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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Far-Reaching Impacts of African Dust- A Calipso Perspective

African dust can transport across the tropical Atlantic and reach the Amazon basin, exerting far-reaching impacts on climate in downwind regions. The transported dust influences the surface-atmosphere interactions and cloud and precipitation processes through perturbing the surface radiative budget and atmospheric radiative heating and acting as cloud condensation nuclei and ice nuclei. Dust also influences biogeochemical cycle and climate through providing nutrients vital to the productivity of ocean biomass and Amazon forests. Assessing these climate impacts relies on an accurate quantification of dust transport and deposition. Currently model simulations show extremely large diversity, which calls for a need of observational constraints. Kaufman et al. (2005) estimated from MODIS aerosol measurements that about 144 Tg of dust is deposited into the tropical Atlantic and 50 Tg of dust into the Amazon in 2001. This estimated dust import to Amazon is a factor of 3-4 higher than other observations and models. However, several studies have argued that the oversimplified characterization of dust vertical profile in the study would have introduced large uncertainty and very likely a high bias. In this study we quantify the trans-Atlantic dust transport and deposition by using 7 years (2007-2013) observations from CALIPSO lidar. CALIPSO acquires high-resolution aerosol extinction and depolarization profiles in both cloud-free and above-cloud conditions. The unique CALIPSO capability of profiling aerosols above clouds offers an unprecedented opportunity of examining uncertainties associated with the use of MODIS clear-sky data. Dust is separated from other types of aerosols using the depolarization measurements. We estimated that on the basis of 7-year average, 118142 Tg of dust is deposited into the tropical Atlantic and 3860 Tg of dust into the Amazon basin. Substantial interannual variations are observed during the period, with the maximum to minimum ratio of about 1.6 and 2.5 for the deposition to the tropical Atlantic and Amazon, respectively. The MODIS-based estimates appear to fall within the range of CALIPSO-based estimates; and the difference between MODIS and CALIPSO estimates can be largely attributed to the interannual variability, which is corroborated by long-term surface dust concentration observations in the tropical Atlantic. Considering that CALIPSO generally tends to underestimate the aerosol loading, our estimate is likely to represent a low bound for the dust transport and deposition estimate. The finding suggests that models have substantial biases and considerable effort is needed to improve model simulations of dust cycle.

dust↗
NASA NTRS1973

An economic assessment of STOL aircraft potential including terminal area environmental considerations. Volume 2: Appendices

An economic assessment of short takeoff aircraft for short haul air transportation applications is presented. The economic viability and environmental compatibility of short takeoff aircraft service in high density areas were evaluated. The subjects discussed are: (1) aircraft configurations and performance, (2) airfield and terminal requirements, and (3) direct and indirect operating costs.

Solomon, H. L.↗
NASA NTRS2004

Space Geodesy Monitoring Mass Transport in Global Geophysical Fluids

Mass transports occurring in the atmosphere-hydrosphere-cryosphere-solid Earth-core system (the 'global geophysical fluids') are important geophysical phenomena. They occur on all temporal and spatial scales. Examples include air mass and ocean circulations, oceanic and solid tides, hydrological water and idsnow redistribution, mantle processes such as post-glacial rebound, earthquakes and tectonic motions, and core geodynamo activities. The temporal history and spatial pattern of such mass transport are often not amenable to direct observations. Space geodesy techniques, however, have proven to be an effective tool in monitorihg certain direct consequences of the mass transport, including Earth's rotation variations, gravitational field variations, and the geocenter motion. Considerable advances have been made in recent years in observing and understanding of these geodynamic effects. This paper will use several prominent examples to illustrate the triumphs in research over the past years under a 'Moore's law' in space geodesy. New space missions and projects promise to further advance our knowledge about the global mass transports. The latter contributes to our understanding of the geophysical processes that produce and regulate the mass transports, as well as of the solid Earth's response to such changes in terms of Earth's mechanical properties.

