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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Facilitated Direct Liquid Fuel Cells with High Temperature Membrane Electrode Assemblies

Dimethyl ether (DME) is a liquid fuel of great potential impact due to its exceptionally high energy density. However, it has received minimal prior investigation as an alternative to either purified hydrogen or other liquid fuels, including methanol (MeOH). In the limited published literature work on direct dimethyl ether fuel cells, regardless of operating temperature, PtRu (either supported or unsupported on carbon) has been established as the standard catalyst of choice. The majority of the work in this program also utilized a Johnson Matthey (JM) HiSPEC ® 12100 PtRu/C (nominally 50% Pt, 25% Ru) while looking at electrode optimizations, beginning of life (BoL) performance, pressure- and temperature-dependent studies to look at the effect of binding affinity of DME oxidation intermediates, mass transport effects, crossover studies, and durability. However, it does also investigate some promising alternatives to PtRu/C as well, which should be investigated in more detail in further work. Those catalysts include a pair of ternary PtRuPd/C catalysts (from Los Alamos National Laboratory (LANL) and Pajarito Powder, LLC. (PP)) as well as a Pt 2 Bi Black catalyst from Professor Anastasios Angelopoulos of the University of Cincinnati (UC). This work achieved several project objectives, including an optimization of the membrane electrode assembly (MEA) process using PtRu/C anode catalyst. Additionally, these direct dimethyl ether fuel cells (DDFCs) were able to match or exceed many performance metrics for the state-of-the-art (SOA) direct methanol fuel cells (DMFCs), a primary and more evolved competitor to direct dimethyl ether fuel cells. This included peak specific power, total platinum group metal (PGM) loading, crossover current, degradation rate, start/stop cycling losses, and anode specific current.

09 BIOMASS FUELS↗
DOE OSTI2026

Size dependent lattice pseudosymmetry for frustrated decahedral nanoparticles

Geometric frustration—where geometry prevents simultaneous satisfaction of local interactions—generates pseudosymmetry and emergent behaviors across physical and biological systems. At the nanoscale, pseudosymmetric features in crystalline materials manifest as local strain and distortion, but how they depend on particle size and control structural stability remains unclear. Here, we report the first study of a size-dependent crossover in pseudosymmetry in multi-twinned gold nanoparticles (NPs), combining four-dimensional scanning transmission electron microscopy with nanoscale strain mapping grounded in continuum solid mechanics. Analysis of more than 20 decahedral NPs (20–55 nm) reveals pronounced heterogeneity in multiple modes of in-plane strain and displacement field in small NPs as five tetrahedral grains close the geometric gap, without extended defects. With increasing particle size, strain fields homogenize across grains and local phases shift from predominantly low-symmetry body-centered tetragonal motifs at small sizes to face-centered cubic character approaching the bulk limit. We identify a crossover particle size of ~35 nm, well below bulk, correlating with a transition from modified-Wulff shapes to pentagonal bipyramids, consistent with finite element predictions. This quantitative framework for mapping size-dependent strain and pseudosymmetry enables precise design and control of functional crystalline solids and phase transformation for catalysis, photonics, electronics, and energy storage.

Lin, Oliver [University of Illinois at Urbana-Cham↗
DOE OSTI2021

Analysis of meiosis in Pristionchus pacificus reveals plasticity in homolog pairing and synapsis in the nematode lineage

Meiosis is conserved across eukaryotes yet varies in the details of its execution. Here we describe a new comparative model system for molecular analysis of meiosis, the nematode Pristionchus pacificus, a distant relative of the widely studied model organism Caenorhabditis elegans. P. pacificus shares many anatomical and other features that facilitate analysis of meiosis in C. elegans. However, while C. elegans has lost the meiosis-specific recombinase Dmc1 and evolved a recombination-independent mechanism to synapse its chromosomes, P. pacificus expresses both DMC-1 and RAD-51. We find that SPO-11 and DMC-1 are required for stable homolog pairing, synapsis, and crossover formation, while RAD-51 is dispensable for these key meiotic processes. RAD-51 and DMC-1 localize sequentially to chromosomes during meiotic prophase and show nonoverlapping functions. We also present a new genetic map for P. pacificus that reveals a crossover landscape very similar to that of C. elegans, despite marked divergence in the regulation of synapsis and crossing-over between these lineages.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1972

Measurement of the wave-normal vector of proton whistlers on Ogo 6.

