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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

Assessment of Technoeconomic Opportunities in Automation for Nuclear Microreactors

Achieving full decarbonization of all economic sectors remains a challenge, especially in niche markets. For example, remote communities and industrial or mining activities detached from the main electric grid heavily rely on fossil fuels, similar to urban and industrial microgrids with combined heat and power needs. A combination of renewables and energy storage is often not suitable due to cost, reliability, intermittency, and large storage requirements. Small nuclear reactors with a flexible purpose could serve these applications. Microreactors (MR) are a class of reactors that are compact, factory manufactured, transportable, and self-regulating. Typically, they generate much less power than their large reactor counterparts. The main advantages of microreactors include the versatile nature of the energy produced, the reliability of supply, and freedom from having to transport and store large quantities of fuels on-site, coupled with the absence of dependence on an electrical grid. A strong business case is needed to move from the microreactor prototype to the commercialization phase. In fact, fossil fuels are still relatively inexpensive, and in the near term, carbon credits will be available to virtually compensate for emissions. For microreactors, one of the main costs in operation and maintenance (O&M) is their staffing levels. In this study, we investigate how to optimize the number (and thus the cost) of workers, moving from a traditional, fully manned, on-site personnel approach to an unmanned, remote personnel approach. We examine four different staffing models that can be implemented as the technology matures and evolves. We estimate the staffing needs of each model and build a business case to justify the substitution of on-site personnel with adequate technologies. To do so, we propose a cost model to quantify potential cost reductions from automating O&M activities. The model accounts for both the reduction in cost derived from the reduced number of full-time-equivalent (FTE) employees and the increase in cost derived from the need to buy new control hardware as needed. Applying the cost model that we created to different scenarios, an on-site O&M cost reduction exceeding 80% can be expected. Additionally, we found that it is more impactful to focus on automating routine O&M tasks rather than attempting to automate transient management (shutdowns, restarts, monitoring condition deviations). In fact, transients typically account for less than 1% of the total FTE time spent on the reactors.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Decision making for implementing non-traditional water sources: a review of challenges and potential solutions

Abstract The effects of climate change, population growth, and future hydrologic uncertainties necessitate increased water conservation, new water resources, and a shift towards sustainable urban water supply portfolios. Diversifying water portfolios with non-traditional water sources can play a key role. Rooftop harvested rainwater (RHRW), atmospheric and condensate harvesting, stormwater, recycled wastewater and greywater, and desalinated seawater and brackish water are all currently utilized and rapidly emerging non-traditional water sources. This review explores the status and trends around these non-traditional water sources, and reviews approaches and models for prioritizing, predicting, and quantifying metrics of concern. The analysis presented here suggests that understanding the challenges of location specific scenarios, socioeconomic knowledge gaps, water supply technologies, and/or water management structure is the crucial first step in establishing a model or framework approach to provide a strategy for improvement going forward. The findings of this study also suggest that clear policy guidance and onsite maintenance is necessary for variable water quality concerns of non-traditional sources like harvested rainwater and greywater. In addition, use of stormwater or reuse of wastewater raises public health concerns due to unknown risks and pathogen levels, thus rapid monitoring technologies and transparent reporting systems can facilitate their adoption. Finally, cost structure of desalination varies significantly around the world, largely due to regulatory requirements and local policies. Further reduction of its capital cost and energy consumption is identified as a hurdle for implementation. Overall, models and process analyses highlight the strength of comparative assessments across scenarios and water supply options.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Landsat at 45: How it Changed the Way We See the Earth