Chao, Benjamin F.↗
DOE OSTI2023

Mitigating Iodine Diffusion by a MoO 3 –Organic Composite Hole Transport Layer for Stable Perovskite Solar Cells

Halide perovskite solar cells (PSCs) exhibit commercialization potential, but long-term stability still must be addressed. Among various products of perovskite decomposition, iodine species are of considerable concern due to their high vapor pressure and corrosive nature. To address this, a small-molecule hole transport layer (HTL), 4,4',4"-tris[(3-methylphenyl)phenylamino]triphenylamine (m-MTDATA), is used; mixing it with molybdenum trioxide (MoO3) p-dopes the layer and slows iodine permeation. Furthermore, we demonstrate that m-MTDATA:MoO3 HTLs employed in PSCs improve stability under both thermal and voltage bias stress compared to devices with a conventional doped 2,2',7,7'-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene (spiro-OMeTAD) HTL.

14 SOLAR ENERGY↗
NASA NTRS1999

Use of On-Line Tracers as a Diagnostic Tool in General Circulation Model Development: Transport Between the Troposphere and Stratosphere - 2

A key component of climate/chemistry modeling is how to handle the influx into (and egress from) the troposphere. This is especially important when considering tropospheric ozone, and its precursors (e.g., NO(x) from aircraft). A study has been conducted with various GISS models to determine the minimum requirements necessary for producing realistic troposphere-stratosphere exchange. Four on-line tracers are employed: CFC-11 and SF6 for mixing from the troposphere into the stratosphere, Rn222 for vertical mixing within the troposphere, and 14C for mixing from the stratosphere into the troposphere. Four standard models are tested, with varying vertical resolution, gravity wave drag and location of the model top, and additional subsidiary models are employed to examine specific features. The results show that proper vertical transport between the troposphere and stratosphere in the GISS models requires lifting the top of the model considerably out of the stratosphere, and including gravity wave drag in the lower stratosphere. Increased vertical resolution without these aspects does not improve troposphere-stratosphere exchange. The transport appears to be driven largely by the residual circulation within the stratosphere; associated E-P flux convergences require both realistic upward propagating energy from the troposphere, and realistic pass-through possibilities. A 23 layer version with a top at the mesopause and incorporating gravity wave drag appears to have reasonable stratospheric-tropospheric exchange, in terms of both the resulting tracer distributions and atmospheric mass fluxes.

Rind, David H.↗
DOE OSTI2020

A Comparison of RESRAD and GoldSim Models for Assessing Radiological Dose for a RCRA Landfill - 20418

US Ecology Idaho (USEI) operates a Resource Conservation and Recovery Act (RCRA) Subtitle C, Hazardous Waste Treatment, Storage, and Disposal (TSD) Facility on a 640-acre property in Owyhee County, Idaho. USEI accepts a wide variety of RCRA-exempt low activity radioactive wastes, including naturally occurring radioactive material (NORM) and technologically enhanced NORM (TENORM) (USEI 2009). The performance of the landfill with regard to radiological operating permit requirements was previously assessed using a model constructed with the residual radioactivity (RESRAD) computer program, developed by Argonne National Laboratory for the U.S. Department of Energy (DOE). RESRAD supports the evaluation of several environmental transport pathways related to a radionuclide-contaminated soil source term, but it was not conceived as a model for the evaluation of landfill radiological performance. A more comprehensive and realistic model is desired in order to better support submissions to both the State of Idaho's Department of Environmental Quality as well as the U.S. Nuclear Regulatory Commission. A Performance Assessment (PA) computer model was developed using GoldSim software for the USEI RCRA Subtitle C landfill. The RESRAD computer model was specifically developed for calculating soil cleanup criteria and radiological dose and cancer risk from residual radioactive material in soil. To evaluate site-specific conditions, users may select from among a number of available environmental transport and exposure pathways and modify 'default' parameter values. In GoldSim, a user must construct the model 'from scratch.' However, this modeling is facilitated by a number of specialized elements available in GoldSim to support a radiological mass transport model. These include elements for defining radiological decay and ingrowth, container failure and radiological release, advective and diffusive transport, and other processes. Advantages afforded by the use of RESRAD for modeling radiological dose for a RCRA Subtitle C landfill include ease of use and reasonable flexibility in specifying site-specific conditions. GoldSim allows for considerably more flexibility and site-specificity than RESRAD, including evaluation of potentially relevant environmental transport processes not supported in RESRAD. The probabilistic modeling capabilities of GoldSim also far exceed those of RESRAD. The pros and cons of RESRAD and GoldSim for this modeling problem are explored with a focus on identifying approaches and critical factors in identifying the appropriate platform. The capabilities of RESRAD and GoldSim for mathematically modeling the disposal system will be contrasted and compared. For example, the existing RESRAD radiological safety assessment evaluated potentially complete exposure pathways related to infiltration to groundwater and upwards diffusion of radon. Additional transport pathways identified in the USEI Idaho facility Conceptual Site Model include deposition of radon decay products in cover material, root uptake of radionuclides in disposed wastes by native plants, and mixing of cover material by burrowing animals. Results of the two models and how the different transport and dose pathways affect results will be discussed. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1982

