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At least 397 records · Page 22

Suspension Device for Use with Low Temperature Refrigerator

A suspension device for use with a low temperature refrigeration system, such as an adiabatic demagnetization refrigerator is provided. A support ring is provided with three spring-loaded tension assemblies equally spaced about the periphery of the support ring. The tension assemblies each have a pulley, about which is entrained a band of material. Connected to this band is a ring that laterally supports a cylindrical salt pill. Undesired variations in the amount of slack in the band as the salt pill cools are compensated for by the spring loading of the tension assemblies.

Wegel, Donald C.↗

On-Orbit Performance of the Adiabatic Demagnetization Refrigerator on XRISM

The X-ray Imaging and Spectroscopy Mission (XRISM) observatory was launched on Sep 7, 2023 from Tanegashima Space Center in Japan. Resolve, one its two instruments, performs high-resolution spectroscopy in the soft x-ray band (0.2-13 keV) using a 6x6 microcalorimeter array. The array cooled to 50 mK by a 3-stage ADR, which is linked to both a liquid helium dewar (at <1.2 K) and a Joule-Thomson (JT) cryocooler operating at <4.5 K. While liquid helium is present, two of the ADR stages provide detector cooling at 50 mK and auxiliary cooling to 0.5 K to intercept some parasitic heat loads, while rejecting waste heat to the helium. Once the helium is exhausted, Resolve enters a cryogen-free mode in which all three ADR stages are operated to provide detector cooling at 50 mK and to continuously cool the helium tank to 1.4 K. In this mode, waste heat is rejected to the JT cryocooler. Cryogen-free operation can be sustained as long as the JT and other cryocoolers remain fully operational. At launch, the helium tank contained approximately 35.6 liters of liquid. Within a few days, the helium cooled below 1.15 K, with an estimated 35.0 liters remaining. With an expected time average heat load of 0.68 mW, the helium lifetime was projected to exceed 4 years, but measurements of He volume on orbit suggest a significantly longer lifetime. Details of the ADR’s design and performance are presented.

x-ray astromony↗

Capillary Pumped Loop 3 Flight Experiment Overview

The Capillary Pumped Loop 3 (CAPL 3) Experiment is a follow on to the CAPL 1 and CAPL 2 experiments which flew on STS-60 (2/94) and STS-69 (9/95), respectively. CAPL 3 is tentatively scheduled to fly on the Space Shuttle in late 2000 as part of the Hitchhiker Experiments Advancing Technology (HEAT) payload. The experiment is a joint Naval Research Laboratory (NRL)/Goddard Space Flight Center (GSFC) payload which will meet technology objectives for both the Department of Defense and NASA. The primary objective of CAPL 3 is to demonstrate in space a multiple evaporator capillary pumped loop system, capable of reliable start-up, reliable continuous operation, and at least 50% heat load sharing with hardware for a deployable radiator. CAPL 3 is a full scale CPL system with four parallel capillary evaporators. The loop also contains a capillary starter pump, 8 parallel direct condensation condensers with associated flow regulators, a back pressure regulator, a two-phase reservoir, and various headers and transport tubing. A variable conductance heat pipe is located between one of the evaporators and the experiment radiator to provide a cooling source for the demonstration of heat load sharing. The experiment has an operating power range of 100 W to approximately 1400 W. The experiment ammonia charge will cause it to transition to a fixed conductance mode of operation if the radiator usage reaches 85%. Ambient functional tests have been performed on the experiment. Tests performed included start-up, low power, power cycles, high power, heat load sharing, variable/fixed conductance transition, saturation temperature changes, and pressure primes while the system was operating. The majority of the testing was performed at an ammonia saturation temperature of 30C, but a few tests were done at temperatures above and below this. The testing was highly successful. Details of the tests performed and a discussion of the results will be given in the presentation.