On October 24, 1946, more than 10 years before the launch of the first artificial satellite Sputnik, scientists at the White Sands Missile Range in New Mexico placed a camera on top of a captured German V-2 ballistic missile. As the rocket flew to an altitude of about 65 miles - just above the generally recognized border of outer space - the 35-millimeter motion picture camera snapped a frame every one and a half seconds. Minutes later, the missile came crashing back down and slammed into the ground at more than 340 mph, but the film survived and gave us our first glimpse of Earth from space. Earth Resources Technology Satellite aka Landsat It was images like those first grainy black and white pictures and later those taken by America's first astronauts in the 1960's that inspired the development of the Earth Resources Technology Satellite (ERTS). From the unique vantage point of space, we could now observe Earth using a variety of different instruments to monitor changes over time. The ERTS-1 satellite, wisely renamed Landsat-1, was launched aboard a Delta rocket on July 23, 1972, into a Sun-synchronous polar orbit at an altitude of about 560 miles. In this unique orbit, Landsat could observe the same point on the Earth every 18 days, always with the same solar illumination, allowing for precise monitoring of changes on the ground over time. Landsat-1, derived from the highly successful Nimbus weather satellites, carried two instruments that allowed it to take images not only in visible light but also in infrared, well-suited to track changes in vegetation over time. Designed to last only one year, Landsat-1 actually operated for nearly three years, by which time it had been joined in space by Landsat-2, a near identical copy of the original. Since then, ever more sophisticated instruments were flown aboard Landsat-3 through -8, with Landsat-9 planned for launch in 2020, acquiring millions of images of Earth over more than four decades. At first, images from Landsat were processed by NASA and hardcopies sold to users for a fee, a somewhat tedious process. Since 2008, images have been made available to all interested users by the US Geological Survey (USGS) at no cost via the Internet in near real time. So, how can Landsat help? In short, Landsat looks. And looks. And proves Yogi right. Space-based images from Landsat and other similar satellites offer a unique and critical capability to observe land use over time by providing repetitive observations of the Earth otherwise unavailable. The data provided by the images can be used by scientists and politicians to inform wise decisions in areas such as agriculture, climate, ecosystems and biodiversity, energy, forest management, human health, fire, natural disasters, urban growth and water management. This overview article doesn't allow for examples from each of these disciplines, but details can be found at the following website: https://landsat.gsfc.nasa.gov/how_landsat_helps/. One third of the US economy is influenced by climate, weather and natural hazards, providing strong economic incentives to sustain a healthy space-based Earth observation program. One example, however, may be illustrative of how Landsat and other space-based observations can be helpful in monitoring and documenting some effects of global climate change. It had been noted since the 1970's that permafrost in subarctic areas like Siberia was melting at an accelerating rate. It also became apparent that this led to the formation of hundreds of melt lakes and the liberation of large quantities of methane, a gas that in the short-term has more potent greenhouse effects than carbon dioxide. The methane turned the water in these lakes blue, making them easy to track over time by satellite. Additionally, the newly released methane has been carbon dated to tens of thousands of years ago, meaning that it had remained frozen since the last Ice Age and therefore hadn't been accounted for in models of the Earth's overall carbon balance. Release of sufficient methane by an increasingly warming climate could actually cause a positive feedback loop in global warming, melting more permafrost and releasing yet more methane. Further monitoring by Landsat and other platforms will reveal whether this process is reversible or whether we've passed the tipping point. In addition to the highly successful Landsat series of satellites, NASA and other agencies such as the National Oceanic and Atmospheric Administration (NOAA) operate a fleet of other Earth observing platforms, many with more specific research goals such as monitoring sea ice levels or atmospheric carbon content. Several instruments aboard the International Space Station also contribute to this overall effort to better understand short- and long-term changes to the Earth. Many of these missions are guided by the 2009 Decadal Survey published by the National Research Council of the National Academy of Sciences. Europe, Russia and China all see the value of space-based Earth observation by deploying their own fleet of satellites.

