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At least 397 records · Page 22

SiC and Si3N4 Recession Due to SiO2 Scale Volatility Under Combustor Conditions

Silicon carbide (SiC) and Si3N4 materials were tested in various turbine engine combustion environments chosen to represent either conventional fuel-lean or fuel-rich mixtures proposed for high-speed aircraft. Representative chemical vapor-deposited (CVD), sintered, and composite materials were evaluated by furnace and high-pressure burner rig exposures. Although protective SiO2 scales formed in all cases, the evidence presented supports a model based on paralinear growth kinetics (i.e., parabolic growth moderated simultaneously by linear volatilization). The volatility rate is dependent on temperature, moisture content, system pressure, and gas velocity. The burner tests were thus used to map SiO2 volatility (and SiC recession) over a range of temperatures, pressures, and velocities. The functional dependency of material recession (volatility) that emerged followed the form A[exp(-Q / RT)](P(sup x)v(sup y). These empirical relations were compared with rates predicted from the thermodynamics of volatile SiO and SiOxHy reaction products and a kinetic model of diffusion through a moving boundary layer. For typical combustion conditions, recession of 0.2 to 2 micrometers/hr is predicted at 1200 to 1400 C, far in excess of acceptable long-term limits.

Smialek, James L.↗

27 Years of Satellite Ozone Data: Merging of Data Records from Multiple Instruments to Observe Global Trends and Recovery

Satellite measurements provide a unique global view of the stratospheric ozone layer. The perspective from satellites allowed for the early mapping of the extent of the phenomenon that became known as the ozone hole. The use of the satellite data for global trends outside of the ozone hole confronts the problem of the possible drift of the calibration of the instrument. The TOMS and SBUV instruments on Nimbus 7 lasted for more than a decade. During that time, the diffuser plate used to reflect sunlight into the measurement degraded (darkened) and the instruments each had a number of events that made calibration determination difficult. Initially the TOMS data were used for global trends by adjusting the overall calibration to agree with a set of ground-based measurement stations. But this was unsatisfactory because the record was not independent of those ground measurements and problems were found in many of the ground stations by using TOMS as a transfer standard. After many years of dedicated work, the TOMS/SBUV team learned how to correct for instrument drift, remove the interfering effects of aerosols, and establish instrument-to-instrument calibrations resulting in a long-term record that can be used for accurate trend and recovery determination. The global view of the satellites allows for determination not only of temporal change in ozone, but spatial fingerprints that allow more confidence in assigning cause to observed changes.

Stolarski, Richard S.↗

ADEOS Total Ozone Mapping Spectrometer (TOMS) Data Products User's Guide

Two data products from the Total Ozone Mapping Spectrometer (ADEOS/TOMS) have been archived at the Distributed Active Archive Center, in the form of Hierarchical Data Format files. The ADEOS/ TOMS began taking measurements on September 11, 1996, and ended on June 29, 1997. The instrument measured backscattered Earth radiance and incoming solar irradiance; their ratio was used in ozone retrievals. Changes in the reflectivity of the solar diffuser used for the irradiance measurement were monitored using a carousel of three diffusers, each exposed to the degrading effects of solar irradiation at different rates. The algorithm to retrieve total column ozone compares measured Earth radiances at sets of three wavelengths with radiances calculated for different total ozone values, solar zenith angles, and optical paths. The initial error in the absolute scale for TOMS total ozone is 3 percent, the one standard deviation random error is 2 percent, and the drift is less than 0.5 percent over the 9-month data record. The Level 2 product contains the measured radiances, the derived total ozone amount, and reflectivity information for each scan position. The Level 3 product contains daily total ozone and reflectivity in a 1-degree latitude by 1.25 degrees longitude grid. The Level 3 files containing estimates of UVB at the Earth surface and tropospheric aerosol information will also be available. Detailed descriptions of both HDF data files and the CDROM product are provided.

