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Aerosciences Implications for Uranus Aerocapture

Exploration of Uranus has been indicated as the highest priority new flagship planetary science missions for NASA in the 2022 Decadal Survey. Due to Uranus’ location as the second furthest planet from the Sun, interplanetary flight times of a traditional propulsive-capture orbiter can expect to take 13-15 years to reach Uranus while requiring up to two-thirds of the launch mass budget to be allocated to propellant alone. Aerocapture presents an alternative means to capture orbit around Uranus by using aerodynamic forces generated from flight through the planetary atmosphere to decelerate to orbital insertion while reducing time in interplanetary transit time and increasing on-orbit payload mass. To date, only one spacecraft (Voyager 2) has visited Uranus, and there have been no missions which have entered its atmosphere. While knowledge of planetary entry at rocky terrestrial planets with Air (N2/O2) and CO2 dominated atmospheres has greatly advanced over the past decades with a variety of missions to learn from, the H2/He composition and much larger atmosphere of ice giants such as Uranus poses new aerosciences implications which are not fully understood. These implications must be better understood not only for aerocapture, but for planetary entry at Uranus as a whole (such as a Uranus probe, as proposed by the 2022 Decadal Survey), as well as other ice giants like Neptune. To conduct a proper analysis of aerocapture methods, aerodynamic and aerothermal analysis of flight trajectories in Uranus atmosphere are required. Previous work has investigated aerocapture at Neptune (with similar atmosphere to Uranus) using a Mid-L/D configuration. Additional previous work considers the convective heating experienced in H2/He atmospheres. The current work looks to use heritage Low-L/D configurations, adding technical depth and maturation to analysis previously performed by Girija. Atmospheric flight at ice giants presents unique challenges, including but not limited to: fidelity of atmospheric models, large entry velocities due to location in the solar system, extended flight in rarefied flow conditions due to atmospheric scale, and unusual aerodynamic flow properties specific to Uranus and Ice Giant atmospheres.

Eli Shellabarger↗
NASA NTRS1982

The moons of Saturn

Knowledge gained of the 17 Saturn moons with observations by the Voyager spacecraft are reviewed. Titan was found to have the only atmosphere, which is opaque and precludes geologic inferences. Synchronous rotation is experienced by the 14 inner moons, with a constant inner face turned toward the planet. Phoebe is too far away from the planet to lose its spin to planetary tidal forces, and has an orbit inclined 150 deg from the equatorial plane, while Iapetus is inclined 14.7 deg in its orbit. The abundance of ice on the moons is accepted as evidence of condensation formation of the moons at very low temperatures. Newly discovered moons of Saturn, including both the shepherd moons, which are suspected to maintain the rings in place, and the moons discovered by earth-based astronomy, are discussed. Finally, photographs of all the moons are examined for definitive details.

Soderblom, L. A.↗
NASA NTRS1985

What have we learned from modeling giant planet interiors?

Models of the giant planets are reviewed. The theoretical techniques used in computing the models are described, and the observational and experimental inputs are summarized. Special emphasis is placed on uncertainties in these input data. The models are then examined and the results of various authors presented. It is demonstrated that all the planets have heavy-element enhancements of between 10 and 40 earth masses, with a large fraction of this material residing in the core. It is also shown that the ratio of ice to rock in Uranus and Neptune is on the order of three. The implications of these results for theories of the origin of the solar system are discussed.

Podolak, M.↗
NASA NTRS1993

Laboratory simulations of lunar darkening processes

It was clear long before the Apollo missions that a darkening process occurs on the moon. However, its nature remains controversial and elusive. Current evidence implies that the darkening is associated with, and is probably caused by, submicroscopic metallic iron in the regolith. Questions discussed at the workshop include: (1) under what conditions will impact vitrification produce a dark glass; (2) what is the role of the submicroscopic metallic Fe (SMFe) in the lunar darkening process; (3) how is the SMFe produced; (4) is there a significant component of the regolith that has been deposited from a vapor, if so, what form is it in, and how can it be recognized, what are its effects on the chemistry of the regolith; (5) how do the processes of impact vitrification, vaporization, sputtering, and SMFe production vary as a function of distance from the sun and location in planetary magnetospheres; and (6) what other processes might affect optical properties. Ices have lower melting and boiling temperatures and sputtering yields several orders of magnitude larger than silicates. Hence, analogous processes will occur to an even greater extent on satellites of the outer planets, and these questions are relevant to those bodies as well.

