Absorption and diffusion of zincate ions in cellulose membranes.
Zinc penetration through regenerated cellulose membrane separators shown to be growth mechanism in silver-zinc cell
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Zinc penetration through regenerated cellulose membrane separators shown to be growth mechanism in silver-zinc cell
Ternary phase diagrams for gallium-phosphorus-zinc and gallium-arsenic-zinc systems with diffusion problem applications
Solar absorptance and emittance of candidate zinc oxides/silicone and zinc oxide/potassium silicate coatings measured at room temperature for application to space radiators
Nuclear magnetic resonance measurements determine which metallochlorophylls, besides magnesium-containing chlorophylls, possess coordination aggregation properties. Infrared spectroscopy reveals that only zinc pheophytin and zinc methyl pheophorbide showed significant coordination aggregation, whereas divalent nickel and copper did not.
Addition of lead ions to electrolyte suppresses zinc dendrite formation during charging cycle. A soluble lead salt can be added directly or metallic lead can be incorporated in the zinc electrode and allowed to dissolve into the electrolyte.
Fuel cell studies on reversibility of organic reactions, oxygen dissolution reaction, and organic adsorption on zinc electrodes of silver zinc batteries
Miniature fuel cells within sealed silver zinc batteries consume evolved hydrogen and oxygen rapidly, preventing pressure rupturing. They do not significantly increase battery weight and they operate in all battery life phases. Complete gas pressure control requires two fuel cells during all phases of operation of silver zinc batteries.
Reflectance measurements of irradiated specimens of zinc oxide and zinc orthotitanate white pigment materials
Production and optical properties of zinc selenide aluminum arsenide heterojunction and platinum zinc selenide Schottky junction
Environmental testing of nickel-cadmium, silver-zinc, silver-cadmium, and zinc-oxygen batteries for spacecraft power supplies
A number of amalgam electrode systems were investigated for possible use as high rate anodes and cathodes. The systems examined include: lithium, sodium, and potassium in Group 1, magnesium, calcium, and barium in Group 2, aluminum in Group 3, lead in Group 4, copper in Group 1b, and zinc and cadmium in Group 2b. The K(Hg) and Na(Hg) anodes in 10 VF and 15 VF (an unambiguous expression of concentration that indicates the number of formula weights of solute dissolved in a liter of solution) hydroxide solutions have proven satisfactory; some of these have produced current densities of more than 8 A/sq cm. None of the amalgam cathodes have approached this performance although the TI(Hg) has delivered 1 A/sq cm. Se(Hg) and Te(Hg) cathodes have given very stable discharges. Zn(Hg) and Cd(Hg) electrodes did not show good high rate characteristics, 200 to 300 mA/sq cm being about the maximum current densities obtainable. Both anodes are charged through a two-step process in which M(Hg) is first formed electrochemically and subsequently reduces Zn(II or Cd(II) to form the corresponding amalgam. The second step is extremely rapid for zinc and very slow for cadmium.
The preparation and evaluation of zinc orthotitanate and of several new pigments and the environmental testing and evaluation of these pigments and of coatings made from them constitute the bulk of the work accomplished. New pigments were prepared and EPR spectra of pigments and their precursor compounds studied. Results of extensive testing of commercially-available, strippable, protective coatings are reported; Owens-Illinois 650 glass resin has been stabilized against progressive mechanical failures; and definite improvements have been noted. A zinc oxide pigmented lithium silicate paint has demonstrated very good ultraviolet stability.
An error was noticed recently in the computer program used to reduce the laboratory sonic measurements to tabulated values of Young's modulus of the bulk samples of experimental glasses. Correction of this error gave revised values for the last fifty experimental glasses prepared in this laboratory. This corrected data, when examined as input material for the calculation of Young's modulus of bulk glasses from composition by the C. J. Phillips procedure, resulted in new values for the contribution per mol of several oxides. The new value for the zinc oxide molal factor is especially significant since it is slightly greater than the factor for beryllia for the types of glasses melted in the UARL research program. This discovery provides a new tool in the search for nontoxic, i.e. without beryllia, high modulus glass fibers particularly when coupled with recent measurements that showed zinc oxide contributes significantly to increased impact strength. New glass compositions prepared in this period and the latest impact strength values measured are also included.
Completion of testing and failure analysis of MDC 40 Ahr silver zinc cells containing largely inorganic separators was accomplished. The results showed that the wet stand and cycle life objectives of the silver zinc cell development program were accomplished. Building, testing and failure analysis of two plate cells employing three optimum separators selected on the basis of extensive screening tests, was performed. The best separator material as a result of these tests was doped calcium zirconate.
The structure of a new separator material for electrochemical cells has been investigated. Investigation into details of the separator structure showed it to be multilayered and to consist mainly of a quasi-impervious organic skin, a porous region of mixed organic and inorganic material, and an area of nonuniformly treated substrate. The essential feature of the coating (slurry) is believed to be interconnected pores which allow ionic conductivity. The interconnected pores are believed to be formed by the interaction of the plasticizer and inorganic fibers. The major failure mode of silver zinc cells using such a separator (zinc nodules shorting adjacent plates) was investigated.
Optimum solar selective properties of black chrome require some tailoring of current and time for plating solution being used. Black zinc is produced from high zinc electroplate by subsequent conversion with chromate dip. Measurements have also been made of reflectance of previously known solar selective coatings of black copper and electroplated black nickel.
Ceramic enamel is found to be more solar selective, (i.e., has high solar absorptance in combination with low infrared emittance) than organic enamel, but neither is as solar selective as black chrome, black copper, black zinc, or black nickel. Ceramic enamel is matched only by black chrome in durability and wide availability. Ceramic enamel and organic enamel have approximately the same cost, and both are currently slightly lower in cost than black chrome, black copper, or black zinc. Black nickel is relatively unavailable and, because of that, realistic cost comparisons are not possible.