Ottenstein, Laura↗

Development of a thermal and structural analysis procedure for cooled radial turbines

A procedure for computing the rotor temperature and stress distributions in a cooled radial turbine are considered. Existing codes for modeling the external mainstream flow and the internal cooling flow are used to compute boundary conditions for the heat transfer and stress analysis. The inviscid, quasi three dimensional code computes the external free stream velocity. The external velocity is then used in a boundary layer analysis to compute the external heat transfer coefficients. Coolant temperatures are computed by a viscous three dimensional internal flow cade for the momentum and energy equation. These boundary conditions are input to a three dimensional heat conduction code for the calculation of rotor temperatures. The rotor stress distribution may be determined for the given thermal, pressure and centrifugal loading. The procedure is applied to a cooled radial turbine which will be tested at the NASA Lewis Research Center. Representative results are given.

Kumar, Ganesh N.↗

Development of a thermal and structural analysis procedure for cooled radial turbines

A procedure for computing the rotor temperature and stress distributions in a cooled radial turbine is considered. Existing codes for modeling the external mainstream flow and the internal cooling flow are used to compute boundary conditions for the heat transfer and stress analyses. An inviscid, quasi three-dimensional code computes the external free stream velocity. The external velocity is then used in a boundary layer analysis to compute the external heat transfer coefficients. Coolant temperatures are computed by a viscous one-dimensional internal flow code for the momentum and energy equation. These boundary conditions are input to a three-dimensional heat conduction code for calculation of rotor temperatures. The rotor stress distribution may be determined for the given thermal, pressure and centrifugal loading. The procedure is applied to a cooled radial turbine which will be tested at the NASA Lewis Research Center. Representative results from this case are included.

Kumar, Ganesh N.↗

Site demonstration and performance evaluation of MPC for a large chiller plant with TES for renewable energy integration and grid decarbonization

Thermal energy storage (TES) for a cooling plant is a crucial resource for load flexibility. Traditionally, simple, heuristic control approaches, such as the storage priority control which charges TES during the nighttime and discharges during the daytime, have been widely used in practice, and shown reasonable performance in the past benefiting both the grid and the end-users such as buildings and district energy systems. However, the increasing penetration of renewables changes the situation, exposing the grid to a growing duck curve, which encourages the consumption of more energy in the daytime, and volatile renewable generation which requires dynamic planning. The growing pressure of diminishing greenhouse gas emissions also increases the complexity of cooling TES plant operations as different control strategies may apply to optimize operations for energy cost or carbon emissions. This paper presents a model predictive control (MPC), site demonstration and evaluation results of optimal operation of a chiller plant, TES and behind-meter photovoltaics for a campus-level district cooling system. The MPC was formulated as a mixed-integer linear program for better numerical and control properties. Compared with baseline rule-based controls, the MPC results show reductions of the excess PV power by around 25%, of the greenhouse gas emission by 10%, and of peak electricity demand by 10%.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Elevated Aerosol Layers and Their Radiative Impact over Kanpur During Monsoon Onset Period

Accurate information about aerosol vertical distribution is needed to reduce uncertainties in aerosol radiative forcing and its effect on atmospheric dynamics. The present study deals with synergistic analyses of aerosol vertical distribution and aerosol optical depth (AOD) with meteorological variables using multisatellite and ground-based remote sensors over Kanpur in central Indo-Gangetic Plain (IGP). Micro-Pulse Lidar Network-derived aerosol vertical extinction (sigma) profiles are analyzed to quantify the interannual and daytime variations during monsoon onset period (May-June) for 2009-2011. The mean aerosol profile is broadly categorized into two layers viz., a surface layer (SL) extending up to 1.5 km (where sigma decreased exponentially with height) and an elevated aerosol layer (EAL) extending between 1.5 and 5.5 km. The increase in total columnar aerosol loading is associated with relatively higher increase in contribution from EAL loading than that from SL. The mean contributions of EALs are about 60%, 51%, and 50% to total columnar AOD during 2009, 2010, and 2011, respectively. We observe distinct parabolic EALs during early morning and late evening but uniformly mixed EALs during midday. The interannual and daytime variations of EALs are mainly influenced by long-range transport and convective capacity of the local emissions, respectively. Radiative flux analysis shows that clear-sky incoming solar radiation at surface is reduced with increase in AOD, which indicates significant cooling at surface. Collocated analysis of atmospheric temperature and aerosol loading reveals that increase in AOD not only resulted in surface dimming but also reduced the temperature (approximately 2-3 C) of lower troposphere (below 3 km altitude). Radiative transfer simulations indicate that the reduction of incoming solar radiation at surface is mainly due to increased absorption by EALs (with increase in total AOD). The observed cooling in lower troposphere in high aerosol loading scenario could be understood as a dynamical feedback of EAL-induced stratification of lower troposphere. Further, the observed radiative effect of EALs increases the stability of the lower troposphere, which could modulate the large-scale atmospheric dynamics during monsoon onset period. These findings encourage follow-up studies on the implication of EALs to the Indian summer monsoon dynamics using numerical models.

