Search NASA⌕ Search

SEARCH · Search NASA

Results for “Contribution”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS2024

Contributions of David Mauzerall to Photosynthesis Research - Celebrating His 95th Birthday

We honor here Professor David Mauzerall, a pioneer in the fields of photochemistry and photobiology of porphyrins and chlorophylls in vitro and in vivo, on the occasion of his 95th birthday. Throughout his career at The Rockefeller University, he refined our understanding of how chlorophyll converts light energy into chemical energy. He exploited top-of-the-line laser technology in developing photoacoustics and a variety of other innovative experimental approaches. His experimental work and conceptual insights contributed greatly to our understanding of photosynthesis and the possible role of photosynthesis in the origin of life. His contributions include many landmark single-authored and collaborative papers, and his legacy includes the training of others who have become authorities themselves. After providing a brief description of his research accomplishments, we include tributes from several of his coworkers and his daughters highlighting their valuable experiences with David Mauzerall on this milestone birthday.

chlorophyll↗
DOE OSTI2021

Progress report on computing the disconnected QCD and the QCD plus QED hadronic contributions to the muon's anomalous magnetic moment

We report progress on calculating the contribution to the anomalous magnetic moment of the muon from the disconnected hadronic diagrams with light and strange quarks and the valence QED contribution to the connected diagrams. The lattice QCD calculations use the highly-improved staggered quark (HISQ) formulation. The gauge configurations were generated by the MILC Collaboration with four flavors of HISQ sea quarks with physical sea-quark masses.

Bazavov, Alexei↗
DOE OSTI2023

Kinetic model-based group contribution method for derived cetane number prediction of oxygenated fuel components and blends

A four-step autoignition model was used to derive an expression for the ignition delay (ID) measured in ignition quality testers (IQT) with the derived cetane number (DCN) determined from this ID using the ASTM D6890 standard correlation. The model predicts DCN for individual compounds and blends as a function of each compound's global initiation and net chain branching rate constants. Expressions for these values were determined assuming they could be related to the functional groups present in each compound. Measurement data for 125 compounds and 94 binary and ternary blends (including oxygenates: alcohols, aldehydes, esters, ethers, and ketones), from literature and from measurements performed in our lab, were used to obtain the dependence of the measured ignition delay on each functional group. The new kinetic model-based group contribution method was able to predict the ignition delay of both pure compounds and blends, with an average DCN error of 4.4 (19%) and 2.8 (11%), respectively. Here, the blend model was also used to develop an ID mixing rule by incorporating existing IQT ignition delay data for each compound. Use of the mixing rule gave an average DCN error of 3.6 (16%) for blends. Both the blend model and mixing rule were found to be superior compared to standard linear by volume fraction or mole fraction mixing rules commonly used to estimate the DCN of mixtures.

42 ENGINEERING↗
DOE OSTI2023

Evidence-based target setting informs blue carbon strategies for nationally determined contributions

The magnitude and pace of global climate change demand ambitious and effective implementation of nationally determined contributions (NDCs). Nature-based solutions present an efficient approach to achieving mitigation, adaptation and resilience goals. Yet few nations have quantified the diverse benefits of nature-based solutions to evaluate and select ecosystem targets for their NDCs. Here we report on Belize’s pursuit of innovative, evidence-based target setting by accounting for multiple benefits of blue carbon strategies. Through quantification of carbon storage and sequestration and optimization of co-benefits, we explore time-bound targets and prioritize locations for mangrove protection and restoration. We find increases in carbon benefits with larger mangrove investments, while fisheries, tourism and coastal risk-reduction co-benefits grow initially and then plateau. We identify locations, currently lacking protected status, where prioritizing blue carbon strategies would provide the greatest delivery of co-benefits to communities. These findings informed Belize’s updated NDCs to include an additional 12,000 ha of mangrove protection and 4,000 ha of mangrove restoration, respectively, by 2030. Our study serves as an example for the more than 150 other countries that have the opportunity to enhance greenhouse gas sequestration and climate adaptation by incorporating blue carbon strategies that provide multiple societal benefits into their NDCs.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2017

LAVA Contribution to HiLiftPW-3

Launch Ascent and Vehicle Aerodynamics (LAVA) (Computational Fluid Dynamics (CFD) solver) contribution to HiLiftPW-3 (3rd AIAA CFD High Lift Prediction Workshop). Including HL-CRM (NASA High Lift Common Research Model) and JSM (Joint Statistical Modeling) case studies.

