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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Automated design of controlled-diffusion blades

A numerical automation procedure has been developed to be used in conjunction with an inverse hodograph method for the design of controlled diffusion blades. With this procedure a cascade of airfoils with a prescribed solidity, inlet Mach number, inlet air flow angle, and air flow turning can be produced automatically. The trailing edge thickness of the airfoil, an important quantity in inverse methods, is also prescribed. The automation procedure consists of a multidimensional Newton iteration in which the objective design conditions are achieved by acting on the hodograph input parameters of the underlying inverse code. The method, although more general in scope, is applied in this paper to the design of axial flow compressor blade sections, and a wide range of examples is presented.

Sanz, J. M.↗
NASA NTRS1989

Automated design of controlled diffusion blades

A numerical automation procedure was developed to be used in conjunction with an inverse hodograph method for the design of controlled diffusion blades. With this procedure a cascade of airfoils with a prescribed solidity, inlet Mach No., inlet air flow angle and air flow turning can be produced automatically. The trailing edge thickness of the airfoil, an important quantity in inverse methods, is also prescribed. The automation procedure consists of a multi-dimensional Newton iteration in which the objective design conditions are achieved by acting on the hodograph input parameters of the underlying inverse code. The method, although more general in scope, is applied to the design of axial flow turbomachinery blade sections, both compressors and turbines. A collaborative effort with U.S. Engine Companies to identify designs of interest to the industry will be described.

Sanz, Jose M.↗
NASA NTRS1951

Preliminary Investigation of Use of Conical Flow Separation for Efficient Supersonic Diffusion

Use of flow separation on a rod projecting upstream of a blunt body to decelerate the supersonic stream ahead of an annular nose inlet was investigated at Mach numbers of 1.76, 1.93, and 2.10. Maximum pressure recoveries were obtained with rod tip projections about 1.5 times the radius of the spherical nose and were higher than those obtained with single-shock solid cones. Subcritical operation was similar to that observed with solid-cone inlets, but the effect of angle of attack on maximum pressure recovery was more severe.

WIND TUNNEL TESTS - LFPL - SUPERSONIC (18"x18")↗
NASA NTRS2004

Enhanced Boiling on Micro-Configured Composite Surfaces Under Microgravity Conditions

Two experimental setups: High Heat Flux Pool Boiling Setup and Optical system of Measuring Contact Angle and Spreading Parameters were established and a series of experiments was conducted. The experimental work on the nucleate boiling performance of both Freon-113 and water on the composite surfaces has been finished and the results show that the composite surface with 25% volume fraction of graphite fibers in the copper matrix has the best enhancing performance. Stronger enhancement was obtained for water compared to Freon-113. The wall superheat initiating boiling was reduced 40% and 35% and the heat flux of the nucleate boiling was augmented up to ten times and 6.7 times, respectively. A bubble departure model has been presented to explain the enhancement mechanism of the boiling heat transfer on the composite surfaces. A powerful optical method to measure contact angle and spreading parameters of liquids on solid surfaces, including both transparent and non-transparent substrates, has been developed and successfully used in the measurements for various liquid-solid systems. The experimental work on identification of profiles near three-phase line by laser shadowgraphy method has been finished and the characteristics of the three-phase line for different liquid-solid systems were unveiled, which is very important to understand the mechanism of boiling under microgravity conditions. The four basic patterns of sessile profile were discovered through caustics and caustic-diffraction analysis by applying wave theory in shadowgraphy technology, which contributes to clearly explain the different characteristics of wetting and spreading of various liquids on a solid surface, and therefore to further understand the bubble departure mechanisms. A new working pattern of heat pipes using working fluids with positive surface-tension gradient against temperature was discovered and analyzed, and then the new heat pipe systems using this kind of working fluids have been presented. Two patent devices, i.e. Shadowgraphic Method to Measure Properties of Sessile Drops and Heat Pipe Systems Using New Working Fluids, have been developed; the former has been approved by The United States Patent & Trademark Office and the latter is being examined.