Uri, John↗

Battery Evaluation Profiles for X-57 and Future Urban Electric Aircraft

Battery energy density is one of the most critical design parameters for sizing all-electric aircraft, however it’s easily overestimated. Establishing the effective, usable energy density is confused by varying degrees of margin needed to account for structural and thermal management between different cell chemistry and pack designs. Therefore, a better methodology is needed to fairly compare emerging battery technologies for electric aircraft. Currently, there is a loss of critical information when vehicle trade studies are performed using “nominal” published cell-level performance metrics. Aircraft power demands rarely match these nominal power profiles, and aircraft designers lack the ability to accurately simulate the battery performance and temperature off-nominally unless the battery chemistry is well established. Conversely, battery suppliers have no generalized reference cases to publish more realistic performance metrics. This can lead to poor assumptions, such as aircraft studies assuming a fixed discharge efficiency of a battery, when in reality the usable energy in a pack is dependent on the power and thermal profile. Information needed to properly assess weight penalties for thermal management is also typically poorly characterized when assessing candidate batteries. This paper serves to better inform battery development, and similarly, provide aircraft designers with more realistic assumptions for applying knockdown margins in their designs. Detailed power and thermal performance estimates are provided, which provide a starting point for sizing power and thermal budgets using experimentally derived battery models. Results show that the X-57 battery-to-shaft efficiency is 77.3% for a particular optimized mission. Considering a 25% reserve on the battery capacity, this means that only roughly half of the original 55.3kWh ‘nominal’ pack energy can be converted to useful work during a mission. Further estimates on a clean-sheet VTOL optimization show an average 82.7% battery-to-shaft efficiency, using 98% peak efficiency inverters and 97.4% peak efficiency motors. Although higher battery efficiencies are possible, the resulting weight penalty negates improvement in vehicle performance. These trade-offs and resulting power profiles are provided as a starting point to better assess future battery designs.

Battery Electric Aircraft↗

Battery Evaluation Profiles for X-57 and Future Urban Electric Aircraft

Battery energy density is one of the most critical design parameters for sizing all-electric aircraft, however it’s easily overestimated. Establishing the effective, usable energy density is confused by varying degrees of margin needed to account for structural and thermal management between different cell chemistry and pack designs. Therefore, a better methodology is needed to fairly compare emerging battery technologies for electric aircraft. Currently, there is a loss of critical information when vehicle trade studies are performed using “nominal” published cell-level performance metrics. Aircraft power demands rarely match these nominal power profiles, and aircraft designers lack the ability to accurately simulate the battery performance and temperature off-nominally unless the battery chemistry is well established. Conversely, battery suppliers have no generalized reference cases to publish more realistic performance metrics. This can lead to poor assumptions, such as aircraft studies assuming a fixed discharge efficiency of a battery, when in reality the usable energy in a pack is dependent on the power and thermal profile. Information needed to properly assess weight penalties for thermal management is also typically poorly characterized when assessing candidate batteries. This paper serves to better inform battery development, and similarly, provide aircraft designers with more realistic assumptions for applying knockdown margins in their designs. Detailed power and thermal performance estimates are provided, which provide a starting point for sizing power and thermal budgets using experimentally derived battery models. Results show that the X-57 battery-to-shaft efficiency is 77.3% for a particular optimized mission. Considering a 25% reserve on the battery capacity, this means that only roughly half of the original 55.3kWh ‘nominal’ pack energy can be converted to useful work during a mission. Further estimates on a clean-sheet VTOL optimization show an average 82.7% battery-to-shaft efficiency, using 98% peak efficiency inverters and 97.4% peak efficiency motors. Although higher battery efficiencies are possible, the resulting weight penalty negates improvement in vehicle performance. These trade-offs and resulting power profiles are provided as a starting point to better assess future battery designs.

Battery↗

Aerosols from anthropogenic and biogenic sources and their interactions – modeling aerosol formation, optical properties, and impacts over the central Amazon basin

