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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

Stone-Wales defect-rich carbon-supported dual-metal single atom sites for Zn-air batteries

In this study, we aim to obtain a fundamental understanding of active sites near stone-wales (SW) defects rich nitrogen-doped graphene (DG) with specific coordination of carbon atom rings. It reveals that the SW rich defects ( e.g., pentagon (5), pentagon—octagon—pentagon ( i.e . 585), or pentagon-heptagon-heptagon-pentagon (5775) rings, appears correspondingly with carbon rings that brought active sites during catalytic reactions. Moreover, we anchored dual isolated metallic atoms (Ni/Fe) on DG support via linkers (O/N) called NiFe-DG. X-ray absorption spectroscopy indicates Ni/Fe metal single atoms are embedded via Fe-N 4 and Ni-N 4 coordination on DG surfaces. It exhibits high catalytic activity for oxygen reduction reaction (ORR) with an onset potential of 0.97 V, a half-wave potential of 0.86 V, and diffusion current density of 5.7 mA cm – 2 , which is at par with commercial Pt/C. The catalyst shows superior stability, retained 82% of the initial current density even after 12 h under an applied potential of 0.86 V. Similarly, the oxygen evolution reaction (OER) overpotential of 358 mV was achieved at 10 mA cm – 2 with a lower Tafel slope value (76 mV/dec) than commercial Pt/C. It maintains 85% stability for 12 h at a constant potential of 1.588 V, shows better stability than commercial Pt/C.

25 ENERGY STORAGE↗

Simulating Long–Term Dynamics of Radiation Belt Electrons Using DREAM3D Model

Here, we compared the performance of DREAM3D simulations in reproducing the long-term radiation belt dynamics observed by Van Allen Probes over the entire year of 2017 with various boundary conditions (BCs) and model inputs. Specifically, we investigated the effects of three different outer boundary conditions, two different low-energy boundary conditions for seed electrons, four different radial diffusion (RD) coefficients (DLL), four hiss wave models, and two chorus wave models from the literature. Using the outer boundary condition driven by GOES data, our benchmark simulation generally well reproduces the observed radiation belt dynamics inside L* = 6, with a better model performance at lower μ than higher μ, where μ is the first adiabatic invariant. By varying the boundary conditions and inputs, we find that: (a) The data-driven outer boundary condition is critical to the model performance, while adding in the data-driven seed population doesn't further improve the performance. (b) The model shows comparable performance with DLL from Brautigam and Albert (2000, https://doi.org/10.1029/1999ja900344), Ozeke et al. (2014, https://doi.org/10.1002/2013ja019204), and Liu et al. (2016, https://doi.org/10.1002/2015gl067398), while with DLL from Ali et al. (2016, https://doi.org/10.1002/2016ja023002) the model shows less RD compared to data. (c) The model performance is similar with data-based hiss models, but the results show faster loss is still needed inside the plasmasphere. (d) The model performs similarly with the two different chorus models, but better capturing the electron enhancement at higher μ using the Wang et al. (2019, https://doi.org/10.1029/2018ja026183) model due to its stronger wave power, since local heating for higher energy electrons is under-reproduced in the current model.

79 ASTRONOMY AND ASTROPHYSICS↗

Modulating effect of evanescent waves on thin film growth

Atomic-scale smooth thin films are keys to successful integration and proper function of many multilayer-structured devices. However, the intrinsic islandlike growth mode prevents human beings from realizing such ultrasmooth films of many important functional materials. To solve this problem, we propose a negative entropy-infusing method that employs evanescent waves to enhance the downward interlayer diffusion of adatoms and thus transform the islandlike growth mode to the layer-by-layer growth mode. In this work, the formulas of the optical force and the lowered diffusion barrier were derived, and the application of this theory on a simplified example demonstrates significantly improved surface morphologies through numerical simulations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Radar signal return from near-shore surface and shallow subsurface features, Darien Province, Panama

The AN/APQ-97 radar imagery over eastern Panama is analyzed. The imagery was directed toward extraction of geologic and engineering data and the establishment of operational parameters. Subsequent investigations emphasized landform identification and vegetation distribution. The parameters affecting the observed return signal strength from such features are considered. Near-shore ocean phenomena were analyzed. Tidal zone features such as mud flats and reefs were identified in the near range, but were not detectable in the far range. Surface roughness dictated the nature of reflected energy (specular or diffuse). In surf zones, changes in wave train orientation relative to look direction, the slope of the surface, and the physical character of the wave must be considered. It is concluded that the establishment of the areal extent of the tidal flats, distributary channels, and reefs is practical only in the near to intermediate range under minimal low tide conditions.

