Search NASA⌕ Search

SEARCH · Search NASA

Results for “Waste Repository”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Implementation and verification of a user-defined element (UEL) for coupled thermal-hydraulic-mechanical-chemical (THMC) processes in saturated geological media

Efficient and accurate modeling of the coupled thermal-hydraulic-mechanical-chemical (THMC) processes in various rock formations is indispensable for designing energy geo-structures such as underground repositories for high-level nuclear wastes. Here, this work focuses on developing and verifying an implicit finite element solver for generic coupled THMC problems in geological settings. Starting from the mass, momentum, and energy balance laws, a specialized set of governing equations and a thermoporoelastic constitutive model is derived. This system is then solved by an implicit finite element (FE) scheme. Specifically, the residuals and the Jacobians are scripted in a user-defined element (UEL) subroutine which is then combined with the general-purpose FE software Abaqus Standard to solve initial-boundary value problems. Considering the complexity of the system, the UEL development follows a stepwise manner by first solving the coupled hydraulic-mechanical (HM) and thermal-hydraulic-mechanical (THM) equations before moving on to the full THMC problem. Each implementation step consists of at least one verification test by comparing computed results with closed-form analytical solutions to ensure that the various coupling effects are correctly realized. To demonstrate the robustness of the algorithm and to validate the UEL, a three-dimensional case study is performed with reference to the in-situ heating test of ATLAS at Belgium in 1980s. A hypothetical radionuclide leakage event is then simulated by activating the chemical-concentration degree of freedom and prescribing a constant high concentration at the heater's surface. The model predicts a limited contaminated regime after six years considering both diffusion and advection effects on species transport.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Radioactive Waste Management in a Treatability and Optimisation Perspective - 17527

In order to meet recycling criteria or to fulfil Waste Acceptance Criteria (WAC) for disposal there are many different management concepts for radioactive waste that can be applied. Which concept or set of concepts to use to optimize waste management depends on several factors, among them, the regulatory framework for recycling, the availability of a disposal facility and the acceptance criteria for disposal. The required pre-treatment and other pre-disposal activities should be carefully analyzed for each of the disposal options, as they are significant contributors to the total cost for managing the waste. Waste Acceptance Criteria are living documents that should be updated when regulatory framework changes as well as when new treatment methods and new packaging and barrier systems develop. Each waste treatment facility, has its own specific limitations and therefore its own WAC/CFA (conditions for acceptance), which depends both on the plant design and national legislation. Many waste owners, countries or licensees, have their preferred, and in some cases well established, waste routes for certain waste streams. In some countries, the full chain from waste treatment through to disposal of radioactive waste is in place, whilst other countries still are in the process of establishing their repository program. The worst case scenario for any licensee or waste owner is waste which is not possible to qualify for disposal. This can be due to poor or degraded waste containers, unspecified content in waste packages, or wastes that are not suitable for disposal in their current form. Such deficiencies result in expensive actions related to waste retrieval, new characterisation and/or costly investigations. The EDF Group has a fleet of waste treatment facilities and has, for decades, provided waste treatment services to domestic and international customers. This paper will discuss important waste owner considerations and EDF experiences related to the optimization of the waste management process. This will be from both a treatment and an end-state perspective. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

