Development of space-stable thermal-control coatings Triannual report, 1 Aug. - 31 Oct. 1967
Preparation of zinc oxide pigmented methyl silicone coating for thermal protection of space flight structures
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Preparation of zinc oxide pigmented methyl silicone coating for thermal protection of space flight structures
Light transmission through body wall of living color-labile desert iguanas measured by spectrophotometry, discussing skin pigment effects
Test program simulating solar wind outside magnetosphere to evaluate high melting point high density ceramic oxides as white thermal control coating pigments
Meteorites pigments identification as porphyrins for extraterrestrial life evidence, noting sample analyses of Orgueil, Murray, Cold Bokkeveld and Mokoia carbonaceous chondrites
Flow visualization of oil smoke and pigmented oil using blade tip vortices
Surface recombination centers protecting against discoloration of thermal control coatings due to chemical changes induced by photoproduced holes and electrons in oxide pigments
UV irradiation effects on ZnO used as pigment for spacecraft thermal control coatings
Apollo 11 lunar fines porphyrin-like pigments content demonstrated by fluorescence spectrometry and analytical demetallation, suggesting rocket exhaust source
New paint formulations, which combine aqueous latex paints with inorganic pigments and additives, produce coatings that are self-extinguishing in pure oxygen at pressures up to twice the partial pressure of atmospheric oxygen. A paint formulation in percent by weight is given and the properties of resultant coatings are discussed.
Using zinc orthotitanate-pigmented potassium silicate paints for thermal control surface coatings
Binder stabilized zinc oxide pigmented coating for spacecraft thermal control
Apollo 11 lunar samples effect on terrestrial microorganisms, noting pigment production effects of Fe leaching from bulk fines and core samples
Experimental technique used in study of damage mechanism to semiconductor pigments exposed to ultraviolet radiation can be adapted for investigations of surface chemistry and may be used analytically to determine contamination.
Ferricyanide/ferrocyanide couple prevents zinc oxide pigment degradation in thermal control coatings. Chemical couple retards physical optical property changes.
The objective was to determine whether the reflectance of the degraded plasmo-clay thermal control coating could be restored by exposing it to an oxygen plasma. An experiment was conducted to determine whether bulk radiation damage would be removed by a reabsorption of oxygen ions into the pigment crystal lattice. Results show that the oxygen plasma treatment can eliminate some of the lunar environment-induced degradation on the plasmo-clay coating. Visual observations of the lunar soil on the surface after plasma treatment indicated that it was still highly absorbent to light. Therefore, part of the residual discoloration could be due to lunar soil.
Test results and data for achieving a low-outgassing polymer resin suitable for potting or a paint pigment are presented. The resin, prepared in 0.5-kg (1-lb) batches, is acceptable for spacecraft use; its weight loss is less than 0.5 percent, and the volatile condensable materials are less than 0.05 percent. The paint adheres to a primed fiber glass or aluminum substrate. Results of UV irradiation, electron and proton radiation, and thermal cycling are presented.
Calculations were made of the magnitude of the optical signature of ocean chlorophyll available to any remote sensor in earth orbit. It was desired to ascertain whether commercially significant concentrations of chlorophyll-A pigments in the ocean would produce a sufficient optical signal at orbital altitudes to operate optical remote sensors, such as those planned for the earth observatory satellite, on clear and hazy days. It was also desired to explore the effect of solar altitude on these optical signals. The best orientation was desired for the field of view for a remote sensor in orbit in order to optimize its ability to detect ocean chlorophyll.
The Murchison meteorite contains aliphatic and aromatic hydrocarbons similar to those made in static Fischer-Tropsch-type syntheses. Principal compound classes above C8 are n-alkanes, mono- and dimethylalkanes, alkenes, alkylbenzenes and -naphthalenes. Below C8, n-alkanes are virtually absent; instead, benzene, toluene, branched alkanes dominate. The CH4/C2H6 ratio is greater than 30, possibly greater than 700. Isoprenoids from C17 to C20 occur in a surface rinse but not in subsequent extracts and appear to be terrestrial contaminants. Thiophenes, porphyrin-like pigments, and chlorobenzenes were also found; the latter appear to be contaminants. In the Allende meteorite, only methane, benzene, toluene and an aromatic polymer seem to be indigeneous. A comprehensive review of current evidence shows that Fischer-Tropsch-type reactions can account for most principal features of meteorite organic matter.