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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Recent developments in 3D-printed membranes for water desalination

The recognition of membrane separations as a vital technology platform for enhancing the efficiency of separation processes has been steadily increasing. Concurrently, 3D printing has emerged as an innovative approach to fabricating reverse osmosis membranes for water desalination and treatment purposes. This method provides a high degree of control over membrane chemistry and structural properties. In particular, when compared to traditional manufacturing techniques, 3D printing holds the potential to expedite customization, a feat that is typically achieved through conventional manufacturing methods but often involves numerous processes and significant costs. This review aims to present the current advancements in membrane manufacturing technology specifically tailored for water desalination purposes, with a particular focus on the development of 3D-printed membranes. A comprehensive analysis of recent progress in 3D-printed membranes is provided. However, conducting experimental work to investigate various influential factors while ensuring consistent results poses a significant challenge. To address this, we explore how membrane manufacturing processes and performance can be effectively pre-designed and guided through the use of molecular dynamics simulations. Finally, this review outlines the challenges faced and presents future perspectives to shed light on research directions for optimizing membrane manufacturing processes and achieving optimal membrane performance.

3D printing membranes↗
DOE OSTI2024

Fast ground-state-to-ground-state separation of small ion crystals

Rapid separation of linear crystals of trapped ions into different subsets is critical for realizing trapped ion quantum computing architectures where ions are rearranged in trap arrays to achieve all-to-all connectivity between qubits. Here we introduce a general theoretical framework that can be used to describe the separation of same-species and mixed-species crystals into smaller subsets. The framework relies on an efficient description of the evolution of Gaussian motional states under quadratic Hamiltonians that only requires a special solution of the classical equations of motion of the ions to describe their quantum evolution under the influence of a time-dependent applied potential and the ions' mutual Coulomb repulsion. We provide time-dependent applied potentials suitable for separation of a mixed-species three-ion crystal on timescales similar to that of free expansion driven by Coulomb repulsion, with all modes along the crystal axis starting and ending close to their ground states. Three separately confined mixed-species ions can be combined into a crystal held in a single well without energy gain by time-reversal of this separation process.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2021

Effects of the dynamical magnetization state on spin transfer

We utilize simulations of electron scattering by a chain of dynamical quantum spins to analyze the interplay between the spin transfer effect and the magnetization dynamics.We show that the complex interactions between the spin-polarized electrons and the dynamical states of the local spins can be decomposed into separate processes involving electron reflection and transmission, as well as absorption and emission of magnons—the quanta of magnetization dynamics. Analysis shows that these processes are substantially constrained by the energy and momentum conservation laws, resulting in a significant dependence of spin transfer on the electron’s energy and the dynamical state of the local spins. Here, our results suggest that exquisite control of spin transfer efficiency and of the resulting dynamical magnetization states may be achievable by tailoring the spectral characteristics of the conduction electrons and of the magnetic systems.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Secondary building units as the turning point in the development of the reticular chemistry of MOFs

The secondary building unit (SBU) approach was a turning point in the discovery of permanently porous metal-organic frameworks (MOFs) and in launching the field of reticular chemistry. In contrast to the single-metal nodes known in coordination networks, the polynuclear nature of SBUs allows these structures to serve as rigid, directional, and stable building units in the design of robust crystalline materials with predetermined structures and properties. This concept has also enabled the development of MOFs with ultra-high porosity and structural complexity. The architectural, mechanical, and chemical stability of MOFs imparted by their SBUs also gives rise to unique framework chemistry. All of this chemistry –including ligand, linker, metal exchange, and metallation reactions, as well as precisely controlled formation of ordered vacancies– is carried out with full retention of the MOF structure, crystallinity, and porosity. The unique chemical nature of SBUs makes MOFs useful in many applications including gas and vapor adsorption, separation processes, and SBU-mediated catalysis. In essence, the SBU approach realizes a long-standing dream of scientists by bringing molecular chemistry (both organic and inorganic) to extended solid-state structures. This contribution highlights the importance of the SBUs in the development of MOFs and points to the tremendous potential still to be harnessed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Biomimetic potassium-selective nanopores