The Green Ocean Amazon experiment – GoAmazon 2014–2015 – explored the interactions between natural biogenic forest emissions from central Amazonia and urban air pollution from Manaus. Previous GoAmazon 2014–2015 studies showed that nitrogen oxide (NO x = NO + NO 2 ) and sulfur oxide (SO x ) emissions from Manaus strongly interact with biogenic volatile organic compounds (BVOCs), affecting secondary organic aerosol (SOA) formation. In previous studies, ground-based and aircraft measurements provided evidence of SOA formation and strong changes in aerosol composition and properties. Aerosol optical properties also evolve, and their impacts on the Amazonian ecosystem can be significant. As particles age, some processes, such as SOA production, black carbon (BC) deposition, particle growth and the BC lensing effect change the aerosol optical properties, affecting the solar radiation flux at the surface. This study analyzes data and models SOA formation using the Weather Research and Forecasting with Chemistry (WRF-Chem) model to assess the spatial variability in aerosol optical properties as the Manaus plumes interact with the natural atmosphere. The following aerosol optical properties are investigated: single scattering albedo (SSA), asymmetry parameter (g aer ), absorption Ångström exponent (AAE) and scattering Ångström exponent (SAE). These simulations were validated using ground-based measurements at three experimental sites, namely the Amazon Tall Tower Observatory – ATTO (T0a), downtown Manaus (T1), Tiwa Hotel (T2) and Manacapuru (T3), as well as the U.S. Department of Energy (DOE) Gulfstream 1 (G-1) aircraft flights. WRF-Chem simulations were performed over 7 d during March 2014. Results show a mean biogenic SOA (BSOA) mass enrichment of 512 % at the T1 site, 450 % in regions downwind of Manaus, such as the T3 site, and 850 % in areas north of the T3 site in simulations with anthropogenic emissions. The SOA formation is rather fast, with about 80 % of the SOA mass produced in 3–4 h. Comparing the plume from simulations with and without anthropogenic emissions, SSA shows a downwind reduction of approximately 10 %, 11 % and 6 % at the T1, T2 and T3 sites, respectively. Other regions, such as those further downwind of the T3 site, are also affected. The g aer values increased from 0.62 to 0.74 at the T1 site and from 0.67 to 0.72 at the T3 site when anthropogenic emissions are active. During the Manaus plume-aging process, a plume tracking analysis shows an increase in SSA from 0.91 close to Manaus to 0.98 160 km downwind of Manaus as a result of SOA production and BC deposition.

54 ENVIRONMENTAL SCIENCES↗

An Open-Source Decarbonization Analytics Framework: Designing for Low-Carbon Emission Districts and Communities: Preprint

This paper introduces an open-source analytics framework designed to assist in creating low or net-zero carbon buildings and urban districts. Integrated within URBANopt, an open-source platform for energy analysis in districts and communities, this framework equips researchers, architects, engineers, and other stakeholders with tools to evaluate the carbon footprint implications of their design choices. The framework enables the analysis of various scenarios, incorporating both historical and future emission factors, and can span across different climate zones, each with distinct grid and emissions characteristics. The results showcase the framework's capability to evaluate the impact of design upgrades and control strategies on carbon emissions in districts and communities. An illustrative analysis using a hypothetical district in Denver, Colorado, shows reduced emissions from energy efficiency upgrades and control strategies, highlighting the sensitivity in their effects on emissions and energy use.

buildings energy efficiency↗

The Evaluation of Composite Energy Absorbers for Use in UAM EVTOL Vehicle Impact Attenuation

The demand for new personal air-taxi services is leading to the development of lightweight Vertical Take-off and Landing (eVTOL) vehicles with electric propulsion for the Urban Air Mobility (UAM) industry. Manufacturers (OEMs) are considering many different designs to develop a vehicle that is able to take-off, cruise, and land autonomously with seating arrangements ranging between 2 and 15 passengers. It is unclear at present how the eventual market will mature; however, one of the common design characteristics noted by many of the OEMs is the use of advanced materials such as composites. A test and analysis program was initiated at NASA Langley Research Center (LaRC) in 2018 to evaluate the impact attenuation capabilities of various composite material systems with the goal of eventual implementation into an eVTOL vehicle. A series of 3-inch diameter by 6-inch length tubular specimens were fabricated from different material systems which included both traditional carbon and hybrid woven layers of fibers. Additionally, a subset of specimens were filled with closed-cell polyisocyanurate foam to help both with stabilization and crush response. The ultimate goal of the test program was to design a specimen capable of limiting the sustained crush acceleration to 20 g through a stable crush progression. After a series of material tests, these specimens were evaluated under both static and dynamic conditions for impact energy attenuation characteristics and crush stability. Additionally, a series of simulation models were developed in parallel to the test efforts. It is anticipated that the models developed using the component level test efforts can be used to help guide the development of a design for use in full-scale eVTOL vehicle applications.

