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Shallow acceptors in single crystal CdTe induced by Group V (P, As, and Sb) doping are identified by thermoelectric effect spectroscopy (TEES). Understanding defects in Group V doped CdTe is critical to improving and controlling the acceptor density and lifetime in the absorber material which is an important factor determining the open circuit voltage and efficiency in CdTe solar cells.
Los Alamos National Laboratory (LANL) is a multidisciplinary national laboratory that conducts research and development in national security, engineering, materials science, computational modeling, and advanced manufacturing. The laboratory develops innovative technologies to address complex scientific and engineering challenges. This project focuses on the development and evaluation of high-performance absorbing structures through computational design, simulation, and engineering analysis. Absorbing structures are used in applications where damage mitigation, structural protection, and material efficiency are critical performance requirements. The increasing demand for lightweight, high-strength, and highly efficient structural systems has created a need for improved design methodologies capable of maximizing absorption while minimizing weight and material usage. The project utilizes advanced engineering software, including 3D CAD software and FEA, to generate and optimize structural concepts. Computational simulations are performed to evaluate structural behavior under loading conditions, while mathematical analyses are conducted using Python-based tools as well as established analytical equations from material and structural mechanics. The project benefits LANL by supporting the development of advanced design methodologies and improving the understanding of material and structural performance. During the internship term, a significant portion of the design development, simulation, and data analysis activities will be completed. Success of the project depends on collaboration among engineering mentors and technical staff members. Work will be conducted at Los Alamos National Laboratory using laboratory computing resources and engineering software.
Propellers with equal total blade area, but with different numbers, were tested at Stanford University. The tests show generally that, for equal total blade area, propellers with the larger number of blades absorb the greater power and, provided hubs have equal drag, develop the higher efficiency. It is shown that the differences found are in agreement, qualitatively, with what might be predicted from simple blade-element theory.
A theoretically perfectly absorbing photoconductive all-dielectric metasurface is provided. This metasurface can improve the efficiency and performance of ultrafast photoconductive switches and detectors. In an embodiment, the metasurface is incorporated in photoconductive THz switches or detectors. In embodiments, the metasurface is constituted by a network of gallium arsenide resonators. Each resonator supports two degenerate and critically coupled magnetic dipole modes. Simultaneous excitation of these two modes leads to theoretically close-to-perfect optical absorption near the resonant wavelength.
A general device-analysis program has been utilized to study the efficiency of silicon solar cells. The analysis is applied to specific geometries of both n(+)-p and n(+)-p-p(+) solar cells, and involves a numerical solution of the basic transport and continuity equations. This approach allows solutions that are free of typical limiting assumptions involved in solving the device equations as well as solutions relating to lifetime, mobility variations, and diffused-region profiles. The analysis includes available empirical information on diffusion length, mobility, and lifetime as a function of doping, as well as a Gaussian profile for the diffused region. Results are presented which illustrate the limitations of efficiency as a function of doping. It is found that the maximum efficiencies for both types of cell converge at lower resistivities to around 16% with air-mass-zero radiation and a single-layer absorbing-SiO antireflecting film. It is also found that the minority-carrier lifetime, both in the n(+) surface and p-type bulk regions, presents serious limitations to conversion efficiency, particularly in the low-resistivity cells.
Reducing the energy loss of sub-cells is critical for high performance tandem organic solar cells, while it is limited by the severe non-radiative voltage loss via the formation of non-emissive triplet excitons. Herein, we develop an ultra-narrow bandgap acceptor BTPSeV-4F through replacement of terminal thiophene by selenophene in the central fused ring of BTPSV-4F, for constructing efficient tandem organic solar cells. The selenophene substitution further decrease the optical bandgap of BTPSV-4F to 1.17 eV and suppress the formation of triplet exciton in the BTPSV-4F-based devices. The organic solar cells with BTPSeV-4F as acceptor demonstrate a higher power conversion efficiency of 14.2% with a record high short-circuit current density of 30.1 mA cm –2 and low energy loss of 0.55 eV benefitted from the low non-radiative energy loss due to the suppression of triplet exciton formation. We also develop a high-performance medium bandgap acceptor O1-Br for front cells. By integrating the PM6:O1-Br based front cells with the PTB7-Th:BTPSeV-4F based rear cells, the tandem organic solar cell demonstrates a power conversion efficiency of 19%. The results indicate that the suppression of triplet excitons formation in the near-infrared-absorbing acceptor by molecular design is an effective way to improve the photovoltaic performance of the tandem organic solar cells.
