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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

Flaw growth of 7075, 7475, 7050 and 7049 aluminum alloy plate in stress corrosion environments

Marine atmosphere and laboratory stress corrosion test results on smooth and precracked specimens from 7075, 7475, 7050, and 7049 alloy plates (1.25 and 3.0-in. thick) are presented. It is shown that for a given strength level, alloys 7050-T7X and 7049-T7X have superior short-transverse stress corrosion resistance (SCR) to 7X75-T7X. At typical strength levels above the minimum, for example, SCR of these alloys is considerably better than that of 7075-T76, and approaches that of 7075-T73. Alloy 7475 maintains an advantage in the area of fracture toughness, however, because it can be thermally processed to give particularly clean microstructures. Results from precracked specimens are in good qualitative agreement with those obtained from smooth specimens. Although both specimen types are capable of distinguishing between -T6, -T76 and -T73 tempers in relatively short time periods the precracked specimen provides more information about crack growth rates.

Dorward, R. C.↗

Potential benefits of a ceramic thermal barrier coating on large power generation gas turbine

Thermal barrier coating design option offers benefit in terms of reduced electricity costs when used in utility gas turbines. Options considered include: increased firing temperature, increased component life, reduced cooling air requirements, and increased corrosion resistance (resulting in increased tolerance for dirty fuels). Performance and cost data were obtained. Simple, recuperated and combined cycle applications were considered, and distillate and residual fuels were assumed. The results indicate that thermal barrier coatings could produce large electricity cost savings if these coatings permit turbine operation with residual fuels at distillate-rated firing temperatures. The results also show that increased turbine inlet temperature can result in substantial savings in fuel and capital costs.

Clark, J. S.↗

Evaluation and control of environmental corrosion for aluminum and steel alloys

Corrosion protection systems for aerospace application and the effects of surface treatments and methods of controlling stress corrosion are evaluated. Chromate pigmented systems were found to be most effective for aluminum alloys; zinc-rich coatings gave the greatest protection to steel alloys. Various steel and aluminum alloys are rated for stress corrosion resistance.

Franklin, D. B.↗

Ferrographic analysis of wear debris generated in accelerated rolling element fatigue tests

The types and quantities of wear particles generated during accelerated ball rolling contact fatigue tests were determined. Ball specimens were made of AMS 5749, a corrosion resistant, high-temperature bearing steel. The lubricant was a super-refined naphthenic mineral oil. Conditions included a maximum Hertz stress of 5.215 times 10 to the 9th power Pa and a shaft speed of 10,000 rpm. Four types of wear particles were observed; normal rubbing wear particles, fatigue spall particles, spheres, and friction polymer.

Jones, W. R., Jr.↗

A Representative Shuttle Environmental Control System

The Representative Shuttle Environmental Control System (RSECS) provides a ground test bed to be used in the early accumulation of component and system operating data, the evaluation of potential system improvements, and possibly the analysis of Shuttle Orbiter test and flight anomalies. Selected components are being subjected to long term tests to determine endurance and corrosion resistance capability prior to Orbiter vehicle experience. Component and system level tests in several cases are being used to support flight certification of Orbiter hardware. These activities are conducted as a development program to allow for timeliness, flexibility, and cost effectiveness not possible in a program burdened by flight documentation and monitoring constraints.

Brose, H. F.↗

Wrought nickel-base superalloy

Superalloy for advanced temperature use is suited to cost-saving powder-metallurgy manufacturing methods and has improved phase stability during longtime heating. Wide variety of applications exists where stainless steels are used for oxidation and/or corrosion resistance.

Miner, R. V.↗

Testing composite sheets at high temperatures

Candidate materials for skins of flexural sandwich beams can be compressive- or tensile-tested at high temperature by using corrosion resistant steel (CRES) for core material. Tests with CRES core have been made at temperatures as high as 260 C. Future tests at temperatures above 371 C may be permissible.

Jones, J. S.↗

Embrittlement proof nickel-alloy bellows

Thin cover of corrosion-resistant steel (CRES) protects metal bellows and ducts against hydrogen embrittlement. Bellow current carries hydrogen at high pressure and currently is used in the engine of Space Shuttle.

