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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS2001

Vapor Growth of Binary and Ternary Chalcogenides in Preparation for Microgravity Experiments

In the bulk crystal growth of some technologically important semiconducting chalcopyrites, such as ZnTe, CdS, ZnSe and ZnS, vapor growth techniques have significant advantages over melt growth techniques due to the high melting points of these materials. The realization of routine production of high-quality single crystals of these semiconductors requires a fundamental, systematic and in-depth study on the PVT growth process and crystal growth by vapor transport in low gravity offers a set of unique conditions for this study. Previously, two reasons have been put forward to account for this. The first is weight-related reductions in crystal strain and defects. These are thought to be caused by the weight of the crystals during processing at elevated temperatures and retained on cooling, particularly for materials with a low yield strength. The second, and more general, reason is related to the reduction in density-gradient driven convection. The PVT crystal growth process consists of essentially three processes: sublimation of the source material, transport of the vapor species and condensation of the vapor species to form the crystal. The latter two processes can be affected by the convection caused by gravitational accelerations on Earth. Reductions in such convection in low gravity is expected to yield a nearly diffusion-limited growth condition which results in more uniform growth rates (on the microscopic scale) and hence greater crystalline perfection and compositional homogeneity. The reduction of convective contamination by performing flight experiments in a reduced gravity environment will help to understand the relation between fluid phase processes (growth parameters) and defect and impurity incorporation in grown crystals.

Su, Ching-Hua↗
NASA NTRS1999

The Oxidation Rate of SiC in High Pressure Water Vapor Environments

CVD SiC and sintered alpha-SiC samples were exposed at 1316 C in a high pressure burner rig at total pressures of 5.7, 15, and 25 atm for times up to 100h. Variations in sample emittance for the first nine hours of exposure were used to determine the thickness of the silica scale as a function of time. After accounting for volatility of silica in water vapor, the parabolic rate constants for Sic in water vapor pressures of 0.7, 1.8 and 3.1 atm were determined. The dependence of the parabolic rate constant on the water vapor pressure yielded a power law exponent of one. Silica growth on Sic is therefore limited by transport of molecular water vapor through the silica scale.

Opila, Elizabeth J.↗
NASA NTRS1991

Case Studies of Water Vapor and Surface Liquid Water from AVIRIS Data Measured Over Denver, CO and Death Valley, CA

High spatial resolution column atmospheric water vapor amounts and equivalent liquid water thicknesses of surface targets are retrieved from spectral data collected by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS). The retrievals are made using a nonlinear least squares curve fitting technique. Two case studies from AVIRIS data acquired over Denver-Platteville area, Colorado and over Death Valley, California are presented. The column water vapor values derived from AVIRIS data over the Denver-Platteville area are compared with those obtained from radiosondes, ground level upward-looking microwave radiometers, and geostationary satellite measurements. The column water vapor image shows spatial variation patterns related to the passage of a weather front system. The column water vapor amounts derived from AVIRIS data over Death Valley decrease with increasing surface elevation. The derived liquid water image clearly shows surface drainage patterns.

Gao, B.-C.↗
NASA NTRS2001

Remote Sensing of Water Vapor and Thin Cirrus Clouds using MODIS Near-IR Channels

The Moderate Resolution Imaging Spectroradiometer (MODIS), a major facility instrument on board the Terra Spacecraft, was successfully launched into space in December of 1999. MODIS has several near-IR channels within and around the 0.94 micrometer water vapor bands for remote sensing of integrated atmospheric water vapor over land and above clouds. MODIS also has a special near-IR channel centered at 1.375-micron with a width of 30 nm for remote sensing of cirrus clouds. In this paper, we describe briefly the physical principles on remote sensing of water vapor and cirrus clouds using these channels. We also present sample water vapor images and cirrus cloud images obtained from MODIS data.

