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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

Emission FTIR analyses of thin microscopic patches of jet fuel residue deposited on heated metal surface

Deposits laid down in patches on metal strips in a high pressure/high temperature fuel system simulator operated with aerated fuel at varying flow rates were analyzed by emission FTIR in terms of functional groups. Significant differences were found in the spectra and amounts of deposits derived from fuels to which small concentrations of oxygen-, nitrogen-, or sulfur-containing heterocyclics or metal naphthenates were added. The spectra of deposits generated on strips by heating fuels and air in a closed container were very different from those of the flowing fluid deposits. One such closed-container dodecane deposit on silver gave a strong surface-enhanced Raman spectrum.

Lauer, J. L.↗

Liquid phase products and solid deposit formation from thermally stressed model jet fuels

The relationship between solid deposit formation and liquid degradation product concentration was studied for the high temperature (400 C) stressing of three hydrocarbon model fuels. A Jet Fuel Thermal Oxidation Tester was used to simulate actual engine fuel system conditions. The effects of fuel type, dissolved oxygen concentration, and hot surface contact time (reaction time) were studied. Effects of reaction time and removal of dissolved oxygen on deposit formation were found to be different for n-dodecane and for 2-ethylnaphthalene. When ten percent tetralin is added to n-dodecane to give a simpler model of an actual jet fuel, the tetralin inhibits both the deposit formation and the degradation of n-dodecane. For 2-ethylnaphthalene primary product analyses indicate a possible self-inhibition at long reaction times of the secondary reactions which form the deposit precursors. The mechanism of the primary breakdown of these fuels is suggested and the primary products which participate in these precursor-forming reactions are identified. Some implications of the results to the thermal degradation of real jet fuels are given.

Kim, W. S.↗

High speed commercial transport fuels considerations and research needs

NASA is currently evaluating the potential of incorporating High Speed Civil Transport (HSCT) aircraft in the commercial fleet in the beginning of the 21st century. NASA sponsored HSCT enabling studies currently underway with airframers and engine manufacturers, are addressing a broad range of technical, environmental, economic, and related issues. Supersonic cruise speeds for these aircraft were originally focused in the Mach 2 to 5 range. At these flight speeds, both jet fuels and liquid methane were considered potential fuel candidates. For the year 2000 to 2010, cruise Mach numbers of 2 to 3+ are projected for aircraft fuel with thermally stable liquid jet fuels. For 2015 and beyond, liquid methane fueled aircraft cruising at Mach numbers of 4+ may be viable candidates. Operation at supersonic speeds will be much more severe than those encountered at subsonic flight. One of the most critical problems is the potential deterioration of the fuel due to the high temperature environment. HSCT fuels will not only be required to provide the energy necessary for flight, but will also be subject to aerodynamic heating and, will be required to serve as the primary heat sink for cooling the engine and airframe. To define fuel problems for high speed flight, a fuels workshop was conducted at NASA Lewis Research Center. The purpose of the workshop was to gather experts on aviation fuels, airframe fuel systems, airport infrastructure, and combustion systems to discuss high speed fuel alternatives, fuel supply scenarios, increased thermal stability approaches and measurements, safety considerations, and to provide directional guidance for future R and D efforts. Subsequent follow-up studies defined airport infrastructure impacts of high speed fuel candidates. The results of these activities are summarized. In addition, an initial case study using modified in-house refinery simulation model Gordian code (1) is briefly discussed. This code can be used to simulate different types of refineries, emphasizing jet fuel production and relative cost factors.

Lee, C. M.↗

Overview of Base Model in Parametric Studies Specific to Performance of U-Mo Plates

This paper provides an overview of the base model specifically developed to perform parametric sensitivity studies on the U-10Mo monolithic fuel system. U-Mo monolithic fuels are being considered for the conversion of test reactors into high-performance research reactors that operate using proliferation-resistant, low-enriched uranium (LEU) fuels. These plate-type fuels contain a high-density, low-enrichment fuel sandwiched between zirconium diffusion barriers and encapsulated in aluminum claddings. All U.S. high-performance research reactors have released the designs of their LEU monolithic fuel reactor cores. These designs include nearly 50 distinct fuel plate geometries with different operational parameters. Consequently, a single generic plate geometry representing all the extreme points in this design matrix is unrealistic. To evaluate the performance for various parameters, a set of sensitivity studies was performed. These studies considered various input parameters (i.e., geometric, operational, and material property-related). The results revealed valuable information about plate performance and the sensitivity of this performance to various modeling inputs. To establish a reference state for comparing these result, base model featuring representative irradiation conditions was developed. To capture in-reactor behavior accurately, incorporation of representative constitutive models capable of evolving properties with respect to temperature, irradiation time, and burnup was needed. The behavioral models considered burnup-dependent properties, swelling, creep, and degradation. This paper introduces the base model created for the parametric sensitivity studies. The detailed description of the procedure includes the model geometry, model discretization, thermo-mechanical coupling, material properties and behavioral models. This paper also provides selected results and assesses the performance of the base model.