aerosol vertical distribution↗

The structural response of unsymmetrically laminated composite cylinders

The responses of an unsymmetrically laminated fiber-reinforced composite cylinder to an axial compressive load, a torsional load, and the temperature change associated with cooling from the processing temperature to the service temperature are investigated. These problems are considered axisymmetric and the response is studied in the context of linear elastic material behavior and geometrically linear kinematics. Four different laminates are studied: a general unsymmetric laminate; two unsymmetric but more conventional laminates; and a conventional quasi-isotropic symmetric laminate. The responses based on closed-form solutions for different boundary conditions are computed and studied in detail. Particular emphasis is directed at understanding the influence of elastic couplings in the laminates. The influence of coupling decreased from a large effect in the general unsymmetric laminate, to practically no effect in the quasi-isotropic laminate. For example, the torsional loading of the general unsymmetric laminate resulted in a radial displacement. The temperature change also caused a significant radial displacement to occur near the ends of the cylinder. On the other hand, the more conventional unsymmetric laminate and the quasi-isotropic cylinder did not deform radially when subjected to a torsional load. From the results obtained, it is clear the degree of elastic coupling can be controlled and indeed designed into a cylinder, the degree and character of the coupling being dictated by the application.

Butler, T. A.↗

Exploring the Potential of ASHRAE Guideline 36 in District Cooling Systems: Preprint

ASHRAE Guideline 36-2021 (G36) provides high-performance control sequences for all-air and hydronic HVAC systems, and it has proven effective at reducing energy use for single building all-air equipment. The most recent version of G36 included control sequences for water-cooled chiller plants, which can be used in district cooling systems (DCSs). Despite not being a traditional application of G36 controls, DCSs could benefit from energy savings that G36 control sequences have demonstrated in single building systems. We therefore investigate the possibility to extend G36 chiller plant control from a single building to district cooling using a real-world district cooling system in Boulder, Colorado as a case study. Four timeframes representing low to peak loads are simulated and analyzed to compare energy use of the district cooling system for three control sequences. Results show that although G36 chiller plant sequences can be applied to DCSs, further analysis and potentially control optimization is needed to ensure energy savings compared to default controls.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Design And Control of Thermal Storage for Ventilative Cooling in Multifamily Buildings (Final Report)