Source record↗
NASA NTRS2006

Solid State NMR Studies of the Aluminum Hydride Phases

Several solid state NMR techniques including magic-angle-spinning (MAS) and multiple-quantum (MQ) MAS experiments have been used to characterize various AlH3 samples. MAS-NMR spectra for the 1H and 27Al nuclei have been obtained on a variety of AlH3 samples that include the (beta)- and (gamma)- phases as well as the most stable (alpha)-phase. While the dominant components in these NMR spectra correspond to the aluminum hydride phases, other species were found that include Al metal, molecular hydrogen (H2), as well as peaks that can be assigned to Al-O species in different configurations. The occurrence and concentration of these extraneous components are dependent upon the initial AlH3 phase composition and preparation procedures. Both the (beta)-AlH3 and (gamma)-AlH3 phases were found to generate substantial amounts of Al metal when the materials were stored at room temperature while the (alpha)-phase materials do not exhibit these changes.

phase compositions↗
NASA NTRS1976

Effect of friction in wedging of elastic solids

In this paper the contact problem for an elastic wedge of arbitrary angle is considered. It is assumed that the external load is applied to the medium through a rigid wedge and the coefficient of friction between the loading wedge and the elastic solid is constant. The problem is reduced to a singular integral equation of the second kind with the contact pressure as the unknown function. An effective numerical solution of the integral equation is described and the results of three examples are presented. The comparison of these results with those obtained from the frictionless wedge problem indicates that generally friction has the tendency of reducing the peak values of the stress intensity factors calculated at the wedge apex and at the end points of the contact area.

Erdogan, F.↗
DOE OSTI2022

Hybrid quantum-classical simulations of magic angle spinning dynamic nuclear polarization in very large spin systems

Solid-state nuclear magnetic resonance can be enhanced using unpaired electron spins with a method known as dynamic nuclear polarization (DNP). Fundamentally, DNP involves ensembles of thousands of spins, a scale that is difficult to match computationally. This scale prevents us from gaining a complete understanding of the spin dynamics and applying simulations to design sample formulations. We recently developed an ab initio model capable of calculating DNP enhancements in systems of up to ~1000 nuclei; however, this scale is insufficient to accurately simulate the dependence of DNP enhancements on radical concentration or magic angle spinning (MAS) frequency. We build on this work by using ab initio simulations to train a hybrid model that makes use of a rate matrix to treat nuclear spin diffusion. We show that this model can reproduce the MAS rate and concentration dependence of DNP enhancements and build-up time constants. Finally, we then apply it to predict the DNP enhancements in core–shell metal-organic-framework nanoparticles and reveal new insights into the composition of the particles’ shells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Stimulated resonant inelastic X-ray scattering in a solid

Abstract When materials are exposed to X-ray pulses with sufficiently high intensity, various nonlinear effects can occur. The most fundamental one consists of stimulated electronic decays after resonant absorption of X-rays. Such stimulated decays enhance the number of emitted photons and the emission direction is confined to that of the stimulating incident photons which clone themselves in the process. Here we report the observation of stimulated resonant elastic (REXS) and inelastic (RIXS) X-ray scattering near the cobalt L 3 edge in solid Co/Pd multilayer samples. We observe an enhancement of order 10 6 of the stimulated over the conventional spontaneous RIXS signal into the small acceptance angle of the RIXS spectrometer. We also find that in solids both stimulated REXS and RIXS spectra contain contributions from inelastic electron scattering processes, even for ultrashort 5 fs pulses. Our results reveal the potential and caveats of the development of stimulated RIXS in condensed matter.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Snapshots of Ce 70 Toroid Assembly from Solids and Solution

Crystallization at the solid–liquid interface is difficult to spectroscopically observe and therefore challenging to understand and ultimately control at the molecular level. The Ce70-torroid formulated [Ce IV 70 (OH) 36 (O) 64 (SO 4 ) 60 (H 2 O) 10 ] 4– , part of a larger emerging family of M IV 70 -materials (M = Zr, U, Ce), presents such an opportunity. We elucidated assembly mechanisms by the X-ray scattering (small-angle scattering and total scattering) of solutions and solids as well as crystallizing and identifying fragments of Ce 70 by single-crystal X-ray diffraction. Fragments show evidence for templated growth (Ce 5 , [Ce 5 (O) 3 (SO 4 ) 12 ] 10- ) and modular assembly from hexamer (Ce 6 ) building units (Ce 13 , [Ce 13 (OH) 6 (O) 12 (SO 4 ) 14 (H 2 O) 14 ] 6– and Ce 62 , [Ce 62 (OH) 30 (O) 58 (SO 4 ) 58 ] 14- ). Ce 62 , an almost complete ring, precipitates instantaneously in the presence of ammonium cations as two torqued arcs that interlock by hydrogen boding through NH 4 + , a structural motif not observed before in inorganic systems. The room temperature rapid assemblies of both Ce 70 and Ce 62 , respectively, by the addition of Li + and NH 4 + , along with ion-exchange and redox behavior, invite exploitation of this emerging material family in environmental and energy applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Discharge Rate‐Driven Li 2 O 2 Growth Exhibits Unconventional Morphology Trends in Solid‐State Li‐O 2 Batteries