National Plan for the Disposal of Existing and Future TRU Wastes - 18616

Now that the Waste Isolation Pilot Plant (WIPP) has re-opened, after being down for three years due to an accident the DOE National TRU Program has re-developed a plan for the disposal of existing and future TRU wastes. The National TRU Waste Management Plan (NTWMP) is an integrated plan to address the needs of DOE sites across the DOE Weapons Complex that create and store TRU waste, and is centered on the capability of WIPP to receive and dispose of TRU waste. The WIPP capability is planned as a weekly shipping rate and is defined by emplacement and receipt rate capabilities since WIPP is not permitted for long-term storage. And, shipping rates may be constrained by new WIPP Waste Acceptance Criteria (WAC) and future plans for repository configurations and disposal package capabilities over the next 30 years. Since WIPP is the only disposal system available to the DOE for TRU waste disposal, DOE has a newly projected life-cycle need for WIPP to remain open and available up to 2050. It is projected that the need for WIPP will continue up to the year 2050 for the disposition of the remaining legacy TRU inventories and for the disposal of TRU waste continuing to be generated at DOE's National Laboratories. In addition, there are several other potential new waste streams in which WIPP is being considered an alternative solution for their disposition. The NTWMP has been updated to reflect the short-term and long-term plans for TRU waste disposal at WIPP. The short-term plan is used by DOE for budget projection and integration purposes to facilitate and inform budget planning, both in DOE's Environmental Management (EM) and National Nuclear Security Administration (NNSA) organizations. Most legacy TRU waste (generated in the past and stored at DOE sites today) is owned and managed by EM. And, EM submits integrated budget requests for DOE sites, including the integration of resources for TRU waste management. NNSA and DOE's Office of Science (OS) funds TRU waste management as part of their mission funding and NNSA should eventually be the primary user of the WIPP resources as EM's legacy TRU waste is cleaned-up. Prior to the unexpected shutdown of WIPP in 2014, there was a small back-log of waste certified for WIPP disposal and shipments of TRU waste to WIPP were 'just-in-time' as waste was certified. After three years of WIPP being down, DOE sites have built significant back-logs of TRU waste to be certified for WIPP. That back-log built up to over 25,000 containers of TRU waste during that three-year period (Table 1). The backlog included both Contact-Handled (CH) TRU waste and Remote-Handled (RH) TRU waste, and even though WIPP re-opened in April of 2017, it is only open for TRU waste containers that can be stacked on disposal room floors. Plans for changing RH waste disposal packages and methods are in-the-works, but are not yet mature enough for significant planning. In addition, the WIPP underground facilities are now partially contaminated with radioactive particulate, which significantly reduces the WIPP operational efficiencies as compared to 2014. With a large back-log of waste ready for WIPP disposal and limited throughput for WIPP disposal rates, the focus of the NTWMP is to prioritize the selection of TRU wastes from the various sites based on WIPP waste emplacement rates and shipping rates to WIPP. Some TRU waste sites have a significant need to be top priority for shipments to WIPP, and that must be balanced with the need for all TRU waste sites to have some shipments to deplete their back-log of TRU wastes. Storage and management of TRU waste is very costly for DOE and many of those resources could be used to optimize the overall disposition of TRU waste and save DOE significant funding. In addition, the plan will show the possible transition of TRU Waste Management from primarily being an EM function to being an NNSA function in the coming years. As legacy TRU waste inventories are removed, and as NNSA mission-related TRU waste inventories are produced, DOE will be faced with deciding where the primary responsibility for TRU waste management should reside. (author)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Computational Studies of Gas Phase Reactions of Zirconium Tetrachloride (ZrCl{sub 4}) and Metal Chloride Impurities

Zirconium-based cladding materials that surround used nuclear fuel (UNF) rods represent a significant fraction of the total amount of high level waste that must be disposed of in long term geological repositories. The decontamination, recovery and reuse of these materials would significantly reduce the high level waste associated with light water reactors and could provide a new source of hafnium free zirconium for the fabrication of new nuclear components. One part in the strategy to recycle zirconium from used cladding materials involves developing a computational modeling (DFT) protocol to understand the reactions between ZrCl{sub 4} and metal chloride impurities that may occur in the gas phase during sublimation. Several of the metal chloride species present are known to form Lewis acid/base adducts in the gas phase and development of purification protocols require investigation into the properties of these ZrCl{sub 4} contaminates.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2026

Corrosion of 316 SS in direct contact with Zircaloy-4 in repository relevant conditions

The effects of interfacial contact between 316 stainless steel (316 SS) waste canister and spent fuel cladding material (Zircaloy-4) in case of water intrusion into a deep geological repository are investigated. Hydrothermal corrosion experiments of 316 SS and Zircaloy-4 in direct contact were performed at elevated temperatures in MilliQ water and simulated Mont Terri groundwater. Hematite, magnetite, chromite, and baddeleyite form as secondary phases. pH of the Mont Terri solution increases with corrosion duration and magnetite forms preferentially instead of hematite. Thermodynamic modeling shows that iron oxidation in 316 SS controls the pH and redox potential of the aqueous environment and is in good agreement with experimental Mont Terri results, showing that experimental Mont Terri results trend to equilibrium. All oxides except hematite are predicted to exist at thermodynamic equilibrium based on calculations, implying that experimentally formed hematite will be reduced or transformed to magnetite at equilibrium. The thermodynamically predicted chromite was observed to form only at the interface where 316 SS was in contact with Zircaloy-4 at 250°C, showing that contact with Zircaloy-4 seems to accelerate the 316 SS corrosion to thermodynamic equilibrium. Finally, Mont Terri groundwater readily trends towards thermodynamic equilibrium, leading to a pH and redox buffered system that is dominated by iron in solution coming from the accelerated corrosion of 316 SS caused by Zircaloy-4 contact.

