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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Radiometer gives true absorption and emission coefficients

Novel radiometer, unaffected by scattering and polarization, measures true absorption and emmission coefficients for arbitrary mixture of gases and polluting particles. It has potential astronomical, meteorological, and environmental applications, such as determination of radiative heat budget, aerosol relative concentration, and morphology of cloud, haze, and fog formations. Data and temperature can be coupled directly to small computer for online calculation of radiation coefficients.

Fymat, A. L.↗
DOE OSTI2021

Laser absorption measurements of electron density in nanosecond-scale atmospheric pressure pulsed plasmas

We report on time-resolved measurements of electron number density by continuous-wave laser absorption in a low-energy nanosecond-scale laser-produced spark in atmospheric pressure air. Laser absorption is a result of free-free and bound-free electron excitation, with the absorption coefficient modeled and evaluated using estimates of the time-variation in electron temperature and probe laser absorption path length. Plasma electron number densities are determined to be as high as n e = 7 x 10 19 cm -3 , and decay to 1/e of their peak values over a period of about 50 ns following plasma formation using a 20 mJ, 10 ns pulse width frequency-doubled Nd:YAG laser. The measured plasma densities at later times are shown to be in reasonable agreement with Stark broadening measurements of the 3s[ 5 S o ]-3p[ 5 P] electronic transition in atomic oxygen at 777 nm. This study provides support for the use of such continuous wave laser absorption for time resolved electron density measurements in low energy spark discharges in air, provided that an estimate of the electron temperature and laser path length can be made by accompanying diagnostics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2024

Symmetry Protected Two-Photon Coherence Time

We report the observation of symmetry protected two-photon coherence time of biphotons generated from backward spontaneous four-wave mixing in laser-cooled 87 Rb atoms. When biphotons are nondegenerate, nonsymmetric photonic absorption loss results in exponential decay of the temporal waveform of the two-photon joint probability amplitude, leading to shortened coherence time. In contrast, in the case of degenerate biphotons, when both paired photons propagate with the same group velocity and absorption coefficient, the two-photon coherence time, protected by space-time symmetry, remains unaffected by medium absorptive losses. Furthermore, our experimental results validate these theoretical predictions. This outcome highlights the pivotal role of symmetry in manipulating and controlling photonic quantum states.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1975

Effects of high energy simulated space radiation on polymeric second-surface mirrors

A radiation effects experimental program was performed, in which second surface mirror type thermal control coatings were exposed to ultraviolet radiation, electrons, and protons simultaneously. Stability was assessed by making periodic spectral reflectance measurements in situ (and in air after testing for comparison). Solar absorption coefficients were derived by computer. Many of the exposed materials showed large amounts of degradation in reflectance absorptance, principally due to the electron exposure. A series of tests was conducted, leading to the identification of a modified second surface mirror that shows considerable improvement and promise for stability during thermal control applications in a charged particle space radiation environment.

Eogdall, L. B.↗
NASA NTRS1991

Infrared radiative energy transfer in gaseous systems

Analyses and numerical procedures are presented to investigate the radiative interactions in various energy transfer processes in gaseous systems. Both gray and non-gray radiative formulations for absorption and emission by molecular gases are presented. The gray gas formulations are based on the Planck mean absorption coefficient and the non-gray formulations are based on the wide band model correlations for molecular absorption. Various relations for the radiative flux and divergence of radiative flux are developed. These are useful for different flow conditions and physical problems. Specific plans for obtaining extensive results for different cases are presented. The procedure developed was applied to several realistic problems. Results of selected studies are presented.

Tiwari, Surendra N.↗
DOE OSTI2018

Absorption at San Antonio with 3-Wavelength Photo Acoustic Soot Spectrometer, Tricolor Absorption Photometer (ASAPT) Field Campaign Report