Gao, Bo-Cai↗
NASA NTRS2001

Continuation of the NVAP Global Water Vapor Data Sets for Pathfinder Science Analysis

This annual report covers August 2000 - August 2001 under NASA contract NASW-0032, entitled "Continuation of the NVAP (NASA's Water Vapor Project) Global Water Vapor Data Sets for Pathfinder Science Analysis". NASA has created a list of Earth Science Research Questions which are outlined by Asrar, et al. Particularly relevant to NVAP are the following questions: (a) How are global precipitation, evaporation, and the cycling of water changing? (b) What trends in atmospheric constituents and solar radiation are driving global climate? (c) How well can long-term climatic trends be assessed or predicted? Water vapor is a key greenhouse gas, and an understanding of its behavior is essential in global climate studies. Therefore, NVAP plays a key role in addressing the above climate questions by creating a long-term global water vapor dataset and by updating the dataset with recent advances in satellite instrumentation. The NVAP dataset produced from 1988-1998 has found wide use in the scientific community. Studies of interannual variability are particularly important. A recent paper by Simpson, et al. that examined the NVAP dataset in detail has shown that its relative accuracy is sufficient for the variability studies that contribute toward meeting NASA's goals. In the past year, we have made steady progress towards continuing production of this high-quality dataset as well as performing our own investigations of the data. This report summarizes the past year's work on production of the NVAP dataset and presents results of analyses we have performed in the past year.

VonderHaar, Thomas H.↗
NASA NTRS2001

Raman Lidar Water Vapor Measurements at the DOE SGP CART Site

The NASA/GSFC Scanning Raman Lidar (SRL) was deployed to the Department of Energy's (DOE) Cloud and Radiation Testbed site in northern Oklahoma September - December, 2000 for two DOE sponsored field campaigns: 1) the Water Vapor Intensive Operations Experiment 2000 and 2) the Atmospheric Radiations Measurement First International Satellite Cloud Climatology Experiment Experiment (AFWEX). WvIOP2000 focussed on water vapor measurements in the lower troposphere while AFWEX focussed on upper tropospheric water vapor. For the first time ever, four water vapor lidars were operated simultaneously: one airborne and three ground-based systems. Intercomparisons of these measurements and others will be presented at the meeting.

Whiteman, David N.↗
NASA NTRS2001

Processes Controlling Water Vapor in the Winter Arctic Tropopause Region

This work describes transport and thermodynamic processes that control water vapor near the tropopause during the SAGE Ozone Loss and Validation Experiment (SOLVE), held during the Arctic 1999-2000 winter season. Aircraft based water vapor, carbon monoxide, and ozone measurements are analyzed so as to establish how deeply tropospheric air mixes into the arctic lower-most stratosphere, and what the implications are for cloud formation and water vapor removal in this region of the atmosphere. There are three major findings. First, troposphere-to- stratosphere exchange extends into the arctic stratosphere to about 13 km. Penetration is to similar levels throughout the winter, however, because ozone increases idly in the early spring, tropospheric air mixes with the highest values of ozone in that season. The effect of this upward mixing is to elevate water vapor mixing ratios significantly above their prevailing stratospheric values of about 5 ppmv. Second, the potential for cloud formation in the stratosphere is highest during early spring, with about 20\% of the parcels which have ozone values of 300-350ppbv experiencing ice saturation in a given 10 day period. Third, during early Spring temperatures at the tropopause are cold enough so that 5-10\% of parcels experience relative humidities above 100\%, even if the water content is as low as 5 ppmv. The implication is that during, this period the arctic tropopause can play an important role in maintaining a very dry upper troposphere during early Spring.

Pfister, Leonhard↗
NASA NTRS2002

Oxidation and Volatilization of Silica-Formers in Water Vapor

At high temperatures SiC and Si3N4 react with water vapor to form a silica scale. Silica scales also react with water vapor to form a volatile Si(OH)4 species. These simultaneous reactions, one forming silica and the other removing silica, are described by paralinear kinetics. A steady state, in which these reactions occur at the same rate, is eventually achieved, After steady state is achieved, the oxide found on the surface is a constant thickness and recession of the underlying material occurs at a linear rate. The steady state oxide thickness, the time to achieve steady state, and the steady state recession rate can all be described in terms of the rate constants for the oxidation and volatilization reactions. In addition, the oxide thickness, the time to achieve steady state, and the recession rate can also be determined from parameters that describe a water vapor-containing environment. Accordingly, maps have been developed to show these steady state conditions as a function of reaction rate constants, pressure, and gas velocity. These maps can be used to predict the behavior of silica formers in water-vapor containing environments such as combustion environments. Finally, these maps are used to explore the limits of the paralinear oxidation model for SiC and Si3N4