316 stainless steel↗
DOE OSTI2024

Coupled hydro-thermal flow and radionuclide transport driven by spatial variation of heat-generating radioactive wastes in shale formations

Deep geologic disposal of multiple nuclear waste packages with various heat sources can induce nonuniform hydro-thermal behaviors in the near-field of the repository, consequently influencing the long-term radionuclide transport in the far-field once waste form breach initiates. Here, this study looks into three cases with variation in the spatial order of six groups of heat sources (10th, 50th, 75th, 90th, 95th, and 99th percentiles of heat outputs generated from 1,981 as-loaded dual-purpose canisters in the field site) in a shale-hosted repository with respect to the uni-directional groundwater flow (from west to east): (1) cooler waste packages from west to east, (2) hotter waste packages from west to east, and (3) hottest waste packages in the middle of the repository. Our field-scale PFLOTRAN simulation represents heat-driven multiphysics coupled mechanisms, including multiphase flow, heat transfer, and chemical/radioactive transport, and also, calculates the onset of waste form breach based on temperature-dependent canister vitality. The results from this sensitivity study will quantify the short- (less than 1 × 10 3 years) and long-term (up to 1 × 10 6 years) impacts of sporadic heat pulses from waste package on the spatio-temporal perturbation in hydro-thermal flow quantities and the rate of radionuclide transport in both near- and far-field of the repository system.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Recent Advances in Corrosion Science Applicable To Disposal of High-Level Nuclear Waste

High level radioactive waste is accumulating at temporary storage locations around the world and will eventually be placed in deep geological repositories. Many different types of geological formation are under consideration, but all will eventually allow water to contact the metallic waste containers considering that the period of performance required to allow sufficient decay of dangerous radionuclides is on the order of 105 – 106 years. Corrosion of the containers and waste forms in the aqueous repository environment is therefore a concern. This review describes the recent advances of the field of materials corrosion based on the work of the Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD) to address the issues associated with the long-term performance assessment and the design of materials with improved performance, where performance is defined as resistance to aqueous corrosion. Glass, crystalline ceramics, and metals are discussed separately, and then the near field interactions of these different materials classes are addressed. Recommendations for future directions are provided.

Frankel, Gerald↗
DOE OSTI2020

Development of PFLOTRAN Transport Capability for Use in the Waste Isolation Pilot Plant Performance Assessment - 20545

Waste Isolation Pilot Plant (WIPP) performance assessment (PA) calculations estimate the probability of radionuclide release from the repository to the land surface and across the land withdrawal boundary for a regulatory period of 10,000 years after facility closure. Simulations of flow and transport in the repository and the surrounding Salado Formation are foundational to the PA. Because proposed additional waste emplacement panels would result in an asymmetric repository layout, the US Department of Energy (DOE) is preparing to transition to use of a three-dimensional (3-D) model domain for simulation of flow and transport instead of the two-dimensional (2-D) flared grid domain currently used. DOE has charged Sandia National Laboratories with developing the capability necessary to simulate processes affecting flow and transport in the WIPP in PFLOTRAN, an open-source massively parallel multi-phase flow and reactive transport code. The new flow and transport capabilities developed in PFLOTRAN incorporate WIPP-specific process models and will replace the 2-D simulators (BRAGFLO and NUTS) that are currently utilized for Salado flow and transport calculations in WIPP PA. The focus of this paper is on the development of a new Nuclear Waste Transport (NWT) mode in PFLOTRAN that has all of the capabilities necessary for Salado transport simulations, including the ability to handle complete dry-out (100% gas saturation) of arbitrary cells in the model domain, radionuclide mass conservation at step changes in porosity associated with borehole intrusion, and the ability to calculate fluxes on a flared grid. The new PFLOTRAN transport capability and a suite of verification tests were designed around a list of functional requirements for WIPP PA calculations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Salt Reconsolidation and Repository Engineered Barriers - 18651