Fine particulate matter (PM2.5; particulate matter with an aerodynamic diameter of 2.5μm and smaller) samples were collected at the University of Texas, San Antonio (UTSA) campus (29.57901, -98.62889) from May 15-30. An additional measurement at the UTSA site included aerosol absorption coefficient of PM1 (particulate matter with an aerodynamic diameter of 1.0μm and smaller) using a tricolor absorption photometer (TAP) (Brechtel Mfg. Inc., Hayward, California). The sampling site is approximately 15 miles northwest of downtown San Antonio and in close proximity to major highway 10 and is just south of a forested area. The setup of the sampler and TAP and collection of PM2.5 samples were completed by Baylor University’s graduate student, Subin Yoon. Three three-wavelength photoacoustic soot spectrometers (PASS-3s) were shipped to San Antonio for testing and possible data collection. R. Subramanian went to San Antonio to lead this effort with assistance from Yoon. Each instrument had a critical flaw that inhibited its use for this campaign. Two instruments had low laser power for each wavelength; in addition, there were power and overheating issues with the one instrument that was installed on a test basis. The third instrument had computer issues that impeded any testing. In short, these three instruments would require a major overhaul in terms of lasers and computer systems to be brought back to field capability. As a result, the filter-based optical measurements were added to the campaign as an alternate measurement that would provide mass absorption efficiency at a single wavelength, but no scattering measurement. The TAP instrument was successfully installed and collected data for San Antonio, but full use of the data would have required a co-located scattering measurement. This campaign was co-located with a Texas Commission on Environmental Quality (TCEQ) ozone field study. That TCEQ field study was a collaboration of the University of Houston (PI James Flynn), Rice University (Co-PI Robert Griffen), and Baylor University (Co-PIs Rebecca Sheesley and Sascha Usenko).

aerosols, tricolor absorption photometer, three-wa↗
DOE OSTI2016

Synthesis of self-organized TiO{sub 2} nanotube arrays: Microstructural, stereoscopic, and topographic studies

In this work, titanium dioxide nanotubes were prepared by using titanium foils via electrochemical anodization in ethylene glycol solutions containing different amounts of water and fluoride in the ranges of 1%–3% and 0.15%–0.5%, respectively, to determine their effects on morphology, optical, and crystalline structure properties. Annealing processes were performed on all samples in the range between 273 and 723 K. Morphology and structure properties of the samples were studied by scanning electron microscopy, X-ray diffraction (XRD), and transmission electron microscopy. Titanium dioxide (TiO{sub 2}) nanotubes, through anodization method, are strongly influenced by conditions, like fluoride concentration and applied voltages. Tube lengths between 2 and 7 μm were obtained, exhibiting different diameters and wall thicknesses. When alternating voltage was applied, the outer surface of the nanotubes exhibited evenly spaced ring-shaped regions, while smooth tubes were observed when constant voltage was applied. Reflection peaks, corresponding to Brookite, Anatase, and Rutile, of TiO{sub 2} phases, were observed from the XRD pattern. These phases were corroborated via μXRD measurements, and the Ti{sub 3}O{sub 5} phase was also observed in detail. Absorption coefficient (α), optical band gap (Eg), and extinction coefficient (ε) of TiO{sub 2} nanotubes were calculated by transmittance spectra in the UV–Vis range. Strong absorption was noted in the UV region from reflectance and absorbance measurements. A correlation between synthesis parameters and physical properties is presented.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Intraband Radiation Absorption by Holes in InAsSb/AlSb and InGaAsP/InP Quantum Wells

Microscopic analysis of intraband radiation absorption by holes with their transition to the spin-split band for InAsSb/AlSb and InGaAsP/InP semiconductor quantum wells is performed in the context of the four-band Kane model. The calculation is performed for two incident-radiation polarizations: along the crystal-growth axis and in the quantum-well plane. It is demonstrated that absorption with transition to the discrete spectrum of spin-split holes has a higher intensity than absorption with transitions to the continuous spectrum. The dependences of the intraband absorption coefficient on temperature, hole density, and quantum- well width are thoroughly analyzed. It is shown that intraband radiation absorption can be the main mechanism of internal radiation losses in lasers based on quantum wells.

36 MATERIALS SCIENCE↗
NASA NTRS1981

On the theory of Gamma Ray Amplification through Stimulated Annihilation Radiation (GRASAR)

The theory of photon emission, absorption, and scattering in a relativistic plasma of positrons, electrons, and photon was studied. Expressions for the emissivities and absorption coefficients of pair annihilation, pair production, and Compton scattering are given and evaluated numerically. The conditions for negative absorption were investigated. In a system of photons and e(+) - e(-) pairs, an emission line at at approximately 0.43 MeV can be produced by grasar action provided that the pair chemical potential exceeds approximately 1 MeV. At a temperature of approximately 10 to the 9th power. This requires a pair density approximately 10 to the 30th power cm to the (-3) power a value much larger than the thermodynamic equilbrium pair density at this temperature. This emission line could account without a gravitational redshift for the observed lines at this energy from gamma ray bursts.