Solid-state lithium oxygen batteries (LOBs) are known for their enhanced safety, higher electrochemical stability, and improved energy density compared to liquid-state LOBs. However, the investigation of solid-state LOBs is limited with little understanding of their discharge and charge processes. In this work, a polymer-based solid-state LOB is used to investigate the effect of discharge rate on lithium peroxide (Li 2 O 2 ) formation, the oxygen evolution reaction (OER), and cycle performance. Notably, we observe a counterintuitive trend: Li 2 O 2 particle size increases with increasing discharge current density, in contrast to liquid systems. This behavior arises from inherent space charge layers that restrict Li⁺ transport under high current, and spatially heterogeneous active sites at the solid electrolyte–cathode interface, directly evidenced by small angle X-ray scattering (SAXS), which govern nucleation accessibility and promote site-selective Li 2 O 2 growth. Furthermore, higher current densities improve ORR and OER efficiency but accelerate anode degradation, while lower currents promote side reactions. These opposing effects result in a trade-off that defines an optimal discharge rate (0.1 mA cm -2 ) for maximizing cycle life. This study provides a new mechanistic perspective on discharge-driven processes in solid-state LOBs and offers practical guidelines for performance optimization in future high-energy battery systems.

Discharge current density↗
DOE OSTI2022

Lens-free compound eye cameras based on angle-sensitive meta-surfaces

A lens-free ultrathin imaging sensor using a compound-eye vision modality can be formed by forming a metasurface on each pixel of an array of pixels in a solid state imaging sensor. The metasurface can be configured to form a diffraction grating that directs light incident on the metasurface at a predefined angle to excite surface plasmon polaritons into the solid state imaging sensor and light incident at any other angle is reflected or diffracted away from the metasurface. Each pixel of the imaging sensor can be configured using the metasurface to only receive light incident from a different portion of a field of view. A computational imaging system can be used to construct the image from the individual pixels.

Paiella, Roberto↗
DOE OSTI2020

Solid-State NMR Studies of Solvent-Mediated, Acid-Catalyzed Woody Biomass Pretreatment for Enzymatic Conversion of Residual Cellulose

Enzymes selectively hydrolyze the carbohydrate fractions of lignocellulosic biomass into corresponding sugars, but these processes are limited by low yields and slow catalytic turnovers. Under certain conditions, the rates and yields of enzymatic sugar production can be increased by pretreating biomass using solvents, heat, and dilute acid catalysts. However, the mechanistic details underlying this behavior are not fully elucidated, and designing effective pretreatment strategies remains an empirical challenge. Herein, using a combination of solid-state and high-resolution magic-angle-spinning NMR, infrared spectroscopy, and X-ray diffractometry, we show that the extent to which cellulase enzymes are able to hydrolyze solvent-pretreated biomass can be understood in terms of the ability of the solvent to break the chemical linkages between cellulose and noncellulosic materials in the cell wall. This finding is of general significance to enzymatic biomass conversion research, and implications for designing improved biomass conversion strategies are discussed. Furthermore, these findings demonstrate the utility of solid-state NMR as a tool to elucidate the key chemical and physical changes that occur during the liquid-phase conversion of real biomass.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1980

Investigation of the flow field surrounding circular-arc boattail nozzles at subsonic speeds

The effects of jet exhaust on the subsonic flow field surrounding boattail nozzles with attached and separated boundary layers were investigated. Measurements of local Mach numbers and flow angles were made at free-stream Mach numbers of 0.60 and 0.80 at an angle of attack of 0 deg. Jet exhaust flow was simulated with a solid cylindrical sting and with high pressure air at jet-nozzle total pressure ratios of 2.9 and 5.0. Results show strong effects of the jet-wave structure on the external flow field. The predicted local Mach numbers and flow angles for attached-flow nozzles with solid jet simulators obtained by using subsonic inviscid/viscous-flow theory are in good agreement with experimental data. Prediction of nozzle surface pressure distributions which include jet-entrainment effects also agree with experimental data for attached-flow nozzles with high pressure air jets.