Daniels, C. M., Jr.↗

Improved ceramic heat exchange material

Improved corrosion resistant ceramic materials that are suitable for use as regenerative heat exchangers for vehicular gas turbines is reported. Two glass-ceramic materials, C-144 and C-145, have superior durability towards sulfuric acid and sodium sulfate compared to lithium aluminosilicate (LAS) Corning heat exchange material 9455. Material C-144 is a leached LAS material whose major crystalline phase is silica keatite plus mullite, and C-145 is a LAS keatite solid solution (S.S.) material. In comparison to material 9455, material C-144 is two orders of magnitude better in dimensional stability to sulfuric acid at 300 C, and one order of magnitude better in stability to sodium sulfate at 1000 C. Material C-145 is initially two times better in stability to sulfuric acid, and about one order of magnitude better in stability to sodium sulfate. Both C-144 and C-145 have less than 300 ppm delta L/L thermal expansion from ambient to 1000 C, and good dimensional stability of less than approximately 100 ppm delta L/L after exposure to 1000 C for 100 hours. The glass-ceramic fabrication process produced a hexagonal honeycomb matrix having an 85% open frontal area, 50 micrometer wall thickness, and less than 5% porosity.

Mccollister, H. L.↗

Electrolytic pretreatment of urine

Electrolysis has been under evaluation for several years as a process to pretreat urine for ultimate recovery of potable water in manned spacecraft applications. The conclusions that were drawn from this investigation are the following: (1) A platinum alloy containing 10 percent rhodium has been shown to be an effective, corrosion-resistant anode material for the electrolytic pretreatment of urine. Black platinum has been found to be suitable as a cathode material. (2) The mechanism of the reactions occurring during the electrolysis of urine is two-stage: (a) a total Kjeldahl nitrogen and total organic carbon (TOC) removal in the first stage is the result of electrochemical oxidation of urea to CO2, H2O, and ammonia followed by chloride interaction to produce N2 from ammonia, (b) after the urea has been essentially removed and the chloride ions have no more ammonia to interact with, the chloride ions start to oxidize to higher valence states, thus producing perchlorates. (3) Formation of perchlorates can be suppressed by high/low current operation, elevated temperature, and pH adjustment. (4) UV-radiation showed promise in assisting electrolytic TOC removal in beaker tests, but was not substantiated in limited single cell testing. This may have been due to non-optimum configurations of the single cell test rig and the light source.

Source record↗

Characterization of wear debris generated in accelerated rolling-element fatigue tests

A ferrographic analysis was used to determine the types and quantities of wear debris generated during accelerated rolling contact fatigue tests. The five-ball rolling contact fatigue tester was used. Ball specimens were made of a corrosion resistant, high-temperature bearing steel. The lubricant was a superrefined naphthenic mineral oil. Conditions included a maximum Hertz stress of 5.52 10 to the 9th power Pa and a shaft speed of 10,000 rpm. Four types of wear debris were observed: (1) normal rubbing wear particles, (2) fatigue microspall particles, (3) spheres, and (4) friction polymer deposits. The characterization of wear debris as a function of time was of limited use in predicting fatigue failures in these accelerated tests.

Jones, W. R., Jr.↗

Design package for instrumentation of the Decade 80 house in Tucson, Arizona

A design package covering instrumentation and system design for the Decade 80 House in Tucson, Arizona is presented. The solar house is instrumented for the purpose of gathering data to determine the solar heating and cooling system performance. The use of copper in the construction of the house is a first choice construction material because it conducts heat and resists corrosion better than other materials and therefore provides a more efficient and economical system. Equipment and site specifications are reported, along with floor plans showing the location of the site instrumentation hardware.

Source record↗

Electron emission from nickel-alloy surfaces in cesium vapor

An experimental apparatus and measurement techniques are described for measuring the thermionic emission from cesium-activated materials having adequate high-temperature properties such as creep strength and corrosion resistance, which might ultimately reduce the cost of thermionic converters. The electron emission characteristics are measured for nickel, Inconel 600, and Hastelloy X probes with a 412 K cesium reservoir. It is found that the nickel alloys exhibit a peak electron emission 1.4 to 2.1 times greater than pure nickel. Both the Inconel and the Hastelloy samples have work functions of 1.64 eV at peak emission. The minimum cesiated work functions are estimated to be 1.37 eV for Inconel at a probe temperature of 750 K and 1.4 eV for Hastelloy at a probe temperature of 665 K. The bare work functions for both alloys is estimated to be about the same as for pure nickel, 4.8 eV.

