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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

Assessment of the biophysical characteristics of rangeland community using scatterometer and optical measurements

Research activities for the following study areas are summarized: single scattering of parallel direct and axially symmetric diffuse solar radiation in vegetative canopies; the use of successive orders of scattering approximations (SOSA) for treating multiple scattering in a plant canopy; reflectance of a soybean canopy using the SOSA method; and C-band scatterometer measurements of the Konza tallgrass prairie.

Kanemasu, E. T.↗

Raman intensity as a probe of concentration near a crystal growing in solution

The feasibility of using Raman spectral scattering signals for measurements of concentration profiles near a crystal interface during growth or dissolution is discussed. With KH2PO4 (KDP) as a test material, optical multichannel analyzer (OMA) detection of a solute Raman vibrational band provided direct quantification of solute concentration with band intensity. The intersection of incident laser and Raman collection optics provided 3-D selective point measurements of the solution concentration field. Unlike many other techniques, the Raman band intensity is not sensitive to the typical temperature variations. Precision calibration of Raman intensity versus KDP concentration with less than 1 pct standard deviation error levels was demonstrated. A fiber optic, which sampled incident laser intensity and coupled it to the OMA, provided a fully synchronized monitor of fluctuations in laser power to correlate with observed Raman signals. With 1 W of laser power at the sample, good data statistics required eight repeated data collections at approximately 2.5 min collection. The accumulated time represents the concentration measurement time at one spatial location. Photomicroscopy documented a 30 micrometer diameter by 200 micrometer of laser Raman scattering region in the solution near the crystal surface. The laser beam was able to approach up to 25 micrometer from the crystal surface. However, a crystal surface reflected intensity contribution was weakly detectable. Nucleated microcrystals were seen in the crystal-growing solution. These microcrystals convect right up to the crystal surface and indicate no quiet diffusion region under normal gravity conditions. Translation of the solution cell with respect to the optics caused systematic intensity errors.

Wilkinson, R. Allen↗

A Semianalytical Ocean Color Inversion Algorithm with Explicit Water Column Depth and Substrate Reflectance Parameterization

A semianalytical ocean color inversion algorithm was developed for improving retrievals of inherent optical properties (IOPs) in optically shallow waters. In clear, geometrically shallow waters, light reflected off the seafloor can contribute to the water-leaving radiance signal. This can have a confounding effect on ocean color algorithms developed for optically deep waters, leading to an overestimation of IOPs. The algorithm described here, the Shallow Water Inversion Model (SWIM), uses pre-existing knowledge of bathymetry and benthic substrate brightness to account for optically shallow effects. SWIM was incorporated into the NASA Ocean Biology Processing Group's L2GEN code and tested in waters of the Great Barrier Reef, Australia, using the Moderate Resolution Imaging Spectroradiometer (MODIS) Aqua time series (2002-2013). SWIM-derived values of the total non-water absorption coefficient at 443 nm, at(443), the particulate backscattering coefficient at 443 nm, bbp(443), and the diffuse attenuation coefficient at 488 nm, Kd(488), were compared with values derived using the Generalized Inherent Optical Properties algorithm (GIOP) and the Quasi-Analytical Algorithm (QAA). The results indicated that in clear, optically shallow waters SWIM-derived values of at(443), bbp(443), and Kd(443) were realistically lower than values derived using GIOP and QAA, in agreement with radiative transfer modeling. This signified that the benthic reflectance correction was performing as expected. However, in more optically complex waters, SWIM had difficulty converging to a solution, a likely consequence of internal IOP parameterizations. Whilst a comprehensive study of the SWIM algorithm's behavior was conducted, further work is needed to validate the algorithm using in situ data.

Great Barrier Reef↗

Spectral and Temperature-Dependent Optical Metrology: Towards More Robust, Effective and Durable Materials for Concentrated Solar Power

The primary objective of this project is to develop reliable and standardized spectroscopic measurement techniques to determine radiative properties, specifically the emittance and reflectance, of materials relevant for the next generation (Gen3) concentrated solar power (CSP) technologies. Experimental measurements will span near- and mid-infrared wavelengths (1–20 µm) with emphasis on quantifying the influences of: (1) operating temperatures of 25–1000 °C, (2) thermal cycling, and (3) environmental exposure of materials during operation (vacuum/air). A secondary goal is to develop open-access and digitized databases to host and share experimental data, together with standardized measurement protocols and operating procedures to determine optical properties of materials. This project will also include reasonable emphasis on developing predictive modeling tools to augment experimental data to extract more fundamental and material-specific radiative properties.

