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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Capturing Correlation Effects in Positron Binding to Atoms and Molecules

A major challenge in contemporary electronic structure theory involves the development of methods to describe in a balanced manner the contribution of correlation effects to energy differences. This challenge can be even greater for multicomponent systems containing more than one type of quantum particle. In the present work, we describe a flexible code for carrying out self-consistent field and configuration interaction (CI) calculations on multicomponent systems and use it to generate trial wave functions for use in diffusion Monte Carlo (DMC) calculations of the positron affinity of Be, Be 2 , Be 4 , Mg, CS 2 , and benzene. The resulting positron affinities (PAs) are in good agreement with the best values from the literature.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Accelerated optimization of pure metal and ligand compositions for light-driven hydrogen production

Photocatalytic hydrogen production is a promising alternative to traditional hydrogen production. To implement photocatalytic hydrogen production the development of efficient, sustainable, and stable catalysts is necessary, and overcoming the current challenges surrounding high dimensional search spaces requires both computational and experimental efforts. Utilizing photo driven processes, stable colloidal metal catalysts can be formed in situ for efficient hydrogen production from water. When considering colloidal catalysts, stability is typically a concern solved through the addition of supports or ligands. In this work, poly(ethylene glycol) methyl ether thiol acts as a stabilizing ligand eliminating the need for catalyst supports while providing stable and active nanoparticle catalysts for more than 45 hours of reaction time and illumination. These systems utilize molecular photosensitizers, water reduction catalysts, stabilizing ligands, water, a sacrificial reductant, and organic solvents, posing new challenges pertaining to the optimization of multi-variable systems. Design of experiments (DOE) is applied to accelerate the understanding of variable interactions and is used as a tool to rapidly optimize the compositions of Au, Cu, Ni, and Fe containing systems. Through a collaboration leveraging computation and experimentation (both high throughput and characterizations), optimized performance peaks were obtained for each of these metals alongside distinct mapping of expected activity associated with photosensitizer, metal, and ligand concentration variations. With the highly digitized workflow, this study allowed for comparative generalizations to be made regarding photo driven hydrogen production for all four metals.

08 HYDROGEN↗
DOE OSTI2020

Energy and momentum conservation in the Euler–Poincaré formulation of local Vlasov–Maxwell-type systems

The action principle by Low for the classic Vlasov–Maxwell system contains a mix of Eulerian and Lagrangian variables. This renders the Noether analysis of reparametrization symmetries inconvenient, especially since the well-known energy- and momentum-conservation laws for the system are expressed in terms of Eulerian variables only. While an Euler–Poincaré formulation of Vlasov–Maxwell-type systems, effectively starting with Low's action and using constrained variations for the Eulerian description of particle motion, has been known for a while Cendra et al, it is hard to come by a documented derivation of the related energy- and momentum-conservation laws in the spirit of the Euler–Poincaré machinery. To our knowledge only one such derivation exists in the literature so far, dealing with the so-called guiding-center Vlasov–Darwin system Sugama et al. The present exposition discusses a generic class of local Vlasov–Maxwell-type systems, with a conscious choice of adopting the language of differential geometry to exploit the Euler–Poincaré framework to its full extent. After reviewing the transition from a Lagrangian picture to an Eulerian one, we demonstrate how symmetries generated by isometries in space lead to conservation laws for linear- and angular-momentum density and how symmetry by time translation produces a conservation law for energy density. Here, we also discuss what happens if no symmetries exist. Finally, two explicit examples will be given—the classic Vlasov–Maxwell and the drift-kinetic Vlasov–Maxwell—and the results expressed in the language of regular vector calculus for familiarity.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1968

Development requirements for a high-energy hybrid propulsion system Final report

This document presents the development requirements, costs, and schedule for a high-energy upper-stage hybrid propulsion system. High energy is achieved through the use of a lithium fuel formulation (solid) and fluorinated oxidizer (liquid). The propulsion system contains 3 2OO lb of propellant and may be used as a terminal stage for Atlas/Centaur or DSV-3M Delta launch vehicle. A program to develop a fluorinated hybrid propulsion system could be initiated with little risk. An extensive investigation revealed that the technology required to develop most of the components has either been demonstrated or is in progress. Further, it was found that there were no areas of critical technology. The cost to develop a hybrid propulsion system to a status where it could be integrated into a flight-test stage is about $17 million. This cost does not include the development of the stage astrionics. Length of the total development program is 34 months. A total recurring cost of $381 600 was estimated for the first unit (less astrionics and fee). This includes purchased hard\rare, manufacturing, material, assembly, and test costs.

