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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
DOE OSTI1995

Nuclear Safety [Vol. 36, No. 1, January-June 1995]

Nuclear Safety is a journal that covers significant issues in the field of nuclear safety. Its primary scope is safety in the design, construction, operation, and decommissioning of nuclear power reactors worldwide and the research and analysis activities that promote this goal, but it also encompasses the safety aspects of the entire nuclear fuel cycle, including fuel fabrication, spent-fuel processing and handling, and nuclear waste disposal, the handling of fissionable materials and radioisotopes, and the environmental effects of all these activities. Table of Contents for this issue follows. THE CHORNOBYL ACCIDENT: 1 The Chornobyl Accident Revisited, Part II: The State of the Nuclear Fuel Located Within the Chornobyl Sarcophagus, A A. Borovoi and A. R. Sich; GENERAL SAFETY CONSIDERATIONS: 33 Nuclear Power Safety in Central and Eastern Europe, R. Wilson; 46 Safety of Nuclear Power Reactors in the Former Eastern European Countries, S. Chakraborty; 53 Technical Note: On the Definition of Common-Cause Failures, H. Paula; ACCIDENT ANALYSIS: 58 Modeling and Analysis of Core-Debris Recriticality During Hypothetical Severe Accidents in the Advanced Neutron Source Reactor, S.-H. Kim, V. Georgevich, D. B. Simpson, C. O. Slater, and R. P. Taleyarkhan; 68 Ignitability of Hydrogen/Oxygen/Diluent Mixtures in the Presence of Hot Surfaces, R. K. Kumar and G. W. Koroll; 94 Coupled RELAP5 and CONTAIN Accident Analysis Using PVM, K. A. Smith, A. J. Baratta, and G. E. Robinson; CONTROL AND INSTRUMENTATION: 109 Application of Fuzzy Logic in Nuclear Reactor Control Part I: An Assessment of State-of-the-Art, A. S. Heger, N. K. Alang-Rashid, and M. Jamshidi; DESIGN FEATURES: 122 Twenty-Third DOE/NRC Nuclear Air-Cleaning and Treatment Conference, R. R. Bellamy, J. J. Hayes, and M. W. First; ENVIRONMENTAL EFFECTS: 135 Atmospheric Dispersion and the Radiological Consequences of Normal Airborne Effluents from a Nuclear Power Plant, D. Fang, C. Z. Sun, and L. Yang; 142 Calculation of Distribution Coefficients for Radionuclides in Soils and Sediments, I. Puigdomenech and U. Bergstrom: OPERATING EXPERIENCES: 155 Reactor Shutdown Experience, Compiled by J. W. Cletcher; U.S. NUCLEAR REGULATORY COMMISSION INFORMATION AND ANALYSES: 158 Operating Experience Feedback Report—Reliability of Safety-Related Steam Turbine-Driven Standby Pumps Used in U.S. Commercial Nuclear Power Plants, J. R. Boardman; 166 Turbine Building Hazards, H. L Ornstein; RECENT DEVELOPMENTS: 169 Reports, Standards, and Safety Guides, D. S. Queener; 175 Proposed Rule Changes as of Dec. 31,1994; ANNOUNCEMENTS: 32 Harvard School of Public Health In-Place Filter Testing Workshop; 134 International Conference on Advances in the Operational Safety of Nuclear Power Plants; 193 30th Tennessee Industries Week; 193 DOE Technical Standards Program 1995 Workshop; 194 Multiphase Flow Experiments and Instrumentation; 180 The Authors; 185 Indexes to Nuclear Safety, Volumes 34 and 35.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2012

Electron density measurement of cesium seeded negative ion source by surface wave probe

Electron density measurements of a large-scaled negative ion source were carried out with a surface wave probe. By comparison of the electron densities determined with the surface wave probe and a Langmuir probe, it was confirmed that the surface wave probe is highly available for diagnostic of the electron density in H{sup -} ion sources. In addition, it was found that the ratio of the electron density to the H{sup -} ion density dramatically decreases with increase of a bias voltage and the H{sup -} ions become dominant negative particles at the bias voltage of more than 6 V.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1981