14 SOLAR ENERGY↗

On the use of the earth resources technology satellite /LANDSAT-1/ in optical oceanography

Observations of the Gulf Stream System in the Gulf of Mexico were obtained in synchronization with LANDSAT-1. Computer enhanced images, which are necessary to extract useful oceanic information, show that the current can be observed by color (diffuse radiance) or sea state (specular radiance) effects associated with the cyclonic boundary even in the absence of a surface thermal signature. The color effect relates to the spectral variations in the optical properties of the water and its suspended particles, and is studied by radiative transfer theory. Significant oceanic parameters identified are: the probability of forward scattering, and the ratio of scattering to total attenuation. Several spectra of upwelling diffuse light are computed as a function of the concentration of particles and yellow substance.

Maul, G. A.↗

Subvisual Cirrus cloud properties derived from a FIRE IFO case study

From the central Wisconsin IFO field at Wausau, the Mobile Polarization Lidar and a surface radiation station from the Lamont-Doherty Geological Observatory observed two very tenuous cirrus clouds on 21 October 1986. The clouds were present just below the height of the tropopause, between -60 to -70 C. The first cloud was not detected visually, and is classified as subvisual cirrus. The second, a relatively narrow cloud band that was probably the remnants of an aircraft contrail, can be termed zenith-subvisual since, although it was invisible in the zenith direction, it could be discerned when viewed at lower elevation angles and also due to strong solar forward-scattering and corona effects. The observations provide an opportunity to assess the threshold cloud optical thickness associated with cirrus cloud visibility. Ruby lidar backscattered signals were converted to isotropic volume backscatter coefficients by applying the pure-molecular scattering assumption just below the cloud base. The backscattering coefficient due to the cloud is then obtained and expressed in relation to the molecular backscattering coefficient in terms of the scattering ratio R. The linear depolarization ratio for the cloud is computed after removing the essentially parallel-polarized scattering contribution from air molecules. The values are also applied to determine the cloud optical thickness through the use of backscatter-to-extinction ratio, and the concentration of cloud particles using the backscattering gain, and the effective diameter of the particles obtained from the analysis of solar corona photographs. The sizes of the particles generating the corona are related to the angular separations between the centers of the red bands and the sun, yielding diameters of approximately 25 microns. The direct and diffuse components of shortwave radiation fluxes, measured by full hemispheric pyranometers, were used to compute the nadir optical thickness of the total atmosphere.

Sassen, Kenneth↗

Diffusion, Viscosity and Crystal Growth in Microgravity

The diffusivity of TriGlycine Sulfate (TGS), Potassium Dihydrogen Phosphate (KDP), Ammonium Dihydrogen Phosphate (ADF) and other compounds of interest to microgravity crystal growth, in supersaturated solutions as a function of solution concentration, 'age' and 'history was studied experimentally. The factors that affect the growth of crystals from water solutions in microgravity have been examined. Three non-linear optical materials have been studied, potassium dihydrogen phosphate (KDP), ammonium dihydrogen phosphate (ADP) and triglycine sulfate (TGC). The diffusion coefficient and viscosity of supersaturated water solutions were measured. Also theoretical model of diffusivity and viscosity in a metastable state, model of crystal growth from solution including non-linear time dependent diffusivity and viscosity effect and computer simulation of the crystal growth process which allows simulation of the microgravity crystal growth were developed.

Myerson, Allan S.↗

Determination of the ground albedo and the index of absorption of atmospheric particulates by remote sensing. I - Theory

A statistical technique is developed for inferring the optimum values of the ground albedo and the effective imaginary term of the complex refractive index of atmospheric particulates. The procedure compares measurements of the ratio of the hemispheric diffuse to directly transmitted solar flux density at the earth's surface with radiative transfer computations of the same as suggested by Herman et al. (1975). A detailed study is presented which shows the extent to which the ratio of diffuse to direct solar radiation is sensitive to many of the radiative transfer parameters. Results indicate that the optical depth and size distribution of atmospheric aerosol particles are the two parameters which uniquely specify the radiation field to the point where ground albedo and index of absorption can be inferred. Varying the real part of the complex refractive index of atmospheric particulates as well as their vertical distribution is found to have a negligible effect on the diffuse-direct ratio. The statistical procedure utilizes a semi-analytic gradient search method from least-squares theory and includes a detailed error analysis.