42 ENGINEERING↗

Gaseous fuel reactors for power systems

Gaseous-fuel nuclear reactors have significant advantages as energy sources for closed-cycle power systems. The advantages arise from the removal of temperature limits associated with conventional reactor fuel elements, the wide variety of methods of extracting energy from fissioning gases, and inherent low fissile and fission product in-core inventory due to continuous fuel reprocessing. Example power cycles and their general performance characteristics are discussed. Efficiencies of gaseous fuel reactor systems are shown to be high with resulting minimal environmental effects. A technical overview of the NASA-funded research program in gaseous fuel reactors is described and results of recent tests of uranium hexafluoride (UF6)-fueled critical assemblies are presented.

Kendall, J. S.↗

Dumbo: A pachydermal rocket motor

A brief historical account is given of the Dumbo nuclear reactor, a type of folded flow reactor that could be used for rocket propulsion. Much of the information is given in viewgraph form. Viewgraphs show details of the reactor system, fuel geometry, and key characteristics of the system (folded flow, use of fuel washers, large flow area, small fuel volume, hybrid modulator, and cermet fuel).

Kirk, Bill↗

Engineering model system study for a regenerative fuel cell: Study report

Key design issues of the regenerative fuel cell system concept were studied and a design definition of an alkaline electrolyte based engineering model system or low Earth orbit missions was completed. Definition of key design issues for a regenerative fuel cell system include gaseous reactant storage, shared heat exchangers and high pressure pumps. A power flow diagram for the 75 kW initial space station and the impact of different regenerative fuel cell modular sizes on the total 5 year to orbit weight and volume are determined. System characteristics, an isometric drawing, component sizes and mass and energy balances are determined for the 10 kW engineering model system. An open loop regenerative fuel cell concept is considered for integration of the energy storage system with the life support system of the space station. Technical problems and their solutions, pacing technologies and required developments and demonstrations for the regenerative fuel cell system are defined.

Chang, B. J.↗

Global Ethanol-Blended-Fuel Vehicle Compatibility Study

The objective of this study is to understand the impact of ethanol-blended fuel at various blending levels (10%, 15%, and 20% vol.) on "in-operation" vehicles built to differing emissions and manufacturing standards around the world. The study focuses on vehicles used in Canada, China, India, Indonesia, Japan, South Korea, and Mexico. Historical experience in the United States and Brazil informs the analysis. The primary study question is: Are vehicles in targeted countries physically and operationally compatible with ethanol blended fuel? For a fuel to be compatible with a vehicle, the fuel must perform its function as part of the integrated fuel-vehicle system, meaning: the car should start easily and drive normally, the fuel should not cause catastrophic fuel system leaks, the fuel should not cause corrosion or degradation of any engine or fuel system components (including emissions control components). The history of E10 use in the United States, beginning in 1978, was evaluated and shows no reliability or operability issues for cars dating back to pre-emissions-control times -- and likely included many cars manufactured in the 1960s. This strongly supports the contention that fuel chemistry and property differences between E0 and E10 are so small that any car made to international standards in the last 50 years will have a very high probability of being fully compatible with E10. This conclusion is supported by the experience in Brazil in the 1970s, where E10 was also introduced, and ethanol blending for conventional cars rapidly ramped up to even higher blend levels. A limited number of fuel system and component manufacturers supply the global market, including Bosch, Continental, Denso, Delphi, and Visteon. To reduce complexity, ethanol-compatible materials began to be integrated in fuel system designs globally. Fuel systems evolved over the following decades to incorporate ethanol-compatible materials with core subsystem families, such as in-tank fuel pumps used across several global vehicle original equipment manufacturers (OEMs). A similarly compelling case can be made that all cars at the Tier 1 (or equivalent) emissions-control technology level or higher are fully compatible with E15 blends, based on the data evaluated by the U.S. Environmental Protection Agency (EPA) and Ricardo in 2010. For cars at this technology level, the minor differences in fuel chemistry and properties between E10 and E15 are not significant. For E20, studies are not as extensive but are still highly significant. A long-term durability study conducted on mileage accumulation dynamometers presents convincing evidence that Tier 2 technology level cars have materials of construction and engine control authority for compatibility with E20, although this conclusion is not as strong as those drawn for E10 and E15, which are also partly based on real-world experience.