Littell, Justin↗

A Decision Support Tool for Planning Neighborhood-Scale Deployment of Low-Speed Shared Automated Shuttles

Increasing interest and investment in connected, automated, and electric vehicles, and mobility-as-a-service concepts are paving the way for the next major shift in transportation through automated and shared mobility. The initial excitement towards rapid deployment and adoption of automated vehicles has subsided, and low-speed automated shuttles are emerging as a more pragmatic pathway for introducing automated mobility in geo-fenced districts. Such shuttles hold the promise to provide a viable alternative for serving short trips in urban districts with high travel densities. As interest in low-speed automated shuttle systems (to improve urban mobility) increases, the need for tools that can inform communities regarding benefits or dis-benefits of automated shuttle deployments is imminent. However, most of the existing transportation planning and simulation tools are not capable of handling emerging shared automated mobility options. This presentation presents a microscopic simulation toolkit that can be used by cities and communities to plan for the deployment of low-speed automated shuttles systems, as well as other shared mobility options. Labeled as the Automated Mobility District (AMD) modeling and simulation toolkit, the proposed decision support tool can help cities evaluate the mobility and sustainability impacts of deploying shared automated vehicles in geofenced regions. This paper presents a description of the toolkit, as well as a sample scenario analysis for the deployment of low-speed automated shuttles in Greenville, South Carolina. Results from the scenario study demonstrate the effectiveness of the proposed simulation toolkit in planning for advanced mobility systems.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Analysis of Automated Transit Network Systems with Battery-Electric Vehicles in Automated Mobility Districts: Preprint

The paper provides an overview of the insights and findings of the National Renewable Energy Laboratory's (NREL) ongoing research on the implementation of automated mobility districts (AMDs). AMD is a term coined by NREL to describe a geographically defined district or major activity center located in a dense urban setting with mobility applications provided by automated/autonomous vehicle (AV) systems spanning internal circulation and first-mile/last-mile connections to regional transportation hubs. Research over the past five years has focused on understanding the evolution of AMDs, beginning with demonstrations of automated shuttles prior to the pandemic, to more integrated on-demand mobility systems currently in initial stages of deployment. Initial insights and findings from earlier studies include the need for designation of a "jurisdiction having authority," a clear vision of a complete system to provide end-to-end mobility services, and the requisite intelligent infrastructure to complement AV technology. NREL's most recent Phase III research investigates station boarding/alighting (curb) issues, the full electrification of fleets, and the need for a systems engineering methodology (SEM) to properly analyze the complexities resulting from the convergence of automation, on-demand mobility, and electrification of the transit systems within the AMD. The paper reviews the findings of AMD research conducted during Phase I, II, and III, with special emphasis on Phase III results with respect to a descriptive example of the proposed SEM when a "digital twin" analytical model is used to simulate the transport fleet's battery-electric vehicle miles of travel and associated duty cycles through a rigorous analytical assessment with a comprehensive modeling process.

ADVANCED PROPULSION SYSTEMS↗

Integrating vehicle trajectory planning and arterial traffic management to facilitate eco-approach and departure deployment

Eco-approach and departure (EAD) enable continuous vehicle motion in urban signalized corridors. Since such a motion can extend to the EAD vehicles’ followers, it makes EAD a promising technology to benefit the traffic flow where automated vehicles and conventional vehicles coexist. Most existing EAD studies envision an ideal setting that neglects real-world operational conditions such as lane changes, multi-movement intersection configuration, partially automated fleet, and/or limited traffic state awareness. This study aims to fill the gap by designing an EAD algorithm considering real-world traffic operation constraints. The proposed algorithm uses a model predictive controller to minimize vehicle speed reduction and variation based on the real-time traffic signal control plan and measured queues at the intersection. The required inputs are readily available at many modern intersections. We observed that the proposed controller’s performance might degrade because of lane-changing maneuvers and lead-left turn traffic signals. These observations motivated our development of a lane change management strategy and a signal control implementation strategy to facilitate the EAD implementation. The lane change management strategies separate the EAD operations and lane-changing maneuvers in time and space. The signal control implementation strategy applies lag-left turn signals to enable EAD operation for both the through and left-turn vehicles. Compared to the non-EAD case, our EAD approach produces 2.5% to 7.8% energy savings while keeping similar intersection mobility. Notably, this approach brings about 2.5% to 3.6% energy savings in a 2% CAV case. This result demonstrates the feasibility of deploying EAD at low connected automated vehicle penetration rates.