Salt repositories for the permanent disposal of hazardous waste provide extraordinary advantage over other geo-media because geotechnical barriers can be constructed with confidence using crushed salt, which is a perfectly compatible material that is readily available by mining practice. Other excellent barrier materials that consist of specialty mixes of salt-based concrete, bentonite, and bitumen bolster confidence that a repository in geologic salt formations will remain impermeable forever. Practically speaking, achieving high-performance engineered barriers assumes an isolation role as important as the host formation itself. Long-term performance assessment intrinsically includes evaluating seal-system design and demonstrated operational characteristics. Consistent with global interests, specific research on salt-repository seal systems not only established significant technical bases but identified possible improvements through straightforward research and laboratory and field investigations. Engineered barriers of crushed salt with possible additives, such as clay and water, evolve to create hydrological and mechanical characteristics that approach those of the host salt formation. Demonstrating early functionality of seal systems reduces uncertainty, which is introduced when calculating or predicting when performance properties become effective in the future. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Environmental Assessment for the Above Ground Storage Capability at the Waste Isolation Pilot Plant Draft

The Waste Isolation Pilot Plant (WIPP) is the nation’s only approved repository for the disposal of defense related/defense generated transuranic (TRU) and mixed hazardous TRU waste (henceforth called TRU waste). The mission of the WIPP Project is to realize the safe disposal of TRU waste from TRU waste generator sites in the Department of Energy waste complex. The WIPP Project was authorized by Title II, Section 213(a) of Public Law 96-164 (U. S. Congress 1979). Congress designated the WIPP facility “for the express purpose of providing a research and development facility to demonstrate the safe disposal of radioactive wastes resulting from the defense activities and programs of the United States exempted from regulation by the Nuclear Regulatory Commission (NRC).” The WIPP facility is operated by the U. S. Department of Energy (DOE). Transuranic waste that is disposed in the WIPP facility is defined by Section 2(18) the WIPP Land Withdrawal Act of 1992 (LWA) (U. S. Congress, 1992) as: “waste containing more than 100 nanocuries of alpha-emitting transuranic isotopes per gram of waste, with half-lives greater than 20 years, except for: (A) high-level radioactive waste; (B) waste that the Secretary has determined, with the concurrence of the Administrator, does not need the degree of isolation required by the disposal regulations; or (C) waste that the NRC has approved for disposal on a case-by-case basis in accordance with part 61 of title 10, Code of Federal Regulations (CFR).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Self-accelerated corrosion of nuclear waste forms at material interfaces

The US plan for high-level nuclear waste includes the immobilization of long-lived radionuclides in glass or ceramic waste forms in stainless-steel canisters for disposal in deep geological repositories. Here we report that, under simulated repository conditions, corrosion could be significantly accelerated at the interfaces of different barrier materials, which has not been considered in the current safety and performance assessment models. Severe localized corrosion was found at the interfaces between stainless steel and a model nuclear waste glass and between stainless steel and a ceramic waste form. The accelerated corrosion can be attributed to changes of solution chemistry and local acidity/alkalinity within a confined space, which significantly alter the corrosion of both the waste-form materials and the metallic canisters. The corrosion that is accelerated by the interface interaction between dissimilar materials could profoundly impact the service life of the nuclear waste packages, which, therefore, should be carefully considered when evaluating the performance of waste forms and their packages. Moreover, compatible barriers should be selected to further optimize the performance of the geological repository system.

Guo, Xiaolei↗
DOE OSTI2024

RANGERS: Modeling Report on Integrity and Performance Assessment of Engineered Barrier Systems in a Salt Repository for HLW/SNF

