Search NASA⌕ Search

SEARCH · Search NASA

Results for “NH3”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Inhomogeneous models of the atmosphere of Saturn

Ultraviolet spectra and absorption band measurements of H2, CH4 and NH3 at visible and near-infrared wavelengths are referred to in developing an inhomogeneous atmospheric model for Saturn. The atmospheric model includes a clear gas layer which lies above an absorbing particle layer surmounting an ammonia haze layer. The distribution of particles in the atmosphere, the radiative transfer calculations, and atmospheric mixing are considered. Comparisons are made with an atmospheric model of Saturn based on infrared observations.

Macy, W.↗
NASA NTRS1977

Theoretical brightness temperature profiles of atmospheric pure H2 rotational quadrupole lines - Jupiter and Uranus

With the advent of high-resolution instruments and their use high above most of the telluric water vapor, the hydrogen pure rotational quadrupole lines at 28, 17, and 12 microns from the atmospheres of the outer planets may be observed. Best values for the line strengths, pressure-broadening coefficients, diffusion constants, and pressure shifts for these rotational transitions are calculated. The collisionally narrowed Galatry profile is used to calculate brightness temperature line profiles for these H2 transitions for the outer planets, Jupiter and Uranus. The effects of the H2 rotational-translational continuum and of the NH3 v2 band are also included.

Goorvitch, D.↗
NASA NTRS1977

The atmosphere of Jupiter from earth-based and spacecraft observations in the thermal infrared

The temperature and cloud structure, relative abundances of H2 and He, and the global climatology of Jupiter's atmosphere have been deduced from Pioneer 10 and 11 infrared radiometer data, along with earth-based observations of the spectrum at 8-14 and 12-24 microns. The H2 and He abundances are near those expected from 'solar' composition. The effective planetary temperature is 125 + or - 3 K. Temperatures at 1.0 bar are near 165 K and drop to 100-110 K at 0.1 bar; an overlying thermal inversion reaches 133-145 K near 0.03 bar. Temperature profiles for various regions of the planet may be quite similar, with differences due to the presence or absence of a thick cloud near 0.7 bar, close to the temperature where NH3 saturation is expected. Remaining problems in the remote sounding of Jupiter's atmosphere are accurate calibration of the global energy balance, sounding in the presence of significant heterogeneity, and temperature recovery of the thermally inverted stratosphere.

Orton, G. S.↗
NASA NTRS1978

Deuterated ammonia toward the Orion Nebula

The detection of transitions in NH2D at 85926.2 and 110153.4 MHz from the Orion molecular cloud is reported. An 11-m radio telescope with an 80-120 GHz cooled Cassegrain receiver and a tunable quasi-optical rejection filter was used in the investigations. Equations of statistical equilibrium for the lowest 34 energy levels of NH2D were solved. It seems unlikely that the observed lines arise in the very extended CO cloud. However, they could originate either in the molecular 'ridge' or the unresolved (Kleinmann-Low) core of the cloud or both. A column density of about 50 trillion/sq cm is deduced. The NH2D spectra, with 1 MHz resolution, are shown in a graph. Using previously reported column densities for NH3, a value of 0.05 with an estimated maximum uncertainty factor of 10 is found for the ratio NH2D/NH3.

Rodriguez Kuiper, E. N.↗
NASA NTRS1978

The evolution of the atmosphere of the earth

Computer simulations of the evolution of the earth's atmospheric composition and surface temperature have been carried out. The program took into account changes in the solar luminosity, variations in the earth's albedo, the greenhouse effect, variation in the biomass, and a variety of geochemical processes. Results indicate that prior to two billion years ago the earth had a partially reduced atmosphere, which included N2, CO2, reduced carbon compounds, some NH3, but no free H2. Surface temperatures were higher than now, due to a large greenhouse effect. When free O2 appeared the temperature fell sharply. Had earth been only slightly further from the sun, runaway glaciation would have occurred at that time. Simulations also indicate that a runaway greenhouse would have occurred early in earth's history had earth been only a few percent closer to the sun. It therefore appears that, taking into account the possibilities of either runaway glaciation or a runaway greenhouse effect, the continuously habitable zone about a solar-type star is rather narrow, extending only from roughly 0.95 to 1.01 AU.

Hart, M. H.↗
NASA NTRS1978

Evidence for CO in Jupiter's atmosphere from airborne spectroscopic observations at 5 microns

High-altitude (12.4 km) spectra of Jupiter recorded at the Kuiper Airborne Observatory are analyzed for the presence of CO absorption lines. A line-by-line comparison of Jupiter's spectrum with that of carbon monoxide is presented, as well as a correlation analysis that includes the influence of other gases present in Jupiter's atmosphere (CH4, NH3, H2O, PH3, and GeH4). The resulting evidence points strongly to the presence of carbon monoxide in Jupiter's atmosphere, thus strengthening Beer's evidence for it. Possible explanations for the existence and observability of Jovian CO, including convection from hotter, deeper layers or decomposition of organic molecules, are explored. A recent suggestion that the Jovian CO is restricted to stratospheric levels is not supported by the observations.

