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At least 397 records · Page 22

Atomic Oxygen Textured Polymers

Atomic oxygen can be used to microscopically alter the surface morphology of polymeric materials in space or in ground laboratory facilities. For polymeric materials whose sole oxidation products are volatile species, directed atomic oxygen reactions produce surfaces of microscopic cones. However, isotropic atomic oxygen exposure results in polymer surfaces covered with lower aspect ratio sharp-edged craters. Isotropic atomic oxygen plasma exposure of polymers typically causes a significant decrease in water contact angle as well as altered coefficient of static friction. Such surface alterations may be of benefit for industrial and biomedical applications. The results of atomic oxygen plasma exposure of thirty-three (33) different polymers are presented, including typical morphology changes, effects on water contact angle, and coefficient of static friction.

Banks, Bruce A.↗

High Temperature Superconductivity in Praseodymium Doped (0%, 2%, 4%) in Melt-Textured Y(1-x)Pr(x)Ba2Cu3O(7-delta) Systems

A study of the magnetic and structural properties of the alloy Y(1-x)Pr(x)Ba2Cu3O(7-delta) of 0%, 2%, and 4% doping of praseodymium is presented. The resulting oxides of the alloy series are a high-temperature superconductor Y-Ba-Cu-O, which has an orthorhombic superconducting crystal-lattice. Magnetic relaxation studies have been performed on the Y-Pr-Ba-CuO bulk samples for field orientation parallel to the c-axis, using a vibrating sample magnetometer. Relaxation was measured at several temperatures to obtain the irreversible magnetization curves used for the Bean model. Magnetization current densities were derived from the relaxation data. Field and temperature dependence of the logarithmic flux-creep relaxation was measured in critical state. The data indicates that the effective activation energy U(eff) increases with increasing T between 77 K and 86 K. Also, the data shows that U(eff)(T) and superconducting transition temperature, Tc, decreased as the lattice parameters increased with increasing Pr ion concentration, x, for the corresponding Y(1-x)Pr(x)Ba(x)Cu3O(7-delta) oxides. One contribution to Tc decrease in this sampling is suspected to be due to the larger ionic radius of the Pr(3+) ion. The upper critical field (H(sub c2)) was measured in the presence of magnetic field parallel to the c axis. A linear temperature dependence with H(sub c2) was obtained.

James, Claudell↗

Surface Textural Properties of Icy Satellites: A Comparison between Europa and Rhea

Solar phase curves for Rhea are presented using new telescopic opposition data along with Voyager imaging observations. Two viable solutions were found to Hapke's model which was used to describe this phase curve. The porosity derived from the model's opposition parameters show that the optically active portion of Rhea's regolith has a porosity between 80 and 95 percent, which is slightly lower than the porosity seen on Europa and higher than the porosity measured for the Moon using similar methods. The macroscopic roughness is comparable to that measured by Vebiscer and Veverka for Rhea. The single particle scattering functions found in this study are predominantly forward scattering, which contradicts the results of Vebiscer and Veverka.

Domingue, D. L.↗

Multi-Scale Fractal Analysis of Image Texture and Pattern

Analyses of the fractal dimension of Normalized Difference Vegetation Index (NDVI) images of homogeneous land covers near Huntsville, Alabama revealed that the fractal dimension of an image of an agricultural land cover indicates greater complexity as pixel size increases, a forested land cover gradually grows smoother, and an urban image remains roughly self-similar over the range of pixel sizes analyzed (10 to 80 meters). A similar analysis of Landsat Thematic Mapper images of the East Humboldt Range in Nevada taken four months apart show a more complex relation between pixel size and fractal dimension. The major visible difference between the spring and late summer NDVI images of the absence of high elevation snow cover in the summer image. This change significantly alters the relation between fractal dimension and pixel size. The slope of the fractal dimensional-resolution relation provides indications of how image classification or feature identification will be affected by changes in sensor spatial resolution.

