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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
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NASA NTRS2019

Quantifying Acetaldehyde in Astronomical Ices and Laboratory Analogues: IR Spectra, Intensities, 13C Shifts, and Radiation Chemistry

Acetaldehyde is of interest to astrochemists for its relevance to both interstellar and cometary chemistry, but little infrared (IR) spectral data have been published for the solid phases of this compound. Here we present IR spectra of three forms of solid acetaldehyde, with spectra for one form being published for the first time. Direct measurements of band strengths and absorption coefficients also are reported for the first time for amorphous aldehyde, the form of greatest interest for astrochemical work. An acetaldehyde band strength at 1350 cm1 that has been used as a reference for about 20 yr is seen to be in error by about 80 per cent when compared to the direct measurements presented here. Spectra and peak positions also are presented for H13C(O)13CH3, and then used for the first identification of ketene as a radiation product of solid acetaldehyde.

Hudson, Reggie L.↗
NASA NTRS1986

Neutron and antineutron production in accretion onto compact objects

Nuclear reactions in the hot accretion plasma surrounding a collapsed star are a source of neutrons, primarily through spallation and pion-producing reactions, and antineutrons, principally through the reaction p+p yields p+p+n+anti-n. We calculate spectra of neutrons and antineutrons produced by a variety of nonthermal energetic particle distributions in which the target particles are either at rest or in motion. If only neutral particles are free to escape the interaction site, a component of the proton and antiproton fluxes in the cosmic radiation results from the neutrons and antineutrons which leave the accretion plasma and subsequently decay in the interstellar medium. This additional antiproton component could account for the enhanced flux of antiprotons in the cosmic radiation, compared to values expected from the standard leaky-box model of cosmic-ray propagation and confinement. Moreover, the low-energy antiproton flux measured by Buffington et al. (1981) could result from target-particle motion in the accretion plasma. This model for the origin of antiprotons predicts a narrow 2.223 MeV line which could be observable.

Dermer, C. D.↗
NASA NTRS1986

Neutron and antineutron production in accretion onto compact objects

Nuclear reactions in the hot accretion plasma surrounding a collapsed star are a source of neutrons, primarily through spallation and pion-producing reactions, and antineutrons, principally through the reaction p+p yields p+p+n+anti-n. We calculate spectra of neutrons and antineutrons produced by a variety of nonthermal energetic particle distributions in which the target particles are either at rest or in motion. If only neutral particles are free to escape the interaction site, a component of the proton and antiproton fluxes in the cosmic radiation results from the neutrons and antineutrons which leave the accretion plasma and subsequently decay in the interstellar medium. This additional antiproton component could account for the enhanced flux of antiprotons in the cosmic radiation, compared to values expected from the standard leaky-box model of cosmic-ray propagation and confinement. Moreover, the low-energy antiproton flux measured by Buffington et al. (1981) could result from target-particle motion in the accretion plasma. This model for the origin of antiprotons predicts a narrow 2.223 MeV line which could be observable.

Dermer, Charles D.↗
DOE OSTI2021

A Foreshock Model for Interstellar Shocks of Solar Origin: Voyager 1 and 2 Observations

The Voyager 1 (V1) and Voyager 2 (V2) spacecraft were launched in 1977 on a mission to explore the outer planets and reach the heliopause, the boundary between the hot solar plasma and the relatively cool interstellar plasma. V1 reached the heliopause on 2012 August 25, at 121.6 au, and V2 reached the heliopause on 2018 November 5, at 119.0 au. One of their remarkable discoveries was the detection of shocks propagating into the interstellar plasma from energetic solar events. These shocks are typically preceded by electron plasma oscillations excited by electron beams streaming along interstellar magnetic field lines ahead of the shocks. The frequencies of the plasma oscillations have now provided radial electron density profiles in the outer heliosphere and in the interstellar medium to radial distances of more than 145 au. The oscillations are typically preceded by bursts of high-energy ∼5–100 MeV electrons. These electron bursts are interpreted as being due to the reflection (and acceleration) of cosmic-ray electrons by the shock at the time the shock first contacts the magnetic field line that passes through the spacecraft. Relative timing between the cosmic rays reflected by the shock and the onset of the plasma oscillations allow us, for the first time, to estimate the energy, ∼20–100 eV, of the electron beams responsible for the plasma oscillations. These observations are combined into a self-consistent model called the foreshock model that describes the interaction of shocks of solar origin with the interstellar plasma.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1995

