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The neutral mass spectrometer on Dynamics Explorer B

A neutral gas mass spectrometer has been developed to satisfy the measurement requirements of the Dynamics Explorer mission. The mass spectrometer, a quadrupole, will measure the abundances of neutral species in the region 300-500 km in the earth's atmosphere. These measurements will be used in concert with other simultaneous observations on Dynamics Explorer to study the physical processes involved in the interactions of the magnetosphere-ionosphere-atmosphere system. The instrument, which is similar to that flown on Atmosphere Explorer, employs an electron beam ion source operating in the closed mode and a discrete dynode multiplier as a detector. The mass range is 22 to 50 amu. The abundances of atomic oxygen, molecular nitrogen, helium, argon, and possibly atomic nitrogen will be measured to an accuracy of about + or - 15% over the specified altitude range, with a temporal resolution of one second.

Carignan, G. R.↗

Laboratory Anion Chemistry: Implications for the DIBs, and a Potential Formation Mechanism for a Known Interstellar Molecule

Due to recent interest in molecular anions as possible interstellar species, we have carried out several laboratory studies of anion chemistry. The reactions of the series C(sub n)(sup -); and C(sub n)H(sup -) with H and H2 were studied to address the viability of such species in the diffuse interstellar medium and to address their ability to be carriers of the diffuse interstellar bands (DIBs). These same molecules were also reacted with N and O to show possible heteroatomic products. C(sub m)N(sup - was a particularly stable product from the reaction of C(sub n)(sup -) + N. C3N(sup -) was further reacted with H to study chemistry that could produce HC3N, a known interstellar species. The reactions were done in a flowing afterglow selected ion flow tube apparatus (FA-SIFT). The anions were generated in an electron impact or cold cathode discharge source and the anion of interest was then selected by a quadrupole mass filter. The selected ion was then reacted with the atomic or molecular species in the flow tube and products were detected by another quadrupole. While the C(sub n)(sup -) species do not appear to be viable DIB carriers, their possible presence could provide a mechanism for the formation of known heteroatomic neutral molecules detected in the interstellar medium (ISM).

Eichelberger, B.↗

Preliminary Spectroscopic Measurements for a Gallium Electromagnetic (GEM) Thruster

As a propellant option for electromagnetic thrusters, liquid ,gallium appears to have several advantages relative to other propellants. The merits of using gallium in an electromagnetic thruster (EMT) are discussed and estimates of discharge current levels and mass flow rates yielding efficient operation are given. The gallium atomic weight of 70 predicts high efficiency in the 1500-2000 s specific impulse range, making it ideal for higher-thrust, near-Earth missions. A spatially and temporally broad spectroscopic survey in the 220-520 nm range is used to determine which species are present in the plasma and estimate electron temperature. The spectra show that neutral, singly, and doubly ionized gallium species are present in a 20 J, 1.8 kA (peak) are discharge. With graphite present on the insulator to facilitate breakdown, singly and doubly ionized carbon atoms are also present, and emission is observed from molecular carbon (CZ) radicals. A determination of the electron temperature was attempted using relative emission line data, and while the spatially and temporally averaged, spectra don't fit well to single temperatures, the data and presence of doubly ionized gallium are consistent with distributions in the 1-3 eV range.

Thomas, Robert E.↗

Measurements of Freestream Fluctuations in the NASA Langley 20-Inch Mach 6 Tunnel