CdTe solar cell technology is one of the lowest-cost methods of generating electricity in the solar industry, benefiting from fast CdTe absorber deposition, CdCl 2 treatment and Cu doping. However, Cu doping has low photovoltage and issues with instability. Doping group V elements into CdTe is therefore a promising route to address these challenges. Although high-temperature in situ group V doped CdSeTe devices have demonstrated efficiencies exceeding 20%, they face obstacles including post-deposition doping activation processes, short carrier lifetimes and low activation ratios. Here, we demonstrate low-temperature and effective ex situ group V doping for CdSeTe solar cells using group V chlorides. For AsCl 3 doped CdSeTe solar cells, the dopant activation ratio can be 5.88%, hole densities reach >2 × 10 15 cm -3 and carrier lifetime is longer than 20 ns. Thus, ex situ As doped CdSeTe solar cells show open-circuit voltages ~863 mV, compared to the highest open-circuit voltage of 852 mV for Cu doped CdSeTe solar cells.
Liquid desiccants can provide efficient dehumidification but have yet to see widespread adoption. Most systems studied previously use natural gas-combustion to heat and regenerate the desiccant, and a central chiller plant or cooling tower for removing the heat of absorption. Here we present modeling and experimental results on a novel packaged air conditioner integrating liquid-desiccant heat and mass exchangers with a vapor compression cycle. The packaged system does not need cold or hot water from a central plant or cooling tower and is suitable for rooftop unit air conditioners. The system uses the evaporator to cool the liquid desiccant that is absorbing moisture from the air, and the condenser to heat the liquid desiccant to regenerate it. Efficiency is improved by reducing the load on the evaporator for a given supply-air dewpoint. This paper presents the measured dehumidification efficiency for a 10- ton packaged air conditioner, focusing on dehumidifying ventilation air. The paper also presents a numerical model to predict the outlet conditions and dehumidification efficiency, which we compare with the measured data.
Vanadium-based membranes have great potential for hydrogen purification due to their perfect selectivity, high permeability, and relatively low cost. With appropriate surface cleaning, V efficiently permeates hydrogen at elevated temperature, but performance declines due to its affinity to absorb impurities. Here, the application of palladium thin films maintains a clean surface that catalyzes hydrogen dissociation and recombination. Hydrogen permeation in Pd-V-Pd membranes initially reach theoretical permeability, but declines due to Pd-V interdiffusion. The objective of this work was to quantify the intermetallic diffusion process as a function of temperature and ambient. Pd-V composites were subjected to various annealing treatments and characterized using Auger electron spectroscopy, X-ray diffraction, and energy dispersive X-ray spectroscopy, as well as correlated to measurements of membrane permeability. In an inert environment Pd-V interdiffusion was observable as low as 300 °C, and the diffusion coefficient had an activation energy of 44 kJ/mol. Furthermore, the presence of hydrogen at partial pressures > 10 kPa accelerated interdiffusion six-fold at T = 400 °C. Membrane performance degraded with an activation energy 75 kJ/mol, suggesting that intermetallic diffusion leads to both a loss of catalytic activity and as well as degradation of bulk permeability. These findings provide a baseline for evaluating hydrogen permeable interdiffusion barriers to overcome these challenges.