The concept of natural ventilation is to provide a heat sink for cooling the building during the occupancy periods at night and improve indoor thermal comfort during the daytime without or with minimal need for mechanical cooling. Commonly, natural ventilation through the window or mechanical circulation of the air through the ventilation ducts are two key methods used to achieve night ventilation. Due to the increasing electric need for space heating and cooling, renewable energies combined with energy storage systems are receiving attention worldwide nowadays. When designed and controlled properly, this strategy can reduce energy use for cooling, reduce the size of mechanical cooling equipment, reduce peak electrical demand for cooling, and better enable demand flexibility for mechanical cooling equipment. In some cases, ventilative cooling can eliminate the need for mechanical cooling altogether. For these reasons, California’s Building Energy Efficiency Standards have recently added prescriptive requirements that all new single-family residences (in most California climates) must include ventilative cooling systems (aka: “whole house fans”). However, the current standards do not address multifamily buildings because market-available ventilative cooling products are designed for single-family residences and are physically incompatible with many multifamily building archetypes. The results from the study show that the combination of thermal energy storage on building walls along with nighttime ventilation cooling assisted with nighttime ventilation can save total building energy usage by up to 9% and peak load by 16% in moderate climate zones. The controlled nighttime ventilation cooling (activate ventilation only when outdoor conditions are favorable) can also provide total electricity savings of up to 5% and 7% in hot and cold climates, respectively. In the case of moderate climates, kitchen exhaust-assisted nighttime ventilation cooling can eliminate the need for cooling during overnight hours. This can also significantly assist in reducing carbon emissions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Techno-Economic Analysis for the Addition of Thermal Energy Storage to a Campus With Existing Battery Storage

Rising global temperatures and increasing energy demands pose significant challenges for energy management, particularly in institutional and commercial settings. As cooling needs grow, campuses must balance operational efficiency, cost control, and grid stability. Energy storage solutions, such as thermal energy storage (TES) systems, offer a promising approach to shifting energy consumption from peak to off-peak periods, alleviating peak demand, reducing utility costs, and enhancing grid resilience. When integrated with existing battery energy storage systems (BESS), TES can further optimize load management and improve energy savings, especially in buildings with diverse energy needs. This article presents a techno-economic analysis of integrating a chilled water TES system into the central plant at California State University, Dominguez Hills, which already operates a BESS. We assess three TES sizing strategies—full storage, load leveling, and peak demand limiting—by modeling and simulations based on historical energy loads. Our findings show that we can control TES systems to complement BESS operation, with campus-level load leveling providing the greatest cost savings by reducing peak demands. Furthermore, the study also evaluates the long-term economic viability of TES, considering installation costs, energy savings, and payback periods under varying tariffs. This research offers practical guidance for institutions seeking to enhance energy resilience and reduce operational costs through energy storage solutions.

25 ENERGY STORAGE↗

Data Center Cybersecurity, Supply Chain Risk Management, and Emerging Regulation Cohort Summary: Takeaways and Action Plans

This report summarizes the outcomes of the Data Center Cohort under the Department of Energy’s Technical Assistance for Digital Assurance (TADA) initiative, aimed at enhancing grid resilience through cybersecurity, supply chain risk management (SCRM), and Cyber-Informed Engineering (CIE). The cohort engaged 17 organizations across utilities, data center operators, vendors, and technology providers in three sessions combining presentations, discussions, and exercises. Key topics included AI-driven load behavior, cybersecurity vulnerabilities in UPS/BESS and cooling systems, governance gaps at utility–data center boundaries, and supply chain integrity. Five cross-cutting themes emerged: interconnection architecture vulnerabilities, fragmented governance, AI-driven stability risks, lack of regulatory frameworks, and long-term supply chain concerns. Actionable recommendations were developed, including implementing DMZ segmentation, formalizing vendor access agreements, designing AI workload limits, and advancing standards through NERC and state-level programs. These strategies aim to strengthen resilience, clarify responsibilities, and ensure secure integration of data centers into the grid.

24 - POWER TRANSMISSION AND DISTRIBUTION↗

Real-time optimization of multi-cell industrial evaporative cooling towers using machine learning and particle swarm optimization