Krueger, A.↗

ALMA Observations of Molecular Clouds in Three Group-centered Elliptical Galaxies:NGC 5846, NGC 4636, and NGC 5044

We present new ALMA CO(2–1) observations of two well-studied group-centered elliptical galaxies: NGC 4636 and NGC 5846. In addition, we include a revised analysis of Cycle 0 ALMA observations of the central galaxy in the NGC 5044 group. We find evidence that molecular gas is a common presence in bright group-centered galaxies (BGG). CO line widths are broader than Galactic molecular clouds, and using the reference Milky Way XCO, the total molecular mass ranges from 2.6 x 10(exp 5)M(☉) in NGC 4636 to 6.1 x 10(exp 7) M(☉) in NGC 5044. Complementary observations using the ALMA Compact Array do not exhibit any detection of a CO diffuse component at the sensitivity level achieved by current exposures. The origin of the detected molecular features is still uncertain, but these ALMA observations suggest that they are the end product of the hot gas cooling process and not the result of merger events. Some of the molecular clouds are associated with dust features as revealed by HST dust extinction maps, suggesting that these clouds formed from dust-enhanced cooling. The global nonlinear condensation may be triggered via the chaotic turbulent field or buoyant uplift. The large virial parameter of the molecular structures and correlation with the warm (10(exp 3)–10(exp 5) K)/hot (≥ 10(exp 6)) phase velocity dispersion provide evidence that they are unbound giant molecular associations drifting in the turbulent field, consistent with numerical predictions of the chaotic cold accretion process. Alternatively, the observed large CO line widths may be generated by molecular gas flowing out from cloud surfaces due to heating by the local hot gas atmosphere.

Pasquale Temi↗

El Chichon and 'mystery cloud' aerosols between 30 and 55 km Global observations from the SME visible spectrometer

Visible limb radiances measured by the Solar Mesosphere Explorer (SME) are used to obtain volume scattering ratios for aerosol loading in the 30-55 km altitude range of the stratosphere. Global maps of these ratios are presented for the period January 1982 to August 1984. Significant aerosol scattering from the 'mystery cloud' and El Chichon aerosol layers are found above 30 km. A timescale of approximately 2 months between the appearance of the aerosol at 30.5 km and at 37.5 km is consistent with vertical transport of aerosol or vapor by eddy diffusion above 30 km. An anticorrelation exists between aerosol scattering and stratospheric temperatures. Periods of lower stratospheric temperatures may account for the formation of aerosol between 40 and 55 km altitude.

Clancy, R. T.↗

Analysis prcedures for ROSAT XRT/PSPC observations of extended objects and the diffuse background

Proper reduction of ROSAT observations of extended sources or the diffuse background requires techniques that are quite different from the standard point-source analysis. We describe in detail an appropriate set of procedures for this purpose for the X-ray Telescope (XRT), Position Sensitive Proportional Counter (PSPC). We define a standard set of pulse-height bands recommended for analyzing extended structure and describe the use of detector efficiency maps for proper flat-fielding of images. Sources of noncosmic background contamination and their modeling and subtraction are discussed and demonstrated. IDL routines for implementing these data reduction procedures are being made available to the community through the ROSAT IDL library maintained at Goddard Space Flight Center (GSFC).

Snowden, S. L.↗

Variations of three-dimensional anisotropy of cosmic rays during Forbush decreases.

Variations of three-dimensional anisotropy of cosmic rays during Forbush decreases are examined by a spherical harmonic method and by constructing successive isointensity contour maps in the solar ecliptic coordinate system. The east-west and north-south anisotropies are studied statistically and for several individual events; the data are based on cosmic ray records from about 24 stations for the 3-year period from 1966 to 1968. For the individual events, the high anisotropies of about 4% are examined in terms of the convective, diffusive and density gradient components of the differential streaming as well as the interplanetary magnetic field and solar wind. In each case, vector gradients are derived that lead to the observed anisotropies, and the magnitude of these gradients is typically 10-20 times that of the quiet time interplanetary gradient.

Yoshida, S.↗

Flight test investigation of the vortex wake characteristics behind a Boeing 727 during two-segment and normal ILS approaches

A series of flight tests were performed to evaluate the vortex wake characteristics of a Boeing 727 (B727-200) aircraft during conventional and two-segment ILS approaches. Flights of the B727, equipped with smoke generators for vortex marking, were flown wherein its vortex wake was intentionally encountered by a Lear Jet model 23 (LR-23) or a Piper Twin Comanche (Pa-30); and its vortex location during landing approach was measured using a system of photo-theodolites. The tests showed that at a given separation distance there were no differences in the upsets resulting from deliberate vortex encounters during the two types of approaches. Timed mappings of the position of the landing configuration vortices showed that they tended to descend approximately 91 meters (300 feet) below the flight path of the B727. The flaps of the B727 have a dominant effect on the character of the trailed wake vortex. The clean wing produces a strong, concentrated vortex. As the flaps are lowered, the vortex system becomes more diffuse. Pilot opinion and roll acceleration data indicate that 4.5 nautical miles would be a minimum separation distance at which roll control could be maintained during parallel encounters of the B727's landing configuration wake by small aircraft.