Contribution↗
DOE OSTI2024

Circular Economy Contributions to Decarbonizing the US Steel Sector

The potential benefits of the circular economy (CE) for decarbonization have recently attracted much attention in the academic and grey literature. The department of energy (DOE) industrial decarbonization roadmap highlight that in addition to the four pillars (energy efficiency, electrification, low-carbon fuels, feedstocks, and energy sources, and carbon capture, utilization, and storage (CCUS)) identified in the roadmap, "scenarios [...] will need to be developed that incorporate materials efficiency and circular economy strategies". Moreover, the roadmap identifies hard-to-abate CO2 emissions across the five industrial subsectors included in the analysis (iron & steel, chemical, food & beverage, refining, and cement manufacturing). Thus, additional options to decarbonize the industrial sector, like the CE, could prove beneficial to address those hard-to-abate emissions. Moreover, they may be less costly, require less R&D or incentives, and be more readily adopted than other strategies such as energy efficiency and CCUS. While the Industrial Decarbonization Roadmap includes some CE strategies (e.g., the increasing market share of steel from electric arc furnaces - which incorporate steel scrap), a deeper dive into what role the CE could play in the United States (US) industrial decarbonization is needed. In this work, we present several industrial decarbonization scenarios that incorporate materials efficiency and circular economy strategies for the iron & steel subsector. The scenarios identify barriers (including technical limits and constraints), opportunities, and R&D needs.Moreover, we estimate the contribution of those scenarios to reducing the industrial sector's CO2 emissions and their potential synergies with the Industrial Decarbonization Roadmap's four pillars. Iron & steel manufacturing was responsible for 90 million tons of industrial CO2 emissions in 2020 - 7% of the industrial sector's total process- related emissions. Besides recycling - which presents technical limitations due to trace contaminants - CE strategies on the demand side could lower iron & steel manufacturing emissions (e.g., the development of lighter products or business models that encourage a more intensive use). This study reviews barriers, opportunities, and trade-offs for 5 material efficiency strategies. Many topics explored in the review call for further research.

barriers↗
DOE OSTI2023

Twin Boundaries Contribute to The First Cycle Irreversibility of LiNiO 2

Abstract LiNiO 2 remains a target for layered oxide Li‐ion cathode development as it can theoretically deliver the highest energy density of this materials class. In practice, LiNiO 2 suffers from poor capacity retention due to electrochemically‐induced structural changes. While the impact of Ni off‐stoichiometry on the electrochemical performance has been extensively studied, that of planar defects present in the as‐synthesized cathode is not well understood. Advanced ex situ and operando structure probes are used to identify and quantify point and planar defects present in as‐synthesized Li 1‐y Ni 1+y O 2 cathodes and monitor their evolution during the first cycle. Specifically, a 7 Li nuclear magnetic resonance (NMR) signature characteristic of Li environments near twin boundaries is identified; an assignment supported by first‐principles calculations and scanning transmission electron microscopy (STEM) images of twin boundary defects. The NMR results suggest that the concentration of twin boundaries depends on the amount of Ni excess. Moreover, operando magnetometry and ex situ synchrotron X‐ray diffraction and NMR demonstrate that these planar defects impede Li reinsertion into the bulk cathode at reasonable discharge rates and contribute to the first cycle irreversible capacity. These findings provide new design rules for Li 1‐y Ni 1+y O 2 cathodes, whereby a reduced concentration of twin boundaries in the pristine material leads to reduced kinetic limitations and improved cathode utilization.