Description of the first experimental determination of the wave-normal vector of proton whistlers in the ionosphere. Between the crossover frequency and the proton gyrofrequency, both right-hand and left-hand modes of propagation can occur for upgoing waves. Theoretically, the amount of energy in the respective modes depends on theta, the angle between the wave normal and the magnetic field. For proton whistlers with only left-hand mode energy between the crossover and proton gyrofrequency, theta ranged from 36 to 51 deg. For proton whistlers with strong right-hand and left-hand mode signals, theta ranged from 24 to 29 deg. The result is in good agreement with Wang's (1971) collisionless mode-coupling model. The angle between the wave normal and the vertical is found to increase with increasing altitude.

Chan, K. W.↗
NASA NTRS1973

Sampling command generator corrects for noise and dropouts in recorded data

Generator measures period between zero crossings of reference signal and accepts as correct timing points only those zero crossings which occur acceptably close to nominal time predicted from last accepted command. Unidirectional crossover points are used exclusively so errors from analog nonsymmetry of crossover detector are avoided.

Anderson, T. O.↗
NASA NTRS1979

Estimation of mean sea surfaces in the north Atlantic, the Pacific and the Indian Ocean using GEOS-3 altimeter data

The mean surfaces of several regions of the world's oceans were estimated using GEOS-3 altimeter data. The northwest Atlantic, the northeast Pacific off the coast of California, the Indian Ocean, the southwest Pacific, and the Phillipine Sea are included. These surfaces have been oriented with respect to a common earth center-of-mass system by constraining the separate solutions to conform to precisely determined laser reference control orbits. The same reference orbits were used for all regions assuring continuity of the separate solutions. Radial accuracies of the control orbits were in the order of one meter. The altimeter measured sea surface height crossover differences were minimized by the adjustment of tilt and bias parameters for each pass with the exception of laser reference control passes. The tilt and bias adjustments removed long wavelength errors which were primarily due to orbit error. Ocean tides were evaluated. The resolution of the estimated sea surfaces varied from 0.25 degrees off the east coast of the United States to about 2 degrees in part of the Indian Ocean near Australia. The rms crossover discrepancy after adjustment varied from 30 cm to 70 cm depending upon geographic location. Comparisons of the altimeter derived mean sea surface in the North Atlantic with the 5 feet x 5 feet GEM-8 detailed gravimetric geoid indicated a relative consistency of better than a meter.

Marsh, J. G.↗
NASA NTRS1980

Calibration validation for the GEOS-3 altimeter

The absolute bias calibration for the GEOS-3 intensive mode altimeter was measured using two satellite passes whose groundtracks were within 1 km of the Bermuda laser station. The Bermuda laser tracked on the two passes, and was supported by two other NASA lasers on one pass and by the NASA Spacecraft Tracking and Data Network on the other pass. For each pass, the altimeter data around Bermuda was smoothed and extrapolated to the point closest to overhead at the laser site. After correcting for tide heights and sea state effects, the two passes give calibration biases which are in agreement to within 26 cm and have a weighted mean of -5.69 + or - 0.16m for correcting altimeter measurements to the center-of-mass of the spacecraft (i.e., including the antenna tracking point correction). It was found impossible to reconcile the two calibration passes, as well as a set of altimeter crossovers in the middle of the GEOS-3 calibration area, without allowing for a data time tag error. On the bias of a selected set of four crossovers, and an assessment of probable sources of timing error, it was concluded that one interpulse period (10.24 msec) should be added to the data time tags.

Martin, C. F.↗
NASA NTRS1979

Determination of secondary electron emission characteristics of lunar soil samples

A procedure is described for the determination of the 'apparent crossover voltage', i.e. the value of the primary (bombarding) electron energy at which an insulating sample surface changes the average sign of its charge. This apparent crossover point is characteristic of the secondary emission properties of insulating powders such as the lunar soil samples. Lunar core samples from well-defined, distinct soil layers are found to differ significantly in their secondary emission properties. This observation supports the suggestion that soil layers were deposited by an electrostatic transport process.

Gold, T.↗
NASA NTRS1981

Boundary-layer analysis for the convection/diffusion transition in dendritic growth

The supercooling dependence of dendritic growth kinetics under the influence of convective heat transport is investigated theoretically and experimentally with emphasis on theoretical prediction of the supercooling level at which the transition from diffusion-controlled to convection-controlled dendritic growth occurs. It is shown that the crossover between diffusive and convective transport depends on the relative thickness of the Stefan length compared with the thermal boundary layer. These lengths become equal at a supercooling which may be calculated from diffusion theory and fluid mechanics. It is also shown that the crossover supercooling varies weakly with the gravitational acceleration, melt viscosity, and the volumetric expansion coefficient.