An experimental campaign was conducted to measure and to characterize the freestream disturbance levels in the NASA Langley Research Center 20-Inch Mach 6 Wind Tunnel. A pitot rake was instrumented with fast pressure transducers, hot wires, and an atomic layer thermopile to quantify the fluctuation levels of pressure, mass flux, and heat flux, respectively. In conjunction with these probe-based measurements, focused laser differential interferometry was used to optically measure density fluctuations. Measurements were made at five nominal different unit Reynolds numbers ranging from (3.28 to 26.5) times 10 (sup 6) per meter. The rake was positioned at two different stream-wise locations and several different roll angles to measure flow uniformity within the test section. In general, noise levels were spatially consistent within the tested region. Pitot pressure fluctuation levels ranged from 0.84 percent at the highest Reynolds number tested to 1.89 percent at the lowest Reynolds number tested. Freestream mass-flux fluctuations remained relatively constant between 1.8-2.5 percent of the freestream. The pressure transducers were also used to determine the dominant disturbance speed and angle of propagation. The disturbances were estimated to travel at approximately 54-81 percent of the freestream speed at an angle of approximately 21-44 degrees from the freestream direction, but these measurements had a significant amount of uncertainty. A comparison to previous measurements of pressure made in 2012 and of mass flux made in 1994 show almost no change in the RMS (Root Mean Square) fluctuation of these flow quantities.

Chou, Amanda↗

A Break In the Size-Stellar Mass Relation: Evidence for Quenching and Feedback in Dwarf Galaxies

Mapping stars and gas in nearby galaxies is fundamental for understanding their growth and the impact of their environment. This issue is addressed by comparing the stellar ‘edges’ of galaxies D stellar, defined as the outermost diameter where in situ star formation significantly drops, with the gaseous distribution parameterized by the neutral atomic hydrogen diameter measured at 1M⊙/pc2,DHI. By sampling a broad HI mass range 105M⊙< MHI<1011M⊙, we find several dwarf galaxies withMHI<109M⊙from the field and Fornax Cluster which are distinguished by D stellar>> DHI. For the cluster dwarfs, the average HI surface density near D stellar is∼0.3M⊙/pc2, reflecting the impact of quenching and outside-in gas removal from ram pressure and tidal interactions. In comparison, D stellar/DHI ranges between 0.5–2 in dwarf field galaxies, consistent with the expectations from stellar feedback. Only more massive disk galaxies in the field can thus be characterized by the common assumption that D stellar≲DHI. We discover a break in the D stellar−M⋆relation atm break∼4×108M⊙that potentially differentiates the low mass regime where the influence of stellar feedback and environmental processes more prominently regulates the sizes of nearby galaxies. Our results highlight the importance of combining deep optical and HI imaging for understanding galaxy evolution.

Scaling relations↗

A facility to produce an energetic, ground state atomic oxygen beam for the simulation of the Low-Earth Orbit environment

Because of the continuing commitment to activity in low-Earth orbit (LEO), a facility is under development to produce energetic atmospheric species, particularly atomic oxygen, with energies ranging from 5 to 80 eV. This relatively high flux facility incorporates an ion engine to produce the corresponding specie ion which is charge exchanged to produce a neutral atomic beam. Ion fluxes of around 10(exp 15) sec(exp -1) with energies of 20-70 eV have been achieved. A geometrically augmented inertially tethered charge exchanger (GAITCE) was designed to provide a large column depth of charge exchange gas while reducing the gas load to the low pressure portion of the atomic beam facility. This is accomplished using opposed containment jets which act as collisional barriers to the escape of the dense gas region formed between the jets. Leak rate gains to the pumping system on the order of 10 were achieved for moderate jet mass flows. This system provides an attractive means for the charge exchange of atomic ions with a variety of gases to produce energetic atomic beams.

Ketsdever, Andrew D.↗

Advances in Studies of Electrode Kinetics and Mass Transport in AMTEC Cells (abstract)