The Engineered Barrier System (EBS) plays an important role in ensuring the long-term safety and containment of high-level waste (HLW) and spent nuclear fuel (SNF) in deep geological repositories in salt formation. As part of a multi-barrier system, the EBS works alongside the natural barrier, which is the salt formation itself and the technical barrier comprising the disposal casks. The primary function of the EBS is to maintain containment during a defined period until the backfill used in the repository made of crushed salt, develops its sealing capacity through compaction. Over the time, the backfill eventually compacts to a state of low porosity and permeability, acting as a long-term seal. However, until this process is complete, the EBS must retain its structural and functional integrity. Regulatory guidelines in Germany currently require the EBS to remain effective for up to next ice age, that is expected in 50,000 years. The significant hydro-geological and topographic changes expected during an ice age could make it impossible to accurately predict the hydro-chemical conditions within the repository system at that time. In response to these challenges, BGE TECHNOLOGY GmbH (BGE TEC) and Sandia National Laboratories (SNL) have jointly developed a comprehensive methodology for the design and safety assessment of engineered barrier systems within the scope of the RANGERS project. This methodology is tailored for repositories in salt formations. The developed methodology provides a structured approach for designing and assessing the performance of the EBS in salt-based repositories. It begins with defining a sealing concept based on the geological characteristics of the selected site and the overall repository design. The entire repository system, comprising the geological site, repository infrastructure, and EBS, is then subjected to a Features, Events, and Processes (FEP) analysis, focusing solely on those FEPs that affect the EBS. The derived FEPs help identify the loads and stresses acting on the EBS, which serve as the foundation for conducting an integrity assessment. This analysis helps predict the EBS’s evolution and performance over the regulatory time frame, feeding into integrated performance assessment simulations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

International collaboration in disposal research: comparative modeling of coupled processes in the DECOVALEX project

Abstract. This presentation gives an overview of an international research collaboration for advancing the understanding and modeling of coupled thermo-hydro-mechanical-chemical (THMC) processes in geological systems. The creation of the international DECOVALEX project, now running for more than 25 years, was motivated by the recognition that prediction of these coupled effects is an essential part of the performance and safety assessment of geologic disposal systems for radioactive waste and spent nuclear fuel. DECOVALEX emphasizes joint analysis and comparative modeling of state-of-the-art field and laboratory experiments, across a range of host rock options and repository designs. Participating research teams are from radioactive waste management organizations, national research institutes, regulatory agencies, universities, and consulting groups, providing a wide range of perspectives and solutions to these complex problems. The presentation provides examples of the research contributions made collectively in past DECOVALEX tasks and also touches on the unique modeling challenges tackled in the ongoing project phase, referred to as DECOVALEX-2023. The current phase comprises 17 partner organizations, about 50 modeling teams, and 7 modeling tasks, which cover a broad portfolio from fundamental studies on gas migration to full-scale in situ heater experiments in different host rocks to performance assessment studies. Together, these examples illustrate that the insight and scientific knowledge gained within the DECOVALEX project would not have been possible if one group had studied these complex THMC modeling challenges alone rather than within a truly collaborative setting.

Birkholzer, Jens T.↗
DOE OSTI2018

Assessment of the potential for criticality in the far field of a used nuclear fuel repository

This study aims to assess the likelihood for criticality in the far field of a repository for direct disposal of commercial light water reactor used nuclear fuel. Two models are used in combination: (1) a neutronics model to estimate the minimum critical masses of spherical, water-saturated depositions of fissile material; (2) a transport model to simulate the dissolution of waste packages arranged in an array and the subsequent transport of fissile solutes through fractured bedrock to a single accumulation location. The neutronics model shows that heavy metals from different types of used fuel present the same minimum critical mass behavior in the parameter space of initial enrichment and burnup, dictated largely by the fissile content. However, the magnitude of the minimum critical mass varies significantly within that parameter space, and secondary effects like the presence of absorbing nuclides play a minor role. Here, the transport model employs various subsurface transport scenarios, and for each scenario the mass of each isotope and the overall fissile content of the accumulation is reported from the time of canister failure up to one hundred million years at various distances from the repository edge. Taking the results of the two models in concert, it is shown that even if the accumulation of a critical mass is possible under conservative conditions, these conditions are unlikely to be present in the vicinity of a carefully engineered repository. Based on the results of each model, recommendations for risk mitigation in terms of waste characteristics and repository design are given.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2026