Hapke, B.↗
NASA NTRS1987

Planetary atmospheres

Observations and theoretical models of planetary atmospheres published during the period 1983-1986 are reviewed, including Vega and Voyager data and results from ground-based remote sensing. Consideration is given to water-vapor and sulfur-compound distributions, electrical phenomena, and dynamics in the Venus atmosphere; dust storms, water cycles, and water and ice erosion on Mars; the compositions, temperature profiles, and dynamics of the Jovian and Saturnian atmospheres; chemical processes and zonal winds on Titan; and the radiation budgets and chemical compositions of the outer planets.

Leovy, Conway↗
NASA NTRS1988

Experimental study of planetary gases with applications to planetary interior models

High-pressure experimental data on planetary materials are critical in developing planetary models and in addressing otherwise insoluble problems of the internal structure of the major planets. Progress in the last five years has been particularly marked. Maximum static pressure of 550 GPa was achieved. For the first time, X-ray diffraction of solidified gases (Ne, Xe) and ices (H2O) were obtained at pressures above one megabar, single-crystal diffraction of ultralight elements (H2, He) were detected up to 25 GPa, pressures over 200 GPa at 77 K were reached in solid hydrogen, including the discovery of a phase transformation in the molecular solid. Advances in instrumentation and new measurements performed during 1983 to 1988 are summarized.

Bell, Peter M.↗
NASA NTRS1990

Heating and melting of small icy satellites by the decay of Al-26

The effect of radiogenic heating due to Al-26 on the thermal evolution of small icy satellites is studied. The object is to find the extent of internal melting as a function of the satellite radius and of the initial Al-26 abundance. The implicit assumption, based on observations of young stars, is that planet and satellite accretion occurred on a time scale of about 10 to the 6th yr (comparable with the lifetime of Al-26. The icy satellites are modeled as spheres of initially amorphous ice, with chondritic abundances of K-40, Th-232, U-235, and U-238, corresponding to an ice/dust mass ratio of 1. Evolutionary calculations are carried out, spanning 4.5 x 10 to the 9th yr, for different combinations of the two free parameters. Heat transfer by subsolidus convection is neglected for these small satellites. The main conclusion is that the initial Al-26 abundance capable of melting icy bodies of satellite size to a significant extent is more than 10 times lower than that prevailing in the interstellar medium (or that inferred from the Ca-Al rich inclusions of the Allende meteorite, about 7 x 10 to the -7th by mass).

Prialnik, Dina↗
NASA NTRS1992

Clouds of ammonia ice - Laboratory measurements of the single-scattering properties

A new apparatus for the growth of clouds of ammonia and water ice has been developed which represents an improvement over the one constructed by Holmes (1981). Better thermal control of the cloud chamber has been achieved so that colder temperature relevant to the outer planets' atmospheres could be reached. The angular resolution of the scattering measurements has been improved from 10 deg to about 2 deg. A rotating filter wheel combined with a much larger computer allows a complete data set to be collected in three colors once per second. This capability is important in monitoring cloud properties as they change with time and in collecting data on larger crystals which can fall through the beam in a few seconds.