King, M. D.↗

Bio-Optical Properties of the Arabian Sea as Determined by In-Situ and SeaWifs Data

The overall objective of this work was to characterize optical and fluorescence properties in the euphotic zone during two British Ocean Flux Study (BOFS) Arabian Sea cruises. This was later expanded in 1995 to include three U.S. Joint Global Ocean Flux Study (JGOFS) Arabian Sea Cruises. The region was to be divided into one or more "bio-optical provinces", within each of which a single set of regression models was to be developed to relate the vertical distribution of irradiance attenuation and normalized fluorescence (SF and NF) to remote sensing reflectance and diffuse attenuation coefficient [K(490)]. The working hypothesis was that over relatively large spatial and temporal scales, the vertical profiles of bio-optical properties were predictable.

Trees, Charles C.↗

Bulk Growth of Wide Band Gap II-VI Compound Semiconductors by Physical Vapor Transport

The mechanism of physical vapor transport of II-VI semiconducting compounds was studied both theoretically, using a one-dimensional diffusion model, as well as experimentally. It was found that the vapor phase stoichiometry is critical in determining the vapor transport rate. The experimental heat treatment methods to control the vapor composition over the starting materials were investigated and the effectiveness of the heat treatments was confirmed by partial pressure measurements using an optical absorption technique. The effect of residual (foreign) gas on the transport rate was also studies theoretically by the diffusion model and confirmed experimentally by the measurements of total pressure and compositions of the residual gas. An in-situ dynamic technique for the transport rate measurements and a further extension of the technique that simultaneously measured the partial pressures and transport rates were performed and, for the first time, the experimentally determined mass fluxes were compared with those calculated, without any adjustable parameters, from the diffusion model. Using the information obtained from the experimental transport rate measurements as guideline high quality bulk crystal of wide band gap II-VI semiconductor were grown from the source materials which undergone the same heat treatment methods. The grown crystals were then extensively characterized with emphasis on the analysis of the crystalline structural defects.

Su, Ching-Hua↗

Bulk Growth of Wide Band Gap II-VI Compound Semiconductors by Physical Vapor Transport

The mechanism of physical vapor transport of II-VI semiconducting compounds was studied both theoretically, using a one-dimensional diffusion model, as well as experimentally. It was found that the vapor phase stoichiometry is critical in determining the vapor transport rate. The experimental heat treatment methods to control the vapor composition over the starting materials were investigated and the effectiveness of the heat treatments was confirmed by partial pressure measurements using an optical absorption technique. The effect of residual (foreign) gas on the transport rate was also studies theoretically by the diffusion model and confirmed experimentally by the measurements of total pressure and compositions of the residual gas. An in-situ dynamic technique for the transport rate measurements and a further extension of the technique that simultaneously measured the partial pressures and transport rates were performed and, for the first time, the experimentally determined mass fluxes were compared with those calculated, without any adjustable parameters, from the diffusion model. Using the information obtained from the experimental transport rate measurements as guideline high quality bulk crystal of wide band gap II-VI semiconductor were grown from the source materials which undergone the same heat treatment methods. The grown crystals were then extensively characterized with emphasis on the analysis of the crystalline structural defects.

Su, Ching-Hua↗

Laboratory studies of the diffuse reflectance spectra of frosts and minerals occurring on astronomical objects

A vacuum monochromator was integrated into the system and optics chosen to increase data collection in the infrared spectral region. Using a InSb detector, good reflectance data was obtained to 5.5 micron from a variety of samples including magnesium oxide, barium sulfate, water frost and Bloedite. Magnesium oxide was found to be a poorer reflector than the barium sulfate throughout the visible and near infrared region. The barium sulfate material was shown to be a Lambert reflector in the visible region and over an angular range of 60 deg. Several samples of water frost were prepared and in reflectance measured from 0.3 micron to 5.5 microm. The fine grained frosts were better reflectors than the coarse grained frosts, usually by 20 percent or more, over the entire spectral range. The minerals Bloedite and sulfur were also investigated further.

Glaser, F. M.↗

X-ray studies of quasars and active galaxies with the Einstein Observatory

Preliminary results of the first six months of an X-ray survey of active galaxies and quasars performed with the imaging proportional counter on board the Einstein Observatory are presented. Consideration is given to detections of Seyfert galaxies, N galaxies, BL Lac objects and quasars, and properties of selected representative objects are discussed in detail. The statistical properties, including class averages and correlation coefficients, of the various X-ray active galaxies are calculated in an attempt to determine the relation of X-ray properties to the similarities and differences between the various classes of galaxies. Evidence is obtained for a continuity of high-energy behavior among all active galaxies, and it is noted that they all exhibit flux variability, often on a short time scale. The soft X-ray emission can be explained in terms of the synchrotron self-Compton model, or alternatively by thermal emission from hot gas. A significant correlation is obtained between the X-ray and optical fluxes for all objects considered, indicating that optical quasar counts may be used to infer the contribution of quasars to the diffuse X-ray background.