The activation of the C(sp 3 )–F bond is extremely difficult due to its unreactive nature. The importance of this bond activation is recently highlighted because extensive distribution of perfluorocarboxylic acids (PFCAs) (C n F 2n+1 COOH) has emerged as a challenging environmental issue. Photocatalytic degradation of PFCAs over a few semiconducting light absorbers is known to remove these water and soil resilient contaminants but with limited efficiency. This work reports density functional theory calculations, through which we present a detailed mechanistic study of photocatalytic degradation of CF 3 COOH (the shortest member of the PFCA family) over hexagonal boron nitride (h-BN). Here, our results clearly demonstrate that the existence of point defects is necessary to activate the h-BN plane for photocatalytic dissociation of the C–F bond. Specifically, we show that vacancies create strong Lewis acid or base sites (B or N vacancy, respectively) that facilitate the activation of the C(sp 3 )–F bond considerably. Furthermore, this study presents vivid theoretical evidence for the significant role of oxygen dopants, which mitigate the strength of the active sites and promote PFCA degradation over h-BN. Our calculations suggest that while the very stable intermediates generated during the reaction, in the case of h-BN with B or N vacancies, practically poison the catalyst, oxygen dopants make the degradation much more plausible and controllable. This work thus provides both an explanation for recently observed photocatalytic activity of h-BN to decompose PFCAs and valuable insights for exploring defected two-dimensional materials for activating and removing the fluorine-containing contaminants from water and soil.
Kirchhoff’s law of thermal radiation imposes a constraint on photon-based energy harvesting processes since part of the incident energy flux is inevitably emitted back to the source. By breaking the reciprocity of the system, it is possible to overcome this restriction and improve the efficiency of energy harvesting. Here, we design and analyze a semitransparent emitter that fully absorbs normally incident energy from a given direction with zero backward and unity forward emissivity. The nearly ideal performance with wavelength-scale thickness is achieved due to the magneto-optical effect and the guided-mode resonance engineered in the emitter structure. We derive the general requirements for the nonreciprocal emitter using the temporal coupled mode theory and the symmetry considerations. As a result, we provide a realistic emitter design based on a photonic crystal slab consisting of a magnetic Weyl semimetal and silicon.
Wide-bandgap (WBG) mixed-halide perovskites as the front cell absorber are accomplishing perovskite-based tandem solar cells with over 29% power conversion efficiency. However, their large voltage deficits limit their ultimate performance. Only a handful of studies probe the fundamental mechanisms underlying the voltage deficits, which remain an unsolved challenge in the field. In this study, we investigate the formation dynamics and defect physics of WBG mixed-halide perovskites in contrast with their corresponding triiodide-based perovskites. Our results show that the inclusion of bromide introduced a halide homogenization process that occurs during the perovskite growth stage from an initial bromide-rich phase toward the final target stoichiometry. We further elucidated a physical model that correlates the role of bromide with the formation dynamics, defect physics, and eventual optoelectronic properties of the film. This work provides a fundamental and unique perspective toward understanding the performance-limiting factors affecting WBG mixed-halide perovskites.
The goal of the project is on understanding the principles of non-covalent assembling of tunable functional materials with various nanocrystals in order to control light-matter interactions by changing localized interfacial refractive properties, coupling parameters, or the ionic environment of surrounding media. We explore novel soft functional matrices with controlled physical properties via the application of light, mechanical stresses, ionic environment, and electrical potential. These functional matrices is used in conjunction with novel anisotropic inorganic nanostructures such as noble metal/metal alloy anisotropic nanostructures with complex optical properties (multiple LSPR modes) and quantum dots with light-emissive or absorbing properties in a broad spectral range from the UV to the NIR for efficient solar energy absorption and light conversion.
In order to determine the efficiency of a propeller as accurately as possible, its revolution speed, thrust and power absorbed must be measured during flight. Unfortunately, these measurements can only be made with very complicated equipment. To surmount this problem the testers contented themselves with approximate results obtainable in two or three hours of flight.