Existing electrical generating stations must operate with greater flexibility due to increasing renewable energy penetration on the electrical grid, and many coal-fired power stations have transitioned away from baseload operation to load-following operation to aid in grid stability. In cases where multiple independently controlled cooling tower cells are used in parallel for the cooling purposes of such stations, there is an opportunity to increase plant efficiency through data-driven optimization across their full load ranges. This work presents a novel application of real-time optimization using machine learning and particle swarm optimization on a multi-cell induced-draft cooling tower servicing a coal-fired power station under variable load. This is the first work to demonstrate simultaneous optimization of a multi-cell cooling tower, in addition to using machine learning for closed-loop control on a cooling tower. A novel control configuration is presented that ensures original control logic is not adversely affected and that the overall plant process is not disrupted using only existing hardware and operational data. To verify this methodology, the 12 independent cooling tower cells are simulated in parallel using historic operating data to demonstrate the effectiveness of real-time optimization compared to current practice. An artificial neural network is trained to predict overall cooling tower power consumption using only operational data and ambient conditions with an R2 value of greater than 0.96. The real-time optimization using particle swarm yields 6.7% annual energy usage savings compared to current practices, although the extent of the real-time savings varies greatly with both plant load and environmental conditions. This is particularly significant for a variable load situation because frequent ramping typically results in reduced overall efficiency. Furthermore, this proposed AI-based solution presents an opportunity to improve the overall heat rate of a load-following coal-fired power plant without the need to perform extensive first-principles modeling or add additional hardware to the cooling tower, resulting in more resources conserved and less overall emissions per unit of electricity generated.

42 ENGINEERING↗

Thermal Assessment of Landsat-7 ETM+ Radiative Cooler in Instrument and Spacecraft Thermal Vacuum Tests and in Flight

During the radiative cooler cool-down phase of the Landsat-7 Enhanced Thematic Mapper Plus (ETM+) instrument thermal vacuum test #3, the coldest temperature that the Cold Focal Plane Array (CFPA) achieved was 89.5 K. The cold stage/CFPA temperature decreased from 315 K to 89.5 K in 80 hours. In the spacecraft and instrument integrated thermal vacuum test, the cold stage/CFPA temperature decreased from 315 K to 86.9 K in 80 hours, and was still decreasing at a rate of 0.08 K/hr when the cool-down was terminated. The cool-down was faster, and a colder CFPA temperature was obtained. In flight, the cooler cool- down was even faster, and colder. The cold stage/CFPA temperature decreased from 315 K to 89.7 K in 33 hours, and was still decreasing at a rate of 1 K/hr when cool- down was terminated at 89.7 K. The factors that affected the ETM+ cooler cool-down are the radiation heat sink temperature for the cold stage and intermediate stage, parasitic radiation heat load to the cooler, parasitic conduction heat load to the cooler, and cooler outgas time preceding cooler cool-down.

Choi, Michael K.↗

Continuous Monitoring and Partial Water Softening for Cooling Tower Water Treatment

Cooling towers are an integral component of many refrigeration systems, providing comfort or process cooling across a broad range of applications. They are the point in the system where heat is dissipated to the atmosphere through the evaporative cooling process. Cooling towers are commonly found in industrial applications and are also often used in water-cooled chilled water plants in medium to large commercial buildings. Continuous monitoring and partial water softening for cooling towers used in medium to large commercial buildings are the focus of this paper. Cooling towers consume large amounts of water. Cooling tower-related water consumption is one of largest potable water loads within buildings in the United States, with substantial building water use associated with heating and cooling. Regional water shortages have highlighted a need to reduce water consumption; the U.S. General Services Administration (GSA) and Executive Order 13834 place priority on reducing water consumption. This priority has fueled interest in the identification, investigation, and potential broad deployment of cost-effective opportunities to reduce water use, such as alternative water treatment (AWT) technologies for cooling towers. Traditional water treatment approaches use chemicals to extend the ability of the water to hold scaling minerals in suspension, minimize corrosion, and prevent biological growth. This treatment protects the chillers and cooling tower equipment; however, even when chemicals are used regularly, a certain percentage of condenser water must be drained and made up with fresh water to maintain system water quality parameters. In addition, the use of chemicals sometimes creates a waste disposal issue and can cause building owners to incur additional fees, such as disposal or wastewater charges. To manage cooling tower water treatment, GSA typically contracts with a company specializing in conventional chemical maintenance for a fixed fee. While there are many types and vendors of AWT systems, this project assesses the effectiveness of one technology provided by Aqualogix. This system is a chilled water plant monitoring and control system aimed at optimizing system performance by reducing the blowdown occurrences used to remove mineral build-up. The technology consists of two components – continuous programmable logic control (PLC) monitoring and side-stream filtration with partial water softening. PLC monitoring calculates cycles of concentration (CoC) and determines the optimum amount of blowdown water required to satisfy all water chemistry requirements. Side-stream filtration removes suspended matter and improves biocide efficacy while precisely dispensing softened water to achieve optimal makeup water hardness. Unlike other AWT systems evaluated by GSA to date, this system does not replace the legacy treatment system but is used in addition to chemical water treatment. The vendor claims their technology will reduce water consumption, water discharge, and maintenance costs. The AWT system evaluated in this demonstration is a commercialized technology. Given its commercialized state, the system evaluated in this report is at a Technology Readiness Level 9 according to National Aeronautics and Space Administration (NASA) definitions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Improvement of Coal Power Plant Dry Cooling Technology through Application of Cold Thermal Energy Storage