Nguyen, H.↗
DOE OSTI2020

Optical Response of MoTe 2 and WTe 2 Weyl Semimetals: Distinguishing between Bulk and Surface Contributions

A first-principles investigation of the optical response of the Weyl Semimetals MoTe 2 and WTe 2 is presented. The approach, based on combining two formulations, allows to both separate the intraband and interband parts of the optical conductivity and to distinguish between the bulk and surface contributions to the optical response. It is found that the response is truly anisotropic, with peaks that can be associated with interband transitions involving either bulk or surface states. The role of the relaxation time, and the relation of the calculated results with available experimental measurements, are also discussed. Furthermore, the approach reported is transferable to any system, topologically trivial or non-trivial, thus addressing the long-standing need for comprehensive characterization of the optical response.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Identifying and Amplifying the Spontaneously Formed Photo‐Charge Contribution in Opaque and Semitransparent Organic Photovoltaics

Abstract Spontaneous photo‐charge (SP) generation within the non‐fullerene (NFA) bulk helps avoid exciton (EX) related loss as compared to the traditional heterojunction route in organic solar cells (OSCs). Unfortunately, the promising SP utilization attracts little attention at this time due to the lack of knowledge on its specific contribution to the photovoltaic performance and rational optimization in high‐efficiency devices. To fill the gap, the NFAs’ SP characteristics are related with their photocurrent loss and power conversion efficiency (PCE) in state‐of‐the‐art materials. Though higher SP population is good for efficient EX utilization, it simultaneously acts as an additional photo‐charge recombination channel. The former can be further enhanced by increasing the NFAs’ crystallinity with preferred lamellar growth, and the latter can be suppressed via electric doping. With the aid of the two‐step optimization strategy, the total photocurrent loss is reduced from 14.4% to 4.8%, accompanying with PCE increment from 16.9% to 18.5%. The SP utilization strategy is finally applied in the semitransparent OSCs (ST‐OSCs), due to its less heterojunction area sensitive photo‐charge generation characteristic. A light utilization efficiency (LUE) is then increased from 3.21% to 3.77%. The findings highlight the pursue of efficient SP utilization as a new design philosophy in future OSCs’ progresses.

Chemistry↗
DOE OSTI2022

Backpack electrofishing does not contribute to external signs of gas bubble trauma in sculpins

Abstract We exposed prickly sculpin Cottus asper and reticulate sculpin Cottus perplexus to electroshock and sham treatments in a controlled laboratory setting to determine if backpack electrofishing contributed to or exacerbated external signs of gas bubble trauma (GBT) in fish exposed to elevated total dissolved gas (TDG) levels. Fish were exposed to 115, 120 and 125% TDG (measured as percent of saturation) for various amounts of time (24–144 h) then subjected to a 5‐s electroshock or sham treatment of no electroshock. Fish were examined to determine the incidence of GBT pre‐ and post‐treatment, and all aspects (i.e., dorsal, ventral, left and right sides) of each fish were photographed. Across all TDG levels in all trials, no sculpin showed any change in GBT incidence following treatment. Analysis of GBT signs evident in photographs of 68 fish found no evidence of change in mean pre‐ and post‐treatment gas bubble sizes in fish in any TDG trial, nor were any new gas bubbles found following treatment. We are aware of no physiological mechanism by which backpack electrofishing can cause GBT in sculpin, and as such, we believe using this gear should not increase GBT incidence rates in sculpin.