Space Operations Center system analysis study extension. Volume 1: Executive summary

The analysis fo Space Operations Center (SOC) systems is summarized. Design considerations, configurations of the manned orbital space station, planned operational and research missions, and subsystem tradeoffs are considered. Integration into the space transportation system is discussed. A modular design concept permitting growth of the SOC as its functions are expanded is described. Additional considerations are special requirements for habitat modules, design modifications needed to operate in geosynchronous orbits, and use of the external tank for cryogenic propellant storage or as a pressurized hangar. A cost summary is presented.

Source record↗
NASA NTRS1988

Transport delay compensation for computer-generated imagery systems

In the problem of pure transport delay in a low-pass system, a trade-off exists with respect to performance within and beyond a frequency bandwidth. When activity beyond the band is attenuated because of other considerations, this trade-off may be used to improve the performance within the band. Specifically, transport delay in computer-generated imagery systems is reduced to a manageable problem by recognizing frequency limits in vehicle activity and manual-control capacity. Based on these limits, a compensation algorithm has been developed for use in aircraft simulation at NASA Ames Research Center. For direct measurement of transport delays, a beam-splitter experiment is presented that accounts for the complete flight simulation environment. Values determined by this experiment are appropriate for use in the compensation algorithm. The algorithm extends the bandwidth of high-frequency flight simulation to well beyond that of normal pilot inputs. Within this bandwidth, the visual scene presentation manifests negligible gain distortion and phase lag. After a year of utilization, two minor exceptions to universal simulation applicability have been identified and subsequently resolved.

Mcfarland, Richard E.↗
NASA NTRS1988

Transport delay compensation for computer-generated imagery systems

In the problem of pure transport delay in a low-pass system, a trade-off exists with respect to performance within and beyond a frequency bandwidth. When activity beyond the band is attenuated because of other considerations, this trade-off may be used to improve the performance within the band. Specifically, transport delay in computer-generated imagery systems is reduced to a manageable problem by recognizing frequency limits in vehicle activity and manual-control capacity. Based on these limits, a compensation algorithm has been developed for use in aircraft simulation at NASA Ames Research Center. For direct measurement of transport delays, a beam-splitter experiment is presented that accounts for the complete flight simulation environment. Values determined by this experiment are appropriate for use in the compensation algorithm. The algorithm extends the bandwidth of high-frequency flight simulation to well beyond that of normal pilot inputs. Within this bandwidth, the visual scene presentation manifests negligible gain distortion and phase lag. After a year of utilization, two minor exceptions to universal simulation applicability have been identified and subsequently resolved.

Mcfarland, Richard E.↗
NASA NTRS1976

Study of the application of advanced technologies to laminar flow control systems for subsonic transports. Volume 1: Summary

A study was conducted to evaluate the technical and economic feasibility of applying laminar flow control to the wings and empennage of long-range subsonic transport aircraft compatible with initial operation in 1985. For a design mission range of 10,186 km (5500 n mi), advanced technology laminar-flow-control (LFC) and turbulent-flow (TF) aircraft were developed for both 200 and 400-passenger payloads, and compared on the basis of production costs, direct operating costs, and fuel efficiency. Parametric analyses were conducted to establish the optimum geometry for LFC and TF aircraft, advanced LFC system concepts and arrangements were evaluated, and configuration variations maximizing the effectiveness of LFC were developed. For the final LFC aircraft, analyses were conducted to define maintenance costs and procedures, manufacturing costs and procedures, and operational considerations peculiar to LFC aircraft. Compared to the corresponding advanced technology TF transports, the 200- and 400-passenger LFC aircraft realized reductions in fuel consumption up to 28.2%, reductions in direct operating costs up to 8.4%, and improvements in fuel efficiency, in ssm/lb of fuel, up to 39.4%. Compared to current commercial transports at the design range, the LFC study aircraft demonstrate improvements in fuel efficiency up to 131%. Research and technology requirements requisite to the development of LFC transport aircraft were identified.

