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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Optical spectroscopy on individual nano-flakes of NiPS 3 2D-antiferromagnet reveals correlated excitons arising from entangled charge, spin, orbital, and lattice degrees of freedom, similar to bulk NiPS 3 but at a completely different energy range.
The conductivity and dielectric properties are integral to the function of polyvinyl chloride (PVC) gel actuators. The frequency-dependent properties of PVC gel actuators are investigated here in terms of their impedance, permittivity, and for the first time, electric modulus. The data shows that PVC gels’ conductive properties are just as, if not more, important as their dielectric properties in electromechanical transduction applications. The electrode polarization (EP) and its impact on the impedance and dielectric spectra of PVC gels, as well as the developed asymmetric space charge at the anode, are discussed. The electric modulus and tan δ spectra are used for the fitting of Cole-Cole (CC) and Debye relaxation models for gels of varying plasticizer content. The electrostatic adhesive force for PVC gels of varying plasticizer is also measured, indicating large electrostatic adhesion (>2 N cm -2 ). A cyclic linear voltage sweep is used to clarify the dynamics of space charge within the gels. The peak current (associated with space charge development) is seen to be concurrent with the onset of mechanical deformation, showing the asymmetric charge as the origin of electromechanical transduction. Additionally, the maximum charge transferred (as measured by the integration of current over time) before space charge development is found to correlate with the electrostatic adhesive force measured for the gels, pointing to a new method of characterizing PVC gels for actuation.
The need for a microscopic description of scintillation light generation in liquid argon becomes increasingly desirable with the upcoming operation of large scale LArTPCs in the next decade. While a detailed mathematical account of the process is still to be achieved, a phenomenological model for simultaneously treating ionization and scintillation, LArQL, has been successfully employed to describe the range of electric fields from 0 to 0.75 kV/cm and dE/dx from 2 to 40 MeV/cm providing the anti-correlation between the free ionization charge and scintillation light. A reanalysis of the original model parameter values has been performed within a global fit procedure and is presented.
BaNi 2 As 2 is a superconductor chemically related to the Fe-based superconductors, with a complex and poorly understood structural phase transition. We show, based on first-principles calculations, that, in fact, there are two distinct competing structures. These structures are different from the electronic, transport, and bonding points of view but are close in energy. These arise due to complex As bonding patterns and drive distortions of the Ni layers. This is supported by photoemission experiments. This is very distinct from views of the distortion as being primarily driven by electrons at the Fermi surface as in a classical charge density wave, or by correlated electron physics associated with the Ni d electrons and the Ni d orbitals. The structural distortion, although connected with As does lead to an interplay of electronic and structural behavior including induced anisotropic electronic transport. Here, the local bonding nature of the instabilities and the competition between distortions is discussed in the context of the complex behavior observed in BaNi 2 As 2 samples.