Tiffan, Kenneth F.↗
DOE OSTI2023

Shading contributes to Sphagnum decline in response to warming

Experimental warming of an ombrotrophic bog in northern Minnesota has caused a rapid decline in the productivity and areal cover of Sphagnum mosses, affecting whole-ecosystem carbon balance and biogeochemistry. Direct effects of elevated temperature and the attendant drying are most likely the primary cause of the effects on Sphagnum, but there may also be responses to the increased shading from shrubs, which increased with increasing temperature. To evaluate the independent effects of reduction in light availability and deposition of shrub litter on Sphagnum productivity, small plots with shrubs removed were laid out adjacent to the warming experiment on hummocks and hollows in three blocks and with five levels of shading. Four plots were covered with neutral density shade cloth to simulate shading from shrubs of 30%–90% reduction in light; one plot was left open. Growth of Sphagnum angustifolium/fallax and S. divinum declined linearly with increasing shade in hollows, but there was no response to shade on hummocks, where higher irradiance in the open plots may have been inhibitory. Shading caused etiolation of Sphagnum—they were thin and spindly under the deepest shade. A dense mat of shrub litter, corresponding to the amount of shrub litter produced in response to warming, did not inhibit Sphagnum growth or cause increases in potentially toxic base cations. CO 2 exchange and chlorophyll-a fluorescence of S. angustifolium/fallax from the 30% and 90% shade cloth plots were measured in the laboratory. Light response curves indicate that maximal light saturated photosynthesis was 42% greater for S. angustifolium/fallax grown under 30% shade cloth relative to plants grown under 90% shade cloth. The response of Sphagnum growth in response to increasing shade is consistent with the hypothesis that increased shade resulting from shrub expansion in response to experimental warming contributed to reduced Sphagnum growth.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Supercell precipitation contribution to the United States hydroclimate

Abstract This research seeks to understand simulated supercell precipitation characteristics across the conterminous United States (CONUS) using high‐resolution, convection‐permitting, dynamically downscaled simulations for three 15‐year epochs. Epochs include a historical end‐of‐20th‐century period (1990–2005) and two end‐of‐21st‐century (2085–2100) scenarios for intermediate and pessimistic greenhouse gas concentration trajectories. Simulated updraft helicity, which measures the corkscrew flow within a storm's updraft, is used as a proxy for supercells. An algorithm tracks and catalogues updraft helicity swaths that, when buffered, are used to acquire simulated precipitation from supercells. The historical epoch provides a baseline climatology of supercell precipitation for a contemporary climate, which is then compared against the two future epochs to assess how supercell precipitation may change during the 21st century. Despite their relatively small size, supercells provide critical precipitation to the Wheat and Corn Belts, large expanses of CONUS pasture and rangeland, regional aquifers and several large river basins. Many areas in the central CONUS receive upwards of 3%–6% of their annual and 5%–8% of their warm‐season precipitation from these storms. Results suggest that precipitation contribution from supercells will decrease in the future across most of the High Plains and Central and Northern Great Plains with robust increases likely across the south‐central and Southeast regions. Supercell precipitation rates are expected to increase for large portions of the CONUS by the end‐of‐the‐21st‐century, suggesting a growing threat for flash floods from these storms as they become more efficient precipitation producers. This research provides an initial perspective on the magnitude of supercell precipitation and potential changes to this important hydrologic input to assist water‐sensitive industries, private and public insurance markets, agriculture entities, as well as inform plans to mitigate and build resilience to rapid environmental and societal change.

Meteorology & Atmospheric Sciences↗
DOE OSTI2021

Contribution of the Sub-Surface to Electrocatalytic Activity in Atomically Precise La 0.7 Sr 0.3 MnO 3 Heterostructures

Electrocatalytic reactions are known to take place at the catalyst/electrolyte interface. Whereas recent studies of size-dependent activity in nanoparticles and thickness-dependent activity of thin films imply that the sub-surface layers of a catalyst can contribute to the catalytic activity as well, most of these studies consider actual modification of the surfaces. Here, in this study, the role of catalytically active sub-surface layers was investigated by employing atomic-scale thickness control of the La 0.7 Sr 0.3 MnO 3 (LSMO) films and heterostructures, without altering the catalyst/electrolyte interface. The activity toward the oxygen evolution reaction (OER) shows a non-monotonic thickness dependence in the LSMO films and a continuous screening effect in LSMO/SrRuO 3 heterostructures. The observation leads to the definition of an “electrochemically-relevant depth” on the order of 10 unit cells. This study on the electrocatalytic activity of epitaxial heterostructures provides new insight in designing efficient electrocatalytic nanomaterials and core-shell architectures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Sub-leading structures in superconformal indices: subdominant saddles and logarithmic contributions