Larson, H. P.↗
NASA NTRS1978

A 10 micron laser heterodyne spectrometer for remote detection of trace gases

Infrared heterodyne spectroscopy provides a means of measuring the intensity profiles of individual rotation-vibration spectral lines with high sensitivity. Considerable effort has been expended on optimizing these instruments for remote measurements of gases in planetary atmospheres with the result that present-generation spectrometers are beginning to provide new and startling results on the planets. The fundamental principles of laser heterodyne spectroscopy are discussed. Detailed considerations of the optical design and the electronic design of the spectral-line receiver are given. Representative results obtained with this spectrometer are discussed, including precision frequency measurements of NH3 (nu-2) lines, detection of auroral emission from Jupiter, and measurements of terrestrial O3 and CO2.

Mumma, M. J.↗
NASA NTRS1978

Evidence for the depletion of ammonia in the Uranus atmosphere

The theoretical disk brightness temperature spectra for Uranus are computed and compared with the observed microwave spectrum. It is shown that the emission observed at short centimeter wavelengths originates deep below the region where ammonia would ordinarily begin to condense. We demonstrate that this result is inconsistent with a wide range of atmospheric models in which the partial pressure of NH3 is given by the vapor-pressure equation in the upper atmosphere. It is estimated that the ammonia mixing ratio must be less than 10 to the minus 6 in the 150 to 200 K temperature range. This is two orders of magnitude less than the expected mixing ratio based on solar abundances. The evidence for this depletion and a possible explanation are discussed.

Gulkis, S.↗
NASA NTRS1978

A rocket observation of the far-ultraviolet spectrum of Saturn

Far-ultraviolet (1160-1750 A) spectra of the Saturnian disk and the ring system have been obtained by using a very sensitive rocket-borne spectrograph with a microchannel plate detector. The use of two apertures of different diameter in the telescope focal plane permitted the separation of the contribution of the planetary disk from that of the rings. H I lambda 1216 was the only atomic spectral line emission detected in the planet and the rings. A weak signal from the disk between 1300 A and 1500 A was observed. Geometric disk albedos, averaged over 50 A, were determined from 1500 A to 1700 A. Measurements of the ring reflectivity longward of 1650 A are compatible with H2O frost but not NH3 frost.

Weiser, H.↗
NASA NTRS1978

Scale covariant cosmology and the temperature of the earth

Geological data are used as cosmological determinants in a study of the temperature of the early earth (2.3 to 4.5 billion years ago). It is known that the energy output of the sun during that period was on the order of 30-40% lower than at present, and deduced that the mean temperature of the earth should have fallen to as low as 245 K, i.e., below the freezing point of seawater. Strong evidence exists, however, to indicate that algae (therefore liquid water) was present. To reconcile the discrepancies, a model is proposed whereby terrestrial G and M vary. It is further noted that atmosphere H2 may be a better agent than NH3 for producing a greenhouse effect.

Canuto, V.↗
NASA NTRS1978

On the detectability of millimeter wavelength spectral lines from planetary atmospheres

This paper adopts a simple line-formation model to estimate detection limits on the fractional absorption produced by molecular lines in the spectra of the planets, when observed with the 14-m antenna and low-noise receivers of the Five College Radio Astronomy Observatory. The results, which can readily be adjusted for receiver and telescope characteristics of other observatories, indicate that three kinds of observing programs may prove fruitful: (1) programs to monitor temporal variations of the strong CO absorption in the spectrum of Venus and Mars; (2) searches for weak absorption lines of other molecules, which are particularly promising for Venus: and (3) efforts to measure broad features in the continuous spectra of Venus, and possibly Jupiter, produced by molecules deep in the planetary atmospheres. Except for delineation of broad features of NH3 and possibly H2O near 25 GHz, hardly any useful observations can be made at frequencies less than 60 GHz.

White, R. E.↗
NASA NTRS1978

Temperature structure and emergent flux of the Jovian planets

Long path, low temperature, moderate resolution spectra of methane and ammonia, broadened by hydrogen and helium, are used to calculate non-gray model atmospheres for the four Jovian planets. The fundamental and first overtone of hydrogen contributes enough absorption to create a thermal inversion for each of the planets. The suite of emergent spectral fluxes and representative limb darkenings and brightenings are calculated for comparison with the Voyager infrared spectra. The temperature differences between Jovian belts and zones corresponds to a difference in the ammonia cirrus particle radii (1 to 3 micron in zones; 10 micron in belts). The Jovian tropopause is approximately at the 0.1 bar level. A thin ammonia cirrus haze should be distributed throughout the Saturnian troposphere; and NH3 gas must be slightly supersaturated or ammonia ice particles are carried upwards convectively in the upper troposphere of Saturn. Substantial methane clouds exist on both Uranus and Neptune. There is some evidence for almost isothermal structures in the deep atmospheres of these two planets.