Opila, E. J.↗
NASA NTRS1999

The Dynamics of Vapor Bubbles in Acoustic Pressure Fields

In spite of a superficial similarity with gas bubbles, the intimate coupling between dynamical and thermal processes confers to oscillating vapor bubbles some unique characteristics. This paper examines numerically the validity of some asymptotic-theory predictions such as the existence of two resonant radii and a limit size for a given sound amplitude and frequency. It is found that a small vapor bubble in a sound field of sufficient amplitude grows quickly through resonance and continues to grow thereafter at a very slow rate, seemingly indefinitely. Resonance phenomena therefore play a role for a few cycles at most, and reaching a limit size-if one exists at all-is found to require far more than several tens of thousands of cycles. It is also found that some small bubbles may grow or collapse depending on the phase of the sound field. The model accounts in detail for the thermo-fluid-mechanic processes in the vapor. In the second part of the paper, an approximate formulation valid for bubbles small with respect to the thermal penetration length in the vapor is derived and its accuracy examined, The present findings have implications for acoustically enhanced boiling heat transfer and other special applications such as boiling in microgravity.

Hao, Y.↗
NASA NTRS2003

Column Closure Studies of Lower Tropospheric Aerosol and Water Vapor During ACE-Asia Using Airborne Sunphotometer, Airborne In-Situ and Ship-Based Lidar Measurements

We assess the consistency (closure) between solar beam attenuation by aerosols and water vapor measured by airborne sunphotometry and derived from airborne in-situ, and ship-based lidar measurements during the April 2001 Asian Pacific Regional Aerosol Characterization Experiment (ACE-Asia). The airborne data presented here were obtained aboard the Twin Otter aircraft. Comparing aerosol extinction o(550 nm) from four different techniques shows good agreement for the vertical distribution of aerosol layers. However, the level of agreement in absolute magnitude of the derived aerosol extinction varied among the aerosol layers sampled. The sigma(550 nm) computed from airborne in-situ size distribution and composition measurements shows good agreement with airborne sunphotometry in the marine boundary layer but is considerably lower in layers dominated by dust if the particles are assumed to be spherical. The sigma(550 nm) from airborne in-situ scattering and absorption measurements are about approx. 13% lower than those obtained from airborne sunphotometry during 14 vertical profiles. Combining lidar and the airborne sunphotometer measurements reveals the prevalence of dust layers at altitudes up to 10 km with layer aerosol optical depth (from 3.5 to 10 km altitude) of approx. 0.1 to 0.2 (500 nm) and extinction-to-backscatter ratios of 59-71 sr (523 nm). The airborne sunphotometer aboard the Twin Otter reveals a relatively dry atmosphere during ACE- Asia with all water vapor columns less than 1.5 cm and water vapor densities w less than 12 g/cu m. Comparing layer water vapor amounts and w from the airborne sunphotometer to the same quantities measured with aircraft in-situ sensors leads to a high correlation (r(sup 3)=0.96) but the sunphotometer tends to underestimate w by 7%.

Schmid, B.↗
NASA NTRS2003

Real-Time Optical Monitoring and Simulations of Gas Phase Kinetics in InN Vapor Phase Epitaxy at High Pressure

Understanding the kinetics of nucleation and coalescence of heteroepitaxial thin films is a crucial step in controlling a chemical vapor deposition process, since it defines the perfection of the heteroepitaxial film both in terms of extended defect formation and chemical integrity of the interface. The initial nucleation process also defines the film quality during the later stages of film growth. The growth of emerging new materials heterostructures such as InN or In-rich Ga(x)In(1-x)N require deposition methods operating at higher vapor densities due to the high thermal decomposition pressure in these materials. High nitrogen pressure has been demonstrated to suppress thermal decomposition of InN, but has not been applied yet in chemical vapor deposition or etching experiments. Because of the difficulty with maintaining stochiometry at elevated temperature, current knowledge regarding thermodynamic data for InN, e.g., its melting point, temperature-dependent heat capacity, heat and entropy of formation are known with far less accuracy than for InP, InAs and InSb. Also, no information exists regarding the partial pressures of nitrogen and phosphorus along the liquidus surfaces of mixed-anion alloys of InN, of which the InN(x)P(1-x) system is the most interesting option. A miscibility gap is expected for InN(x)P(1-x) pseudobinary solidus compositions, but its extent is not established at this point by experimental studies under near equilibrium conditions. The extension of chemical vapor deposition to elevated pressure is also necessary for retaining stoichiometric single phase surface composition for materials that are characterized by large thermal decomposition pressures at optimum processing temperatures.