Ramaty, R.↗
DOE OSTI2020

Role of water vapour in the absorption of nanosecond 266-nm laser pulses by atmospheric air

The absorption of the Nd : YAG fourth harmonic in air and binary mixtures of water vapour with nitrogen and oxygen at atmospheric pressure has been measured as a function of pulse energy (peak intensity). The mixtures obtained by adding equal amounts of water vapour to dry nitrogen and oxygen have been found to differ significantly in absorption. Preliminary quantitative data have been obtained for two- and three-photon absorption cross sections of water and oxygen molecules: σ{sup (2)}(H{sub 2}O) = (4 ± 1) ± 10{sup –49} cm{sup 4} s and σ{sup (3)}(O{sub 2}) = (5.6 ± 1.4) ± 10{sup –78} cm{sup 6} s{sup 2}. The absorption of 266-nm pulses with peak intensities from 0.05 to 2 GW cm{sup –2} in the near-surface atmosphere has been shown to be determined by two-photon absorption in water vapour and three-photon absorption in oxygen. In moist air containing 1 % water vapour, the absorption coefficient for 266-nm laser pulses exceeds that in dry air by four to five times. There is no absorption in nitrogen. We have developed a technique for photoacoustic measurements of multiphoton absorption cross sections in single-component gases and gas mixtures. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1971

Vibration-rotation double resonance effects in symmetrical top molecules.

Rotational transitions in symmetrical top molecules in the wavelength regions of 1-3 mm are sufficiently strong to be observed directly on an oscilloscope. Changes in the vibrational level populations induced by laser radiations affect the intensity of the rotational transitions. Observation of the microwave lines under the influence of chopped laser radiation shows a variety of interesting and potentially informative effects. At pressures above a few tenths of a torr the effect of laser radiation is to reduce the microwave response. This is true for all microwave lines at all those laser frequencies which are absorbed by the gas, and this effect is roughly proportional to the absorption coefficient. The rise and decay times of this effect increase with pressure and the the linear dimensions of the absorption cell. At low pressures the microwave response may increase, decrease, or remain unaffected depending on the observed microwave transitions and the specific laser line applied to the gas.

Marantz, H.↗
NASA NTRS1984

Ice-Soil Mixtures: Visual and Near-Infrared Remote Sensing Techniques

The spectral properties of ice soil mixtures are reviewed. Water ice has an absorption coefficient which varies by several orders of magnitude in the visual and near infrared, and has several prominent overtone absorptions. Different wavelengths can be used to probe to different depths in the surface as well as for different mineral impurity concentrations. Empirical and/or theoretical models might be used to derive characteristics grain size of the ice or of the impurity minerals and to derive abundance of the ice and rock or soil components. Quantitative analysis of remotely obtained reflectance spectra can only be performed by using absorption features in the spectra of ice and soil, and not by broadband response. It is suggested that this might be done by special selection of several narrow band filters in the near infrared which will adequately define the ice absorptions.

Clark, R. N.↗
NASA NTRS1981

Laboratory measurements of selected optical, physical, chemical, and remote-sensing properties of five water mixtures containing Calvert clay and a nonfluorescing dye

Total suspended solids concentrations ranged from 6.1 ppm to 24.3 ppm and sizes ranged between 1.5 micrometers and 10 micrometers with the most frequently occurring size less than 2 micrometers. Iron concentration was less than 1 percent of the total suspended solids. Nonfluorescing dye concentrations of the two mixtures were 20 ppm and 40 ppm. Attenuation coefficient for the five mixtures ranged from 4.8/m to 21.3/m. Variations in volume scattering function with phase angle were typical. Variations in attenuation and absorption coefficient with wavelength were similar for the mixtures without the dye. Attenuation coefficient of the mixtures with the dye increased for wavelengths less than 600 nm due to the dye's strong absorption peak near 500 nm. Reflectance increased as the concentration of Calvert clay increased and peaked near 600 nm. The nonfluorescent dye decreased the magnitude of the peak, but had practically no effect on the variation for wavelengths greater than 640 nm. At wavelengths less than 600 nm, the spectral variations of the mixtures with the dye were significantly different from those mixtures without the dye.

Usry, J. W.↗
DOE OSTI2017

Two-photon absorption measurements of deep UV transmissible materials at 213 nm

We report on two photon absorption measurements at 213nm of deep UV transmissible media including LiF, MgF 2 , CaF 2 , BaF 2 , Sapphire (Al 2 O 3 ) and high purity grades of fused-silica (SiO 2 ). A high stability 24ps Nd:YAG laser operating at the 5th harmonic (213nm) was used to generate a high intensity, long Rayleigh length Gaussian focus inside the samples. The measurements of the Fluoride crystals and Sapphire indicate two photon absorption coefficients between 0.004 and 0.82 cm/GW. We find that different grades of fused silica performed near identically for two photon absorption, however, there are differences in linear losses associated with purity. A low two photon absorption cross section is measured for MgF 2 making it an ideal material for the propagation of high intensity deep UV lasers.