Emerson, Charles W.↗

Multi-Scale Fractal Analysis of Image Texture and Pattern

Analyses of the fractal dimension of Normalized Difference Vegetation Index (NDVI) images of homogeneous land covers near Huntsville, Alabama revealed that the fractal dimension of an image of an agricultural land cover indicates greater complexity as pixel size increases, a forested land cover gradually grows smoother, and an urban image remains roughly self-similar over the range of pixel sizes analyzed (10 to 80 meters). A similar analysis of Landsat Thematic Mapper images of the East Humboldt Range in Nevada taken four months apart show a more complex relation between pixel size and fractal dimension. The major visible difference between the spring and late summer NDVI images is the absence of high elevation snow cover in the summer image. This change significantly alters the relation between fractal dimension and pixel size. The slope of the fractal dimension-resolution relation provides indications of how image classification or feature identification will be affected by changes in sensor spatial resolution.

Emerson, Charles W.↗

Multi-Scale Fractal Analysis of Image Texture and Pattern

Fractals embody important ideas of self-similarity, in which the spatial behavior or appearance of a system is largely scale-independent. Self-similarity is a property of curves or surfaces where each part is indistinguishable from the whole. The fractal dimension D of remote sensing data yields quantitative insight on the spatial complexity and information content contained within these data. Analyses of Normalized Difference Vegetation Index (NDVI) images of homogeneous land covers near Huntsville, Alabama revealed that the fractal dimension of an image of an agricultural land cover indicates greater complexity as pixel size increases, a forested land cover gradually grows smoother, and an urban image remains roughly self-similar over the range of pixel sizes analyzed(l0 to 80 meters). The forested scene behaves as one would expect-larger pixel sizes decrease the complexity of the image as individual clumps of trees are averaged into larger blocks. The increased complexity of the agricultural image with increasing pixel size results from the loss of homogeneous groups of pixels in the large fields to mixed pixels composed of varying combinations of NDVI values that correspond to roads and vegetation. The same process occur's in the urban image to some extent, but the lack of large, homogeneous areas in the high resolution NDVI image means the initially high D value is maintained as pixel size increases. The slope of the fractal dimension-resolution relationship provides indications of how image classification or feature identification will be affected by changes in sensor resolution.

Emerson, Charles W.↗

Partial Melting of the Indarch (EH4) Meteorite : A Textural, Chemical and Phase Relations View of Melting and Melt Migration

To Test whether Aubrites can be formed by melting of enstatite Chondrites and to understand igneous processes at very low oxygen fugacities, we have conducted partial melting experiments on the Indarch (EH4) chondrite at 1000-1500 C. Silicate melting begins at 1000 C. Substantial melt migration occurs at 1300-1400 C and metal migrates out of the silicate change at 1450 C and approx. 50% silicate partial melting. As a group, our experiments contain three immiscible metallic melts 9Si-, and C-rich), two immiscible sulfide melts(Fe-and FeMgMnCa-rich) and Silicate melt. Our partial melting experiments on the Indarch (EH4) enstatite Chondrite suggest that igneous processes at low fO2 exhibit serveral unique features. The complete melting of sulfides at 1000 C suggest that aubritic sulfides are not relicts. Aubritic oldhamite may have crystallized from Ca and S complexed in the silicate melt. Significant metal-sulfide melt migration might occur at relatively low degrees of silicate partial melting. Substantial elemental exchange occurred between different melts (e.g., between sulfide and silicate, Si between silicate and metal), a feature not observed during experiments at higher fO2. This exchange may help explain the formation of aubrites from known enstatite chondrites.

McCoy, Timothy J.↗

Using Scaled Visual Texture for Autonomous Rock Clustering

To maximize the return on future planetary missions, it will be critical that rovers have the capability to analyze information onboard and select and return data that is most likely to yield valuable scientific discoveries. Additional information is contained in the original extended abstract.