Dietz, Nikolaus↗
NASA NTRS2003

Compositional Grading in an Impact-produced Spherule Bed, Barberton Greenstone Belt, South Africa: A Key to Condensation History of Rock Vapor Clouds

The chemical and physical processes by which spherules form during the condensation of impact-produced rock vapor clouds are poorly understood. Although efforts have been made to model the processes of spherule formation, there is presently a paucity of field data to constrain the resulting theoretical models. The present study examines the vertical compositional variability in a single early Archean spherule bed in the Barberton Greenstone Belt (BGB), South Africa, in order to better identify the process by which impact vapor clouds condense and spherules form and accumulate. The BGB spherule beds are suitable for this type of study because of their great thickness, often exceeding 25cm of pure spherules, due to the massive sizes of the impactors. Two main problems complicate analysis of vertical compositional variability of graded spherule beds: (1) differential settling of particles in both the vapor and water column due to density and size differences and (2) turbulence within the vapor cloud. The present study compares sections of spherule bed S3 from four different depositional environments in the Barberton Greenstone Belt: (1) The Sheba Mine section (SAF-381) was deposited under fairly low energy conditions in deep water, providing a nice fallout sequence, and also has abundant Ni-rich spinels; (2) Jay's Chert section (SAF-380) was deposited in subaerial to shallow-water conditions with extensive post-depositional reworking by currents. The spherules also have preserved spinels; (3) the Loop Road section (loc. SAF-295; samp. KSA-7) was moderately reworked and has only rare preservation of spinels; and (4) the shallow-water Barite Syncline section (loc. SAF-206; samp KSA-1) has few to no spinels preserved and is not reworked. Although all of the spherule beds have been altered by silica diagenesis and K-metasomatism, most of the compositional differences between these sections appear to reflect their diagenetic histories, possibly related to their differing depositional environments. Sulfate diagenesis in the Barite Syncline and Loop road sections may account for the loss of spinels.

Krull, A. E.↗
NASA NTRS2003

SPARC-IGAC Symposium on Climate-Chemistry Interactions. Climate Feedback by Water Vapor in the Tropical Upper Troposphere

The strong greenhouse forcing by atmospheric water vapor is expected to play an important role in shaping the direction of any future changes in climate. We present calculations that provide a new perspective on the sensitivity of upper tropospheric water vapor to changes in surface temperature. Equilibrium states of our atmospheric model show unambiguously that as the surface warms, changes in the vertical distribution and temperature of detraining air parcels from tropical convection lead to higher water vapor mixing ratios in the upper troposphere. However, the increase in mixing ratio is not as large as the increase in saturation mixing ratio due to warmer environmental temperatures, so that the relative humidity decreases. Our analysis suggests that models that maintain a fixed relative humidity are likely overestimating the magnitude of the water vapor feedback.

Dessler, A. E.↗
NASA NTRS2004

Observations of the Upper Tropospheric Water Vapor Feedback in UARS MLS and HALOE Data

One of the biggest uncertainties in climate science today concerns the water vapor feedback. Most GCMs hold relative humidity fixed as the climate changes, which provides a strong positive feedback to warming due from anthropogenic greenhouse gas emissions. Some in the community, on the other hand, have speculated that tropospheric specific humidity will remain fixed as the climate changes. Observational studies have attempted to resolve this disagreement, but the results have been inconclusive, and few of the studies have focused on the upper troposphere (UT). This is a significant oversight: the surface temperature is especially sensitive to changes in water vapor in the UT owing to the cold temperatures found there. We present an analysis of UARS MLS and HALOE water vapor measurements at 21 5 hPa. We find strong evidence that the water vapor feedback in the UT is positive, but not as strong as fixed relative humidity scenarios. This suggests that GCMs are overestimating the sensitivity of the climate.