Sturgeon, R. F.↗
DOE OSTI2022

Correlating the Morphological Changes to Electrochemical Performance During Carbon Corrosion in Polymer Electrolyte Fuel Cells

A mechanistic understanding of carbon corrosion in polymer electrolyte fuel cells (PEFCs) is required to design durable catalyst layers. Uncontrolled startup and shutdown of PEFCs cause electrochemical oxidation of carbon, which leads to several degradation phenomena, such as loss in electrochemical surface area (ECSA), pore structure collapse or increase in mass transport resistance. In this study, the chronology of morphological changes in the cathode catalyst layer due to carbon corrosion was identified and correlated with electrochemical performance degradation. PEFCs were subjected to the Department of Energy carbon corrosion accelerated stress test (AST) protocol. The study revealed two phases: in the initial phase (~500 AST cycles), amorphous carbon in contact with Pt nanoparticles oxidized fast. Rapid carbon loss and catalyst layer thinning occurred, but pore structure did not change significantly. Pt nanoparticles detached from the support and ECSA decreased drastically. In the second phase (~1500 AST cycles), carbon corrosion slowed down, but severe pore structure collapse was observed. Porosity and pore connectivity within the cathode catalyst layer decreased considerably. Electrochemical diagnostics corroborated this finding by showing significantly higher O2 mass transport resistance. Lastly, no significant change was observed in the concentration of oxides on the carbon surface after AST. But overall water management in the cathode catalyst layer deteriorated as the pore structure collapsed. This study provides an in-depth understanding of morphological changes during PEFC carbon corrosion AST protocol and motivates novel material design strategies to enable durable PEFCs.

catalyst layers↗
DOE OSTI2025

Porous transport electrodes for oxygen evolution reaction in proton exchange membrane water electrolysis -cells: Materials, designs, and diagnoses

H 2 production using proton exchange membrane (PEM) water electrolysis (PEMWE) cells has received considerable attention because of the high efficiencies of these cells and no harmful emissions from the related process. In PEMWE cells, porous transport electrodes (PTEs) composed of a catalyst layer (CL) comprising O 2 evolution reaction (OER) catalysts, porous transport layer (PTL), and PEM play key roles in the stack performance and lifetime. Herein, Ir-based and non-precious-metal OER catalysts that are highly active and stable at low pH values and high anodic potentials are reviewed to understand their OER mechanisms. Various strategies are proposed for engineering CLs and PTLs to improve the interfacial properties and mass transfers of reactants and products to and from the active sites. Additionally, diagnoses of PTEs is significantly crucial for interpreting electrochemical processes and addressing their current challenges. Therefore, half-cell analyses, including diffusion electrode (DE), floating electrode (FE), and modified rotating disk electrode (MRDE) techniques, are explored, and membrane electrode assembly (MEA)-based analyses, such as the polarization technique, electrochemical impedance spectroscopy, and magnetic field analysis, are established. In conclusion, this study aims to provide an overview of recent technologies used for the engineering and diagnostic tools of PEMWE cells and insights into the advanced components and systems to be developed in this field.

Diagnosis of PEMWE Cells↗
NASA NTRS1998

Laminae in the Tropical Middle Stratosphere: Origin and Age Estimation

Isentropic transport of stratospheric air from mid-latitudes into the tropics has been a subject of considerable interest recently. This exchange process is important for the understanding of the distribution of trace gases and ozone, and for the prediction of the exhaust dispersion of a proposed fleet of high speed civil transport aircraft (HSCT), which would operate in the 15 to 20 km altitude range.

middle↗
DOE OSTI2022

Pathways for the Formation of C 2+ Products under Alkaline Conditions during the Electrochemical Reduction of CO 2