Analysis of the Effects of Postclosure Criticality on Repository Performance

The United States Department of Energy’s (DOE) Office of Nuclear Energy’s Disposal Research & Development Campaign seeks to better understand the technical basis, risks, and uncertainty associated with the safe and secure disposition of spent nuclear fuel (SNF) and high-level radioactive waste (HLW). Commercial nuclear power generation in the United States has resulted in thousands of metric tons of SNF, the disposal of which is the responsibility of DOE (Nuclear Waste Policy Act of 1982, as amended). Any repository licensed to dispose of SNF will be subject to requirements regarding the long-term performance of that repository. Evaluating the long-term performance of the repository may consider the consequences of the SNF achieving a critical configuration during the postclosure period. Of particular interest is the potential for this to occur in dual-purpose canisters (DPCs), which are currently licensed and being used to store and transport SNF but were not designed for permanent geologic disposal. DOE has been considering disposing of SNF in DPCs to avoid the costs and worker dose associated with repackaging the SNF currently stored in DPCs into repository-specific canisters. This report examines the consequences of postclosure criticality to provide technical support to DOE in developing a disposal plan.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1982

Analysis of space systems for the space disposal of nuclear waste follow-on study. Volume 1: Executive summary

The impact on space systems of three alternative waste mixes was evaluated as part of an effort to investigate the disposal of certain high-level nuclear wastes in space as a complement to mined geologic repositories. A brief overview of the study background, objectives, scope, approach and guidelines, and limitations is presented. The effects of variations in waste mixes on space system concepts were studied in order to provide data for determining relative total system risk benefits resulting from space disposal of the alternative waste mixes. Overall objectives of the NASA-DOE sustaining-level study program are to investigate space disposal concepts which can provide information to support future nuclear waste terminal storage programmatic decisions and to maintain a low level of research activity in this area to provide a baseline for future development should a decision be made to increase the emphasis on this option.

Source record↗
NASA NTRS2000

Modeling of Solid Waste Processing Options in BIO-Plex

BIO-Plex is a ground-based test bed currently under development by NASA for testing technologies and practices that may be utilized in future long-term life support missions. All aspects of such an Advanced Life Support (ALS) System must be considered to confidently construct a reliable system, which will not only allow the crew to survive in harsh environments, but allow the crew time to perform meaningful research. Effective handling of solid wastes is a critical aspect of the system, especially when recovery of resources contained in the waste is required. This is particularly important for ALS Systems configurations that include a Biomass Production Chamber. In these cases, significant amounts of inedible biomass waste may be produced, which can ultimately serve as a repository of necessary resources for sustaining life, notably carbon, water, and plant nutrients. Numerous biological and physicochemical solid waste processing options have been considered. Biological options include composting, aerobic digestion, and anaerobic digestion. Physicochemical options include pyrolysis, SCWO (supercritical water oxidation), various incineration configurations, microwave incineration, magnetically assisted gasification, and low temperature plasma reaction. Modeling of these options is a necessary step to assist in the design process. A previously developed top-level model of BIO-Plex implemented in MATLAB Simulink (r) for the use of systems analysis and design has been adopted for this analysis. Presently, this model only considered incineration for solid waste processing. Present work, reported here, includes the expansion of this model to include a wider array of solid waste processing options selected from the above options, bearing in mind potential, near term solid waste treatment systems. Furthermore, a trade study has also been performed among these solid waste processing technologies in an effort to determine the ideal technology for long-term life support missions.

Rodriguez, Luis F.↗
DOE OSTI2017

Purification of Zirconium Tetrachloride (ZrCl{sub 4}) from UNF Cladding - A Progress Report

Zirconium-based cladding materials that surround used nuclear fuel (UNF) rods represent a significant fraction of the total amount of high level waste that must be disposed of in long term geological repositories. The decontamination and/or recovery and reuse of these materials would significantly reduce the amount of high level waste associated with light water nuclear energy reactors and could provide a new source of hafnium free zirconium for the fabrication of new nuclear components. A step in a strategy to recycle zirconium from used cladding materials is the direct, high yield chlorination reaction that produces zirconium tetrachloride (ZrCl{sub 4}). The ZrCl{sub 4} so obtained is contaminated with other metal chloride species (FeCl{sub 3}, NbCl{sub 5}, NbOCl{sub 3}, SnCl{sub 4}, CsCl, SbCl{sub 5}, etc.) that originate from the alloying metals present initially as well as contaminants from oxide layers on the cladding, trace fission products, fuel residues, activation byproducts, and tritium. The suggested strategy to remove the metal chloride impurities is based on sublimation at atmospheric pressure combined with chemical treatments influencing volatility of the impurities.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