This study evaluated gamma irradiation for sterilization and reuse of two models of N95 respirators after gamma radiation sterilization as a method to increase availability of N95 respirators during a shortage. The Sandia National Laboratories Gamma Irradiation Facility was used to irradiate two different models of N95 filtering facepiece respirators at doses ranging from 0 kGy(tissue) to 50 kGy(tissue). The following tests were used to determine the efficacy of the respirator after irradiation sterilization: Ambient Aerosol Condensation Nuclei Counter Quantitative Fit Test, tensile test, strain cycling, oscillatory dynamic mechanical analysis, microscopic image analysis of fiber layers, and electrostatic field measurements. Both of the respirator models exhibited statistically significant changes after gamma irradiation as shown by the Quantitative Fit Test, electrostatic testing and the aerosol testing. The change in electrostatic charge of the filter was correlated with a reduction in capturing particles near the 200 nm size by approximately 40-50%. Both tested respirators showed statistically significant changes associated with gamma sterilization. However, our results indicate that choices in materials and manufacturing methods to achieve N95 filtration lead to different magnitudes of damage when exposed to gamma radiation at sterilization relevant doses. This damage results in lower filtration performance. While our sample size (2 different types of respirators) was small, we did observe a change in electrostatic properties on a filter layer that coincided with the failure on the Quantitative Fit Test and reduction in aerosol filtering efficiency. Key Words: N95 respirators, respirators, airborne transmission, pandemic prevention, COVID-19, gamma sterilization
Surface modified reduced graphene oxide (rGO) aerogels were synthesized using the hydrothermal method. Ethylene diamine (EDA) and α-cyclodextrin (CD) were used to functionalize the surface of the graphene oxide layers. The oxygen reduction and surface modification occurred in-situ during the hydrothermal self-assembly process. The chemical functionality and structure of the resulting ethylene diamine modified (rGO-EDA) and cyclodextrin modified (rGO-CD) aerogels as well as of the pristine unmodified rGO aerogel were studied using XPS, SEM, XRD, and SANS techniques. The overall surface composition showed a significant decrease in the oxygen content for all synthesized aerogels. The surface modified aerogels were characterized by a disordered stacking of the assembled rGO layers. The surface functionalities resulted in a broad distribution of the interlayer spacing and introduced structural heterogeneities. Such disordered structures can enable a better adsorption mechanism of the sodium ions. Coin cells based on the synthesized aerogels and sodium metal were assembled and tested at several charge and discharge rates. The correlation between the surface functionality of the rGO, the induced structural heterogeneities due to the disordered stacking, and the electrochemical performance of sodium-ion batteries were investigated. Operando XRD measurements were carried out during the battery cycling to investigate the adsorption or intercalation nature of the sodiation mechanism.
Simultaneous measurements were made of the speed of flame and the rise in pressure during explosions of mixtures of carbon monoxide, normal heptane, iso-octane, and benzene in a 10-inch spherical bomb with central ignition. From these records, fundamental properties of the explosive mixtures, which are independent of the apparatus, were computed. The transformation velocity, or speed at which flame advances into and transforms the explosive mixture, increases with both the temperature and the pressure of the unburned gas. The rise in pressure was correlated with the mass of charge inflamed to show the course of the energy developed.
This paper describes a battery power model that has been developed to simulate and predict the behavior of the 50 ampere-hour nickel-cadmium battery that supports the Extreme Ultraviolet Explorer (EUVE) spacecraft in its low Earth orbit. First, for given orbit, attitude, solar array panel and spacecraft load data, the model calculates minute-by-minute values for the net power available for charging the battery for a user-specified time period (usually about two weeks). Next, the model is used to calculate minute-by-minute values for the battery voltage, current and state-of-charge for the time period. The model's calculations are explained for its three phases: sunrise charging phase, constant voltage phase, and discharge phase. A comparison of predicted model values for voltage, current and state-of-charge with telemetry data for a complete charge-discharge cycle shows good correlation. This C-based computer model will be used by the EUVE Flight Operations Team for various 'what-if' scheduling analyses.
The research project at Howard University seeks to develop analytical and numerical capabilities to study heat transfer and fluid flow characteristics, and the prediction of the performance of solar heat receivers for space applications. Specifically, the study seeks to elucidate the effects of internal and external thermal radiation, geometrical and applicable dimensionless parameters on the overall heat transfer in space solar heat receivers. Over the last year, a procedure for the characterization of the state-of-charge (SOC) in solar heat receivers for space applications has been developed. By identifying the various factors that affect the SOC, a dimensional analysis is performed resulting in a number of dimensionless groups of parameters. Although not accomplished during the first phase of the research, data generated from a thermal simulation program can be used to determine values of the dimensionless parameters and the state-of-charge and thereby obtain a correlation for the SOC. The simulation program selected for the purpose is HOTTube, a thermal numerical computer code based on a transient time-explicit, axisymmetric model of the total solar heat receiver. Simulation results obtained with the computer program are presented the minimum and maximum insolation orbits. In the absence of any validation of the code with experimental data, results from HOTTube appear reasonable qualitatively in representing the physical situations modeled.