Garodz, L. J.↗

The diffuse soft X-ray background as seen with the Einstein Observatory

A systematic survey of the diffuse soft X-ray background as seen directly with the Einstein Observatory is presented. With the aid of 1633 selected 1 x 1 deg fields of view obtained by the IPC to provide about 5-percent sky coverage, with some bias toward the Galactic plane, the background in the 0.16-3.5 keV spectral region was spatially resolved on this angular scale. Maps of the background are characterized and produced at different energies within the Einstein passband. It is confirmed that the Galactic ridge is not present at energies below 0.33 keV and it is demonstrated that the appearance of the ridge above this energy is not due to hard Galactic sources with a flux above 10 exp -13 ergs/sq cm/s. A southern Galactic region is identified, with l between 80 and 180 deg and b less than -5 deg, where the mean background intensity has the lowest value and is homogeneous within better than 9 percent. The implications of these results for the Galactic structure and for the nature of the extragalactic X-ray background are discussed.

Micela, G.↗

SiC and Si3N4 Recession Due to SiO2 Scale Volatility Under Combustor Conditions

SiC and Si3N4 materials were tested under various turbine engine combustion environments, chosen to represent either conventional fuel-lean or fuel-rich mixtures proposed for high speed aircraft. Representative CVD, sintered, and composite materials were evaluated in both furnace and high pressure burner rig exposure. While protective SiO2 scales form in all cases, evidence is presented to support paralinear growth kinetics, i.e. parabolic growth moderated simultaneously by linear volatilization. The volatility rate is dependent on temperature, moisture content, system pressure, and gas velocity. The burner tests were used to map SiO2 volatility (and SiC recession) over a range of temperature, pressure, and velocity. The functional dependency of material recession (volatility) that emerged followed the form: exp(-QIRT) * P(exp x) * v(exp y). These empirical relations were compared to rates predicted from the thermodynamics of volatile SiO and SiO(sub x)H(sub Y) reaction products and a kinetic model of diffusion through a moving, boundary layer. For typical combustion conditions, recession of 0.2 to 2 micron/h is predicted at 1200- 1400C, far in excess of acceptable long term limits.

Smialek, James L.↗

Subdiffraction Imaging of Carrier Dynamics in Halide Perovskite Semiconductors: Effects of Passivation, Morphology, and Ion Motion

In this article, we spatially resolve photocarrier dynamics in halide perovskites using time-resolved electrostatic force microscopy (trEFM) to map surface potential equilibration during photoexcitation. We present a unified interpretation of trEFM, which measures the evolution of the surface potential in response to photoexcitation. We show that trEFM measurements correlate with surface recombination velocity and carrier lifetimes, validated with time-resolved photoluminescence imaging. We further validate the interpretation of trEFM through wavelength- and intensity-dependent measurements and with drift-diffusion simulations. We compare several passivation agents, including (3-aminopropyl)trimethoxysilane (APTMS), [3-(2-aminoethylamino)propyl]trimethoxysilane (AEAPTMS), and phenethylammonium iodide (PEAI). The results reveal heterogeneity in surface potential equilibration times that correlates with perovskite film morphology and nanoscale variations in recombination dynamics following surface passivation. Not only do our results highlight the potential for further improvement of passivation strategies, but also the necessity of high spatial and temporal resolution methods, like trEFM, to evaluate next-generation semiconductors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Characteristics of wake vortex generated by a Boeing 727 jet transport during two-segment and normal ILS approach flight paths