Previous work reported from JPL has included characterization of electrode kinetics and alkali atom transport from electrodes including Mo, W, WRh(sub x), WPt(sub x)(Mn), in sodium AMTEC cells and vapor exposure cells, and Mo in potassium vapor exposure cells. These studies were generally performed in cells with small area electrodes (about 1 to 5 cm(sup 2)), and device geometry had little effect on transport. Alkali diffusion coefficients through these electrodes have been characterized, and approximate surface diffusion coefficients derived in cases of activated transport. A basic model of electrode kinetic at the alkali metal vapor/porous metal electrode/alkali beta'-alumina solid electrolyte three phase boundary has been proposed which accounts for electrochemical reaction rates with a collision frequency near the three phase boundary and tunneling from the porous electrode partially covered with adsorbed alkali metal atoms. The small electrode effect in AMTEC cells has been discussed in several papers, but quantitative investigations have described only the overall effect and the important contribution of electrolyte resistance. The quantitative characterization of transport losses in cells with large area electrodes has been limited to simulations of large area electrode effects, or characterization of transport losses from large area electrodes with significant longitudinal temperature gradients. This paper describes new investigations of electrochemical kinetics and transport, particularily with WPt(sub 3.5) electrodes, including the influence of electrode size on the mass transport loss in the AMTEC cell. These electrodes possess excellent sodium transport properties making verification of device limitations on transport much more readily attained.

electrode kinetics alkali atom transport transport↗

Polymers Erosion and Contamination Experiment Being Developed

The Polymers Erosion and Contamination Experiment (PEACE) is currently being developed at the NASA Lewis Research Center by the Electro-Physics Branch in conjunction with students and faculty from Hathaway Brown School in Cleveland. The experiment is a Get Away Special Canister shuttle flight experiment sponsored by the American Chemical Society. The two goals of this experiment are (1) to measure ram atomic oxygen erosion rates of approximately 40 polymers that have potential use in space applications and (2) to validate a method for identifying sources of silicone contamination that occur in the shuttle bay. Equipment to be used in this flight experiment is shown in the schematic diagram. Spacecraft materials subjected to attack by atomic oxygen in the space environment experience significant degradation over the span of a typical mission. Therefore, learning the rates of atomic oxygen erosion of a wide variety of polymers would be of great benefit to future missions. PEACE will use two independent techniques to determine the atomic oxygen erosion rates of polymers. Large (1-in.-diameter) samples will be used for obtaining mass loss. Preflight and postflight dehydrated masses will be obtained, and the mass lost during flight will be determined. Small (0.5-in.-diameter) samples will be protected with isolated particles (such as NaCl crystals) and then exposed to the space environment. After flight, the protective particles will be removed (washed off) and atomic force microscopy (AFM) will be used to measure the erosion depth from protected mesas. Erosion depth measurements are more sensitive than traditional mass measurements and are very useful for materials with low erosion yields or with very low fluence missions.

deGroh, Kim K.↗

Atomic hydrogen as a launch vehicle propellant

An analysis of several atomic hydrogen launch vehicles was conducted. A discussion of the facilities and the technologies that would be needed for these vehicles is also presented. The Gross Liftoff Weights (GLOW) for two systems were estimated; their specific impulses (I sub sp) were 750 and 1500 lb(sub f)/s/lb(sub m). The atomic hydrogen launch vehicles were also compared to the currently planned Advanced Launch System design concepts. Very significant GLOW reductions of 52 to 58 percent are possible over the Advanced Launch System designs. Applying atomic hydrogen propellants to upper stages was also considered. Very high I(sub sp) (greater than 750 lb(sub f)/s/lb(sub m)) is needed to enable a mass savings over advanced oxygen/hydrogen propulsion. Associated with the potential benefits of high I(sub sp) atomic hydrogen are several challenging problems. Very high magnetic fields are required to maintain the atomic hydrogen in a solid hydrogen matrix. The magnetic field strength was estimated to be 30 kilogauss (3 Tesla). Also the storage temperature of the propellant is 4 K. This very low temperature will require a large refrigeration facility for the launch vehicle. The design considerations for a very high recombination rate for the propellant are also discussed. A recombination rate of 210 cm/s is predicted for atomic hydrogen. This high recombination rate can produce very high acceleration for the launch vehicle. Unique insulation or segmentation to inhibit the propellant may be needed to reduce its recombination rate.