Hanson, B. C.↗

Investigation of the environmental change pattern of Japan

The author has identified the following significant results. ERTS-1 imagery clearly identifies the relationships between the status of erosion, effluent patterns affected by the coastal current, and the cultural construction activities. Simple photographic techniques can be used for detecting water mass distribution separately from cloud cover and also noise caused by reflected sunlight from wave surfaces. Polluted water does not diffuse continuously into the oceanic water, but forms masses in the water in the Kuroshio area. The polluted or turbid water in the area just north of the Tomogashima Channel, the south outlet of the Osaka Bay, shows that the northward tidal current runs in a clockwise eddy at the tidal period when the imagery was taken. Such an eddy-like pattern of tidal current had never been revealed by conventional oceanographic data. A front between an oceanic water mass and a polluted water mass runs in a NW-SE direction in the central part of the Osaka Bay. The patterns of turbid water discharged from the Kii River and Yoshino River show a northward tidal current in the North Kii Straits. The pattern of lighter turbid or polluted water located in the northwest region of the North Kii straits suggests the existence of a clockwise eddy in the straits.

Maruyasu, T.↗

Nonlinear evolution of the collisionless tearing mode

For a broad k vector spectrum, the collisionless tearing mode grows linearly until the Landau electrons become magnetized by the wave field. The electrons then spatially diffuse as a result of turbulent magnetic-gradient drifts which leads to a nonlinearly enhanced growth rate. At large amplitudes the nonlinear growth rate is dominated by ions.

Coroniti, F. V.↗

Calculation of the three-dimensional flow field in supersonic inlets at angle of attack using a bicharacteristic method with discrete shock wave fitting

An analysis is presented for calculating the flow field in supersonic mixed-compression aircraft inlets operating at angle of attack. The flow field is computed by a steady three-dimensional bicharacteristic method. The bow shock wave and the reflected internal shock wave system are computed by a three-dimensional discrete shock wave fitting procedure. Viscous and thermal diffusion may be included as source terms in the bicharacteristic method. A production type computer program capable of determining the flow field in a variety of axisymmetric mixed-compression supersonic inlets is available. The results of the present analysis agree well with those produced by the two-dimensional method of characteristics when axisymmetric flow fields are computed. For three-dimensional flow fields, the results of the present analysis agree well with experimental data except in regions of high viscous interaction and boundary layer removal. The present analysis does not compute the boundary layer, nor does it account for boundary layer bleed.

Vadyak, J.↗

Effects of internal heat transfer on the structure of self-similar blast waves

An analysis of the problem of self-similar, nonadiabatic blast waves, where both conduction and radiation are allowed to take place, show the problem to be reducible to the integration of a system of six coupled nonlinear ordinary differential equations. Consideration of these equations shows that although radiation tends to produce uniform fields through temperature gradient attenuation, all the energy carried by radiation is deposited on the front and the bounding shock becomes increasingly overdriven. When conduction is taken into account, the distribution of gasdynamic parameters in blast waves in the case of Rosseland diffusion radiation is more uniform than in the case of the Planck emission radiation.

Ghoniem, A. F.↗

Plasma rest frame frequencies and polarizations of the low-frequency upstream waves - ISEE 1 and 2 observations

The plasma rest frame frequencies and polarizations of the large amplitude low frequency (0.03 Hz) upstream waves are investigated using magnetic field data from the dual ISEE 1 and 2 spacecraft. The monochromatic sinusoidal waves associated with intermediate ion fluxes are propagating in both the Alfven and magnetosonic modes, in both cases with typical frequencies approximately 0.1 times the local proton gyrofrequency and wavelengths of approximately 1 R(E). It is shown that the generation of the magnetosonic mode can be explained by the cyclotron resonance mechanism driven by narrow reflected ion beams, but the concurrent observation of Alfven mode waves appears to require wave generation by the more isotropic diffuse ion distributions as well.

Hoppe, M. M.↗

The Jovian magnetosphere

Research on Jovian magnetospheric physics from 1979 through 1982 is surveyed, with a focus on the observations of Voyagers 1 and 2. Jovian fields and plasmas are characterized in the order of their distance from the planet, and special emphasis is given to the Io plasma torus (IPT) in the 4.9-8-Jovian-radius region and to the extended Jovian magnetotail. Topics reviewed include synchrotron radiation, magnetic-field models, Na and S emissions in the IPT, aurora, the magnetic-anomaly model, IPT plasma diffusion-convection, Io-generated Alfven wave, plasma configuration beyond the IPT, low-energy charged particles, cosmic-ray-energy particles, particle acceleration, magnetic configuration, tail current sheet and plasma disc, magnetopause and magnetosheath, interplanetary ions of Jovian origin, and the Jovian magnetosphere at Saturnian distances.

Birmingham, T. J.↗

Turbulent heating in solar cosmic ray theory

The heating of minor ions in solar flares by wave-wave-particle interaction with Langmuir waves, or ion acoustic waves, can be described by a diffusion equation in velocity-space for the particle distribution function. The dependence of the heating on the ion charge and mass, and on the composition of the plasma, is examined in detail. It is found that the heating mechanisms proposed by Ibragimov and Kocharov cannot account for the enhanced abundances of heavy elements in the solar cosmic rays.

Weatherall, J.↗

Turbulent heating in solar cosmic-ray theory

The heating of minor ions in solar flares by wave-wave-particle interaction with Langmuir waves, or ion acoustic waves, can be described by a diffusion equation in velocity-space for the particle distribution function. The dependence of the heating on the ion charge and mass, and on the composition of the plasma, is examined in detail. It is found that the heat mechanisms proposed by Ibragimov and Kocharov cannot account for the enhanced abundances of heavy elements in the solar cosmic rays.

