concentrations of water vapor shows an annual cycle that is dominated by supersaturation in the boreal winter months, when the upward mass fluxes are larger, and subsaturation in the summer. The longitudinal dependence of these cycles is discussed as well as the possible implications for the seasonality of stratospheric-troposheric exchanges of water.

climates↗

NASA NTRS1972

U-Th-Pb and Rb-Sr measurements on some Apollo 14 lunar samples.

The concentrations of selected elements and elemental ratios in some Apollo 14 samples are presented in a table. Another table shows the isotopic composition of lead and strontium in some Apollo 14 samples. Graphs are provided with lead isotope ratio plots and a strontium evolution diagram. Rb-Sr ages are discussed together with isochron age methods of U-Th-Pb, a primary Pb-Pb isochron, a secondary Pb-Pb isochron, U-Pb concordia age relations, and U-Th-Pb concordia relations. Breccias and some soil samples as well as a basalt sample give evidence of significant enrichment of lead relative to uranium and thorium billions of years ago at the Fra Mauro site.

Tatsumoto, M.↗

NASA NTRS1976

A geochemical anomaly contiguous with the Dorsa Geike wrinkle ridge in Mare Fecunditatis

The orbital Al/Si X-ray fluorescence data from Apollo 15 and 16 reveal a concentration of unusually low Al/Si intensity ratios associated with a 220-km long ray along the northeast-southwest trending wrinkle ridge, Dorsa Geike, of the Mare Fecunditatis. The paper describes in detail the analysis of the Al/Si X-ray fluorescence data by which this geochemical anomaly was discovered. Correlation with other remote sensing data also indicates that the ridge area is different from the rest of the mare. It is possible that the material associated with the low Al/Si intensity ratio is of different composition than the adjacent mare regolith. Downslope transport along the ridge and arch could expose basalts which contrast chemically with surrounding regolith. The anomaly could also be due to extrusion of a volcanic rock of different composition at the fracture system represented by the wrinkle ridge.

Andre, C. G.↗

NASA NTRS1977

Primordial noble gases in chondrites - The abundance pattern was established in the solar nebula

Ordinary chondrites, like carbonaceous chondrites, contain primordial noble gases mainly in a minor phase comprising not more than 0.05 percent of the meteorite, probably an iron-chromium sulfide. The neon-20/argon-36 ratios decrease with increasing argon-36 concentration, as expected if the gas pattern was established by condensation from the solar nebula, and was negligibly altered by metamorphism in the meteorite parent bodies. Meteoritic and planetary matter apparently condensed over a substantial range of temperatures.

Alaerts, L.↗

NASA NTRS1978

Quantitative mapping of particulate iron in an ocean dump using remotely sensed data

A remote sensing experiment was conducted at the industrial acid waste ocean dump site located approximately 38 n mi SE of Cape Henlopen, Delaware, to see if there was a relationship between aircraft remotely sensed spectral signatures and the iron concentration measured in the plume. Results are presented which show that aircraft remotely sensed spectral data can be used to quantify and map an acid waste dump in terms of its particulate iron concentration. A single variable equation using the ratio of band 2 (440-490 nm) radiance to band 4 (540-580 nm) radiance was used to quantify the acid plume and the surrounding water. The acid waste varied in age from freshly dumped to 3 1/2 hours old. Particulate iron concentrations in the acid waste were estimated to range up to 1.1 mg/liter at the 0.46 meter depth. A classification technique was developed to remove sunglitter-affected pixels from the data set.

Ohlhorst, C. W.↗

NASA NTRS1982

Compilation of atmospheric gas concentration profiles from 0 to 50 km

A set of 52 atmospheric gas concentration profiles between 0 and 50 km was compiled as a convenient reference data set for calculation of atmospheric infrared absorption or emission signals and for initialization of iterative procedures for retrieval of gas concentrations from measured data. The distributions of volume mixing ratio as a function of altitude generally correspond to typical diurnally averaged, seasonally averaged Northern Hemisphere midlatitude gas concentration profiles. Profiles are given for all gases included in current infrared atmospheric absorption line parameter compilations, and for a number of additional important trace gases.