Glicksman, M. E.↗
NASA NTRS1982

Optical crystal temperature gauge with fiber optic connections

An optical temperature gauge uses a semiconductor crystal with a band-edge shift property which is temperature dependent. An external narrow band light source provides optical excitation through a optical fiber and light energy thus passed through the crystal is conveyed by a second optical fiber to a light-to-electric transducers at an external location. The crystal can be located in cryogenic or other systems, to provide remote read-out. The light wavelength is varied (scanned) in a repetitive pattern in source with the instantaneous wavelength passing over the band-edge wavelength during each cycle of the scan. The timing of the crossover is related to the temperature of the crystal by electronic means. Several alternative elements of instrumentation are disclosed. A variation in the basic measurement apparatus is also disclosed, in which the band gap voltage of a light source such as a laser diode is evaluated at the time of band-edge crossover in the crystal and converted to a temperature value.

Sharma, M. M.↗
NASA NTRS1982

Evaluation of the Seasat altimeter time tag bias

Two methods were used in analyses of Seasat altimeter data, aimed at the corroboration of an inherent altimeter microprocessor delay compensation value of -79.4 msec, which benefited from a global data distribution in the oceanic areas: (1) the crossover method, using altimeter data differenced at points where the Seasat ground track intersected with itself, and (2) the direct use of the altimeter data. Because the former method is independent of errors in the geoid model, it is considered the more reliable. For all crossover method results, the adopted value of -79.4 msec is within the bounds of the standard deviation associated with the estimates, of which -78.1 + or - 2.0 msec is considered the best representative.

Schutz, B. E.↗
NASA NTRS1983

Surface elevation contours of Greenland and Antarctic ice sheets

Preliminary results from Seasat radar altimetry over Antarctica north of 72 deg S and Greenland south of 72 deg N are presented. Surface elevations of the ice sheets, obtained from computer retracking of the radar altimeter waveforms, are contoured at 50-m intervals for Greenland and at 100-m intervals for Antarctica. Elevation differences at orbital crossover points are analyzed to obtain a precision of 1.9 m; this figure is partly determined by radial errors of approximately 1.0 m in orbital determination and partly by noise due to ice surface irregularities. Adjustment of the radial components of the orbits to minimize the differences in elevations at crossovers over a small, relatively flat region reduces the rms difference to 0.25 m, which is indicative of the optimum precision obtainable over the ice sheets. However, the precision degrades as the slope of the surface or amplitude of the undulations increases, yielding an overall precision of + or - 1.6 m.

Zwally, H. J.↗
NASA NTRS1986

Orbit determination using dual crossing arc altimetry

Accurate knowledge of the position of an altimetric satellite is required for the altimeter range data to be effective in measuring ocean topography. This study addresses the use of high-precision altimeter data from NASA's TOPEX Mission in reducing the radial component of the orbit of the U.S. Navy's N-ROSS satellite. Simulated altimeter crossing arc residuals between the TOPEX and N-ROSS orbits are minimized using both geometric and dynamic techniques in an effort to reduce the N-ROSS radial error to a level comparable to that of TOPEX. Tracking of N-ROSS by the Navy's NAVSPASUR system is simulated, and crossover residuals are created from the TOPEX and N-ROSS orbits. A simple geometric fit is shown to reduce the radial component of the NAVSPASUR N-ROSS orbit error from 350 m RMS to below 10 m RMS. In comparison, the dynamic approach of estimating the initial conditions of the N-ROSS orbit using a twentieth degree and order gravity field and a combined data set of tracking and altimeter crossover data yields a 6 m RMS residual error. Sub-meter accuracy can be attained by geometrically fitting these residuals to remove long wavelength orbit error.

Born, G. H.↗
NASA NTRS1987

Altimeter measurements for the determination of the Earth's gravity field

The ability of satellite-borne radar altimeter data to measure the global ocean surface with high precision and dense spatial coverage provides a unique tool for the mapping of the Earth's gravity field and its geoid. The altimeter crossover measurements, created by differencing direct altimeter measurements at the subsatellite points where the orbit ground tracks intersect, have the distinct advantage of eliminating geoid error and other nontemporal or long period oceanographic features. In the 1990's, the joint U.S./French TOPEX/POSEIDON mission and the European Space Agency's ERS-1 mission will carry radar altimeter instruments capable of global ocean mapping with high precision. This investigation aims at the development and application of dynamically consistent direct altimeter and altimeter crossover measurement models to the simultaneous mapping of the Earth's gravity field and its geoid, the ocean tides and the quasi-stationary component of the dynamic sea surface topography. Altimeter data collected by SEASAT, GEOS-3, and GEOSAT are used for the investigation.