09 BIOMASS FUELS↗

Segmented annular combustion system with dual fuel capability

A segmented annular combustion system with dual fuel capability includes an alternating arrangement of fuel injection modules and integrated combustor nozzles. The fuel injection module includes a bundled tube fuel nozzle portion and fuel injection lances, which are fluidly coupled via conduits to respective fuel plenums. A liquid fuel cartridge is disposed within the bundled tube fuel nozzle portion, within one of the plurality of fuel injection lances, or within both the bundled tube fuel nozzle portion and one of the plurality of fuel injection lances. A gas turbine having the segmented annular combustion system is also provided.

Berry, Jonathan Dwight↗

The Advantages of Non-Flow-Through Fuel Cell Power Systems for Aerospace Applications

NASA has been developing proton-exchange-membrane (PEM) fuel cell power systems for the past decade, as an upgraded technology to the alkaline fuel cells which presently provide power for the Shuttle Orbiter. All fuel cell power systems consist of one or more fuel cell stacks in combination with appropriate balance-of-plant hardware. Traditional PEM fuel cells are characterized as flow-through, in which recirculating reactant streams remove product water from the fuel cell stack. NASA recently embarked on the development of non-flow-through fuel cell systems, in which reactants are dead-ended into the fuel cell stack and product water is removed by internal wicks. This simplifies the fuel cell power system by eliminating the need for pumps to provide reactant circulation, and mechanical water separators to remove the product water from the recirculating reactant streams. By eliminating these mechanical components, the resulting fuel cell power system has lower mass, volume, and parasitic power requirements, along with higher reliability and longer life. These improved non-flow-through fuel cell power systems therefore offer significant advantages for many aerospace applications.

Hoberecht, Mark↗

Study of high-speed civil transports

A systems study to identify the economic potential for a high-speed commercial transport (HSCT) has considered technology, market characteristics, airport infrastructure, and environmental issues. Market forecasts indicate a need for HSCT service in the 2000/2010 time frame conditioned on economic viability and environmental acceptability. Design requirements focused on a 300 passenger, 3 class service, and 6500 nautical mile range based on the accelerated growth of the Pacific region. Compatibility with existing airports was an assumed requirement. Mach numbers between 2 and 25 were examined in conjunction with the appropriate propulsion systems, fuels, structural materials, and thermal management systems. Aircraft productivity was a key parameter with aircraft worth, in comparison to aircraft price, being the airline-oriented figure of merit. Aircraft screening led to determination that Mach 3.2 (TSJF) would have superior characteristics to Mach 5.0 (LNG) and the recommendation that the next generation high-speed commercial transport aircraft use a kerosene fuel. The sensitivity of aircraft performance and economics to environmental constraints (e.g., sonic boom, engine emissions, and airport/community noise) was identified together with key technologies. In all, current technology is not adequate to produce viable HSCTs for the world marketplace. Technology advancements must be accomplished to meet environmental requirements (these requirements are as yet undetermined for sonic boom and engine emissions). High priority is assigned to aircraft gross weight reduction which benefits both economics and environmental aspects. Specific technology requirements are identified and national economic benefits are projected.