Anderson, R. C.↗

Modeling Heat Flow In a Calorimeter Equipped With a Textured Solar Collector

Heat engines are being considered for generating electric power for minisatellite applications, particularly for those missions in high radiation threat orbits. To achieve this objective, solar energy must be collected and transported to the hot side of the heat engine. A solar collector is needed having the combined properties of high solar absorptance, low infrared emittance, and high thermal conductivity. To test candidate solar collector concepts, a simple calorimeter was designed, manufactured, and installed in a bench top vacuum chamber to measure heat flow. In addition, a finite element analysis model of the collector/calorimeter combination was made to model this heat flow. The model was tuned based on observations from the as-manufactured collector/calorimeter combination. In addition, the model was exercised to examine other collector concepts, properties, and scale up issues.

Jaworske, Donald A.↗

The Effect of Film Composition on the Texture and Grain Size of CuInS2 Prepared by Spray Pyrolysis

CuInS2 was deposited by spray pyrolysis using single-source precursors synthesized in-house. Films with either (112) or (204/220) preferred orientation always showed Cu-rich and In-rich composition respectively. The In-rich (204/220)-oriented films always contained a secondary phase evaluated as an In-rich compound, and the hindrance of (112)-oriented grain growth was confirmed by glancing angle X-ray diffraction. In conclusion, only the Cu-rich (112)-oriented films with dense columnar grains can be prepared without the secondary In-rich compound. The effect of extra Cu on the grain size and the solar cell results will be also presented.

Jin, Michael H.-C.↗

The Vaguries of Pyroxene Nucleation and the Resulting Chondrule Textures

Pyroxene is a major phase in chondrules, but often follows olivine in the crystallization sequence and depending on the melting temperature and time may not nucleate readily upon cooling. Dynamic crystallization experiments based on total or near total melting were used to study PO (porphyritic olivine) and PP (Porphyritic pyroxene) compositions as defined by. The experiments showed that pyroxene nucleated only at subliquidus temperatures in the PP melts and rarely in the PO melts. Porphyritic chondrules with phenocrysts of both olivine and pyroxene (POP chondrules) were not easily produced in the experiments. POP chondrules are common and it is important for deciphering their formation that we understand pyroxene nucleation properties of chondrule melts.

Lofgren, G. E.↗

High Resolution Laser Scanning Techniques for Rock Abrasion and Texture Analyses on Mars and Earth

Aeolian abrasion is operative in many arid locations on Earth and is probably the dominant rock erosion process in the current Martian environment. Therefore, understanding the controlling parameters and rates of aeolian abrasion provides 1) insight into the stability of rocks on planetary surfaces and the environments under which the rocks abrade, and 2) a link between ventifact (a rock abraded by windblown particles) morphology and: a) abrasion conditions, b) possible ancient environments under which the rocks were abraded, and c) rock properties. promising and we plan further investigations in the wind tunnel and field. Our intent here is to discuss the basic technique, initial results, and upcoming plans.

Bridges, N. T.↗

Characterization of the Micro Textures in a Friction Stir Weld

In friction stir welding (FSW), a rotating threaded pin tool is inserted into a weld seam and literally stirs the edges of the seam together. The Dynamically-Recrystallized-Zone (DXZ) of a polished and etched FSW cross-section exhibits contrasting bands (the "onion-ring" structure), the origins of which are unclear. An orientation image mapping (OIM) study suggests that the corresponding bands may correspond respectively to a "straight-through" current of metal bypassing the pin tool in a single rotation or less and a "maelstrom" current rotating a number of times around the pin tool.