Palaszewski, Bryan A.↗

Atomic hydrogen as a launch vehicle propellant

An analysis of several atomic hydrogen launch vehicles was conducted. A discussion of the facilities and the technologies that would be needed for these vehicles is also presented. The Gross Liftoff Weights (GLOW) for two systems were estimated; their specific impulses (I sub sp) were 750 and 1500 lb (sub f)/s/lb(sub m). The atomic hydrogen launch vehicles were also compared to the currently planned Advanced Launch System design concepts. Very significant GLOW reductions of 52 to 58 percent are possible over the Advanced Launch System designs. Applying atomic hydrogen propellants to upper stages was also considered. Very high I(sub sp) (greater than 750 1b(sub f)/s/lb(sub m) is needed to enable a mass savings over advanced oxygen/hydrogen propulsion. Associated with the potential benefits of high I(sub sp) atomic hydrogen are several challenging problems. Very high magnetic fields are required to maintain the atomic hydrogen in a solid kilogauss (3 Tesla). Also the storage temperature of the propellant is 4 K. This very low temperature will require a large refrigeration facility for the launch vehicle. The design considerations for a very high recombination rate for the propellant are also discussed. A recombination rate of 210 cm/s is predicted for atomic hydrogen. This high recombination rate can produce very high acceleration for the launch vehicle. Unique insulation or segmentation to inhibit the propellant may be needed to reduce its recombination rate.

Palaszewski, Bryan A.↗

Solar concentrator materials development

Materials with potential applications in reflective and refractive solar dynamic concentrators are tested for resistance to atomic oxygen degradation. It is found that inorganic coatings such as MgF2, SiO(x), and ITO provide excellent protection for reflective surfaces while organic materials are much more susceptible to erosion and mass loss. Of the organic polymers tested, the silicones have the highest intrinsic resistance to atomic oxygen degradation.

Morel, D. E.↗

Advances in atomic oxygen simulation

Atomic oxygen (AO) present in the atmosphere at orbital altitudes of 200 to 700 km has been shown to degrade various exposed materials on Shuttle flights. The relative velocity of the AO with the spacecraft, together with the AO density, combine to yield an environment consisting of a 5 eV beam energy with a flux of 10(exp 14) to 10(exp 15) oxygen atoms/sq cm/s. An AO ion beam apparatus that produces flux levels and energy similar to that encountered by spacecraft in low Earth orbit (LEO) has been in existence since 1987. Test data was obtained from the interaction of the AO ion beam with materials used in space applications (carbon, silver, kapton) and with several special coatings of interest deposited on various surfaces. The ultimate design goal of the AO beam simulation device is to produce neutral AO at sufficient flux levels to replicate on-orbit conditions. A newly acquired mass spectrometer with energy discrimination has allowed 5 eV neutral oxygen atoms to be separated and detected from the background of thermal oxygen atoms of approx 0.2 eV. Neutralization of the AO ion beam at 5 eV was shown at the Martin Marietta AO facility.

Froechtenigt, Joseph F.↗

Material interactions with the Low Earth Orbital (LEO) environment: Accurate reaction rate measurements

To resolve uncertainties in estimated LEO atomic oxygen fluence and provide reaction product composition data for comparison to data obtained in ground-based simulation laboratories, a flight experiment has been proposed for the space shuttle which utilizes an ion-neutral mass spectrometer to obtain in-situ ambient density measurements and identify reaction products from modeled polymers exposed to the atomic oxygen environment. An overview of this experiment is presented and the methodology of calibrating the flight mass spectrometer in a neutral beam facility prior to its use on the space shuttle is established. The experiment, designated EOIM-3 (Evaluation of Oxygen Interactions with Materials, third series), will provide a reliable materials interaction data base for future spacecraft design and will furnish insight into the basic chemical mechanisms leading to atomic oxygen interactions with surfaces.