We systematically study various sub-leading structures in the superconformal index of N = 4 supersymmetric Yang-Mills theory with SU(N) gauge group. We concentrate in the superconformal index description as a matrix model of elliptic gamma functions and in the Bethe-Ansatz presentation. Our saddle-point approximation goes beyond the Cardy-like limit and we uncover various saddles governed by a matrix model corresponding to SU(N) Chern-Simons theory. The dominant saddle, however, leads to perfect agreement with the Bethe-Ansatz approach. We also determine the logarithmic correction to the superconformal index to be log N, finding precise agreement between the saddle-point and Bethe-Ansatz approaches in their respective approximations. We generalize the two approaches to cover a large class of 4d N = 1 superconformal theories. We find that also in this case both approximations agree all the way down to a universal contribution of the form log N. The universality of this last result constitutes a robust signature of this ultraviolet description of asymptotically AdS 5 black holes and could be tested by low-energy IIB supergravity.

1/N expansion↗
DOE OSTI2022

Study of charmonium and charmonium-like contributions in $\mathrm{B}^+$ → $\mathrm{J/ψηK^+}$ decays

A study of B+ → J/ψηK + decays, followed by J/ψ → μ + μ – and η → γγ, is performed using a dataset collected with the LHCb detector in proton-proton collisions at centre-of-mass energies of 7, 8 and 13 TeV, corresponding to an integrated luminosity of 9 fb –1 The J/ψη mass spectrum is investigated for contributions from charmonia and charmonium-like states. Evidence is found for the B + →(ψ2(3823) → J/ψη)K + and B + → (ψ(4040) → J/ψη)K + decays with significance of 3.4 and 4.7 standard deviations, respectively. This constitutes the first evidence for the ψ 2 (3823) → J/ψη decay.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2026

Heavy-quark contributions to the DIS structure functions F 4 and F 5 at NLO in the ACOT scheme

We compute the contributions of heavy quarks to the deep-inelastic scattering structure functions F 4 and F 5 at next-to-leading order of perturbative QCD in the ACOT scheme. Both analytic results including the details of the calculation as well as numerical results for the neutral and charged current cases are presented. Our study thus lays the groundwork for future measurements of these two structure functions in experiments such as the SHiP experiment.

deep inelastic scattering↗
DOE OSTI2022

Electroweak corrections to the Charm-Top-Quark Contribution to ϵ K

We calculate the leading-logarithmic and next-to-leading-logarithmic electroweak corrections to the charm-top-quark contribution to the effective |ΔS| = 2 Lagrangian, relevant for the parameter ϵ K . We find that these corrections lead to a –0.5% shift in the corresponding Wilson coefficient. Moreover, our calculation removes an implicit ambiguity in the standard-model prediction of ϵ K , by fixing the renormalization scheme of the electroweak input parameters.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

The DECOVALEX international collaboration on modeling of coupled subsurface processes and its contribution to confidence building in radioactive waste disposal

Abstract The long-lived radiotoxicity of the high-level radioactive waste generated by nuclear power plants requires safe isolation from the biosphere for many hundreds of thousands of years. An international consensus has emerged that such isolation can best be provided by disposal in mined geologic repositories, a strategy that today is pursued by most countries dealing with radioactive waste. However, the need to predict the performance of such repositories over very long time periods generates large uncertainties that have to be accounted for in safety assessments. The findings from such safety assessments need to be conveyed to all stakeholders in a clear way, such that public confidence in geologic disposal solutions can be achieved. It is suggested here that close international collaboration on the technical aspects of geologic waste disposal has helped, and will continue to help, building trust and increasing confidence. This paper discusses a particular international collaboration initiative referred to as DECOVALEX, which brings together multiple teams and disciplines to collectively tackle complex experimental and modeling challenges related to geologic disposal. By describing how DECOVALEX works and by providing joint research examples, a case is made that such international collaboration contributes to knowledge transfer and confidence building in radioactive waste disposal science.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