A series of flight tests was conducted to evaluate the vortex wake characteristics of a Boeing 727 (B727-200) aircraft during conventional and two-segment ILS approaches. Twelve flights of the B727, which was equipped with smoke generators for vortex marking, were flown and its vortex wake was intentionally encountered by a Lear Jet model 23 (LR-23) and a Piper Twin Comanche (PA-30). Location of the B727 vortex during landing approach was measured using a system of photo-theodolites. The tests showed that at a given separation distance there were no readily apparent differences in the upsets resulting from deliberate vortex encounters during the two types of approaches. Timed mappings of the position of the landing configuration vortices showed that they tended to descend approximately 91 m(300 ft) below the flight path of the B727. The flaps of the B727 have a dominant effect on the character of the trailed wake vortex. The clean wing produces a strong, concentrated vortex but as the flaps are lowered, the vortex system becomes more diffuse. Pilot opinion and roll acceleration data indicate that 4.5 n.mi. would be a minimum separation distance at which roll control of light aircraft (less than 5,670 kg (12,500 lb) could be maintained during parallel encounters of the B727's landing configuration wake. This minimum separation distance is generally in scale with results determined from previous tests of other aircraft using the small roll control criteria.

Kurkowski, R. L.↗

Characteristics of the magnetospheric source of interplanetary energetic particles

The Earth's bow shock is frequently cited as an example of an astrophysical shock where particle acceleration is observed. However, because energetic particles observed upstream of the bow shock may be accelerated within the magnetosphere, it is important to understand the properties of the magnetospheric source. A first order picture of the spatial distribution of magnetospheric particles in the magnetosheath and upstream is obtained by mapping those magnetic field lines which drape over the magnetopause through the bow shock. Subsets of these field lines that connect to potential sites of magnetic merging on the magnetopause are also traced in the event that leakage occurs preferentially where normal components of the field are present across the boundary. The results can be used to determine whether the so-called diffuse particles observed upstream are accelerated locally or within the magnetosphere.

Luhmann, J. G.↗

Fracture Network Quantification during CO2 Injection

This is the presentation prepared for the ARMA 2025 (59th US Rock Mechanics/Geomechanics Symposium) Conference held in Santa Fe, New Mexico, June 8-11, 2025. Accurate mapping and quantification of these networks are essential to ensure the integrity of CO2 storage reservoirs, understand and reduce potential leakage, and maintain long-term environmental safety. This study presents a novel machine learning-driven approach, integrated with geomechanical analysis, to quantify fracture networks and assess their spatial distribution during CO2 injection. This paper combines microseismic monitoring data with principles of hydraulic diffusivity and geomechanical analysis to characterize reservoir scale fracture network. The novelty of our approach lies in its capacity to assimilate time-dependent pressure data and microseismicity into a cohesive framework, which not only identifies microseismic triggering fronts but also tracks fracture distribution during active injection. Besides, leveraging image log data and analysis our approach also provides another angle of the insights to solidate the fracture networks understanding and geomechanical impacts. Key results from our study include the detection of over 100 distinct fracture clusters across the injection site, with fracture orientations strongly correlated with the prevailing in-situ stress field.

CO2 storage and sequestration↗

Organic Ices in Titan's Stratosphere

Titan’s stratospheric ice clouds are by far the most complex of any observed in the solar system, with over a dozen organic vapors condensing out to form a suite of pure and co-condensed ices, typically observed at high winter polar latitudes. Once these stratospheric ices are formed, they will diffuse throughout Titan’s lower atmosphere and most will eventually precipitate to the surface, where they are expected to contribute to Titan’s regolith. Early and important contributions were first made by the InfraRed Interferometer Spectrometer (IRIS) on Voyager 1, followed by notable contributions from IRIS’ successor, the Cassini Composite InfraRed Spectrometer (CIRS), and to a lesser extent, from Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) and the Imaging Science Subsystem (ISS) instruments. All three remote sensing instruments made new ice cloud discoveries, combined with monitoring the seasonal behaviors and time evolution throughout Cassini’s 13-year mission tenure. A significant advance by CIRS was the realization that co-condensing chemical compounds can account for many of the CIRS-observed stratospheric ice cloud spectral features, especially for some that were previously puzzling, even though some of the observed spectral features are still not well understood. Relevant laboratory transmission spectroscopy efforts began just after the Voyager encounters, and have accelerated in the last few years due to new experimental efforts aimed at simulating co-condensed ices in Titan’s stratosphere. This review details the current state of knowledge regarding the organic ice clouds in Titan’s stratosphere, with perspectives from both observational and experimental standpoints.