Two primary detection techniques (optical and RF) have a proven capability for detecting lightning from low earth orbit. However, the lightning processes that generate the optical and RF signals are vastly different providing significantly different information content from each sensor type. Because of the intervening ionosphere, low frequency RF components do not reach satellite altitudes. As a consequence, many of the processes associated with the major energy release of a lightning event (i.e. return strokes, k-changes, recoil streamers, etc), in all likelihood contribute little to the RF signal arriving at the satellite. The optical output from lighting, on the other hand, has been shown to be highly correlated with the energetic, charge-transferring processes mentioned above. On the down side, the optical energy, while essentially unaffected by the atmosphere once it emerges from the cloud, is heavily scattered within the cloud. While there is little absorption by the cloud, the great optical depth makes the total light energy emerging from the cloud to be dependent on where in the cloud the lightning occurred. Analyses suggest that when lightning is confined to the lowest regions of the cloud, the light is strongly attenuated and detection becomes problematic. Fortunately, the vast majority of lightning flashes are comprised of channels that propagate through the middle of the cloud and higher. These flashes produce bright signals at the top of a cloud and are readily detectable. Presently, we have two optical instruments in orbit. The Optical Transient Detector (OTD) has been orbiting the earth since April, 1995, while the Lightning Imaging Sensor (LIS) was launched on the Tropical Rainfall Measuring Mission (TRMM) in November of 1997. Both instruments are relatively small, solid state optical imagers, designed specifically to detect and locate lightning activity from low earth orbit with high detection efficiency and location accuracy.
Correlations between azimuthal anisotropy and mean transverse momentum of charged particles in proton-proton (pp), proton-lead (pPb), and peripheral lead-lead (PbPb) collisions are presented as a function of charged particle multiplicity. The pp, pPb and PbPb collision data were collected using the CMS detector at the LHC with a center-of-mass energy per nucleon pair of 13, 8.16 and 5.02 TeV, respectively. The two- and four-particle cumulants for the second- and third-order Fourier anisotropy harmonics are correlated with the mean transverse momentum of charged particles on an event-by-event basis. In pp and pPb systems, the observed correlation coefficients based on two-particle cumulants are found to change from negative to positive values as the charged particle multiplicity decreases. The sign changes disappear when the correlated particles are required to be further apart in pseudorapidity. Additionally, no sign changes in correlation coefficients are observed when employing four-particle cumulants. Models incorporating initial-state gluon saturation and final-state hydrodynamic evolutions are compared to pPb data and the predicted sign changes are not observed.
Halide-induced rate enhancements are correlated with the desorption barriers of aqueous metal–anion complexes on electrodes, which can guide electrode and electrolyte selection to enhance redox kinetics of metal ion charge transfer reactions.
The interplay between electron-electron correlations and disorder has been a central theme of condensed matter physics over the past several decades, with particular interest in the possibility that interactions might cause delocalization of an Anderson insulator into a metallic state, and the disrupting effects of randomness on magnetic order and the Mott phase. In this work, we extend this physics to explore electron-phonon interactions and show, via exact quantum Monte Carlo simulations, that the suppression of the charge density wave correlations in the half-filled Holstein model by disorder can stabilize a superconducting phase. Our simulations thus capture qualitatively the suppression of charge ordered phases and emergent superconductivity recently seen experimentally.