Thermal Balance in Dense Molecular Clouds: Radiative Cooling Rates and Emission-Line Luminosities

We consider the radiative cooling of fully shielded molecular astrophysical gas over a wide range of temperatures ( 10 K < T < 2500 K) and H2 densities ( 10(exp 3)/cc < n(H2) < 10(exp 10)/cc). Our model for the radiative cooling of molecular gas includes a detailed treatment of the interstellar chemistry that determines the abundances of important coolant molecules, and a detailed treatment of the excitation of the species H2, CO, H2O, HCl, O2, C, O, and their isotopic variants where important. We present results for the total radiative cooling rate and for the cooling rate due to individual coolant species, as a function of the gas temperature, density, and optical depth. We have also computed the individual millimeter, submillimeter, and far-infrared line strengths that contribute to the total radiative cooling rate, and we have obtained example spectra for the submillimeter emission expected from molecular cloud cores. Many of the important cooling lines will be detectable using the Infrared Space Observatory and the Submillimeter Wave Astronomy Satellite.

Neufeld, David A.↗
NASA NTRS1981

Experimental and Theoretical Studies of Interstellar Grains

Steady state vibrational populations of SiO and CO in dilute black body radiation fields were calculated as a function of total pressure, kinetic temperature and chemical composition of the gas. Approximate calculations for polyatomic molecules are presented. Vibrational disequilibrium becomes increasingly significant as total pressure and radiation density decrease. Many regions of postulated grain formation are found to be far from thermal equilibrium before the onset of nucleation. Calculations based upon classical nucleation theory or equilibrium thermodynamics are expected to be of dubious value in such regions. Laboratory measurements of the extinction of small iron and magnetite grains were made from 195 nm to 830 nm and found to be consistent with predictions based upon published optical constants. This implies that small iron particles are not responsible for the 220 nm interstellar extinction features. Additional measurements are discussed.

Nuth, J. A., III↗
NASA NTRS1975

Interstellar clouds containing optically thick H2

Interstellar clouds containing optically thick H2 are investigated on the basis of the hypothesis that the population of the H2 rotational levels can be understood in terms of optical pumping in the Lyman and Werner bands. The observed populations are used to infer the densities and radiation fields within the clouds. The theoretical model adopted for an interstellar cloud and the analytical procedure are described. It is found that, of the 10 clouds studied, five are illuminated by a UV field appropriate to within a factor of two to that in the solar neighborhood, four appear to be near the stars against which they are observed, and one is irradiated by a very low intensity field. The results suggest that there are substantial pressure variations in the interstellar gas, even among those clouds not located near H II regions.