Visentine, James T.↗

The NASA/JPL Evaluation of Oxygen Interactions with Materials-3 (EOIM-3)

The deleterious effects of hyperthermal atomic oxygen (AO) found in low-earth-orbit (LEO) environments on critical flight materials has been known since early shuttle flights. This corrosive effect is of considerable concern because it compromises the performance and longevity of spacecraft/satellite materials deployed for extended periods in LEO. The NASA Evaluation of Oxygen Interactions with Materials-3 (EOIM-3) experiment served as a testbed for a variety of candidate flight materials for space assets. A total of 57 JPL test specimens were present in six subexperiments aboard EOIM-3. In addition to a number of passive exposure materials for flight and advanced technology programs, several subexperiments were included to provide data for understanding the details of atomic oxygen interactions with materials. Data and interpretations are presented for the heated tray, heated strips, solar ultraviolet exposure, and scatterometer subexperiments, along with a detailed description of the exposure conditions experienced by materials in the various experiments. Mass spectra of products emerging from identical samples of a (sup 13)C-enriched polyimide polymer (chemically equivalent to Kapton) under atomic oxygen bombardment in space and in the laboratory were collected. Reaction products unambiguously detected in space were (sup 13)CO, NO, (sup 12)CO2, and (sup 13)CO2. These reaction products and two others, H2O and (sup 12)CO, were detected in the laboratory, along with inelastically scattered atomic and molecular oxygen. Qualitative agreement was seen in the mass spectra taken in space and in the laboratory; the agreement may be improved by reducing the fraction of O2 in the laboratory molecular beam.

Brinza, David E.↗

A new computational model for the prediction of mass loading phenomena for solar wind interactions with cometary and planetary ionospheres

The modified gasdynamic convected-magnetic-field MHD model developed by Spreiter and Stahara (1980) to simulate the supersonic flow of the solar wind past planetary magnetoionospheres is extended to account for cases (such as Venus and comets) in which significant numbers of neutral atmospheric atoms become ionized in the surrounding flow and add to its momentum, energy, and mass. The mathematical model and the solution procedures for the nose and tail regions are explained; typical computational grids are shown; and numerical results for a comet and for the Venus ionosheath and bow shock are presented graphically. It is found that the bow shock weakens and moves further upstream of the obstacle as mass loading is increased and the flow upstream of the bow shock becomes more compressed.

Stahara, Stephen S.↗

Molecule formation in fast neutral winds from protostars

A time-dependent chemical model is used to analyze the processes generating and destroying molecules in very high velocity winds from low-mass protostars. CO and SiO are found to be generated in significant quantities despite the persistence of H in atomic form, consistently with recent protostellar wind detections of CO and H I at velocities in excess of 100 km/sec. A moderate mass-loss rate, in conjunction with a temperature distribution that decreases rather rapidly with distance from the protostar, are the conditions for substantial molecule formation.

Glassgold, A. E.↗

Measurement of Atomic Oxygen in Diffuse Aurora and Ion Density in the E-Region

An ion mass spectrometer (IMS) was refurbished, calibrated and supplied to the University of Colorado payload (Dr. Charles Barth, P.I.) which was launched from White Sands in September of 1993 as NASA 33.062. The nose cone failed to deploy and their were problems with the ACS so the mission was declared a failure. However, the door covering the IMS deployed and the instrument obtained data. The launch occurred shortly after a payload carrying solar x-ray detectors was launched. Thus a small portion of the Colorado payload science was salvaged; namely, the NO(+)/O2(+) ratio to compare with the measured x-ray flux. Figure I shows the NO(+) to O2(+) ratio vs. altitude. The behavior is typical of the E-region.

Sharp, William E.↗

Comment on 'A non-mass-dependent isotopic fractionation effect' by F. Robert, J. Halbout and J. Baudon

The fractionation model of Robert et al. (1988) treats the gas-phase isotopic exchange reaction between kinetically excited atoms aX and diatomic MbX yielding bX and MaX and finds an abundance-dependent fractionation superimposed on the usual mass dependent fractionation. This paper shows that the treatment of Robert et al. is in error and presents a more straightforward treatment of the same system. This model shows only mass-dependent fractionation.

Sund, Mark T.↗