M.B. Adams↗
NASA NTRS2010

Research on Spoken Dialogue Systems

Research in the field of spoken dialogue systems has been performed with the goal of making such systems more robust and easier to use in demanding situations. The term "spoken dialogue systems" signifies unified software systems containing speech-recognition, speech-synthesis, dialogue management, and ancillary components that enable human users to communicate, using natural spoken language or nearly natural prescribed spoken language, with other software systems that provide information and/or services.

Aist, Gregory↗
NASA NTRS2022

Components Refurbishment and Chemical Analysis Facility Hot Spot 1 Year 2 Annual Performance Monitoring Report

The Performance Monitoring Report presents the Year 2 operations, maintenance, and monitoring (OM&M) activities for the hydraulic containment system (HCS) Interim Measures (IM) at the Components Refurbishment and Chemical Analysis (CRCA) Facility located at John F. Kennedy Space Center (KSC), Florida. Year 2 operations extended from September 2020 to August 2021 and included: operation, maintenance and monitoring of the HCS; performance monitoring through collection of groundwater samples; and sub-slab gas and ambient air sampling. The existing hydrogeologic model was also updated. The system is performing as designed, and groundwater data demonstrate contaminant reduction.

CRCA↗
DOE OSTI2019

The Effect of Citric Acid on Physicochemical Properties of Hydrophilic Carboxymethyl Starch-Based Films

The carboxymethyl starch-based films in a presence of citric acid were prepared by casting technique. The influence of citric acid content on physicochemical properties of obtained hydrophilic films were evaluated (solubility in water, moisture absorption, mechanical and thermal properties). The crosslinking of starch derivative chains has been confirmed by FTIR spectroscopy, however, an excess of citric acid could cause hydrolysis of carboxymethyl starch chains. The best mechanical performance has been noted for the system containing 30 wt% (the highest tensile strength as well Young modulus 160 kPa and 650 kPa, respectively) as well as the highest T{sub g} (ca. 58 °C). Additionally for the mentioned system the lowest solubility in water has been determined.

36 MATERIALS SCIENCE↗
NASA NTRS1987

Dynamic behavior of dissymmetric rotor bearings modelled with a periodic coefficient large system

The instability and unbalance response of dissymmetric rotor-bearing systems containing periodic coefficients when modeling produces matrices with a large number of degrees of freedom are discussed. It is important to solve the equations and then predict the dynamic behavior of the system. This can be done knowing the instability areas and the unbalance response in the stable areas. One deals here with a large number of equations and a reduction of the number of degrees of freedom of the system is achieved through a pseudo modal method. This method is shown to give satisfactory results.

Guilhen, P. M.↗
NASA NTRS1989

NASA/RECON - Its unique resources

The capabilities of the NASA/RECON system are described. Over half of this online information retrieval system contains computerized versions of STAR and IAA. NASA/RECON also contains work in progress, contract, preview, computer software (COSMIC), space commercialization, NACA, Nalnet, NASA TechBriefs, and the Library of Congress Aerospace Medicine and Biology files. The availability and updating of the NASA/RECON system are discussed. A list of printed materials that are helpful tools for using NASA/RECON is provided.

Buchan, Ronald L.↗
NASA NTRS1995

Theory and Observations of Non-Thermal Phenomena in Hot Massive Binaries

The shock between the colliding winds in binary systems containing two massive stars accelerates particles to relativistic energies. These energetic particles can produce observable non-thermal radiation from the radio to gamma-rays. The important physical processes in such systems are very similar to those we have proposed for non-thermal emissions from single hot stars, which have shocks generated by instabilities in the radiatively driven stellar winds. This paper discusses the theory and observations of non-thermal radiation in the radio, X-ray, and gamma-ray regions from both single stars and massive binaries. Similarities and differences between the two types of systems are outlined. We discuss two important physical effects that apparently have been neglected in previous theoretical work on colliding wind binaries.

White, Richard L.↗
NASA NTRS2000

Laboratory Astrophysics Using a Spare XRS Microcalorimeter

The XRS instrument on Astro-E is a fully self-contained microcalorimeter x-ray instrument capable of acquiring optimally filtering, and characterizing events for 32 independent pixels. With the launch of the Astro-E spacecraft, a full flight spare detector system has been integrated into a laboratory cryostat for use on the electron beam ion trap (EBIT) at Lawrence Livermore National Laboratory. The detector system contains a microcalorimeter array with 32 instrumented pixels heat sunk to 60 mK using an adiabatic demagnetization refrio,erator. The instrument has a composite resolution of 8eV at 1 keV and 12eV at 6 keV with a minimum of 95% quantum efficiency. This will allow high spectral resolution, broadband observations of collisionally excited plasmas which are produced in the EBIT experiment. Unique to our instrument are exceptionally well characterized 1000 Angstrom thick aluminum on polyimide infrared blocking filters. The detailed transmission function including the edc,e fine structure of these filters has been measured in our laboratory using an erect field grating spectrometer. This will allow the instrument to perform the first broadband absolute flux measurements with the EBIT instrument. The instrument performance as well as the results of preliminary measurements will be discussed. Work performed under the auspices of the U.S. D.o.E. by Lawrence Livermore National Laboratory under contract W-7405-ENG-48 and was supported by the NASA High Energy Astrophysics Supporting Research and Technology Program.