Jura, M.↗
NASA NTRS2003

Small-Scale Interstellar Structure Toward the Open Cluster CHI Persei-Fuse II

The purpose of this study was to measure the physical conditions of gas along sight lines toward 6 stars in the core Chi Persei open cluster. These sight lines traverse gas in both the Orion and Perseus spiral arms of the Galaxy, at distances of 500 and 2000 pc, respectively. The stars have angular separations ranging from 45 to 280 arcsec; 60 arcsec corresponds to linear distances of 0.15 and 0.6 pc in the two arms. Thus, abundance variations in these observations would constitute evidence for small-scale variations in the properties of the interstellar medium. Ground-based Na I observations at high resolution (approx. 15 km/sec) toward 172 stars (including the 6 in this study) in the double open cluster h and Chi Persei have revealed complex spatial variation. These variations are especially evident in the gas at velocities of -40 and -55 km/sec, corresponding to the Perseus spiral arm. 21 cm observations of HI emission using the Low Resolution DRAO Survey, with a 12-arcmin beam, also show variations. Averaging the Na I apparent optical depth profiles of neighboring sight lines in order to mimic such a beam size reduces the variation, as compared to the individual Na I measurements, but still show variations larger than seen in the 21 cm profiles. Na I is not the dominant ionization state of Na in the interstellar medium. Thus, it is possible that the variations seen really trace physical structures in the interstellar medium, or they may simply result from variations in the radiation field seen by the gas, or be due to some other environmental circumstance. To distinguish among these possibilities in the present study we obtained FUSE spectra toward the 6 targets in order to measure the molecular hydrogen absorption profiles along these sight lines. The higher J states of H2 are populated by the ambient W radiation field, and thus can provide insight into the environment affecting the gas. If both the high and low J states reveal absorption line profiles with variations similar to that observed in Na I, this would indicate that the variations are due to real structures in the interstellar medium. On the other hand, if the only the high J profiles mimicked the Na I profiles, then the variations may be attributable to environmental effects. We found that the H2 profiles showed considerable variation over the 6 sight lines, and that the profiles, despite having somewhat lower velocity resolution, resemble the Na I profiles. Thus, it appears that the gas really does exhibit variations in physical structures along these sight lines. Useful follow-up work would be to obtain higher signal-to-noise FUSE observations of H2, since the present data are of only moderate quality, and to obtain data on additional targets in this double cluster, in order to map out in more detail the extent and magnitude of the small-scale variations.

Sonneborn, George↗
DOE OSTI2024

Modeling Molecular Hydrogen in Low-metallicity Galaxies

We use a suite of hydrodynamics simulations of the interstellar medium (ISM) within a galactic disk, which includes radiative transfer, a nonequilibrium model of molecular hydrogen, and a realistic model for star formation and feedback, to study the structure of the ISM and H 2 abundance as a function of local ISM properties. We show that the star formation rate and structure of the ISM are sensitive to the metallicity of the gas with a progressively smoother density distribution with decreasing metallicity. In addition to the well-known trend of the H I–H 2 transition shifting to higher densities with decreasing metallicity, the maximum achieved molecular fraction in the ISM drops drastically at Z ≲ 0.2 Z ⊙ as the formation time of H 2 becomes much longer than a typical lifetime of dense regions of the ISM. We present accurate fitting formulae for both volumetric and projected ƒ H 2 measured on different scales as a function of gas metallicity, UV radiation field, and gas density. We show that when the formulae are applied to the patches in the simulated galaxy, the overall molecular gas mass is reproduced to better than a factor of ≲1.5 across the entire range of metallicities and scales. We also show that the presented fit is considerably more accurate than any of the previous ƒ H 2 models and fitting formulae in the low-metallicity regime. The fit can thus be used for modeling molecular gas in low-resolution simulations and semi-analytic models of galaxy formation in the dwarf and high-redshift regimes.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1978

Multiple Discipline science assessment

Various science disciplines were examined to determine where and when it is appropriate to include their objectives in the planning of planetary missions. The disciplines considered are solar astronomy, stellar and galactic astronomy, solar physics, cosmology and gravitational physics, the geosciences and the applied sciences. For each discipline, science objectives are identified which could provide a multiple discipline opportunity utilizing either a single spacecraft or two spacecraft delivered by a single launch vehicle. Opportunities using a common engineering system are also considered. The most promising opportunities identified include observations of solar images and relativistic effects using the Mercury orbiter; collection of samples exposed to solar radiation using the Mars surface sample return; studies of interstellar neutral H and He, magnetic fields, cosmic rays, and solar physics during Pluto or Neptune flybys; using the Mars orbiter to obtain solar images from 0.2 AU synchronous or from 90 deg orbit; and the study of the structure and composition of the atmosphere using atmospheric probes and remotely piloted vehicles.