Weatherall, J.↗

A CCIR aeronautical mobile satellite report

Propagation effects in the aeronautical mobile-satellite service differ from those in the fixed-satellite service and other mobile-satellite services because: small antennas are used on aircraft, and the aircraft body may affect the performance of the antenna; high aircraft speeds cause large Doppler spreads; aircraft terminals must accommodate a large dynamic range in transmission and reception; and due to their high speeds, banking maneuvers, and three-dimensional operation, aircraft routinely require exceptionally high integrity of communications, making even short-term propagation effects very important. Data and models specifically required to characterize the path impairments are discussed, which include: tropospheric effects, including gaseous attenuation, cloud and rain attenuation, fog attenuation, refraction and scintillation; surface reflection (multipath) effects; ionospheric effects such as scintillation; and environmental effects (aircraft motion, sea state, land surface type). Aeronautical mobile-satellite systems may operate on a worldwide basis, including propagation paths at low elevation angles. Several measurements of multipath parameters over land and sea were conducted. In some cases, laboratory simulations are used to compare measured data and verify model parameters. The received signals is considered in terms of its possible components: a direct wave subject to atmospheric effects, and a reflected wave, which generally contains mostly a diffuse component.

Davarian, Faramaz↗

Nonlinear vibration and radiation from a panel with transition to chaos

The dynamic response of an aircraft panel forced at resonance and off-resonance by plane acoustic waves at normal incidence is investigated experimentally and numerically. Linear, nonlinear (period doubling), and chaotic responses are obtained by increasing the sound pressure level of the excitation. The response time history is sensitive to the input level and to the frequency of excitation. The change in response behavior is due to a change in input conditions, triggered either naturally or by modulation of the bandwidth of the incident waves. Off-resonance bifurcation is diffused and difficult to maintain; thus the panel response drifts into a linear behavior. The acoustic pressure emanated by the panel is either linear or nonlinear as is the vibration response. The nonlinear effects accumulate during the propagation with distance. Results are also obtained on the control of the panel response using damping tape on an aluminum panel and a graphite epoxy panel having the same size and weight. Good agreement is obtained betwen the experimental and numerical results.

Maestrello, Lucio↗

Nonlinear vibration and radiation from a panel with transition to chaos induced by acoustic waves

The dynamic response of an aircraft panel forced at resonance and off-resonance by plane acoustic waves at normal incidence is investigated experimentally and numerically. Linear, nonlinear (period doubling) and chaotic responses are obtained by increasing the sound pressure level of the excitation. The response time history is sensitive to the input level and to the frequency of excitation. The change in response behavior is due to a change in input conditions, triggered either naturally or by modulation of the bandwidth of the incident waves. Off-resonance, bifurcation is diffused and difficult to maintain, thus the panel response drifts into a linear behavior. The acoustic pressure emanated by the panel is either linear or nonlinear as is the vibration response. The nonlinear effects accumulate during the propagation with distance. Results are also obtained on the control of the panel response using damping tape on aluminum panel and using a graphite epoxy panel having the same size and weight. Good agreement is obtained between the experimental and numerical results.

Maestrello, Lucio↗

Energy and radiation balance components for three grass surfaces near Kursk, Russia

The energy and radiation balance components were determined over three grass surfaces, located on the Streletskaya steppe during July 1991. The Bowen ratio energy balance method was used to determine the sensible and latent heat flux densities using six computer controlled systems. A total of 126 variables were sampled, including global, diffuse, and reflected solar radiation, long wave radiation (up and down), net radiation, photosynthetically active radiation above and below the vegetation, infrared surface temperatues, soil temperature and heat flow, air temperature and vapor pressure at two levels, wind speed and direction, and precipitation. The ranking of the sites from greatest to smallest for net radiation and latent heat flux density were preserve, mowed in 1990, and mowed in 1991. The ranking of the sites from greatest to smallest for sensible heat flux density were mowed in 1990, mowed in 1991, and preserve.

Fritschen, Leo J.↗

Migrational Instabilities in Particle Suspensions

This work deals with an instability arising from the shear-induced migration of particles in dense suspensions coupled with a dependence of viscosity on particle concentration. The analysis summarized here treats the inertialess (Re = O) linear stability of homogeneous simple shear flows for a Stokesian suspension model of the type proposed by Leighton and Acrivos (1987). Depending on the importance of shear-induced migration relative to concentration-driven diffusion, this model admits short-wave instability arising from wave-vector stretching by the base flow and evolving into particle-depleted shear bands. Moreover, this instability in the time-dependent problem corresponds to loss of ellipticity in the associated static problem (Re = O, Pe = O). While the isotropic version of the Leighton-Acrivos model is found to be stable with their experimentally determined parameters for simple shear, it is known that the stable model does not give a good quantitative description of particle clustering in the core of pipe flow (Nott and Brady 1994). This leads to the conjecture that an appropriate variant on the above model could explain such clustering as a two-phase bifurcation in the base flow.

Goddard, Joe D.↗