Silvaggio, P.↗
NASA NTRS1979

Molecules of significance in planetary aeronomy

This monograph is basically devoted to spectroscopic information of the molecules of planetary interest. Only those molecules have been dealt with which have been confirmed spectroscopically to be present in the atmosphere of major planets of our solar system and play an important role in the aeronomy of the respective planets. An introduction giving the general conditions of planets and their atmospheres including the gaseous molecules is given. Some typical planetary spectra is presented and supported with a discussion on some basic concepts of optical absorption and molecular parameters that are important to the study of planetary atmospheres. Quantities like dipole moments, transition probabilities, Einstein coefficients and line strengths, radiative life times, absorption cross sections, oscillator strengths, line widths and profiles, equivalent widths, growth curves, bond strengths, electronic transition moments, Franck-Condon factors and r-centroids, etc., are discussed. Spectroscopic information and relevant data of 6 diatomic (HF, HCL, CO, H2, O2, N2) and 6 polyatomic (CO2, N2), O3, HeO, NH3, CH4) molecules are presented.

Mohan, H.↗
NASA NTRS1978

An analysis of the coma of comet Bennett 1970 II

Brightness profiles for emission features of H2O(+) in comet Bennett 1970 II are analyzed, taking into account the role of chemical reactions in the coma. By comparing the rates of transport processes derived from the brightness profile with known chemical rate constants, upper limits on the abundances and production rates of H2O, CH4, NH3, and other possible coma constituents are found. The derived upper limit on the H2O production rate inside 10 to the 4th power km is less than the observed OH production rate averaged over the coma of this comet. It is concluded that the brightness profiles of H2O(+) and OH in comet Bennett 1970 II which are presently available are inconsistent with production of OH primarily by photodissociation of H2O molecules sublimating from the nucleus. The existence of an extended source of H2O is not ruled out.

Oppenheimer, M.↗
NASA NTRS1978

The ammonia mixing ratio in Jupiter's stratosphere

The paper describes the theory that underlies the model calculations which show that the far-infrared bands of ammonia are very sensitive to the ammonia distribution above the Jovian atmospheric inversion layer. Observation of the J = 5 and J = 6 ammonia bands at moderate resolution might permit choice between a cold trap model or the irreversible uv photodestruction model for the ammonia distribution. The lack of prominent emission cores in the NH3 rotation-inversion lines only implies that the mixing ratio is low. The ammonia is uniformly mixed if the inversion temperature is low but, at a higher inversion temperature, emission cores will be observed unless the photodissociation is extremely efficient down to at least the inversion layer.

Goorvitch, D.↗
NASA NTRS1978

Nonequilibrium chemistry in shocked molecular clouds

The gas-phase chemistry is studied behind a 10-km/s shock propagating into a dense molecular cloud. The principal conclusions are that: the concentrations of certain molecules (CO, NH3, HCN, N2) are unperturbed by the shock; other molecules (H2CO, CN, HCO(+)) are greatly decreased in abundance; and substantial amounts of H2O, HCO, and CH4 are produced. Approximately 1 million yr (independent of the density) must elapse after shock passage before chemical equilibrium is attained.

Iglesias, E. R.↗
NASA NTRS1979

Tholins - Organic chemistry of interstellar grains and gas

The paper discusses tholins, defined as complex organic solids formed by the interaction of energy - for example, UV light or spark discharge - with various mixtures of cosmically abundant gases - CH4, C2H6, NH3, H2O, HCHO, and H2S. It is suggested that tholins occur in the interstellar medium and are responsible for some of the properties of the interstellar grains and gas. Additional occurrences of tholins are considered. Tholins have been produced experimentally; 50 or so pyrolytic fragments of the brown, sometimes sticky substances have been identified by gas chromatography-mass spectrometry, and the incidence of these fragments in tholins produced by different procedures is reported.

Sagan, C.↗
NASA NTRS1979

Rotational excitation of symmetric top molecules by collisions with atoms. II - Infinite order sudden approximation

The infinite order sudden (IOS) approximation is extended to rotational excitation of symmetric tops by collisions with atoms. After development of a formalism for 'primitive' or 'one-ended' tops, proper parity-adapted linear combinations describing real rotors are considered and modifications needed for asymmetric rigid rotors are noted. The generalized spectroscopic relaxation cross sections are discussed. IOS calculations for NH3-He and H2CO-He are performed and compared with more accurate calculations, and the IOS approximation is found to provide a reasonably accurate description.

Green, S.↗