The U.S. power infrastructure is currently heavily reliant on water cooling. The power plants in the U.S. account for approximately 40% of freshwater withdrawals, with 90% of it used in condenser cooling. The most used cooling technology in coal-fired power plants is a once-through condenser; however, this cooling method requires high water withdrawal rates and results in thermal pollution of the water source. Wet WCTs offer an alternative to once-through condensers due to much lower water withdrawals. However, these systems suffer from water consumption through evaporation making them undesirable options in areas subject to droughts and in arid areas. The direct dry cooled condensers (ACCs) and dry cooling towers (DCT) account for 1.8%, hybrid cooling (ACC + WCT) accounts for 0.5%, while other cooling technologies represent the rest (0.7%). The ACC/DCTs represent an attractive alternative for power plants; however, this technology has not been widely adopted in the US (less than 2% of power plants) due to its negative impact on plant performance. As a rule of thumb, dry cooling results in performance penalty equivalent to approximately 2%-point efficiency loss compared to wet cooling, although the actual magnitude varies with ambient dry bulb temperature, DBT which may vary considerably during the day. As DBT increases, the plant power output decreases, reaching a minimum at the hottest period of the day, which usually coincides with the highest electricity demand for air condition load. Therefore, performance of power plants using DCT/ACC cooling technology is the lowest during the summer mid-day when ambient temperature is the highest. For example, the decrease of the inlet air temperature to the DCT/ACC by 2 Deg C could generate up to 5% additional power at peak demand. It is, therefore, important to improve dry cooling technology to maintain the viability of coal-fired power plants in a carbon constrained future. The method for reducing the cooling air temperature and keeping it constant would mitigate this problem significantly. Objectives of this project were to develop, design, evaluate, and demonstrate a cost-effective system for improving performance of a DCT or ACC for thermal (coal-fired) power plant applications using a low-cost heat storage materials, such as pervious concrete (PC) and phase change material (PCM). Thus, the study focused on development of the system(s) that could be used to alleviate the difficulties in operating DCT/ACC during the summer months by storing cold energy during the nighttime in inexpensive materials PC and PCM and using it during the hottest period(s) of the day. Since very large quantities of cold energy need to be stored to make an impact on performance of a large power plant, it is essential that the storage materials and associated cold energy storage design(s) are inexpensive and the system is simple to build, maintain and operate. To achieve the project objectives, a comprehensive approach, including material development and characterization, component and system modeling, and laboratory- and prototype-scale experiments, was employed including modeling of the system components and of the entire system, development (engineering) of the materials for the heat storage modules of the Cold Thermal Energy Storage System (CTESS) and determination of their properties, design, manufacturing and setup of the laboratory- and prototype-scale test facility and testing, design, manufacturing and setup of the prototype-scale test facility. A modular design of CTESS was employed, where representative modules were designed as the integrated direct contact heat exchanger and thermal energy storage (TES) system. CTESS modules were manufactured and tested. Two prototype-scale designs of the CTESS modules were developed and tested. The use of CTESS increases plant generation increases since it lowers air temperature entering ACC/DCT and keeps it constant during the hottest time of the day. For a PCM-based CTESS, the ambient air temperature is lowered close to the PCM phase change temperature. The duration of the cooling effect depends on the latent heat and mass of PCM in the CTESS. For this project, commercial grade CaCl2 hexahydrate (CaCl2·6H2O or CC6) PCM with phase change temperature of 25 Deg. C was used due to its low cost. For practical reasons, the CTESS was designed to maintain the cooling effect for four hours. The low phase change temperature associated with the commercial grade PCM used in CTESS results in considerably higher improvement in net generation compared to the laboratory (pure) grade. The resistance to heat transfer results in lower net generation compared to the ideal case where resistance to heat transfer is zero. The results demonstrate that CTESS is effective in improving the performance of a dry cooling system. However, its effectiveness depends on the relationship between the ambient air conditions and PCM phase change temperature. As is the case with the heat rejection system, for the best performance, the PCM used in CTESS would need to be matched to the ambient air conditions. The results obtained in this report for selected geographical locations are valid for CC6 and demonstrate that the level of performance to be achieved by the technology will be location-dependent, as is the case with the air cooled condensers. The methodology for engineering of PC-PCM-based heat storage medium is applicable to other PCMs that may need to be used for other ambient air conditions and geographical locations.