Dessler, A. E.↗
NASA NTRS2004

Climatic Analysis of Oceanic Water Vapor Transports Based on Satellite E-P Datasets

Understanding the climatically varying properties of water vapor transports from a robust observational perspective is an essential step in calibrating climate models. This is tantamount to measuring year-to-year changes of monthly- or seasonally-averaged, divergent water vapor transport distributions. This cannot be done effectively with conventional radiosonde data over ocean regions where sounding data are generally sparse. This talk describes how a methodology designed to derive atmospheric water vapor transports over the world oceans from satellite-retrieved precipitation (P) and evaporation (E) datasets circumvents the problem of inadequate sampling. Ultimately, the method is intended to take advantage of the relatively complete and consistent coverage, as well as continuity in sampling, associated with E and P datasets obtained from satellite measurements. Independent P and E retrievals from Special Sensor Microwave Imager (SSM/I) measurements, along with P retrievals from Tropical Rainfall Measuring Mission (TRMM) measurements, are used to obtain transports by solving a potential function for the divergence of water vapor transport as balanced by large scale E - P conditions.

Smith, Eric A.↗
NASA NTRS2001

Low power, lightweight vapor sensing using arrays of conducting polymer composite chemically-sensitive resistors

Arrays of broadly responsive vapor detectors can be used to detect, identify, and quantify vapors and vapor mixtures. One implementation of this strategy involves the use of arrays of chemically-sensitive resistors made from conducting polymer composites. Sorption of an analyte into the polymer composite detector leads to swelling of the film material. The swelling is in turn transduced into a change in electrical resistance because the detector films consist of polymers filled with conducting particles such as carbon black. The differential sorption, and thus differential swelling, of an analyte into each polymer composite in the array produces a unique pattern for each different analyte of interest, Pattern recognition algorithms are then used to analyze the multivariate data arising from the responses of such a detector array. Chiral detector films can provide differential detection of the presence of certain chiral organic vapor analytes. Aspects of the spaceflight qualification and deployment of such a detector array, along with its performance for certain analytes of interest in manned life support applications, are reviewed and summarized in this article.

NASA Discipline Life Sciences Technologies↗
NASA NTRS2004

In Situ Water Vapor Measurements Using Coupled UV Fragment Fluorescence/Absorption Spectroscopy in Support of CRYSTAL-FACE

Understanding the coupling of dynamics, chemistry, and radiation within the context of the NASA Earth Science Enterprise (ESE) and the national Climate Change Science Program (CCSP) requires, as a first-order priority, high spatial resolution, high-accuracy observations of water in its various phases. Given the powerful diagnostic importance of the condensed phases of water for dynamics and the impact of phase changes in water on the radiation field, the accurate, in situ observation of water vapor is of central importance to CRYSTAL FACE (CF). This is clear both from the defined scientific objectives of the NRA and from developments in the coupled fields of stratosphere/troposphere exchange, cirrus cloud formation/removal and mechanisms for the distribution of water vapor in the middle/upper troposphere. Accordingly, we were funded under NASA Grant NAG5-11548 to perform the following tasks for the CF mission: 1. Prepare the water vapor instrument for integration into the WB57F and test flights scheduled for Spring 2002. 2. Calibrate and prepare the water vapor instrument for the Summer 2002 CF science flights based in Jacksonville, Florida. 3. Provide both science and engineering support for the above-mentioned efforts. 4. Analyze and interpret the CF data in collaboration with other mission scientists. 5. Attend the science workshop in Spring 2003. 6. Publish the data and analysis in peer-reviewed journals.

Anderson, James G.↗
NASA NTRS2005

Vapor Pressures in the Al(I)+Al2O3(s) System: Reconsidering Al2O3(s) Condensation

The vaporization behavior of the A1-O system has been studied on numerous occasions but significant uncertainties remain. The origin of this uncertainty must be understood before A1-O vaporization behavior can be accurately determined. The condensation of A12O3 and clogging of the effusion orifice is a difficult problem for the Knudsen effusion technique that influences the measured vaporization behavior but has only received limited attention. This study reconsiders this behavior in detail. A new theory for A12O3 condensation is proposed together with procedures that will improve the measured thermodynamic properties of A1-O vaporization.

Copland, Evan↗