Hot-gas cold-dust pumping for water masers associated with H II regions

A collisional pump with an internal sink is proposed for the water masers associated with H II regions, where the population inversion occurs due to the absorption by cold ice-mantle grains in a highly dusty cloud of the far-infrared line radiation of hot water vapor. A new escape probability method is developed to calculate the transfer of line radiation in dusty medium. The pump mechanism explains the power of usual maser sources associated with H II regions and the enormous power of the sources associated with W49 N and external galaxies. Models of maser clouds have a radius of 5 x 10 to the 15th-10 to the 16th cm, an H2 number density of 4 x 10 to the 9th/cu cm, an expansion velocity of 10-30 km/s, a kinetic temperature of 350 K, and a grain temperature of 100 K. Giant maser sources require grains of the size about 1 micron. The apparent size of the emission spots (approximately 10 to the 13th cm) observed by VLBI is interpreted as due to a fluctuation in the cloud, and the assembly of the spots is spread within a size of 10 to the 16th cm. The temperature difference between the dust and gas is due to a relaxation process after an infrared burst accompanying protostar formation.

Deguchi, S.↗
DOE OSTI2022

A crossed molecular beams and computational study on the unusual reactivity of banana bonds of cyclopropane (c-C 3 H 6 ; X 1 A$^{'}_{1}$ ) through insertion by ground state carbon atoms (C( 3 P j ))

The mechanism and chemical dynamics of the reaction of ground electronic state atomic carbon C( 3 P j ) with cyclopropane c-C 3 H 6 (X 1 A$^{'}_{1}$) have been explored by combining crossed molecular beams experiments with electronic structure calculations of the pertinent triplet C 4 H 6 potential energy surface and statistical computations of product branching ratios under single-collision conditions. The experimental findings suggest that the reaction proceeds via indirect scattering dynamics through triplet C 4 H 6 reaction intermediate(s) leading to C 4 H 5 product(s) plus atomic hydrogen via a tight exit transition state, with the overall reaction exoergicity evaluated as 231 ± 52 kJ mol –1 . The calculations indicate that C( 3 P j ) can easily insert into one of the three equivalent C–C ‘banana’ bonds of cyclopropane overcoming a low barrier of only 2 kJ mol –1 following the formation of a van der Waals reactant complex stabilized by 15 kJ mol –1 . The carbon atom insertion into one of the six C–H bonds is also feasible via a slightly higher barrier of 5 kJ mol –1 . Here, these results highlight an unusual reactivity of cyclopropane's banana C–C bonds, which behave more like unsaturated C–C bonds with a π-character than saturated σ C–C bonds, which are known to be generally unreactive toward the ground electronic state atomic carbon such as in ethane (C 2 H 6 ). The statistical theory predicts the overall product branching ratios at the experimental collision energy as 50% for 1-butyn-4-yl, 33% for 1,3-butadien-2-yl, i-C 4 H 5 , and 11% for 1,3-butadien-1-yl, n-C 4 H 5 , with i-C 4 H 5 (230 kJ mol –1 below the reactants) favored by the C–C insertion providing the best match with the experimentally observed reaction exoergicity. The C( 3 P j ) + c-C 3 H 6 reaction is predicted to be a source of C 4 H 5 radicals under the conditions where its low entrance barriers can be overcome, such as in planetary atmospheres or in circumstellar envelopes but not in cold molecular clouds. Both i- and n-C 4 H 5 can further react with acetylene eventually producing the first aromatic ring and hence, the reaction of the atomic carbon with c-C 3 H 6 can be considered as an initial step toward the formation of benzene.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2010

THE THERMALLY UNSTABLE WARM NEUTRAL MEDIUM: KEY FOR MODELING THE INTERSTELLAR MEDIUM

We present 21 cm absorption measurements toward 12 radio continuum sources with previously identified thermally unstable warm neutral medium (WNM). These observations were obtained with the Expanded Very Large Array and were complemented with the H I emission spectra obtained with the Arecibo Observatory. Out of 12 sources, H I absorption was detected along five lines of sight (seven new absorption features in total), resulting in a detection rate of {approx}42%. While our observations are sensitive to the WNM with a spin temperature T{sub s} < 3000 K, we detected only two wide absorption lines with T{sub s} = 400-900 K. These temperatures lie above the range allowed for the cold neutral medium (CNM) by the thermal equilibrium models and signify the thermally unstable WNM. Several absorption features have an optical depth of only a few x10{sup -3}. While this is close to or lower than what is theoretically expected for the CNM, we show that these weak lines are important for constraining the fraction of the thermally unstable WNM. Our observations demonstrate that, for the first time, high bandpass stability can be achieved with the Very Large Array, allowing detection of absorption lines with a peak optical depth of {approx}10{sup -3}.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