01 COAL, LIGNITE, AND PEAT↗

An analytical investigation of the performance of solar collectors as nighttime heat radiators in airconditioning cycles

It was found that if the upper and lower ends of a collector were opened, large free convention currents may be set up between the collector surface and the cover glass(es) which can result in appreciable heat rejection. If the collector is so designed that both plates surfaces are exposed to convection currents when the upper and lower ends of the collector enclosure are opened, the heat rejection rate is 300 watts sq m when the plate is 13 C above ambient. This is sufficient to permit a collector array designed to provide 100 percent of the heating needs of a home to reject the accumulated daily air conditioning load during the course of a summer night. This also permits the overall energy requirements for cooling to be reduced by at least 15 percent and shift the load on the utility entirely to the nighttime hours.

Jones, C. B.↗

Dual‐Functional High‐Entropy Polymer Exhibiting Giant Cross‐Energy Couplings at Low Fields

A key component of cooling devices is the transfer of entropy from the cold load to heat sink. An electrocaloric (EC) polymer capable of generating both large electrocaloric effect (ECE) and substantial electroactuation can enable EC cooling devices to pump heat without external mechanisms, resulting in compact designs and enhanced efficiency. However, achieving both high ECE and significant electroactuation remains challenging. Herein, it is demonstrated that poly(vinylidene fluoride‐trifluoroethylene‐chlorofluoroethylene‐double bond) [P(VDF‐TrFE‐CFE‐DB)] tetrapolymers can simultaneously generate high electrocaloric effects and electroactuations under low fields. These P(VDF‐TrFE‐CFE‐DB) tetrapolymers are synthesized through the dehydrochlorination of P(VDF‐TrFE‐CFE) terpolymer. By facile tuning the composition of the initial terpolymer to avoid pure relaxor state, tetrapolymers with optimal DB compositions are achieved, near the critical endpoint of normal ferroelectric phase with diffused phase transition. The nearly vanishing energy barriers between the nonpolar to polar phases result in a strong electrocaloric response and significant electroactuation. Specifically, the P(VDF‐TrFE‐CFE‐DB) tetrapolymer exhibits an EC entropy change Δ S of 100 J kg −1 K −1 under 100 MV m −1 : comparable to state‐of‐the‐art (SOA) EC polymers, while delivering nearly twice the electroactuation of the SOA EC polymers. This work presents a general strategy for developing EC materials that combine large electrocaloric effect and electroactuation at low electric fields.

36 MATERIALS SCIENCE↗