Abeyounis, W. K.↗
DOE OSTI2021

Stabilizing the Solid‐Electrolyte Interphase with Polyacrylamide for High‐Voltage Aqueous Lithium‐Ion Batteries

Abstract The introduction of “water‐in‐salt” electrolyte (WiSE) concept opens a new horizon to aqueous electrochemistry that is benefited from the formation of a solid‐electrolyte interphase (SEI). However, such SEI still faces multiple challenges, including dissolution, mechanical damaging, and incessant reforming, which result in poor cycling stability. Here, we report a polymeric additive, polyacrylamide (PAM) that effectively stabilizes the interphase in WiSE. With the addition of 5 molar % PAM to 21 mol kg −1 LiTFSI electrolyte, a LiMn 2 O 4 ∥L‐TiO 2 full cell exhibits enhanced cycling stability with 86 % capacity retention after 100 cycles at 1 C. The formation mechanism and evolution of PAM‐assisted SEI was investigated using operando small angle neutron scattering and density functional theory (DFT) calculations, which reveal that PAM minimizes the presence of free water molecules at the anode/electrolyte interface, accelerates the TFSI − anion decomposition, and densifies the SEI.

25 ENERGY STORAGE↗
NASA NTRS1973

Energy spectra and pitch angle distributions of storm-time and substorm injected protons.

Discussion of the energy spectra and pitch angle distributions of ring current protons observed with the solid-state proton detector of Explorer 45 during the main and fast recovery phases of a storm on Dec. 17, 1971. Appearances of characteristic changes in the pitch angle distributions of roughly 100-eV protons are interpreted as pitch angle dispersion of rapidly injected protons during their azimuthal drift at L values above 5.

Konradi, A.↗
DOE OSTI2022

Dynamic heterogeneity and nanophase separation in rubber-toughened amine-cured highly cross-linked polymer networks

Solid state nuclear magnetic resonance (NMR) spectroscopy and small-to wide-angle X-ray scattering (SWAXS) methods were used to characterize the heterogeneous dynamics and polymer domain structure in rubber modified thermoset materials containing the diglycidyl ether of bisphenol A (DGEBA) epoxy resin and a mixture of Jeffamine reactive rubber and 4,4-diaminodicyclohexylmethane (PACM) amine curing agent. The polymer chain dynamics and morphologies as a function of the PACM/Jeffamine ratio were determined. Using dipolar-filtered NMR experiments, the resulting networks are shown to be composed of mobile and rigid regions that are separated on nanometer length scales, along with a dynamically immobilized interface region. Proton NMR spin diffusion experiments measured the dimensions of the mobile phase to range between 9 and 66 nm and varied with the relative PACM concentration. Solid state 13 C magic angle spinning NMR experiments show that the highly mobile phase is composed entirely of the dynamically flexible polyether chains of the Jeffamine rubber, the immobilized interface region is a mixture of DGEBA, PACM, and the Jeffamine rubber, with the PACM cross-linked to DGEBA predominantly residing in the rigid phase. The SWAXS results showed compositional nanophase separation spanning the 11–77 nm range. These measurements of the nanoscale compositional and dynamic heterogeneity provide molecular level insight into the very broad and controllable glass transition temperature distributions observed for these highly cross-linked polymer networks.

36 MATERIALS SCIENCE↗
NASA NTRS2001

Reducing Bolt Preload Variation with Angle-of-Twist Bolt Loading

Critical high-pressure sealing joints on the Space Shuttle reusable solid rocket motor require precise control of bolt preload to ensure proper joint function. As the reusable solid rocket motor experiences rapid internal pressurization, correct bolt preloads maintain the sealing capability and structural integrity of the hardware. The angle-of-twist process provides the right combination of preload accuracy, reliability, process control, and assembly-friendly design. It improves significantly over previous methods. The sophisticated angle-of-twist process controls have yielded answers to all discrepancies encountered while the simplicity of the root process has assured joint preload reliability.

Thompson, Bryce↗
NASA NTRS1986

Investigation of solid plume simulation criteria to produce flight plume effects on multibody configuration in wind tunnel tests

An investigation to determine the sensitivity of the space shuttle base and forebody aerodynamics to the size and shape of various solid plume simulators was conducted. Families of cones of varying angle and base diameter, at various axial positions behind a Space Shuttle launch vehicle model, were wind tunnel tested. This parametric evaluation yielded base pressure and force coefficient data which indicated that solid plume simulators are an inexpensive, quick method of approximating the effect of engine exhaust plumes on the base and forebody aerodynamics of future, complex multibody launch vehicles.

Frost, A. L.↗