Plasma characterization of the superconducting proton linear accelerator plasma generator using a 2 MHz compensated Langmuir probe

The CERN study for a superconducting proton Linac (SPL) investigates the design of a pulsed 5 GeV Linac operating at 50 Hz. As a first step towards a future SPL H{sup -} volume ion source, a plasma generator capable of operating at Linac4 or nominal SPL settings has been developed and operated at a dedicated test stand. The hydrogen plasma is heated by an inductively coupled RF discharge e{sup -} and ions are confined by a magnetic multipole cusp field similar to the currently commissioned Linac4 H{sup -} ion source. Time-resolved measurements of the plasma potential, temperature, and electron energy distribution function obtained by means of a RF compensated Langmuir probe along the axis of the plasma generator are presented. The influence of the main tuning parameters, such as RF power and frequency and the timing scheme is discussed with the aim to correlate them to optimum H{sup -} ion beam parameters measured on an ion source test stand. The effects of hydrogen injection settings which allow operation at 50 Hz repetition rate are discussed.

43 PARTICLE ACCELERATORS↗
DOE OSTI2015

The alfalfa “almost darks” campaign: Pilot VLA HI observations of five high mass-to-light ratio systems

We present new Very Large Array (VLA) H i spectral line imaging of five sources discovered by the ALFALFA extragalactic survey. These targets are drawn from a larger sample of systems that were not uniquely identified with optical counterparts during ALFALFA processing, and as such have unusually high H i mass to light ratios. The candidate “Almost Dark” objects fall into four broad categories: (1) objects with nearby H i neighbors that are likely of tidal origin; (2) objects that appear to be part of a system of multiple H i sources, but which may not be tidal in origin; (3) objects isolated from nearby ALFALFA H i detections, but located near a gas-poor early type galaxy; (4) apparently isolated sources, with no object of coincident redshift within ∼400 kpc. Roughly 75% of the 200 objects without identified counterparts in the α.40 database (Haynes et al. 2011) fall into category 1 (likely tidal), and were not considered for synthesis follow-up observations. The pilot sample presented here (AGC193953, AGC208602, AGC208399, AGC226178, and AGC233638) contains the first five sources observed as part of a larger effort to characterize H i sources with no readily identifiable optical counterpart at single dish resolution (3.′5). These objects span a range of H i mass [7.41 < log(M{sub Hi}) < 9.51] and H i mass to B-band luminosity ratios (3 < M{sub Hi}/L{sub B} < 9). We compare the H i total intensity and velocity fields to optical imaging drawn from the Sloan Digital Sky Survey and to ultraviolet imaging drawn from archival GALEX observations. Four of the sources with uncertain or no optical counterpart in the ALFALFA data are identified with low surface brightness optical counterparts in Sloan Digital Sky Survey imaging when compared with VLA H i intensity maps, and appear to be galaxies with clear signs of ordered rotation in the H i velocity fields. Three of these are detected in far-ultraviolet GALEX images, a likely indication of star formation within the last few hundred Myrs. One source (AGC208602) is likely tidal in nature, associated with the NGC 3370 group. Consistent with previous efforts, we find no “dark galaxies” in this limited sample. However, the present observations do reveal complex sources with suppressed star formation, highlighting both the observational difficulties and the necessity of synthesis follow-up observations to understand these extreme objects.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