Tapley, B. D.↗
NASA NTRS1987

Three-step cylindrical seal for high-performance turbomachines

A three-step cylindrical seal configuration representing the seal for a high performance turbopump (e.g., the space shuttle main engine fuel pump) was tested under static (nonrotating) conditions. The test data included critical mass flux and pressure profiles over a wide range of inlet temperatures and pressures for fluid nitrogen and fluid hydrogen with the seal in concentric and fully eccentric positions. The critical mass flux (leakage rate) was 70% that of an equivalent straight cylindrical seal with a correspondingly higher pressure drop based on the same flow areas of 0.3569 sq cm but 85% that of the straight seal based on the third-step flow area of 0.3044 sq cm. The mass flow rates for the three step cylindrical seal in the fully eccentric and concentric positions were essentially the same, and the trends in flow coefficient followed those of a simple axisymmetric inlet configuration. However, for inlet stagnation temperatures less than the thermodynamic critical temperature the pressure profiles exhibited a flat region throughout the third step of the seal, with the pressure magnitude dependent on the inlet stagnation temperature. Such profiles represent an extreme positive direct stiffness. These conditions engendered a crossover in the pressure profile upstream of the postulated choke that resulted in a local negative stiffness. Flat and crossover profiles resulting from choking within the seal are practically unknown to the seal designer. However, they are of critical importance to turbomachine stability and must be integrated into any dynamic analysis of a seal of this configuration. In addition, choking is highly dependent on geometry, inlet-to-backpressure ratio, and inlet temperature and can occur within the seal even though the backpressure is above the critical pressure.

Hendricks, Robert C.↗
NASA NTRS1989

Chemoviscosity modeling for thermosetting resin systems, 4

An experimental study on the changes of chemorheological properties has been conducted and analyzed on commercial Hercules 3501-6 resin system cured under several isothermal conditions between 375 and 435 K. For the cure temperatures equal to or greater than 385 K, the storage modulus curing curves, G prime (t), exhibited abrupt changes in slope which occurred at various times depending on the curing temperatures and were attributed to the onset of gelation reactions. The crossover points between G prime (t) and G double prime (t) curves were observed for curing temperatures equal to or greater than 400 K. The gelation and the crossover points obtained from the chemorheological measurements, therefore, defined two characteristic resin states during cure. Approximately the same value for the degree of cure was reached by the advancement of the reaction at each of these states. The temperature dependency of the viscosities for the characteristic resin states and the rate constants of increase in moduli at different stages of curing were analyzed. Various G prime (t) and G double prime (t) isothermal curing curves were also shown to be capable of being superimposed on one another by the principle of time-temperature superposition. The resultant shift factors a sub t(t) and a Eta(T) were shown to follow the Arrhenius type relationship. Values of the activation energy suggested that the reaction kinetics, instead of the diffusion mechanism, was the limiting step in the overall resin advancement for the cure at temperatures equal to or greater than 385 K.

Hou, T. H.↗
NASA NTRS1989

Genetic algorithms applied to the scheduling of the Hubble Space Telescope

A prototype system employing a genetic algorithm (GA) has been developed to support the scheduling of the Hubble Space Telescope. A non-standard knowledge structure is used and appropriate genetic operators have been created. Several different crossover styles (random point selection, evolving points, and smart point selection) are tested and the best GA is compared with a neural network (NN) based optimizer. The smart crossover operator produces the best results and the GA system is able to evolve complete schedules using it. The GA is not as time-efficient as the NN system and the NN solutions tend to be better.

Sponsler, Jeffrey L.↗
NASA NTRS1990

Analysis of altimetry over inland seas

Satellite-based altimetric data taken by GEOS-3 and SEASAT over the Black Sea and Caspian Sea are analyzed and a least squares collocation technique is used to predict the geoid undulation on a .25-degree by .25-degree grid and to transform these geoid undulations to free air gravity anomalies. This project entailed processing satellite altimeter data over inland seas for recovery of area mean gravity information. Gravity information in this area of the world is not readily available, so the possibility of obtaining it from the processing of altimeter observations is attractive. The principal objective was to complete and extend analyses done in a previous study, verify those results, and document the results and techniques. A secondary objective was to improve the algorithms and results, if possible. The approach used involved editing geoid height data to remove overland data; evaluating geoid height differences at crossover points; removing orbit errors from geoid heights using crossover differences; gridding geoid height data at .25-degree by .25-degree intervals; and estimating the gravity anomalies from gridded geoid heights using the collocation technique.

Au, A. Y.↗