Applying Hines Doppler Spread Parameterization for gravity waves (GW), our 3D model reproduces some essential features that characterize the observed seasonal variations of tides and planetary waves in the upper mesosphere. In 2D, our model also reproduces the large Semi-Annual Oscillation (SAO) and Quasi Biennial Oscillation (QBO) observed in this region at low latitudes. It is more challenging to describe these features combined in a more comprehensive self consistent model, and we give a progress report that outlines the difficulties and reports some success. In 3D, the GW's are partially absorbed by tides and planetary waves to amplify them. Thus the waves are less efficient in generating the QBO and SAO at equatorial latitudes. Some of this deficiency is compensated by the fact that the GW activity is observed to be enhanced at low latitudes. Increasing the GW source has the desired effect to boost the QBO, but the effect is confined primarily to the stratosphere. With increasing altitude, the meridional circulation becomes more important in redistributing the momentum deposited in the background flow by the GW's. Another factor involved is the altitude at which the GW's originate, which we had originally chosen to be the surface. Numerical experiments show that moving this source altitude to the top of the troposphere significantly increases the efficiency for generating the QBO without affecting much the tides and planetary waves in the model. Attention to the details in which the GW source comes into play thus appears to be of critical importance in modeling the phenomenology of the MLT. Among the suite of numerical experiments reported, we present a simulation that produced significant variations of tides and planetary waves in the upper mesosphere. The effect is related to the QBO generated in the model, and GW filtering is the likely cause.
Four papers have been written. One reports on the major study funded by this grant: a pan-chromatic study of the quasar continuum at redshift 3. Two others make use of the quasar continuum shapes to find the minimum total accretion luminosity of the Universe, and hence the efficiency and spin of supermassive black holes; the second shows that the reemission of absorbed quasar radiation alleviates a major problem with galaxy formation and the FIR background. The last paper recognizes the role quasars may play in the initial formation of dust in the early Universe.
Quantum well infrared photodetector technology has shown remarkable success by realizing large-format focal plane arrays in both broad-bands and in multi-bands. The spectral response of these detectors based on the III-V material system are tailorable within the mid and long wavelength IR bands (similar to 3-25 mu m) and possibly beyond. Multi-band and broad-band detector arrays have been developed by vertically integrating stacks of multi quantum wells tailored for response in different wavelengths bands. Each detector stack absorbs photons within the specified wavelength band while allowing the transmission other photons, thus efficiently permitting multiband detection. Flexibility in many design parameters of these detectors allows for tuning and tailoring the spectral shape according to application requirements, specifically for spectral imaging instruments.
Climate change in tundra regions may alter vegetation species composition and ecosystem carbon balance. Remote sensing provides critical tools for monitoring these changes as optical signals provide a way to scale from plot measurements to regional patterns. Gas exchange measurements of pure patches of key vegetation functional types (lichens, mosses, and vascular plants) in sedge tundra at Barrow AK, show three significantly different values of light use efficiency (LUE) with values of 0.013+/-0.001, 0.0018+/-0.0002, and 0.0012 0.0001 mol C/mol absorbed quanta for vascular plants, mosses and lichens, respectively. Further, discriminant analysis of patch reflectance identifies five spectral bands that can separate each vegetation functional type as well as nongreen material (bare soil, standing water, and dead leaves). These results were tested along a 100 m transect where midsummer spectral reflectance and vegetation coverage were measured at one meter intervals. Area-averaged canopy LUE estimated from coverage fractions of the three functional types varied widely, even over short distances. Patch-level statistical discriminant functions applied to in situ hyperspectral reflectance successfully unmixed cover fractions of the vegetation functional types. These functions, developed from the tram data, were applied to 30 m spatial resolution Earth Observing-1 Hyperion imaging spectrometer data to examine regional variability in distribution of the vegetation functional types and from those distributions, the variability of LUE. Across the landscape, there was a fivefold variation in tundra LUE that was correlated to a spectral vegetation index developed to detect vegetation chlorophyll content.