Manda, M.↗

Ferrographic analysis of wear debris generated in accelerated rolling element fatigue tests

Ferrographic analysis was used to determine the types and quantities of wear particles generated during accelerated rolling contact fatigue tests. The NASA five-ball rolling contact fatigue tester was used. Ball specimens were made of AMS 5749, a corrosion-resistant high-temperature bearing steel. The lubricant was a super-refined naphthenic mineral oil. Conditions included a maximum Hertz stress of 5.52 billion Pa and a shaft speed of 10,000 rpm. Four types of wear particles were observed: normal rubbing wear particles, fatigue spall particles, spheres, and friction polymer.

Jones, W. R., Jr.↗

New alloys to conserve critical elements

Previous studies and surveys on availability of domestic reserves have shown that chromium is a most critical element within the U.S. metal industry. More precisely, the bulk of chromium is consumed in the production of stainless steels, specifically Type 304 stainless steel (304SS) which contains 18% Cr. The present paper deals with means of reducing chromium in commercial stainless steels by substituting more abundant or less expensive elements with the intent of maintaining the properties of 304SS. The discussion focuses on some of the oxidation and corrosion properties of new substitute stainless steels with only 12% Cr, which represents a potential saving of 33% of the chromium consumed in the production of 304SS. The alloying elements substituted for Cr in 304SS are selected according to their potential for protective oxide formation during high-temperature oxidation; these are Al, Si, Ti, Y, and misch metal which is 99.7% rare-earth metals containing 50 to 55% cerium. Other alloying elements to impart corrosion resistance are Mn, Mo, and V.

Stephens, J. R.↗

Thermal barrier coatings: Burner rig hot corrosion test results

A Mach 0.3 burner rig test program was conducted to examine the sensitivity of thermal barrier coatings to Na and V contaminated combustion gases simulating potential utility gas turbine environments. Coating life of the standard ZrO2-12Y2O3/Ni-16.2Cr-5.6Al-0.6Y NASA thermal barrier coating system which was developed for aircraft gas turbines was significantly reduced in such environments. Two thermal barrier coating systems, Ca2SiO4/Ni-16.2Cr-5.6Al-0.6Y and ZrO2-8Y2O3/Ni-16.4Cr-5.1Al-0.15Y and a less insulative cermet coating system, 50 volume percent MgO-50 volume percent Ni-19.6Cr-17.1Al-0.97Y/Ni-16.2Cr-5.6Al-0.6Y, were identified as having much improved corrosion resistance compared to the standard coating.

Hodge, P. E.↗

Tests of NASA ceramic thermal barrier coating for gas-turbine engines

A two-layer thermal barrier coating system with a bond coating of nickel-chromium-aluminum-yttrium and a ceramic coating of yttria-stabilized zirconia was tested for corrosion protection, thermal protection and durability. Full-scale gas-turbine engine tests demonstrated that this coating eliminated burning, melting, and warping of uncoated parts. During cyclic corrosion resistance tests made in marine diesel fuel products of combustion in a burner rig, the ceramic cracked on some specimens. Metallographic examination showed no base metal deterioration.

Liebert, C. H.↗

Design and fabrication of a skin stringer discrete tube actively cooled structural panel

The design optimization and practical implementation of actively cooled structural panel concepts was investigated. The desired actively cooled structural panel consisted of the cooled skin and a substructure. The primary load carrying components were fabricated from 2024-T3 aliminum alloy. The 3003-H14 coolant passage tubing was chosen because of its excellent corrosion resistance, workability needed to obtain the desired cross sectional shape, and strength. The Epon 951 adhesive was selected for its excellent structural properties and is the thinnest of available films, 0.064 mm. The Eccobond 58C silver filled epoxy was chosen because of its high thermal conductivity, and the alumina filled Epon 828 was chosen for structural and expansion characteristics.

Anthony, F. M.↗