Arterial corridor management↗

Assessment of Urban Aerial Taxi with Cryogenic Components under Design Environment for Novel Vertical Lift Vehicles (DELIVER)

Assessing the potential to bring 100 years of aeronautics knowledge to the entrepreneurs desktop to enable a design environment for emerging vertical lift vehicles is one goal for the NASAs Design Environment for Novel Vertical Lift Vehicles (DELIVER). As part of this effort, a system study was performed using a notional, urban aerial taxi system to better understand vehicle requirements along with the tools and methods capability to assess these vehicles and their subsystems using cryogenic cooled components. The baseline was a vertical take-off and landing (VTOL) aircraft, with all-electric propulsion system assuming 15 year technology performance levels and its capability limited to a pilot with one or two people and cargo. Hydrocarbon-fueled hybrid concepts were developed to improve mission capabilities. The hybrid systems resulted in significant improvements in maximum range and number of on demand mobility (ODM) missions that could be completed before refuel or recharge. An important consideration was thermal management, including the choice for air-cooled or cryogenic cooling using liquid natural gas (LNG) fuel. Cryogenic cooling for critical components can have important implications on component performance and size. Thermal loads were also estimated, subsequent effort will be required to verify feasibility for cooling airflow and packaging. LNG cryogenic cooling of selected components further improved vehicle range and reduced thermal loads, but the same concerns for airflow and packaging still need to be addressed. The use of the NASA Design and Analysis of Rotorcraft (NDARC) tool for vehicle sizing and mission analysis appears to be capable of supporting analyses for present and future types of vehicles, missions, propulsion, and energy sources. Further efforts are required to develop verified models for these new types of propulsion and energy sources in the size and use envisioned for these emerging vehicle and mission classes.

systems analysis↗

Assessment of Urban Aerial Taxi with Cryogenic Components Under Design Environment for Novel Vertical Lift Vehicles (DELIVER)

Assessing the potential to bring 100 years of aeronautics knowledge to the entrepreneurs desktop to enable a design environment for emerging vertical lift vehicles is one goal for the NASA's Design Environment for Novel Vertical Lift Vehicles (DELIVER). As part of this effort, a system study was performed using a notional, urban aerial taxi system to better understand vehicle requirements along with the tools and methods capability to assess these vehicles and their subsystems using cryogenic cooled components. The baseline was a vertical take-off and landing (VTOL) aircraft, with all-electric propulsion system assuming 15 year technology performance levels and its capability limited to a pilot with one or two people and cargo. Hydrocarbon-fueled hybrid concepts were developed to improve mission capabilities. The hybrid systems resulted in significant improvements in maximum range and number of on demand mobility (ODM) missions that could be completed before refuel or recharge. An important consideration was thermal management, including the choice for air-cooled or cryogenic cooling using liquid natural gas (LNG) fuel. Cryogenic cooling for critical components can have important implications on component performance and size. Thermal loads were also estimated, subsequent effort will be required to verify feasibility for cooling airflow and packaging. LNG cryogenic cooling of selected components further improved vehicle range and reduced thermal loads, but the same concerns for airflow and packaging still need to be addressed. The use of the NASA Design and Analysis of Rotorcraft (NDARC) tool for vehicle sizing and mission analysis appears to be capable of supporting analyses for present and future types of vehicles, missions, propulsion, and energy sources. Further efforts are required to develop verified models for these new types of propulsion and energy sources in the size and use envisioned for these emerging vehicle and mission classes.

thermal analysis↗

Complex pH-Dependent Interactions between Weak Polyelectrolyte Block Copolymer Micelles and Molecular Fluorophores