Reproducing the exquisite ion selectivity displayed by biological ion channels in artificial nanopore systems has proven to be one of the most challenging tasks undertaken by the nanopore community, yet a successful achievement of this goal offers immense technological potential. Here, we show a strategy to design solid-state nanopores that selectively transport potassium ions and show negligible conductance for sodium ions. The nanopores contain walls decorated with 4'-aminobenzo-18-crown-6 ether and single-stranded DNA (ssDNA) molecules located at one pore entrance. The ionic selectivity stems from facilitated transport of potassium ions in the pore region containing crown ether, while the highly charged ssDNA plays the role of a cation filter. Achieving potassium selectivity in solid-state nanopores opens new avenues toward advanced separation processes, more efficient biosensing technologies, and novel biomimetic nanopore systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Understanding Li-Ion Cell Internal Short Circuit and Thermal Runaway through Small, Slow and In Situ Sensing Nail Penetration

Here we report a small, slow and in situ sensing (3S) nail penetration test method to understand Li-ion cell internal short circuit (ISC) and thermal runaway. The method not only keeps conventional nail penetration's advantage of simple implementation, but also enhances its relevance to field failures and enables detailed in situ diagnosis. It was applied to 3-Ah pouch cells and revealed insights that could not be captured by conventional methods. Most interestingly, multiple in situ temperature peaks were observed during a period of over 100 s before thermal runaway. These initial peaks exceeded safety limit but the temperature rapidly decreased after each peak instead of causing immediate thermal runaway. Further investigation suggested that the initial temperature peaks occurred when nail tip reached aluminum foil current collector to form a low resistance ISC between anode and aluminum foil. The rapid temperature decrease after each peak can be attributed to sudden drop of ISC current, which can be further attributed to rupture of aluminum foil and increase of contact resistance. The findings show that 3S nail penetration test can separate processes of ISC from thermal runaway and provide details of ISC at the level of individual electrode and current collector.

25 ENERGY STORAGE↗
DOE OSTI2019

Modeling Sulfur Poisoning of Palladium Membranes Used for Hydrogen Separation

Hydrocarbons are the most important source for hydrogen production. A combined reaction-separation process using inorganic membranes can significantly increase the reaction conversion by shifting the equilibrium toward product formation. Sulfur poisoning is a significant problem as it deactivates the most commonly used metallic membranes. The relationship of the membrane activity and surface coverage with the surface structure has been recognized in the literature. A theoretical model to simulate hydrogen transport in the presence of sulfur compounds is presented. This model accounts for active site deactivation and permanent structural damage to the membrane. Transport and reaction rate parameters used in the model have been estimated from experimental data. Qualitatively, the model represents well the behavior of inorganic membranes, including partial membrane activity regeneration after the sulfur source is removed.

08 HYDROGEN↗
DOE OSTI2020

Performing k eff Validation of As-Loaded Criticality Safety Calculations Using UNF-ST&DARDS: Sensitivity Calculations

The general method for performing validation of as loaded criticality safety calculations using UNF ST&DARDS is presented in a paper by Clarity, which includes a description of the UNF-ST&DARDS system. Proof-of-principle analyses were performed in the summer of 2019 for MPC-32 dual purpose canisters (DPCs) containing pressurized water reactor (PWR) fuel assemblies. Summaries of these results are presented in this and a companion paper for this conference. The current paper describes the TSUNAMI-3D calculations performed to generate sensitivity data, and the companion paper discusses the selection of critical experiments applicable for validation of the 11 MPC-32 DPCs considered. The generation of sensitivity data for as-loaded spent nuclear fuel (SNF) DPCs is a challenge given the detailed model of the fuel compositions generated by UNF ST&DARDS. Each fuel assembly is modeled with its own irradiation history in 18 axial nodes, unless the fuel assembly is damaged and thus considered as fresh by design basis. This results in a set of 576 fuel compositions, each of which must be processed separately in a multigroup (MG) calculation. Therefore, a continuous-energy (CE) TSUNAMI-3D method was chosen to alleviate this challenge. Two CE TSUNAMI-3D methods are available in SCALE 6.2.3: the iterated fission probability (IFP) and contribution-linked eigenvalue sensitivity/uncertainty estimation via track-length importance characterization (CLUTCH). Since the IFP method is not feasible because of memory requirements associated with its implementation in SCALE, the CLUTCH method was selected for these calculations. CLUTCH has been implemented in SCALE in parallel, allowing long calculations to be performed in reasonable timeframes. The two primary user inputs necessary for CLUTCH calculations are the F*(r) mesh and the number of latent generations used in determining the F*(r) function. This F*(r) function is used as the importance function for fission chains originating in a given volume element (voxel), and it is calculated using the IFP method in the skipped generations. A large number of skipped generations is thus required to ensure accurate calculation of this importance function. In these calculations, 500 generations were used to calculate the F*(r) function. For more information regarding the calculation of F*(r), see Jones [4]. The remainder of this paper is focused on the selection of the F*(r) mesh and the number of latent generations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2019