Ku, W. H.-M.↗

Material growth and characterization for solid state devices

Manganese was used as the dopant for p-type InGaAs layers grown on semi-insulating (Fe-doped) and n-type (Sn-doped) InP substrates. Optical, electrical (Hall) and SIMS measurements were used to characterize the layers. Mn-diffusion into the substrate (during the growth of In GaAs) was observed only when Fe-doped substrates were used. Quaternary layers of two compositions corresponding to wavelengths (energy gaps) of approximated 1.52 micrometers were successfully grown at a constant temperature of 640 C and InP was grown in the temperature range of 640 C to 655 C. A study of the effect of pulses on the growth velocity of InP indicated no significant change as long as the average applied current was kept constant. A system for depositing films of Al2O3 by the pyrolysis of aluminum isopropoxide was designed and built. Deposited layers on Si were characterized with an ellipsometer and exhibited indices of refraction between 1.582 and 1.622 for films on the order of 3000 A thick. Undoped and p-type (Mn-doped) InGaAs epitaxial layers were also grown on Fe-doped InP substrates through windows in sputtered SiO2 (3200 A thick) layers.

Stefanakos, E. K.↗

The radio source in the very luminous gamma-ray Seyfert galaxy MCG 8-11-11

VLA high resolution observations of the Seyfert 1.5 galaxy MCG 8-11-11 at 2 and 6 cm show the center of the galaxy to contain a triple radio source of 400 pc, with a less than 30-pc diameter central component that may be identified as the center of the galaxy. The triple source is in turn embedded in more diffuse emission which has a major axis position angle similar to that in the optical galaxy, but differing from the position angle of the triple source by 50 deg. While the overall morphology of the source is S-shaped, the curvature of the triple source at the ends is abrupt rather than continuous and gradual. It appears that the core radio emission in Seyfert 1 and 1.5 galaxies may be weakly correlated with their X-ray emission.

Ulvestad, J. S.↗

Ocean color measurements

Ocean color observations by the Coastal Zone color scanner (CZCS) aboard the Nimbus-7 satellite are discussed, together with the factors contributing to the 'apparent' color of the ocean. The CZCS optical systems and the tecniques for extraction of the phytoplankton pigment concentration and the diffuse attenuation coefficient K from the 'apparent' water color are described in detail. Special consideration is given to the use of biooptical algorithms and the development of the K algorithm for the CZCS imagery. It is shown that under typical atmospheric conditions, the pigment concentration can be extracted from the satellite imagery to within + or - 30 percent over concentration ranges from 0 to 5 mg/cu m for the Morel case 1 water (Morel and Prieur, 1977), to which the oceanic waters belong as a rule.

Gordon, H. R.↗

On the relationship between optical polarization and extinction

A sample of stars including lines of sight within various dense clouds and stars in the diffuse interstellar medium are examined in order to investigate the relationship between various color ratios and the wavelength of the maximum of the interstellar polarization, lambda(max). The correlation of Serkowski (1975) is confirmed. The extinction laws have been fitted by minimizing the square deviations from the observed colors and the derived law. The results suggest that variations in lambda(max) are caused by differences in particle size distributions. Stars with large lambda(max) are noted in the outer regions of dense clouds, regions which are probably disturbed.

Clayton, Geoffrey C.↗

The radio properties of cD galaxies in Abell clusters. I - An X-ray selected sample

The radio and X-ray properties of a sample of 27 cD galaxies in rich clusters are presented. The radio data consist of 6 cm VLA maps at a resolution of 1-2 arcsec. The X-ray data consist of images and surface-brightness profiles from the Einstein IPC and derived quantities such as cooling times, mass-accretion rates, and thermal pressures from Arnaud (1988). These data are used to explore the relationship between X-ray cooling cores, and the power and morphology of the radio emission. It is found that 71 percent of the cD's with X-ray cooling cores are radio loud, whereas a smaller but still significant 23 percent of cD's without cooling cores are detected at 6 cm above 0.2 mJy. Among the radio galaxies in noncooling core clusters are luminous and extended wide-angle tails. There is a weak correlation between the mass-accretion rate and the radio power for cD's. There is also an interesting class of cooling core cluster (e.g., A2052) with small diameter, amorphous radio emission that may be the result of diffusion along radial magnetic fields set up in cooling inflows. Finally, the relationships between optical emission-line luminosity with radio power and mass-accretion rate are examined.

Burns, Jack O.↗