Smith, M. A. H.↗

NASA NTRS1983

Sixth foray for pristine nonmare rocks and an assessment of the diversity of lunar anorthosites

A compositional and petrographic characterization of 11 nonmare samples shows five to be pristine, and four probably pristine. Five of the 11 are unique anorthosites that considerably extend the diversity of lunar anorthosites. Alkali anorthosites are rich in incompatible elements. The nature of the correlations between longitude and such parameters as Eu and Sm concentrations, and Sc/Sm, Ti/Sm, and Ca/Na ratios, has been elucidated for the case of the pristine samples because five are fro a western site (Apollo 14). The ratios determined for the ferroan anorthosite 14312c are close to normal, but significantly displaced in the direction of the nonferroan, western pristine rocks. This suggests that the composition-longitude relationships are as old as the late stages of the crystallization of the putative magma ocean.

Warren, P. H.↗

NASA NTRS1983

The Cancer Cluster - An unbound collection of groups

A surface density contour map of the Cancer Cluster derived from galaxy counts in the Zwicky catalog is presented. The contour map shows that the galaxy distribution is clumpy. When this spatial distribution is combined with nearly complete velocity information, the clumps stand out more clearly; there are significant differences in the mean velocities of the clumps which exceed their internal velocity dispersions. The Cancer Cluster is not a proper 'cluster' but is a collection of discrete groups, each with a velocity dispersion of approximately 300 km/s, separating from one another with the cosmological flow. The mass-to-light ratio for galaxies in the main concentration is approximately 320 solar masses/solar luminosities (H sub 0 = 100 km/s Mpc).

Geller, M. J.↗

NASA NTRS1985

The effect of tantalum on the structure/properties of two polycrystalline nickel-base superalloys: B-1900 + Hf MAR-M247

The microstructure, phase compositions, and phase fractions were studied in conventionally cast B-1900 + Hf and both conventionally cast and directionally solidified MAR-M247 as a function of tantalum concentration. The hot tensile and creep rupture properties of the solutionized and aged MAR-M247-type alloys were also determined as a function of tantalum level. The effects of tantalum on the microstructure and phase compositions of B-1900 + Hf and MAR-M247 (conventionally cast and directionally solidified) were found to be very similar. The addition of tantalum to the as cast and heat treated alloys was shown to cause the partial replacement of the Hf in the MC carbides by Ta, although the degree of replacement was decreased by the solutionizing and aging heat treatment. The gamma prime and minor phase fractions (primarily MC type carbides) both increased approximately linearly with tantalum concentration. The gamma prime phase compositions were relatively insensitive to tantalum variations with the exception of the tantalum and/or hafnium levels. Bulk tantalum additions increased the tantalum, chromium, and cobalt levels of the gamma phase in both alloy series. The increase in the concentrations of the latter two elements in the gamma phase was a result of the decrease in the gamma phase fraction with increasing bulk tantalum concentration and constant gamma/gamma prime partitioning ratio. Tantalum additions increased the yield stress and ultimate tensile strength of the directionally solidified MAR-M247 type alloys and had no significant effect on ductility.

Janowski, G. M.↗

NASA NTRS1984

Noble gas contents of shergottites and implications for the Martian origin of SNC meteorites

Three meteorites belonging to the rare group of SNC achondrites, which may have originated in the planet Mars, have been subjected to noble gas isotopic concentration measurements. The elemental and isotopic ratios obtained are unlike those for any other noble gas components except those obtained in analyses of the Martian atmosphere by Viking spacecraft. It is hypothesized that the Kr and Xe gases represent a portion of the Martian atmosphere which was shock-implanted in the case of Elephant Moraine A79001, and that they constitute direct evidence of a Martian origin for the shergottite meteorites. If the SNC meteorites were ejected from Mars at the shergottite shock age of about 180 My ago, they must have been objects more than 6 m in diameter which experienced at least three space collisions to initiate cosmic ray exposure.

Bogard, D. D.↗