A Sustainable Approach to Decision-Making in CCUS Systems

This study proposes a methodology for operational decision-making leading to the sustainability CO 2 -EOR systems. The methodology is a simple, yet comprehensive, integration of environmental and economic carbon capture, utilization and storage (CCUS) performance. Understanding the interplay between the environmental and economic conditions allows the EOR operator to manage the CO 2 -EOR flood so it remains within the limits of carbon balance neutrality and favorable economics under given prices and costs. The environmental performance and the main operational inputs (fluid production, CO 2 injection, and purchase requirements) were taken from a dynamic carbon Life Cycle Assessment (LCA) study previously performed for a CO 2 -EOR site in Cranfield, Mississippi. The LCA study accounts for greenhouse gases (GHG) emissions within a gate-to-grave CCUS system boundary, considering four different CO 2 injection strategies and four gas separation processes. The economic performance assessment was made through a marginalist analysis (Marginalist Production Theory), which determines important technical and economic relations through basic differential calculus derived from production, cost, and income functions. This method allows to define the operational economic optimum (optimum profit). The assessment considers four CO 2 price scenarios and uses World Bank estimated oil prices. In a first step of the proposed methodology, environmental limits of the operation are estimated. These limits are then compared with operative maximum productivity as well as with the economic optimum. According to the methodology, the EOR operation is sustainable as long as the environmental optimum is greater, or lasts longer, than the economic optimum along the project’s life. Results show that for this operation and assumed parameters, CO 2 -EOR could be classified as a sustainable activity depending on the operator’s strategic decision-making. In the case study, all injection strategies reach the environmental optimum after maximum productivity is reached. As a result, only two strategies (continuous gas injection and water alternating gas) find their economic optimum within the environmental limits, fulfilling the defined necessary and sufficient condition for CCUS sustainability.

02 PETROLEUM↗
DOE OSTI2017

Radiation Chemistry of the Hydrophilic DGAs

Short chain diglycolamides (DGAs) are water soluble, and have been used as aqueous stripping and hold back agents in both European and American fuel cycle solvent extraction proposals. An understanding of the influence of radiation on these ligands is critical to the development and implementation of robust separation processes. Therefore, the rates of degradation under radiolysis were measured for four hydrophilic DGAs and compared to the organic-soluble DGAs. Water soluble DGAs were degraded at a faster rate than lipophilic DGAs, but were more stable with increasing molecular weight. The degradation products of the tetraethyldiglycolamide (TEDGA) were also identified and found to be analogous to those produced for lipophilic DGAs in irradiated alkanes. It was concluded that similar products are obtained since reactions in both diluents are by oxidation followed rupture of the weak ether linkage. The fast rate constants of the reactions of two hydrophilic DGAs with the oxidizing •OH radical product of water radiolysis are also shown. Since water-soluble DGAs have been proposed for use as stripping or holdback agents in both European and American fuel cycle scenarios this work was performed in collaboration with colleagues at Forschungszentrum Jülich (FZJ).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2018

Functionalized Porous Organic Polymers as Uranium Nano-Traps for Efficient Recovery of Uranium from Seawater