J-PLUS: Spectral evolution of white dwarfs by PDF analysis

We estimated the spectral evolution of white dwarfs with effective temperature using the Javalambre Photometric Local Universe Survey (J-PLUS) second data release (DR2), which provides 12 photometric optical passbands over 2176 deg 2 . We analyzed 5926 white dwarfs with r ≤ 19.5 mag in common between a white dwarf catalog defined from Gaia EDR3 and J-PLUS DR2. We performed a Bayesian analysis by comparing the observed J-PLUS photometry with theoretical models of hydrogen- and helium-dominated atmospheres. We estimated the probability distribution functions for effective temperature (T eff ), surface gravity, parallax, and composition; and the probability of having a H-dominated atmosphere (p H ) for each source. We applied a prior in parallax, using Gaia EDR3 measurements as a reference, and derived a self-consistent prior for the atmospheric composition as a function of T eff . We described the fraction of white dwarfs with a He-dominated atmosphere (f He ) with a linear function of the effective temperature at 5000 < T eff < 30 000 K. We find f He = 0.24 ± 0.01 at T eff = 10 000 K, a change rate along the cooling sequence of 0.14 ± 0.02 per 10 kK, and a minimum He-dominated fraction of 0.08 ± 0.02 at the high-temperature end. We tested the obtained p H by comparison with spectroscopic classifications, finding that it is reliable. We estimated the mass distribution for the 351 sources with distance d < 100 pc, mass M > 0.45 M ⊙ , and T eff > 6000 K. The result for H-dominated white dwarfs agrees with previous studies, with a dominant M = 0.59 M ⊙ peak and the presence of an excess at M ~ 0.8 M ⊙ . This high-mass excess is absent in the He-dominated distribution, which presents a single peak. The J-PLUS optical data provide a reliable statistical classification of white dwarfs into H- and He-dominated atmospheres. We find a 21 ± 3% increase in the fraction of He-dominated white dwarfs from T eff = 20 000 K to T eff = 5000 K.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2019

Interrelationship of Thermal Effects on Calcium Sulfate Dihydrate Casts Containing Borax and Kaolin: Differential Thermal Analysis (DTA), Thermogravimetric Analysis (TGA), and Contact Dilatometry

The core composition of gypsum wallboard is calcium sulfate dihydrate (CaSO 4 ·2H 2 O) with varying impurities, additives, or both. This study compares here two commercially calcined sources of hemihydrate (CaSO 4 ·½H 2 O) from a natural source and a synthetic by-product of flue gas desulfurization and neutralization to reagent grade hemihydrate. Two common ingredients, borax and kaolin, are mixed into a slurry with distilled water. The analysis supports the hypothesis that minor components in the cast have an effect on the high temperature performance of gypsum casts. The analysis is enhanced when the differential thermal analysis, thermogravimetric analysis, and dilatometry data are combined to study the changes in density versus heat flow. Specifically, the thermal performance is affected by (1) the impurities found in hemihydrate sources; (2) during the fluidization phase, the reaction of borax with free Ca ++ ions to form new borate salts that melt at lower temperatures; and (3) the intercalation of these and other ions with kaolin, providing thermal stability by reducing the formation of thermally active salts.

36 MATERIALS SCIENCE↗
NASA NTRS1995

ROSAT detection of diffuse hot gas in the edge-on galaxy NGC 4631

We present our ROSAT observation of the edge-on spiral galaxy NGC 4631, a nearby Sc/SBd galaxy best known for its extended radio halo. Because of the low foreground Galactic X-ray-absorbing gas column density, N(sub HI) approximately = 1.4 x 10(exp 20)/sq cm, this observation is sensitive to gas of temperature greater than or approximately = a few x 10(exp 5) K. We detected soft (approximately 0.25 keV) X-ray radiation out to more than 8 kpc above the midplane of the galaxy. The stongest X-ray emission in the halo is above the central disk, a region of about 3 kpc radius which shows high star formation activity. The X-ray emission in the halo is bordered by two extended filaments of radio continuum emission. We also found diffuse X-ray emission from hot gas in the galaxy's disk. The spectrum of the radiation can be characterized by a thermal plasma with a temperature of 3 x 10(exp 6) K and a radiative cooling rate of approximately 8 x 10(exp 39) ergs/sec. This rate is only a few percent of the estimated supernova energy release in the interstellar medium of the galaxy. Analysis of the X-ray spectrum shows evidence for the presence of a cooler (several times 10(exp 5) K) halo gas component that could consume a much larger fraction of the supernova energy. We found strong evidence for disk/halo interaction. Hot gas apparently blows out from supershells in the galaxy's disk at a rate of approximately 1 solar mass/yr. This outflow of hot gas drags magnetic field lines up in the halo and forms a magnetized gaseous halo. If the magnetic field lines are still anchored to the disk gas at large disk radii, the outflowing gas may be confined high above the disk by magnetic pressure. We have identified a strong X-ray source which coincides spatially with an H I supershell. However, the source is likely an extremely luminous X-ray binary with L(sub x)(0.1-2 keV) approximately = 5 x 10(exp 39) ergs/sec, which makes it a stellar mass black hole candidate.