Source record↗

In-situ thermomechanical measurements during burst testing of Zr claddings using digital image correlation and infrared thermography techniques

Burst testing has long been a relied-on method for assessing fuel cladding materials in light-water reactoraccident scenarios. However, burst testing historically provided minimal in-situ observations beyond a few thermocouple readings, pressure from transducers, and post-test deformation measurements. Acquisition of full cladding thermomechanical data throughout a burst test would be invaluable to fuel system qualification, material model development and fuel performance code validation, such as the BISON fuel performance code. Recently, methodologies for simultaneously applying 2-dimensional digital image correlation and infrared thermography techniques to quantify the relationship between temperature, internal cladding pressure, and deformation during burst testing were developed. This work details results from the application of these techniques to burst testing of Zircaloy-4 cladding segments subjected to loss-of-coolant accident transients in an air environment. Two types of tests were performed with: (a) cladding segments connected to a fixed pressure reservoir as well as (b) closed systems where internal pressure increased during transients. In-situ thermomechanical measurements including strain and thermal gradient data are presented, demonstrating the effectiveness of applying combined surface measurement techniques to burst testing

Bell, Sam↗

Remote Fiber Based Velocimeter For Interface Strength Measurements

The understanding of the performance of nuclear reactor plate fuels is essential when developing new fuel systems. The condition of pre and post irradiated plate fuels must be characterized effectively and efficiently prior to irradiation and then post irradiation within a high rad environment. The post characterization work must be performed remotely and in an environment hostile to instrumentation. Laser based characterization methods provide the capability to be remote and robust within a hot-cell environment. Laser based characterization can provide high spatial resolution appropriate for scanning and imaging large areas. The INL is currently developing a laser shock system for Post Irradiation Examination (PIE) station for use in the Hot Fuel Examination Facility (HFEF) at the INL. The laser shock system is designed to characterize fuel to cladding and cladding to cladding interface strength. The laser shock-technique induces large amplitude shock waves to mechanically characterize interfaces such as the fuel-clad interface. The shock wave propagates as a compressional wave through the fuel plate to the free (unconfined) backside surface and is reflected back through the test plate as a rarefaction (tensile) wave. This rarefaction wave is the physical mechanism that produces internal delamination failure. The focus or this paper is on the accurate measurement of surface velocity to quantify the amount of energy traveling through the interfaces to the back surface of the fuel plate. The original fiber based velocimeter design was biased by parasitic back reflections. This paper will discuss the discovery of the back-reflection issue and the design changes to resolve the issue. Supporting data will be presented.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Double-Wiebe Function for Reactivity Controlled Compression Ignition Combustion Using Reformate Diesel

Abstract Reactivity controlled compression ignition (RCCI) combustion has previously been proposed as a method to achieve high fuel conversion efficiency and reduce engine emissions. A single-fuel RCCI combustion strategy can have decreased fuel system complexity by using a reformate fuel for port fuel injection and the parent fuel (diesel) for direct injection. This paper presents a one-dimensional computational model of a compression ignition engine with single-fuel RCCI. A Wiebe function is used to predict the combustion process by representing the mass fraction burned (MFB) on a crank angle resolved basis. One single-Wiebe function (SWF) and two double-Wiebe functions(DWFs) were fitted to experimentally derive MFB data using the least-square method. The fitted results were compared with MFBs calculated from experimental data to verify the accuracy. The SWF did not fully capture the MFB curve with high fidelity while the detailed DWF captured the MFB curve within a root mean square error of 1.4%. The reduced double-Wiebe function (RDWF) also resulted in a predicted combustion profile with similar accuracy. Hence, the RDWF was used in a GT-power thermodynamic study to understand the effects of the low-temperature heat release (LTHR) fraction and combustion phasing on combustion characteristics. At optimum phasing of 5–10 crank angle degree after the top dead center, increasing the LTHR fraction from 20% to 60% resulted in the fuel conversion efficiency increasing from 39.5% to 41.1%, thus suggesting that the reformate fuel-based RCCI strategy is viable to unlock improved combustion performance.

Energy & Fuels↗

The pollution reduction technology program for can-annular combustor engines - Description and results

Pollutant reduction and performance characteristics were determined for three successively more advanced combustor concepts. Program Element I consisted of minor modifications to the current production JT8D combustor and fuel system to evaluate means of improved fuel preparation and changes to the basic airflow distribution. Element II addressed versions of the two-staged Vorbix (vortex burning and mixing) combustor and represented a moderate increase in hardware complexity and difficulty of development. The concept selected for Element III employed vaporized fuel as a means of achieving minimum emission levels and represented the greatest difficulty of development and adaptation to the JT8D engine. Test results indicate that the Element I single-stage combustors were capable of dramatic improvement in idle pollutants. The multistage combustors evaluated in Program Elements II and III simultaneously reduced CO, THC and NOx emissions, but were unable to satisfy the current 1979 EPA standards.

Roberts, R.↗