The long-term use of nuclear power for energy applications relies on the secure and economical supply of nuclear fuel. Among various natural sources of uranium for use in nuclear reactors, seawater is highly appealing given that the oceans contain about 4.5 billion tons of dissolved uranium, almost 1000 times that estimated for mineral reserves. Nonetheless, the concentration of uranium in seawater is extremely low (3-3.3 mg L -1 or 3-3.3 ppb); this, coupled with the presence of a relatively high concentration of other metal ions, makes uranium recovery from seawater a challenge that requires the development of efficient and effective separation processes. Various adsorbent technologies based upon synthetic organic polymers, biopolymers, inorganic materials, mesoporous silica materials, porous carbon-based adsorbents, and ionic liquids have been widely developed for the extraction of uranium from seawater. However, these benchmark sorbent materials suffer from a number of drawbacks such as low adsorption capacity (typically 0.1~3.2 mg-U g -1 adsorbent), poor selectivity, and slow kinetics. Given the extreme complexity and vast volume of seawater, as well as the very low concentration of uranium present, to attain this ambitious task demands the design of adsorbents with high affinity and fast kinetics. The main objective of this project is to develop functional porous organic polymers (POPs) as a new type of adsorbent for mining uranium from seawater. This class of porous materials has quickly moved to the forefront of materials research due to their high internal surface areas, exceptional water/chemical stability, facile chemical tunability, and extraordinary capability to selectively adsorb large quantities of guest species The potential to deploy POPs in uranium extraction is related to the ease with which their internal surfaces can be decorated with high densities of strong binding sites. Beyond introducing postsynthetic modification, the specific functionalities also can be used as building units to be incorporated into porous frameworks. Our approach to fulfill this task involves the custom-design of POP-based uranium “nano-traps” via a “crystal engineering” guided design followed by stepwise post-synthetic modification. Furthermore, to increase the density of chelating groups and to enhance their affinity towards uranyl ions, judiciously designed chelating systems were constructed into porous organic polymers. Moreover, to improve the accessibility of the chelating groups and thereby the utilization efficiency, we assembled the chelating groups into highly crystalline materials where they are aligned in periodic arrays on the open channels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2018

The Quasi-Biennial Oscillation in Model-Simulated and Observed Equatorial Temperature of the Lower Stratosphere

In an otherwise thorough survey of metrics for models that simulate the Quasi-Biennial Oscillation, Schenzinger et al. say “there is no comparable observational dataset” to compare with model-simulated stratospheric temperatures (Geosci. Model Dev. 10, 2157-2168, 2017). They compare model temperatures only with reanalysis datasets, which come from numerical weather prediction models and therefore are not direct observations. But stratospheric brightness temperatures have been directly observed by microwave radiometers on board a series of satellites since 1979. Christy and Drouilhet (J. Climate 7, 106-120, 1994) found a QBO signal in 1979-1992 data from the Microwave Sounding Unit’s lower stratospheric Channel 4 (with peak weighting function at the 75hPa pressure level and half-power values at 120 and 40hPa, about 20±5 km altitude). To detect the QBO signal, Christy and Drouilhet used a latitude weighting that matches the QBO’s anti-correlation between the Equator and ±15°. Fernandez et al. also found a QBO signal in 1979-2000 MSU data, using EOF analysis (J. Climate 17, 3934-3946, 2004). Recently, Christy and Covey extended Christy and Drouilhet’s analysis through 2017 (“Stratospheric Temperature,” Section 2b5 in State of the Climate in 2017. Bull. Amer. Meteor. Soc. 99, S150–S152; Figure 2.10c). The QBO signal was again clearly visible. Although temperature trends for the lower atmosphere are sensitive to inter-satellite calibration and other processing details, giving rise to some controversy, data for the lower stratosphere are more robust. Christy and Covey’s Figure 2.9 shows that data processed separately by the National Oceanic and Atmospheric Administration (NOAA) and by Remote Sensing Systems (RSS) gives a QBO index that is virtually identical to that of Christy’s group at the University of Alabama at Huntsville (UAH).

58 GEOSCIENCES↗
DOE OSTI2019

Chemical Looping Coal Gasification Sub-Pilot Unit Demonstration and Economic Assessment for IGCC applications (Final Report)