Schneider, Judy↗

Protective coating and hyperthermal atomic oxygen texturing of optical fibers used for blood glucose monitoring

Disclosed is a method of producing cones and pillars on polymethylmethacralate (PMMA) optical fibers for glucose monitoring. The method, in one embodiment, consists of using electron beam evaporation to deposit a non-contiguous thin film of aluminum on the distal ends of the PMMA fibers. The partial coverage of aluminum on the fibers is randomly, but rather uniformly distributed across the end of the optical fibers. After the aluminum deposition, the ends of the fibers are then exposed to hyperthermal atomic oxygen, which oxidizes the areas that are not protected by aluminum. The resulting PMMA fibers have a greatly increased surface area and the cones or pillars are sufficiently close together that the cellular components in blood are excluded from passing into the valleys between the cones and pillars. The optical fibers are then coated with appropriated surface chemistry so that they can optically sense the glucose level in the blood sample than that with conventional glucose monitoring.

Banks, Bruce A.↗

Instrument and method for X-ray diffraction, fluorescence, and crystal texture analysis without sample preparation

An X-ray diffraction and X-ray fluorescence instrument for analyzing samples having no sample preparation includes a X-ray source configured to output a collimated X-ray beam comprising a continuum spectrum of X-rays to a predetermined coordinate and a photon-counting X-ray imaging spectrometer disposed to receive X-rays output from an unprepared sample disposed at the predetermined coordinate upon exposure of the unprepared sample to the collimated X-ray beam. The X-ray source and the photon-counting X-ray imaging spectrometer are arranged in a reflection geometry relative to the predetermined coordinate.

Gendreau, Keith↗

Micro-Textured Black Silicon Wick for Silicon Heat Pipe Array

Planar, semiconductor heat arrays have been previously proposed and developed; however, this design makes use of a novel, microscale black silicon wick structure that provides increased capillary pumping pressure of the internal working fluid, resulting in increased effective thermal conductivity of the device, and also enables operation of the device in any orientation with respect to the gravity vector. In a heat pipe, the efficiency of thermal transfer from the case to the working fluid is directly proportional to the surface area of the wick in contact with the fluid. Also, the primary failure mechanism for heat pipes operating within the temperature range of interest is inadequate capillary pressure for the return of fluid from the condenser to the wick. This is also what makes the operation of heat pipes orientation-sensitive. Thus, the two primary requirements for a good wick design are a large surface area and high capillary pressure. Surface area can be maximized through nanomachined surface roughening. Capillary pressure is largely driven by the working fluid and wick structure. The proposed nanostructure wick has characteristic dimensions on the order of tens of microns, which promotes menisci of very small radii. This results in the possibility of enormous pumping potential due to the inverse proportionality with radius. Wetting, which also enhances capillary pumping, can be maximized through growth of an oxide layer or material deposition (e.g. TiO2) to create a superhydrophilic surface.

Yee, Karl Y.↗

Investigation of Backside Textures for Genesis Solar Wind Silicon Collectors

Genesis solar wind collectors were comprised of a suite of 15 types of ultrapure materials. The single crystal, pure silicon collectors were fabricated by two methods: float zone (FZ) and Czochralski (CZ). Because of slight differences in bulk purity and surface cleanliness among the fabrication processes and the specific vendor, it is desirable to know which variety of silicon and identity of vendor, so that appropriate reference materials can be used. The Czochralski method results in a bulk composition with slightly higher oxygen, for example. The CZ silicon array wafers that were Genesis-flown were purchased from MEMC Electronics. Most of the Genesis-flown FZ silicon was purchased from Unisil and cleaned by MEMC, although a few FZ wafers were acquired from International Wafer Service (IWS).

Gonzalez, C. P.↗

Variations in Surface Texture of the North Polar Residual Cap of Mars

The northern polar residual cap (NPRC) of Mars is a water ice deposit with a rough surface made up of pits, knobs, and linear depressions on scales of tens of meters. This roughness manifests as a series of bright mounds and dark hollows in visible images; these bright and dark patches have a characteristic wavelength and orientation. Spectral data indicate that the surface of the NPRC is composed of large-grained (and therefore old) water ice. Due to the presence of this old ice, it is thought that the NPRC is in a current state of net loss of material a result potentially at odds with impact crater statistics, which suggest ongoing deposition over the past 10-20 Kyr.

Mars↗