Wang, Q. Daniel↗
NASA NTRS2024

Rapid Variability of Mrk 421 During Extreme Flaring as Seen Through the Eyes of XMM-Newton

By studying the variability of blazars across the electromagnetic spectrum, it is possible to resolve the underlying processes responsible for rapid flux increases, so-called flares. We report on an extremely bright X-ray flare in the high-peaked BL Lacertae object Markarian 421 (Mrk 421) that occurred simultaneously with enhanced γ-ray activity detected at very high energies by First G-APD Cherenkov Telescope on 2019 June 9. We triggered an observation with XMM–Newton, which observed the source quasi-continuously for 25 h. We find that the source was in the brightest state ever observed using XMM–Newton, reaching a flux of 2.8 × 10 −9 erg cm -2 s -1 over an energy range of 0.3–10 keV. We perform a spectral and timing analysis to reveal the mechanisms of particle acceleration and to search for the shortest source-intrinsic time-scales. Mrk 421 exhibits the typical harder-when-brighter behaviour throughout the observation and shows a clock-wise hysteresis pattern, which indicates that the cooling dominates over the acceleration process. While the X-ray emission in different sub-bands is highly correlated, we can exclude large time lags as the computed z-transformed discrete correlation functions are consistent with a zero lag. We find rapid variability on time-scales of 1 ks for the 0.3–10 keV band and down to 300 s in the hard X-ray band (4–10 keV). Taking these time-scales into account, we discuss different models to explain the observed X-ray flare, and find that a plasmoid-dominated magnetic reconnection process is able to describe our observation best.

acceleration of particles↗
DOE OSTI2011

Linear diffusion into a Faraday cage.

Linear lightning diffusion into a Faraday cage is studied. An early-time integral valid for large ratios of enclosure size to enclosure thickness and small relative permeability ({mu}/{mu}{sub 0} {le} 10) is used for this study. Existing solutions for nearby lightning impulse responses of electrically thick-wall enclosures are refined and extended to calculate the nearby lightning magnetic field (H) and time-derivative magnetic field (HDOT) inside enclosures of varying thickness caused by a decaying exponential excitation. For a direct strike scenario, the early-time integral for a worst-case line source outside the enclosure caused by an impulse is simplified and numerically integrated to give the interior H and HDOT at the location closest to the source as well as a function of distance from the source. H and HDOT enclosure response functions for decaying exponentials are considered for an enclosure wall of any thickness. Simple formulas are derived to provide a description of enclosure interior H and HDOT as well. Direct strike voltage and current bounds for a single-turn optimally-coupled loop for all three waveforms are also given.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

THE SPATIOKINEMATICAL STRUCTURE OF H{sub 2}O AND OH MASERS IN THE ''WATER FOUNTAIN'' SOURCE IRAS 18460-0151

Using the Very Long Baseline Array and the European Very Long Baseline Interferometry Network, we have observed 22.2 GHz H{sub 2}O and 1612 MHz OH masers in the water fountain source IRAS 18460-0151. The H{sub 2}O maser spectrum has a very wide line-of-sight velocity range ( Almost-Equal-To 310 km s{sup -1}) and consists of three groups of emission features at the blueshifted (-68 km s{sup -1}{approx}< V{sub LSR} {approx}< -17 km s{sup -1}) and redshifted (V{sub LSR} {approx_equal} 240 km s{sup -1}) edges as well as around the systemic velocity (112 km s{sup -1} {approx}< V{sub LSR} {approx}< 133 km s{sup -1}). The first two H{sub 2}O spectral components exhibit a highly collimated high-velocity bipolar jet on the sky, with an angular separation of Almost-Equal-To 120 milliarcsec (mas) (240 AU in linear length) and a three-dimensional flow velocity of Almost-Equal-To 160 km s{sup -1}. The flow dynamical age is estimated to be only Almost-Equal-To 6 yr (at the time of the observation epochs of 2006-2007). Interestingly, the systemic velocity component clearly exhibits a spherically expanding outflow with a radius of Almost-Equal-To 36 AU and a flow velocity of Almost-Equal-To 9 km s{sup -1}. On the other hand, the OH maser spectrum shows double peaks with a velocity separation of Almost-Equal-To 25 km s{sup -1} (V{sub LSR} = 111-116 and 138-141 km s{sup -1}), as typically seen in circumstellar envelopes of OH/IR stars. The angular offset between the velocity-integrated brightness peaks of the two high-velocity H{sub 2}O components is Almost-Equal-To 25 mas (50 AU). The offset direction and the alignment of the redshifted maser spots are roughly perpendicular to the axis of the H{sub 2}O maser flow. High-accuracy astrometry for the H{sub 2}O and OH masers demonstrates that the collimated fast jet and the slowly expanding outflow originate from a single or multiple sources which are located within 15 mas (30 AU). On the other hand, the estimated systemic velocity of the collimated jet (V{sub sys} Almost-Equal-To 87-113 km s{sup -1}) has a large uncertainty. This makes it difficult to provide strong constraints on models of the central stellar system of IRAS 18460-0151.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2011