Establishing how Cu facilitates the electrochemical CO 2 reduction reaction (CO2RR) to C 2+ products remains a critical challenge. Under typical reaction conditions, the pH near the electrode is considerably more alkaline than that in the bulk due to mass transport limitations. Challenges with probing alkaline pathways using computational methods have limited understanding of the CO2RR under experimentally relevant conditions. In this work, using the Volmer reaction on Cu (100), we demonstrate that predicted activation barriers can substantially differ between acidic and alkaline pathways. We compute reaction energetics for alkaline *CO protonation and find that, while the formation of *CHO is preferred thermodynamically, the formation of *COH is favored kinetically at high overpotential. However, we find formation of *CHO via reaction of *H and *CO feasible at room temperature. Further, we report potential-dependent energetics for forming the first C-C bond in CO2RR and find that CO dimerization likely dominates. Finally, we investigate how long-range van der Waals interactions impact our results by comparing to the meta-GGA B97M-rV.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Hopping frustration-induced flat band and strange metallicity in a kagome metal

The introduction of localized electronic states into a metal can alter its physical properties, for example enabling exotic metal physics including heavy fermion and strange metal behaviour. A common source of localized states in such systems are partially filled 4f and 5f shells because of the inherently compact nature of those orbitals. The interaction of electrons in these orbitals with the conduction sea is well described by the Kondo framework. However, there have also been observations of Kondo-like behaviour in 3d transition metal oxides and in 4d- and 5d-containing van der Waals heterostructures. This calls for a broader consideration of the physical requirements for Kondo systems. Here we show transport and thermodynamic hallmarks of heavy fermion and strange metal behaviour that arise in the kagome metal Ni3In, wherein the source of localized states is destructive interference-induced band flattening of partially filled Ni 3d states. With magnetic field and pressure tuning, here we also find evidence that the system is proximate to quantum criticality, extending the analogy to f-electron Kondo lattices. These observations highlight the role of hopping frustration in metallic systems as a potential source for strong correlations. Additionally, this suggests a lattice-driven approach to realizing correlated metals with non-trivial band topology.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Giant magnetoresistance in the crystalline YCd 6 intermetallic compound

Giant magnetoresistance (GMR) in bulk nonmagnetic compounds has received considerable attention since this phenomenon challenged the classical understanding of electron transport under a magnetic field. Here, we report magnetotransport properties of the diamagnetic intermetallic compound YCd 6 for applied magnetic fields up to 35 T and temperatures down to 0.4 K that reveal GMR. We argue that the large MR value can be explained in terms of field-induced pseudogaps on a Fermi surface. These results are relevant to the understanding of the Fermi-surface topology of quasicrystal approximants.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Intelligent, grid-friendly, modular extreme fast charging system with solid-state DC protection

The development of electric vehicle (EV) charging infrastructure is crucial for the widespread adoption of electric transportation. However, implementing such infrastructure is a complex task that requires consideration of factors such as space limitations, adherence to industry standards, grid capacity, and other technical and policy issues. This project seeks to create a framework for the efficient design of compact medium voltage (MV) extreme fast charging (XFC) stations for EVs. The station design involves the use of a solid-state transformer (SST) that connects to the MV distribution network, delivering power to a shared DC bus. This innovative approach eliminates the need for a step-down transformer to provide low-voltage service by connecting directly to the MV distribution network. Eliminating the low-frequency transformer not only reduces the system footprint and losses but also eliminates inrush currents during grid black-start. Additionally, placing power electronics directly on the distribution system allows for high-bandwidth filtering and power factor correction. The inclusion of a shared DC bus enables multiple charging dispensers and DC storage/generation units to connect, forming a DC microgrid. This setup facilitates power sharing with minimal conversion stages. The project showcases a DC distribution network protected by intelligent solid-state (SS) DC circuit breakers (DCCB) capable of isolating the smallest section of the faulted circuit much faster than existing mechanical solutions.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2023

Western Smart Regional EV Adoption and Infrastructure at Scale- WestSmartEV@Scale (Budget Period 2 – Milestone Report – TNC EV Study)

WestSmartEV@Scale is a comprehensive research project addressing key opportunities to decarbonize transportation throughout the Rocky Mountain West. Building upon the framework established in the original WestSmart project, unique subprojects are scoped targeting transportation emissions across light-, medium-, and heavy-duty vehicles with consideration of equity and access. This report summarizes the progress to date on Subproject 6, TNC EV Study (Urban Mobility). It is comprised of three sections: • Outreach and participant recruitment; • Survey data collection and analysis; and • BEV driver driving and charging behavior data collection and analysis.

33 ADVANCED PROPULSION SYSTEMS↗