Pope, Shelly K.↗
NASA NTRS2010

Cryogenic Carbonate Formation on Mars: Clues from Stable Isotope Variations Seen in Experimental Studies

Discoveries of large deposits of sedimentary materials on the planet Mars by landers and orbiters have confirmed the widely held hypothesis that water has played a crucial role in the development of the martian surface. Recent studies have indicated that both water ice and liquid water may have been present and in the case of water ice perhaps is still present on or near the surface of Mars. However, there remains much controversy about the prevailing atmospheric conditions and climate of Mars during its history and whether liquid water existed on the martian surface simply during discrete geological events or whether this water was present over relatively much longer geologic time periods. The recent identification of Ca-rich carbonate by the Phoenix lander as well as its measurement of the isotopic composition of atmospheric CO2 has shown the importance of understanding the carbonates on Mars as an important sink of atmospheric carbon. This work compliments that of our past experiments where we produced cryogenic calcite in open containers, as analogs for terrestrial aufeis formation, and as a means for evaluating the fractionation of C-13 in CO2 during bicarbonate freezing [13]. Unlike our previous experiments in which carbonates were grown in ambient laboratory condition in open containers (atmospheric pressure and composition), this work attempts to quantify the amount of delta C-13 enrichment possible in both fluids and secondary carbonates formed from freezing of bicarbonate fluids under martian-like atmospheric conditions. Morphologic textures of produced carbonates in these experiments are also examined under SEM in order to identify the effect that the cryogenic freezing process has on the mineral's mineralogy. Understanding the role of kinetic isotope fractionation during formation of carbonates under martian-like conditions will aid in our ability to quantify the isotopic composition of the carbonate sink furthering our ability to model the climate history of Mars.

Socki, Richard A.↗
NASA NTRS2006

Laboratory Studies on the Formation of Carbon-Bearing Molecules in Extraterrestrial Environments: From the Gas Phase to the Solid State

A detailed knowledge of the formation of carbon-bearing molecules in interstellar ices and in the gas phase of the interstellar medium is of paramount interest to understand the astrochemical evolution of extraterrestrial environments (1). This research also holds strong implications to comprehend the chemical processing of Solar System environments such as icy planets and their moons together with the atmospheres of planets and their satellites (2). Since the present composition of each interstellar and Solar System environment reflects the matter from which it was formed and the processes which have changed the chemical nature since the origin (solar wind, planetary magnetospheres, cosmic ray exposure, photolysis, chemical reactions), a detailed investigation of the physicochemical mechanisms altering the pristine environment is of paramount importance to grasp the contemporary composition. Once these underlying processes have been unraveled, we can identify those molecules, which belonged to the nascent setting, distinguish molecular species synthesized in a later stage, and predict the imminent chemical evolution of, for instance, molecular clouds. Laboratory experiments under controlled physicochemical conditions (temperature, pressure, chemical composition, high energy components) present ideal tools for simulating the chemical evolution of interstellar and Solar System environments. Here, laboratory experiments can predict where and how (reaction mechanisms; chemicals necessary) in extraterrestrial environments and in the interstellar medium complex, carbon bearing molecules can be formed on interstellar grains and in the gas phase. This paper overviews the experimental setups utilized in our laboratory to mimic the chemical processing of gas phase and solid state (ices) environments. These are a crossed molecular beams machine (3) and a surface scattering setup (4). We also present typical results of each setup (formation of amino acids, aldehydes, epoxides; synthesis of hydrogen terminated carbon chains as precursors to complex PAHs and to carbonaceous dust grains in general; nitriles as precursor to amino acids).

Jamieson, C. S.↗
NASA NTRS1985

Plasma-dominated magnetic field configurations for the magnetosphere of Uranus

There is significant indirect evidence that the planet Uranus possesses a magnetic field. This evidence is based on the observation of hydrogen Lyman alpha emission from Uranus with the aid of the International Ultraviolet Explorer (IUE) spacecraft. The detection of water ice on the Uranian moons led Cheng (1984) to suggest that charged particle sputtering of the icy satellites could provide a significant internal source of oxygen ions and protons to the Uranian magnetosphere. Cheng concluded that this mechanism would predict aurorae around both magnetic poles of Uranus. Cheng's idea of the presence of a continuous internal plasma supply to the Uranian magnetosphere is further pursued in the present investigation. Questions are considered regarding the evolution of Uranus' magnetosphere from a vacuum configuration toward a plasma pressure dominated equilibrium configuration, taking into account the amount of the thermal plasma pressure as a free parameter.