The Ohio State University (OSU) coal to syngas (CTS) technology is an advanced air separation process that can be applied for electricity production via an integrated gasification combined cycle (IGCC). The objective of the proposed project is to enable the OSU CLG technology for a commercially relevant demonstration by 2020. In order to accomplish this objective, small pilot scale demonstration of the CLG reactor system was performed. The small pilot test unit incorporates commercially scalable non-mechanical gas sealing and solids flow control components for extended operations of the integrated reactor system. A cumulative demonstration of greater than 100 hours was performed to confirm the reliability of the reactors (reducer and oxidizer) and non-mechanical devices in maintaining controlled solid circulation, gas sealing, and coal distribution in the reactor (reducer) as well as to confirm sustained syngas product performance. A comprehensive techno-economic analysis (TEA) of the OSU CLG process for IGCC application was conducted with the support of WorleyParsons, Ltd. (WP) and compared to the Department of Energy (DOE) baseline IGCC report. Using the data gained from the small pilot demonstration, a complete comprehensive techno-economic analysis (TEA) of the CLG process was conducted. The evaluation was used as basis to attract utilities and coal industries in Ohio. The project duration lasts 30 months (6 months of no cost extension). Ohio coal was used in the integrated CLG small pilot unit to convert to high hydrogen syngas. A demonstration of the integrated chemical looping reactor system at the 15 kW th scale accelerates technology commercialization in the near term. The 15 kWth demonstration addressed several major technology gaps, such as coal injection and distribution in the reducer, controllable solids circulation with the desired fuel to solids ratio, system pressure distribution for proper gas sealing, effects of contaminants and fuel/oxygen carrier residence time requirements. The fates of impurities, such as SO x and NO x was also investigated in unit demonstrations. WP conducted a comprehensive system TEA to optimize the OSU CLG process design for efficient electricity generation with greater than 90% CO 2 capture in IGCC applications. The conclusion of this project supports the further scale-up of the technology to a commercially applicable large pilot scale test unit for operation by 2020. More importantly, it benefits Ohio as it provides an economically competitive mean for power generation with carbon capture. Given the rise of natural gas usage and strict environmental regulations, the use of Ohio coal is expected to decrease and thus impact the coal economy in Ohio. The conclusion of this project provided way for Ohio coal to compete in the future and secure jobs in the energy sector.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2019

Life Cycle Inventory of Current Photovoltaic Module Recycling Processes in Europe

With the rapid and accelerating growth of PV module installation and an increase of PV modules from the nineteen eighties and nineties reaching the end of their 30 year lifespan, their proper end of life treatment gets into focus. This report deals with the approaches, the environmental impacts and the recovered materials of PV module recycling. In this report, the environmental life cycle assessment of the current generation recycling of crystalline silicon (c-Si) and cadmium telluride (CdTe) PV modules is described. Due to the still limited waste stream today, c-Si PV modules are mainly treated in recycling plants designed for treatment of laminated glass, metals or electronic waste. Only the bulk materials glass, aluminium and copper are recovered, while the cells and other materials such as plastics are incinerated. CdTe PV modules have been treated in dedicated recycling plants for many years and life cycle inventories of this process have been published. The semiconductor is recovered in addition to glass and copper. Life cycle inventories of the recycling of current c-Si and CdTe PV modules are compiled following two modelling approaches related to recycling. The cut-off approach uses economic allocation to divide the total efforts of the recycling process between the treatment of the used PV module and the recovered products. The end-of-life approach considers the recycling process separately from the potentially avoided burdens due to recovered materials. The life cycle inventories of c-Si PV module recycling are based on data obtained from four European recyclers surveyed between 2015 and 2016. For CdTe PV module recycling, the life cycle inventories were established based on published data for the First Solar recycling facility in Germany. The life cycle impact assessment is done based on six environmental indicators previously identified as most relevant for PV electricity: particulate matter, freshwater ecotoxicity, human toxicity non-cancer effects, human toxicity cancer effects, mineral, fossil and renewable resource depletion and climate change. The life cycle inventories according to the cut-off approach can be applied to complement existing life cycle inventory data on PV systems. The environmental impacts of the recycling of c-Si PV modules are very small (maximum 1.1 %) compared to the impacts caused by the production of a 3 kWp residential PV system mounted on a slanted roof. In the case of CdTe PV module recycling, the treatment of the PV panels has the highest but still rather minor contribution in the indicator climate change (4.8 %). The life cycle inventories according to the end-of-life approach allow an assessment of the net environmental benefits of recycling. The recovery of glass, metals, and semiconductor material from c-Si and CdTe PV modules causes lower environmental impacts than the extraction, refinement and supply of the respective materials from primary resources. The highest potential benefits are observed in the indicator mineral, fossil and renewable resource depletion. The data quality of the recycling of c-Si PV modules is classified as fair since only limited information is available. In contrast, the data quality of CdTe PV module recycling is considered very good. The study was financed by the Swiss Federal Office of Energy (SFOE) and carried out in the framework of the Task 12 of the Photovoltaic Powers System Programme (PVPS) of the International Energy Agency (IEA).