THE QUaD GALACTIC PLANE SURVEY. II. A COMPACT SOURCE CATALOG

We present a catalog of compact sources derived from the QUaD Galactic Plane Survey. The survey covers {approx}800 deg{sup 2} of the inner galaxy (|b| < 4{sup 0}) in Stokes I, Q, and U parameters at 100 and 150 GHz, with angular resolutions of 5 and 3.5 arcmin, respectively. Five hundred and twenty-six unique sources are identified in I, of which 239 are spatially matched between frequency bands, with 53 (234) detected at 100 (150) GHz alone; 170 sources are identified as ultracompact H II regions. Approximating the distribution of total intensity source fluxes as a power law, we find a slope of {gamma}{sub S,100} = -1.8 {+-} 0.4 at 100 GHz and {gamma}{sub S,150} = -2.2 {+-} 0.4 at 150 GHz. Similarly, the power-law index of the source two-point angular correlation function is {gamma}{sub {theta},100} = -1.21 {+-} 0.04 and {gamma}{sub {theta},150} = -1.25 {+-} 0.04. The total intensity spectral index distribution peaks at {alpha}{sub I} {approx} 0.25, indicating that dust emission is not the only source of radiation produced by these objects between 100 and 150 GHz; free-free radiation is likely significant in the 100 GHz band. Four sources are detected in polarized intensity P, of which three have matching counterparts in I. Three of the polarized sources lie close to the Galactic center, Sagittarius A*, Sagittarius B2, and the Galactic Radio Arc, while the fourth is RCW 49, a bright H II region. An extended polarized source, undetected by the source extraction algorithm on account of its {approx}0.{sup 0}5 size, is identified visually, and is an isolated example of large-scale polarized emission oriented distinctly from the bulk Galactic dust polarization.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