Audley, M. Damian↗
NASA NTRS2000

Erosion Coatings for High-Temperature Polymer Composites: A Collaborative Project With Allison Advanced Development Company

The advantages of replacing metals in aircraft turbine engines with high-temperature polymer matrix composites (PMC's) include weight savings accompanied by strength improvements, reduced part count, and lower manufacturing costs. Successfully integrating high-temperature PMC's into turbine engines requires several long-term characteristics. Resistance to surface erosion is one rarely reported property of PMC's in engine applications because PMC's are generally softer than metals and their erosion resistance suffers. Airflow rates in stationary turbine engine components typically exceed 2.3 kg/sec at elevated temperatures and pressures. In engine applications, as shown in the following photos, the survivability of PMC components is clearly a concern, especially when engine and component life-cycle requirements become longer. Although very few publications regarding the performance of erosion coatings on PMC's are available particularly in high-temperature applications the use of erosion-resistant coatings to significantly reduce wear on metallic substrates is well documented. In this study initiated by the NASA Glenn Research Center at Lewis Field, a low-cost (less than $140/kg) graphite-fiber-reinforced T650 35/PMR 15 sheet-molding compound was investigated with various coatings. This sheet-molding compound has been compression molded into many structurally complicated components, such as shrouds for gas turbine inlet housings and gearboxes. Erosion coatings developed for PMC s in this study consisted of a two-layered system: a bondcoat sprayed onto a cleaned PMC surface, followed by an erosion-resistant, hard topcoat sprayed onto the bondcoat as shown in following photomicrograph. Six erosion coating systems were evaluated for their ability to withstand harsh thermal cycles, erosion resistance (ASTM G76 83 "Standard Practice for Conducting Erosion Tests by Solid Particle Impingement Using Gas Jets") using Al2O3, and adhesion to the graphite fiber polyimide composite (ASTM D 4541 95 "Pull Off Strength of Coatings"). Glenn and Allison Advanced Development Company collaborated to optimize erosion coatings for gas turbine fan and compressor applications. All the coating systems survived aggressive thermal cycling without spalling. During erosion tests (see the final photo), the most promising coating systems tested had Cr3C2-NiCr and WC-Co as the hard topcoats. In all cases, these coating systems performed significantly better than that with a TiN hard topcoat. When material depth (thickness) loss is considered, the Cr3C2-NiCr and WC-Co coating systems provided, on average, an erosion resistance 8.5 times greater than that for the uncoated PMR 15/T650 35 composite. Similarly, Cr3C2-NiCr and WC-Co coating systems adhered to the PMC substrate during tensile tests significantly better than systems containing a TiN topcoat. Differences in topcoats of Cr3C2-NiCr and WC-Co were determined by considering issues such as cost and environmental impact. The preferred erosion-resistant coating system for PMR 15/T650 35 has WC-Co as the hard topcoat. This system provides the following benefits in comparison to the coating system with Cr3C2-NiCr topcoat: lower powder material cost (15 to 20 percent), environmentally friendly materials (Cr3C2-NiCr is hazardous), and higher deposition yield (10 to 15 percent), which results in less waste.

Sutter, James K.↗
NASA NTRS1990

Search for resonances in positron-atom systems

No one likes to see a scattering cross section curve that is too smooth; it is much more interesting to find bumps and wiggles and most interesting if it is possible to understand their cause. Several types of resonances were clearly established in positron-containing systems: those lying just below a degenerate threshold (like 2s-2p in hydrogenic atoms or ions) and those representing Coulomb bound states in a rearranged channel (like Ps + H reversing positron +H(-)). Recently, two new sorts of resonances have been reported for which the resonant mechanism is not clear. The first is a very low lying resonance in the e-Ps system (obtained by an adiabatic expansion method), and the second is a similarly low lying two channel resonance in the positron -H system (obtained by a close-coupling technique.) These developments encouraged the examination of such systems using the standard methods of stabilization and complex rotation. Most of the results are negative; the low lying resonances in either system are verified. Some indication of new resonances in the e(+)-He(+) system is found; this may be caused by the attraction between Ps in the n=2 state and the He(++) nucleus.