Amphiphilic block copolymers with weak polyelectrolyte blocks can assemble stimulus-responsive nanostructures and interfaces. Applications of these materials in drug delivery, biomimetics, and sensing largely rely on the well-understood swelling of polyelectrolyte chains upon deprotonation, often induced by changes in pH or ionic strength. This deprotonation can also tune interfacial interactions between the polyelectrolyte blocks and surrounding solution, an effect which is less studied than morphological swelling of polyelectrolytes but can be just as critical for intended function. Here, we investigate whether the pH-driven morphological response of polyelectrolyte-bearing nanostructures also affects the interactions of these nanostructures with molecules in solution, using micelles of a short-chain polybutadiene-block-poly(acrylic acid) (pBd–pAA) as a model system. Here we introduce a Förster resonance energy transfer (FRET) approach to probe interactions between micelles and fluorescent molecular solutes as a function of solution pH. As expected, the pAA corona of these pBd–pAA micelles increases in thickness monotonically as a function of pH. However, FRET efficiency, which provides a metric of the spatial proximity of fluorescently labeled micelles and freely diffusing fluorophores, exhibits complex nonmonotonic behavior as a function of pH, indicating that the average separation of micelles and acceptor fluorophores is not strictly correlated with micelle swelling. Dialysis experiments quantify the affinity of fluorophores for micelles as a function of pH, confirming that changes in FRET are driven almost entirely by the pH-dependent affinity of the pAA block for the investigated molecular fluorophores, not simply by a shape change of the pAA corona. This study provides key insights into the interfacial interactions between weak-polyelectrolyte-bearing nanostructures and molecular solutes, of importance for the development of their stimulus-responsive applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A Summary of Results from Vertical Drop Testing of Hybrid III and WIAMan ATDs

With the development and maturation of the Urban Air Mobility (UAM) market, many new types of electric vertical take-off and landing (eVTOL) vehicles will be flying in the national airspace carrying goods, people or conducting operations for a variety of missions. These types of vehicles are unlike current aircraft due to their novel design and operational profile. Several considerations must be examined in areas including noise, comfort and safety in order for these vehicles to be utilized and accepted into the current airspace system. Researchers at NASA Langley Research Center (LaRC) have conducted sub-scale and full-scale tests on representative eVTOL airframes and seats under a variety of dynamic impact conditions. These tests were conducted to generate data necessary to inform the development of standards in the areas specific to crashworthiness of eVTOL vehicle systems and safety. The data in this report relates to occupant responses obtained during a test campaign utilizing various makes, models, and sizes of Anthropomorphic Test Devices (ATD’s, a.k.a. crash test dummies) undergoing vertical impacts in a variety of seats. The data is intended to provide occupant behavior response and injury metrics for several anticipated impact scenarios that may occur in eVTOL operations. This report will present test data highlighting the effects of several variables on the test results. Discussions on the ATD sizes, along with comparisons between different ATD makes and types will be included. The performance of an in-house developed energy absorbing seat will be detailed, and discussions pertaining to the applicability in various loading conditions will be presented. Finally, a discussion as to the applicability of the tested results to eVTOL full-scale conditions will be included.

Dynamic Drop Testing↗

From Theory to Practice: Feasibility Study of a Thermal Microgrid at a DoD Installation: Preprint

Advanced district thermal energy systems, also known as thermal microgrids, can electrify and decarbonize urban districts in a highly efficient way, but adoption of such systems, especially in the US, has been slow. Thermal microgrids use a network circulating water at near-ambient (60-80 degree F) (15- 25 degree C) temperatures, and water-source heat pumps at connected buildings to boost or lower the temperature for space conditioning and domestic hot water. Addressing challenges related to retrofits of existing buildings for integration with such systems, as well as quantifying the benefits of different configurations, will be key to unlocking the full potential of thermal microgrids for energy savings, decarbonization, and resiliency. This paper will do that, by reporting on preliminary results from a feasibility study of a thermal microgrid, and illustrating the process of conceptual design to seek the best possible performance, within the many constraints of existing buildings. The feasibility study focuses on a cluster of existing buildings, including a grocery store, big box style retail store, motel, and clinic, at a US Department of Defense installation in Germany. The study will assess the performance of a pilot-scale thermal microgrid serving those buildings, in terms of energy, emissions, and life cycle cost, and assess practical considerations (such as building retrofits and scalability) for future implementation. A significant opportunity exists for waste heat recovery from refrigeration at the grocery store (more than offsetting the entire building s space heating load in terms of waste heat availability), and modeling of the proposed thermal microgrid will assess the benefits of the waste heat integration. The moderate operating temperatures of thermal microgrids facilitate the integration of waste heat from a variety of sources, and the networks allow waste heat to be shared amongst buildings in proximity. Along with results on expected energy and emissions performance, as well as waste heat integration, the paper will assess implications of load diversity on system performance. The paper will also discuss the process of evaluating existing building HVAC systems for compatibility with a thermal microgrid, including the feasibility of lower heating hot water temperatures compatible with currently-available water-to-water heat pumps. The cluster of buildings under consideration in this study has much in common with commercial buildings in the United States. The process of and results from this feasibility study can inform assessment of the potential for thermal microgrids in other locations and help unlock the benefits of such systems for decarbonization and energy savings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Investigation of Long-Term Impacts of Urbanization when Considering Global Warming for a Coastal Tropical Region