14 SOLAR ENERGY↗
DOE OSTI2019

Modeling Salt-Material Interactions in Molten Salt Reactors: Opportunities and Path Forward

A revitalized interest in molten salt reactor technology has resulted in a concerted effort across US based national laboratories and universities to investigate and overcome the remaining scientific and engineering questions facing the industry. This report provides a detailed description of the atomistic modelling techniques that could be employed to investigate the atomic-level forces and behaviors governing salt chemistry and thermodynamics, and the corrosion of container materials in these systems. The molten salt environment is broken down into three unique regions in which atomic behaviors are governed by separate processes and forces. A discussion is given on how each region can be modelled using different computational methods. The objective of the models presented for each region is to understand and quantify the individual atom-to-atom forces driving corrosion processes and changes in salt chemistry. Once these fundamental mechanisms are better understood, larger models, which connect the regions, can be designed to investigate the long-term non-equilibrium behaviors exhibited by these molten salt systems. With a large enough computational effort, employing the modeling techniques discussed in this report to supplement experimental investigations, a greater understanding of the degradation of salt-facing structural materials can be gained, enabling more accurate lifetime prediction, greater safety and regulatory compliance, and faster material innovation.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Analysis of Organoiodide Adsorption Mechanisms

If the United States were to engage in the reprocessing of used nuclear fuel, radioactive iodine must be removed from multiple plant off-gas streams to comply with governing regulations. One of these streams is the vessel off-gas (VOG), which arises from the separations process and is expected to contain iodine in primarily organic iodine forms and at parts-per-billion concentrations. The relative lack of knowledge surrounding organic iodine removal from the VOG prompted the US Department of Energy’s Office of Nuclear Energy to initiate experimental efforts targeted at understanding organic iodide removal from prototypic VOG streams. At Oak Ridge National Laboratory (ORNL), this effort has focused on developing a comprehensive understanding of iodine removal from VOG streams by using silver-based sorbents. An important aspect of this testing is developing an understanding of how the sorption of methyl iodide (CH 3 I), the most studied organic iodide species to date, compares with the sorption of other volatile organic iodide species potentially present in the VOG. The work presented here reflects initial testing that will continue to be developed, and final results will be incorporated into an end-of-year report that details a multiyear testing campaign designed to understand iodine mitigation from VOG streams. The goal of these experiments was to determine whether similar reaction pathways govern both CH 3 I and iodobutane (C 4 H 9 I) sorption onto silver mordenite (AgZ), a common silver-based iodine sorbent. More specifically, the authors hypothesized that the sorption of C 4 H 9 I by AgZ will result in the formation of butanol (C 4 H9OH). Effluent monitoring of CH 3 I sorption testing has confirmed methanol production, but analogous monitoring of effluents from C 4 H 9 I sorption studies has not been performed. A series of tests was completed to test this hypothesis with the aim of detecting C 4 H 9 OH downstream of the AgZ bed. Test conditions varied the bed depth, gas stream humidity, and bed temperature post sorption. The effluent gas stream downstream of the AgZ bed was sampled by using gas-tight syringes, and these samples were analyzed by a gas chromatograph coupled to a mass spectrometer. Thin bed C 4 H 9 I tests conducted at -65 and 0°C dew points did not result in C 4 H 9 OH detection in the effluent. This suggests that the sorption mechanism and subsequent reactions could be different from those observed for CH 3 I. The sorption testing continues; additional results will be included in final end-of-year report and will increase the fundamental understanding of organic iodide sorption by AgZ from VOG streams.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Environmental Monitoring Report, Calendar year 2020. Knolls Laboratory and Kesselring Site

The results of the effluent and environmental monitoring programs at the Knolls Laboratory and Kesselring Site are summarized and assessed in this report. Tables 1 - 4 summarize the major elements of the environmental monitoring programs at each site. Information regarding the U.S. Department of Energy – Office of Environmental Management (DOE-EM) Separations Process Research Unit (SPRU) Disposition Project (SPRU DP), is also included in this report; however, the project was completed in 2020 and will no longer be reported in subsequent reports. DOE-EM will be continuing to perform other Decontamination & Decommissioning (D&D) work at Knolls Laboratory and Kesselring Site, which may require environmental monitoring, and will be included in this report, as warranted. Operations at the Knolls Laboratory, which includes SPRU and other DOE-EM activities, and the Kesselring Site continue to have no adverse effect on human health and the quality of the environment.

54 ENVIRONMENTAL SCIENCES↗