Bhatia, A. K.↗
DOE OSTI2018

Reactive molecular dynamics simulations of an excess proton in polyethylene glycol-water solutions

We investigate the effects of both triethylene glycol (TEG) and polyethylene glycol (PEG) on the structure and transport of an excess proton (H + ) in aqueous solution. A new reactive force field (ReaxFF) parameterisation is carried out to better describe proton transfer of H + with PEG polymers in aqueous solution via training against density functional theory (DFT) calculations. Using this ReaxFF parameterisation, reactive molecular dynamics simulations are carried out for three different systems containing H + : bulk water, aqueous TEG, and aqueous PEG with a single, oriented polymer chain. The H + diffusivity is suppressed due to the presence of TEG and enhanced in the oriented chain PEG system, particularly along the axis parallel to the PEG chain, relative to bulk water. The enhancement in proton mobility along the chain axis is mainly due to the structural, rather than vehicular, component. From free energy calculations for H + transfer, the increase in proton mobility is not due to a reduction in activation energy. Finally, from pair distribution function analysis of the local structure for water and hydronium we hypothesise the increased mobility is due to an entropic effect, specifically a favourable hydrogen bond network for long range proton transport due to the oriented PEG chain.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Milky Way globular clusters in γ-rays: analysing the dynamical formation of millisecond pulsars

ABSTRACT Globular clusters (GCs) are evolved stellar systems containing entire populations of millisecond pulsars (MSPs), which are efficient γ-ray emitters. Observations of this emission can be used as a powerful tool to explore the dynamical processes leading to binary system formation in GCs. In this work, 9 yr of Fermi Large-Area Telescope data were used to investigate the γ-ray emission from all GCs in the Milky Way. Twenty-three clusters were found as γ-ray bright, with two of them never having been reported before. It was also found that magnetic braking probably has a smaller impact on the formation rate of binary systems in metal-rich GCs than previously suggested, while a large value for the two-body encounter rate seems to be a necessary condition. The influence of the encounter rate per formed binary was for the first time explored in conjunction with γ-ray data, giving evidence that if this quantity is very high, binary systems will get destroyed before having time to evolve into MSPs, thus decreasing the total number of MSPs in a GC. No extended emission was found even for clusters whose optical extent is ≈0.5°; all of them are point-like sources spatially in agreement with the optical cores of the GCs, supporting previous X-ray results of heavier objects sinking into the clusters’ cores via dynamical friction. The possibility of extrapolating these results to ultra-compact dwarf galaxies is discussed, as these systems are believed to be the intermediate case between GCs and dwarf galaxies.

de Menezes, Raniere↗
DOE OSTI2021

Power Cylinder Friction Reduction Through Coatings, Surface Finish and Design

About 7-10% of the total energy input in a vehicle is lost due to mechanical friction, and in an engine, about 50% of the total frictional losses occur at the interface between the cylinder and pistons and piston rings. Therefore, this interface offers great opportunities for friction reduction. The goal of this proposed study is to demonstrate friction reduction potential using advanced coatings, surface finish, and design on power cylinder system containing cylinder bore, piston rings, crankshaft, and advanced engine oils. Experience through years of research in this area lead us to believe that full benefit potential can be realized only by considering a systems approach.

33 ADVANCED PROPULSION SYSTEMS↗
NASA NTRS1970

Development of a portable life support system and emergency life support pack

The design, development, and fabrication of a feasibility model of a breathing bag life support system for extravehicular activity are discussed. The breathing vest and back pack portable life support system contains connectors which allow external water and gas supply. At a metabolic rate of 2000 BTU per hour, the two low pressure bottles provide 27 minutes of breathing gas for a total filled system weight of 30.5 pounds.

Source record↗
NASA NTRS1992

The binary Cepheid BP Cir - A test of evolutionary tracks

IUE spectra of the system containing the Cepheid BP Cir are used to derive the magnitude difference between the two stars (Delta V = 1.88 +/- 0.3 mag) and the spectral type of the companion (B6.0V). This is the first system yet encountered for which the standard Seaton reddening law is inappropriate. For BP Cir, a stronger 2200-A bump than the standard law is required. However, this does not affect the determination of the temperature of the hot star or the magnitude difference between the two stars, because those use the wavelength regions shorter than 1600 A and longer than 2500 A. The stars are very similar in mass. Possible pulsation in the first overtone mode implies that BP Cir B is evolved beyond the ZAMS but is still in the main sequence band. The best match to BP Cir A and B is with isochrones by Stothers and Chin (1991) with Inglesias and Rogers (1991) opacities and no core convective overshoot and Cepheid pulsation in the first overtone.

Evans, Nancy R.↗