The coupling between charge and spin orderings in strongly correlated systems plays a crucial role in fundamental physics and device applications. As a candidate of multiferroic materials, LuFe 2 O 4 with a nominal Fe 2.5+ valence state has the potential for strong charge–spin interactions; however, these interactions have not been fully understood until now. Here, combining complementary characterization methods with theoretical calculations, two types of charge orderings with distinct magnetic properties are revealed. The ground states of LuFe 2 O 4 are decided by the parallel/antiparallel coupling of both charge and spin orderings in the adjacent FeO double layers. Whereas the ferroelectric charge ordering remains ferrimagnetic below 230 K, the antiferroelectric ordering undergoes antiferromagnetic–ferrimagnetic–paramagnetic transitions from 2 K to room temperature. This study demonstrates the unique aspects of strong spin-charge coupling within LuFe 2 O 4 . Our results shed light on the coexistence and competing nature of orderings in quantum materials.
MXenes are a large family of two-dimensional materials that are attractive for energy storage due to their high-rate charging capabilities as well as for electrochemical actuators, water purification, and many other technologies. Ion intercalation during electrochemically driven charge and discharge processes is the fundamental process associated with MXene functionality, which we have characterized here using in situ and operando X-ray reflectivity (XRR). Experiments performed at the Advanced Photon Source at Argonne National Laboratory monitored the changes in the structure of a Ti 3 C 2 MXene film on a platinum current collector as a function of static applied potential between 0.3 and –0.7 V vs Ag/AgCl in an aqueous 0.1 M Li 2 SO 4 electrolyte. Negative potential sweeps lead to a contraction of 1.2 Å in the interlayer spacing and a loss of electron density between the layers, likely due to Li + ion insertion and water removal. The change in lattice spacing includes a continuous variation vs potential as well as an additional discrete contraction that occurs near –0.35 V that has the characteristics of a first-order transition. The continuous change in the MXene interlayer spacing is associated with the capacitive charge, while the discrete change in structure correlated to the weak feature in the cyclic voltammogram at –0.35 V can be interpreted as either a pseudocapacitive charging process or a potential-dependent change in capacity.
This paper provides a template of expected uncertainties and correlations for measurements of neutron-induced capture and charged-particle production cross sections. Measurements performed in-beam include total absorption spectroscopy, total energy detection, γ -ray spectroscopy, and direct charged-particle detection. Offline measurements include activation analysis and accelerator mass spectrometry. The information needed for proper use of the datasets in resonance region and high energy region evaluations is described, and recommended uncertainties are provided when specific values are not available for a dataset.
The D-measure of net-charge fluctuations quantifies the variance of net charge in strongly interacting matter. It was introduced over 20 years ago as a potential signal of quark-gluon plasma (QGP) in heavy-ion collisions, where it is expected to be suppressed due to the fractional electric charges of quarks. Measurements have been performed at RHIC and LHC, but the conclusion has been elusive in the absence of quantitative calculations for both scenarios. We address this issue by employing a recently developed formalism of density correlations and incorporate resonance decays, local charge conservation, and experimental kinematic cuts. We find that the hadron gas scenario is in fair agreement with the ALICE data for $\sqrt{{𝑠}_{\textrm{NN}}}$ = 2.76 TeV Pb–Pb collisions only when a very short rapidity range of local charge conservation is enforced, while the QGP scenario is in excellent agreement with experimental data and largely insensitive to the range of local charge conservation. A Bayesian analysis of the data utilizing different priors yields moderate evidence for the freeze-out of charge fluctuations in the QGP phase relative to hadron gas. The upcoming high-fidelity measurements from LHC Run 2 will serve as a precision test of the two scenarios.
Work continues on a minimally invasive, nitrogen fluorescence gas sheet at the Facility for Rare Isotope Beams (FRIB). A low density gas sheet may be used to observe the 2D transverse beam profile of high intensity, multiple charge state beams with minimal interference. Spatially and temporally correlated profiles are of particular interest in locations where there is significant charge state spread, such as the FRIB linac folding segments. A low-density gas sheet measurement system offers advantages for gas handling in nitrogen sensitive areas, however signal intensity is significantly lower than techniques using higher density gas sheets and jets. This work discusses measurement considerations for photon distributions generated by several spatially separated interaction points and design considerations for a high-sensitivity optics system for handling the expected low signal intensity.