Chemical Differences Between Sludge Solids at the F and H Area Tank Farms

The primary source of waste solids received into the F Area Tank Farm (FTF) was from PUREX processing performed to recover uranium and plutonium from irradiated depleted uranium targets. In contrast, two primary sources of waste solids were received into the H Area Tank Farm (HTF): a) waste from PUREX processing; and b) waste from H-modified (HM) processing performed to recover uranium and neptunium from burned enriched uranium fuel. Due to the differences between the irradiated depleted uranium targets and the burned enriched uranium fuel, the average compositions of the F and H Area wastes are markedly different from one another. Both F and H Area wastes contain significant amounts of iron and aluminum compounds. However, because the iron content of PUREX waste is higher than that of HM waste, and the aluminum content of PUREX waste is lower than that of HM waste, the iron to aluminum ratios of typical FTF waste solids are appreciably higher than those of typical HTF waste solids. Other constituents present at significantly higher concentrations in the typical FTF waste solids include uranium, nickel, ruthenium, zinc, silver, cobalt and copper. In contrast, constituents present at significantly higher concentrations in the typical HTF waste solids include mercury, thorium, oxalate, and radionuclides U-233, U-234, U-235, U-236, Pu-238, Pu-242, Cm-244, and Cm-245. Because of the higher concentrations of Pu-238 in HTF, the long-term concentrations of Th-230 and Ra-226 (from Pu-238 decay) will also be higher in HTF. The uranium and plutonium distributions of the average FTF waste were found to be consistent with depleted uranium and weapons grade plutonium, respectively (U-235 comprised 0.3 wt% of the FTF uranium, and Pu-240 comprised 6 wt% of the FTF plutonium). In contrast, at HTF, U-235 comprised 5 wt% of the uranium, and Pu-240 comprised 17 wt% of the plutonium, consistent with enriched uranium and high burn-up plutonium. X-ray diffraction analyses of various FTF and HTF samples indicated that the primary crystalline compounds of iron in sludge solids are Fe 2 O 3 , Fe 3 O 4 , and FeO(OH), and the primary crystalline compounds of aluminum are Al(OH) 3 and AlO(OH). Also identified were carbonate compounds of calcium, magnesium, and sodium; a nitrated sodium aluminosilicate; and various uranium compounds. Consistent with expectations, oxalate compounds were identified in solids associated with oxalic acid cleaning operations. The most likely oxidation states and chemical forms of technetium are assessed in the context of solubility, since technetium-99 is a key risk driver from an environmental fate and transport perspective. The primary oxidation state of technetium in SRS sludge solids is expected to be Tc(IV). In salt waste, the primary oxidation state is expected to be Tc(VII). The primary form of technetium in sludge is expected to be a hydrated technetium dioxide, TcO 2 ⋅ xH 2 O, which is relatively insoluble and likely co-precipitated with iron. In salt waste solutions, the primary form of technetium is expected to be the very soluble pertechnetate anion, TcO 4 - . The relative differences between the F and H Tank Farm waste provide a basis for anticipating differences that will occur as constituents of FTF and HTF waste residue enter the environment over the long-term future. If a constituent is significantly more dominant in one of the Tank Farms, its long-term environmental contribution will likely be commensurately higher, assuming the environmental transport conditions of the two Tank Farms share some commonality. It is in this vein that the information cited in this document is provided - for use during the generation, assessment, and validation of Performance Assessment modeling results.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2013

GREEN BANK TELESCOPE DETECTION OF POLARIZATION-DEPENDENT H I ABSORPTION AND H I OUTFLOWS IN LOCAL ULIRGs AND QUASARS

We present the results of a 21 cm H I survey of 27 local massive gas-rich late-stage mergers and merger remnants with the Robert C. Byrd Green Bank Telescope. These remnants were selected from the Quasar/ULIRG Evolution Study sample of ultraluminous infrared galaxies (ULIRGs; L{sub 8{sub -{sub 1000{sub {mu}m}}}} > 10{sup 12} L{sub Sun }) and quasars; our targets are all bolometrically dominated by active galactic nuclei (AGNs) and sample the later phases of the proposed ULIRG-to-quasar evolutionary sequence. We find the prevalence of H I absorption (emission) to be 100% (29%) in ULIRGs with H I detections, 100% (88%) in FIR-strong quasars, and 63% (100%) in FIR-weak quasars. The absorption features are associated with powerful neutral outflows that change from being mainly driven by star formation in ULIRGs to being driven by the AGN in the quasars. These outflows have velocities that exceed 1500 km s{sup -1} in some cases. Unexpectedly, we find polarization-dependent H I absorption in 57% of our spectra (88% and 63% of the FIR-strong and FIR-weak quasars, respectively). We attribute this result to absorption of polarized continuum emission from these sources by foreground H I clouds. About 60% of the quasars displaying polarized spectra are radio-loud, far higher than the {approx}10% observed in the general AGN population. This discrepancy suggests that radio jets play an important role in shaping the environments in these galaxies. These systems may represent a transition phase in the evolution of gas-rich mergers into ''mature'' radio galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1974

Infrared emission from H II regions

Analysis of observations made at infrared wavelengths of a large number of H II regions. Several types of IR sources are found associated with H II regions, and a single region can contain a number of varied IR emitting objects. The main sources of IR emission are ionized hydrogen concentrations, heated dust particles, and OH/H2O masers. Flux density maps for both radio and IR emission suggest that there is a physical association between the IR and radio-emitting regions. The properties of several H II regions indicate that they may be protostellar objects at various stages of evolution.

Wynn-Williams, C. G.↗