36 MATERIALS SCIENCE↗
NASA NTRS1976

Complex refractive index of Martian dust - Mariner 9 ultraviolet observations

Mariner 9 ultraviolet spectrometer observations of the 1971 dust clouds obscuring the surface of Mars have been analyzed by matching the observed dust phase function with Mie scattering calculations for size distributions of homogeneous and isotropic material. Preliminary results indicate an effective particle radius of not less than 0.2. The real component of the index of refraction is not less than 1.8 at both 268 and 305 nm; corresponding values for the imagery component are 0.02 and 0.01. These values are consistent with those found by Mead (1970) for the visible and near-visible wavelengths. The refractive index and the absorption coefficient increase rapidly with decreasing wavelength in going from the visible to the ultraviolet, indicating the presence of an ultraviolet absorption band which may shield organisms from ultraviolet irradiation.

Pang, K.↗
NASA NTRS1993

Near-surface temperature gradients and their effects on thermal-infrared emission spectra of particulate planetary surfaces

The infrared energy emitted from a planetary surface is generated within a finite depth determined by the material's absorption skin depth. This parameter varies significantly with wavelength in the infrared but has an average value of around 50 microns for most geologic materials. In solid rock, heat transfer is efficient enough so that this 50 micron zone of the near surface from which the radiation emanates will be more or less isothermal. In particulate materials, however, heat transfer is more complicated and occurs via a combination of mechanisms, including solid conduction within grains and across grain contacts, conduction through the interstitial gas, and thermal radiation within individual particles and across the void spaces in between grains. On planets with substantial atmospheres, the gas component dominates the heat transfer and tends to mitigate near-surface thermal gradients. However, on airless bodies, the gas component is absent and heat transfer occurs via solid conductions and radiation. If the particles are small relative to the average absorption skin depth, then the top 50-100 microns or so of the surface will be cooled by radiation to space allowing the creation of significant near-surface thermal gradients. In those regions of the spectrum where the absorption coefficient is low, the emission will come from the deeper, warmer parts of the medium, whereas in regions of high absorption, the emission will emanate from shallower, cooler parts of the medium. The resulting emission spectrum will show non-compositional features as a result of the thermal structure in the material. We have modeled the heat transfer in a particulate medium in order to determine the magnitude of near-surface thermal gradients for surfaces on airless bodies and on Mars. We use the calculated thermal structure to determine the effects it has on the infrared emission spectrum of the surface.

Henderson, B. G.↗
NASA NTRS2005

Bio-Optics of the Chesapeake Bay from Measurements and Radiative Transfer Calculations

We combined detailed bio-optical measurements and radiative transfer (RT) modeling to perform an optical closure experiment for optically complex and biologically productive Chesapeake Bay waters. We used this experiment to evaluate certain assumptions commonly used when modeling bio-optical processes, and to investigate the relative importance of several optical characteristics needed to accurately model and interpret remote sensing ocean-color observations in these Case 2 waters. Direct measurements were made of the magnitude, variability, and spectral characteristics of backscattering and absorption that are critical for accurate parameterizations in satellite bio-optical algorithms and underwater RT simulations. We found that the ratio of backscattering to total scattering in the mid-mesohaline Chesapeake Bay varied considerably depending on particulate loading, distance from land, and mixing processes, and had an average value of 0.0128 at 530 nm. Incorporating information on the magnitude, variability, and spectral characteristics of particulate backscattering into the RT model, rather than using a volume scattering function commonly assumed for turbid waters, was critical to obtaining agreement between RT calculations and measured radiometric quantities. In situ measurements of absorption coefficients need to be corrected for systematic overestimation due to scattering errors, and this correction commonly employs the assumption that absorption by particulate matter at near infrared wavelengths is zero.

Tzortziou, Maria↗
DOE OSTI2015

Non-resonant below-bandgap two-photon absorption in quantum dot solar cells

We study the optically nonlinear sub-bandgap photocurrent generation facilitated by an extended tailing distribution of states in an InAs/GaAs quantum dots (QDs) solar cell. The tailing states function as both the energy states for low energy photon absorption and the photocarriers extraction pathway. One of the biggest advantages of our method is that it can clearly differentiate the photocurrent due to one-photon absorption (1PA) process and two-photon absorption (2PA) process. Both 1PA and 2PA photocurrent generation efficiency in an InAs/GaAs QD device operated at 1550 nm have been quantitatively evaluated. A two-photon absorption coefficient β = 5.7 cm/GW is extracted.

77 NANOSCIENCE AND NANOTECHNOLOGY↗