Wells, W. C.↗
NASA NTRS1980

Excitation mechanisms for the unidentified infrared emission features

Infrared and radio observations of various objects are analyzed to put observational constraints on the mechanism which gives rise to the unidentified emission features at 3.3, 3.4, 6.2, 7.7, 8.6, and 11.3 microns. The results show that gas-grain collisions or fluorescence is not likely to be the excitation mechanism responsible for the observed features. Thermal emission by dust is reanalyzed and it is concluded that this mechanism can explain the emission features. A simple model in which the emission features arise in a population of small, hot, interstellar grains is constructed. These grains are very efficient radiators, and the emitting materials only need be a minor grain constituent to provide the power that is emitted in the features. The model offers, therefore, a simple explanation for the absence of these features in absorption.

Dwek, E.↗
NASA NTRS1987

High-resolution spectroscopy of the z = 1.79 absorption-line system toward B2 1225 + 317

The results of Multiple Mirror Telescope echelle spectroscope scans of species in the z = 1.79 system toward the quasar B2 1225 + 317 are reported. The campaign was undertaken to compare quasar absorption-line systems with gas absorption lines in other galaxies. Relative column densities obtained for Zn II, Si II, Mg II, Fe II and H I were similar to those observed for the interstellar medium. Data analyses with photoionization models for the radiation field above the Lyman limit yielded upper and lower limits to the specific intensity at 1000 A that were consistent with the UV radiation field in the halo of a spiral galaxy.

Bechtold, Jill↗
NASA NTRS1991

Origins of the 12-200 micron flux in NGC 6946 - Starlight and continuum dust emission from AN Sc galaxy

Infrared maps and optical CCD images of NGC 6946, a nearly face-on spiral with evidence of active star formation, are presented. Consideration is given, at 1-3 kpc spatial scales, to the relationship of the infrared continuum to spiral and radial structure, tracers of the interstellar medium, and ionizing and nonionizing sources of stellar radiation. Two infrared components were revealed - one with surface brightnesses of 20-60 Jy per 45 arcsec aperture at 160 microns, and the other with a surface brightness of less than 20 Jy. Various continuum distributions show discrete sources coinciding with giant H II regions superposed on a smooth unresolved disk background which decreases exponentially with the radius. The optical and spectral properties of the nuclear source and the disk are described. Dust properties and heating conditions, and far-infrared emitting phases are discussed.

Engargiola, G.↗
NASA NTRS1991

Distances to diffuse interstellar clouds from IRAS measurements and observations of optical absorption lines

Distances to diffuse interstellar clouds were determined from the amount of ultraviolet radiation that penetrates into the cloud and that arises from a nearby B star. The environment around 67 Ophiuchi, 20 Aquilae, kappa Aquilae, and 9 Cephei were studied. The intensities at 60 and 100 micron, as measured by IRAS, were used to derive dust temperatures for the clouds. Enhanced dust temperatures would indicate an influence of the star's radiation field on a cloud. Observation of molecular absorption were compared to the results of simplified chemical models in order to search for enhanced photodissociation that is caused by the star. Enhanced dust temperatures were observed for clouds in the vicinities of 20 Aql, kappa Agl, and 9 Cep. The range of the star's influence was found to be typically 1-5 pc. On the other hand, chemical analyses of the molecular data, which pertain to foreground gas, did not reveal the presence of enhanced dissociative flux from the sample of stars. Thus, upper limits were derived for the distances from the sun to the foreground material.