The overachieving goal of this project is to gain a better understanding of the climate impacts caused by the combined effects of land cover and land use (LCLU) changes and increasing global concentrations of green house gases (GHG) in tropical coastal areas, regions where global, regional and local climate phenomena converge, taking as the test case the densely populated northeast region of the Caribbean island of Puerto Rico. The research uses an integrated approach of high-resolution remote sensing information linked to a high resolution Regional Atmospheric Modeling System (RAMS), which was employed to perform ensembles of climate simulations (combining 2-LCLU and 2-GHG concentration scenarios). Reconstructed agricultural maps are used to define past LCLU, and combined with reconstructed sea surface temperatures (SST) for the same period form the PAST climate scenario (1951-1956); while the PRESENT scenario (2000-2004) was additionally supported by high resolution remote sensing data (10-m-res). The climate reconstruction approach is validated with available observed climate data from surface weather stations for both periods of time simulated. The selection of the past and present climate scenarios considers large-scale biases (i.e. ENSO/NAO) as reflected in the region of interest. Direct and cross comparison of the results is allowing quantifying single, combined, and competitive effects. Results indicate that global GHG have dominant effects on minimum temperatures (following regional tendencies), while urban sprawl dominates maximum temperatures. To further investigate impacts of land use the Bowen Ratio and the thermal response number (TRN) are analyzed. The Bowen ratio indicates that forestation of past agricultural high areas have an overwhelmingly mitigation effect on increasing temperatures observed in different LCLU scenarios, but when abandoned agricultural lands are located in plains, the resulting shrub/grass lands produce higher surface temperatures. The TRN (J/m^2/degC) is a surface property defined as the ratio of the surface net radiation to the rate of change in surface temperature, expresses how those fluxes are reacting to radiant energy inputs. Natural vegetated surfaces have a greater TRN than urban and barren surfaces because the net radiation processed by them is mostly used for latent heat and thermal storage heat rather than sensible heat (heating the air). Significant changes in TRN were observed in the metropolitan area of San Juan for the two analyzed periods reflecting a reduction of this variable in the present from the past consistent with increasing in thermal mass, or intense urbanization.

Gonalez, Jorge E.↗

Statistical Treatment of Convolutional Neural Network Superresolution of Inland Surface Wind for Subgrid-Scale Variability Quantification

Abstract Machine learning models have been employed to perform either physics-free data-driven or hybrid dynamical downscaling of climate data. Most of these implementations operate over relatively small downscaling factors because of the challenge of recovering fine-scale information from coarse data. This limits their compatibility with many global climate model outputs, often available between ∼50- and 100-km resolution, to scales of interest such as cloud resolving or urban scales. This study systematically examines the capability of a type of superresolving convolutional neural network (SR-CNNs) to downscale surface wind speed data over land from different coarse resolutions (25-, 48-, and 100-km resolution) to 3 km. For each downscaling factor, we consider three convolutional neural network (CNN) configurations that generate superresolved predictions of fine-scale wind speed, which take between one and three input fields: coarse wind speed, fine-scale topography, and diurnal cycle. In addition to fine-scale wind speeds, probability density function parameters are generated through which sample wind speeds can be generated, accounting for the intrinsic stochasticity of wind speed. For assessing generalization to new data, CNN models are tested on regions with different topography and climate that are unseen during training. The evaluation of superresolved predictions focuses on subgrid-scale variability and the recovery of extremes. Models with coarse wind and fine topography as inputs exhibit the best performance when compared with other model configurations, operating across the same downscaling factor. Our diurnal cycle encoding results in lower out-of-sample generalizability when compared with other input configurations.

17 WIND ENERGY↗