Astronomy↗

Organic Ices in Titan's Stratosphere

Titan’s stratospheric ice clouds are by far the most complex of any observed in the solar system, with over a dozen organic vapors condensing out to form a suite of pure and co-condensed ices, typically observed at high winter polar latitudes. Once these stratospheric ices are formed, they will diffuse throughout Titan’s lower atmosphere and most will eventually precipitate to the surface, where they are expected to contribute to Titan’s regolith. Early and important contributions were first made by the InfraRed Interferometer Spectrometer (IRIS) on Voyager 1, followed by notable contributions from IRIS’ successor, the Cassini Composite InfraRed Spectrometer (CIRS), and to a lesser extent, from Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) and the Imaging Science Subsystem (ISS) instruments. All three remote sensing instruments made new ice cloud discoveries, combined with monitoring the seasonal behaviors and time evolution throughout Cassini’s 13-year mission tenure. A significant advance by CIRS was the realization that co-condensing chemical compounds can account for many of the CIRS-observed stratospheric ice cloud spectral features, especially for some that were previously puzzling, even though some of the observed spectral features are still not well understood. Relevant laboratory transmission spectroscopy efforts began just after the Voyager encounters, and have accelerated in the last few years due to new experimental efforts aimed at simulating co-condensed ices in Titan’s stratosphere. This review details the current state of knowledge regarding the organic ice clouds in Titan’s stratosphere, with perspectives from both observational and experimental standpoints.

C. M. Anderson↗

Organic Ices in Titan’s Stratosphere

Titan’s stratospheric ice clouds are by far the most complex of any observed in the solar system, with over a dozen organic vapors condensing out to form a suite of pure and co-condensed ices, typically observed at high winter polar latitudes. Once these stratospheric ices are formed, they will diffuse throughout Titan’s lower atmosphere and most will eventually precipitate to the surface, where they are expected to contribute to Titan’s regolith. Early and important contributions were first made by the InfraRed Interferometer Spectrometer (IRIS) on Voyager 1, followed by notable contributions from IRIS’ successor, the Cassini Composite InfraRed Spectrometer (CIRS), and to a lesser extent, from Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) and the Imaging Science Subsystem (ISS) instruments. All three remote sensing instruments made new ice cloud discoveries, combined with monitoring the seasonal behaviors and time evolution throughout Cassini’s 13-year mission tenure. A significant advance by CIRS was the realization that co-condensing chemical compounds can account for many of the CIRS-observed stratospheric ice cloud spectral features, especially for some that were previously puzzling, even though some of the observed spectral features are still not well understood. Relevant laboratory transmission spectroscopy efforts began just after the Voyager encounters, and have accelerated in the last few years due to new experimental efforts aimed at simulating co-condensed ices in Titan’s stratosphere. This review details the current state of knowledge regarding the organic ice clouds in Titan’s stratosphere, with perspectives from both an observational and experimental standpoint.

Ices↗

Fracture Network Quantification during CO2 Injection

This is the conference paper accompanying an oral presentation at the ARMA 2025 (59th US Rock Mechanics/Geomechanics Symposium) Conference held in Santa Fe, New Mexico, June 8-11, 2025. Accurate mapping and quantification of these networks are essential to ensure the integrity of CO2 storage reservoirs, understand and reduce potential leakage, and maintain long-term environmental safety. This study presents a novel machine learning-driven approach, integrated with geomechanical analysis, to quantify fracture networks and assess their spatial distribution during CO2 injection. This paper combines microseismic monitoring data with principles of hydraulic diffusivity and geomechanical analysis to characterize reservoir scale fracture network. The novelty of our approach lies in its capacity to assimilate time-dependent pressure data and microseismicity into a cohesive framework, which not only identifies microseismic triggering fronts but also tracks fracture distribution during active injection. Besides, leveraging image log data and analysis our approach also provides another angle of the insights to solidate the fracture networks understanding and geomechanical impacts. Key results from our study include the detection of over 100 distinct fracture clusters across the injection site, with fracture orientations strongly correlated with the prevailing in-situ stress field.

CO2 storage and sequestration↗