Federman, S. R.↗
NASA NTRS1990

Photodissociation regions

Photodissociation regions are interstellar regions of predominantly neutral gas where the FUV radiation field plays a significant role in the chemistry and/or the heating. Photodissociation, grain attenuation of the FUV flux and grain photoelectric heating lead to copious emission of C II (158 microns), O I (63 microns), Si II (35 microns), C I (370,609 microns), H2 vibrotational and CO rotational transitions, and IR continuum. Theoretical models compared with observations diagnose such physical parameters as the density and temperature structure, the elemental abundances, and the FUV radiation field. Applications are made to Orion, M17 and galactic nuclei. Theoretical photodissociation models can explain the correlation in the C II (158 microns) and CO J = 1-0 emission and the correlation of the CO J = 1-0 luminosity with the molecular mass. Theoretical models also point to feedback mechanisms which may control the rate of star formation in galaxies and which may regulate the column density through giant molecular clouds.

Hollenbach, David J.↗
NASA NTRS1993

Molecular line emission models of Herbig-Haro objects. II - HCO(+) emission

We present time-dependent models of the chemistry and temperature of interstellar molecular gas clumps that are exposed to the radiation from propagating stellar-jet shocks. The X-ray, EUV, and FUV radiation from the shock initiates ion chemistry and also heats the gas in the clumps. Using representative parameters, we show that, on the shock transit time between the clumps, the abundances of the ionized molecular species that are produced in the clumps can exceed the values determined from steady state models by several orders of magnitude. Collisional excitation by the heated gas can lead to measurable line emission from several ionized species; as in previous investigations of X-ray-irradiated molecular gas, we find that electron impacts contribute significantly to this process. We apply these results to the interpretation of the HCO(+) line emission that has already been detected in several Herbig-Haro objects. We demonstrate that this picture provides a natural explanation of the fact that the line intensity typically peaks ahead of the associated shock, as well as of the reported low line-center velocities and narrow line widths. We tabulate several diagnostic line intensities of HCO(+) and other molecular species that may be used to infer the physical conditions in the emitting gas.

Wolfire, Mark G.↗
NASA NTRS1999

The Return of Astromaterials to Earth Over the Next Decade

We are entering a new and golden age of sample return missions. In the coming decade we will harvest samples from Comet P/Wild II and interstellar dust courtesy of the STARDUST Mission (Brownlee et al., 1997), an asteroid (probably 4660 Nereus or 1989ML) by the ISAS MUSES-C Mission (ISAS, 1997), and solar wind by the Genesis Mission. A sample return from Mars is also envisioned as early as 2008, and possibly one from the two moons of Mars. It is, however, sobering to realize that MUSES-C aims to return 3-10 g of sample, STARDUST will provide micrograms of comet and interstellar dust, and Genesis will harvest only few micrograms of atoms. The diminutive size of the returning samples may be a source of concern for petrologists used only to looking at hefty lunar rocks and meteorites. How much sample is really needed to achieve prime science objectives, while maintaining a cost effective mission? The range of geological processes that we will want to address with these samples is staggering, encompassing not merely the entire history of the Solar system, but the history of the elements themselves. The interstellar processes include element formation, production and interactions with radiation, formation of organics, grain condensation and evolution, and interactions with magnetic fields. In the pre-accretionary (nebular) environment we wish to understand grain condensation, evaporation and recondensation, shock, radiation processing, solar energetic particle implantation, gas composition, the magnetic environment, and the evolution of organics. Finally, for solid bodies we wish to examine accretion history, shock, brecciation, impact gardening, metamorphism, aqueous alteration, weathering, exposure history, volcanism, fumarolic activity, differentiation, the magnetic environment, atmosphere evolution, and the evolution of organics. Since 1981, NASA has supported asteroid and comet science by collecting dust grains from these bodies in the stratosphere, and making them available for analysis in laboratories worldwide (Warren and Zolensky, 1994). Over the succeeding 17 years, many new techniques have been developed for these painstaking analyses, by at least 24 different laboratories across the globe. Despite the fact that the particle supply has always exceeded the demand, the painstaking efforts required for most of the nano-scale analyses have resulted in only 1520 grains having been analyzed, with a total mass of only 0.52 micrograms. Thus we really require less sample for analysis than one might imagine.

Zolensky, Michael E.↗