Ip, A. K.↗
NASA NTRS1989

Pluto's atmosphere near perihelion

A recent stellar occultation has confirmed predictions that Pluto has an atmosphere which is sufficiently thick to uniformly envelope the planet and to extend far above the surface. Pluto's atmosphere consists of methane and perhaps other volatile gases at temperatures below their freezing points; it should regulate the surface temperature of its volatile ices to a globally uniform value. As Pluto approaches and passes through perihelion, a seasonal maximum in the atmospheric bulk and a corresponding minimum in the exposed volatile ice abundance is expected to occur. The lag in maximum atmospheric bulk relative to perihelion will be diagnostic of the surface thermal properties. An estimate of Pluto's atmospheric bulk may result if a global darkening (resulting from the disappearance of the seasonally deposited frosts) occurs before the time of maximum atmospheric bulk. The ice deposited shortly after perihelion may be diagnostic of the composition of Pluto's volatile reservoir.

Trafton, L. M.↗
NASA NTRS1992

The interannual variability of polar cap recessions as a measure of Martian climate and weather: Using Earth-based data to augment the time line for the Mars observer mapping mission

The recessions of the polar ice caps are the most visible and most studied indication of seasonal change on Mars. Circumstantial evidence links these recessions to the seasonal cycles of CO2, water, and dust. The possible advent of a planet encircling storm during the Mars Observer (MO) mission will provide a detailed correlation with a cap recession for that one Martian year. That cap recession will then be compared with other storm and nonstorm years. MO data will also provide a stronger link between cap recessions and the water and CO2 cycles. Cap recession variability might also be used to determine the variability of these cycles. After nearly a century of valiant attempts at measuring polar cap recessions, including Mariner 9 and Viking data, MO will provide the first comprehensive dataset. In contrast to MO, the older data are much less detailed and precise and could be forgotten, except that it will still be the only information on interannual variability. By obtaining simultaneous Earth-based observations (including those from Hubble) during the MO mission, direct comparisons can be made between the datasets.

Martin, L. J.↗
NASA NTRS2000

Latest Results from the Mars Orbiter Laser Altimeter (MOLA)

The first MOLA data were acquired in Sept. 1997 shortly after the arrival of Mars Global Surveyor (MGS) at Mars and before the start of aerobraking. Subsequently, data were obtained during several months in the spring and summer of 1998. All these data were obtained over the northern hemisphere. At the beginning of March 1999 the mapping phase of the MGS mission began in the designed 400 km near circular, near polar orbit and MOLA began collecting continuous global data. By the end of 1999 MOLA had acquired over 250 million altimeter measurements of the radius of the planet at accuracies of the order of a few meters radially and about 100 meters horizontally. These observations revealed the detailed structure of the Martian surface, the form of the polar caps, as well as the shape of the planet. The early results provided a unique view of the north polar cap and subsequently of the south polar cap from which an estimate of the total volume of present-day surface water ice of 3.2 to 4.7 million cubic km was obtained. To obtain full coverage of the polar caps it was necessary for MOLA to be pointed off nadir approximately 20 degrees and on several occasions MGS has performed a roll maneuver to make these observations. It is hoped that these off-nadir observations of the central region of the cap (MGS only reaches to latitudes plus or minus 86.5) will assist in the detection of the seasonal deposition of CO2 since it is believed that these high latitudes regions may be the accumulation zone.

Smith, David E.↗
NASA NTRS2010

Ultraviolet Irradiation of Pyrimidine in Interstellar Ice Analogs: Formation and Photo-Stability of Nucleobases

Astrochemistry laboratory experiments recently showed that molecules of prebiotic interest can potentially form in space, as supported by the detection of amino acids in organic residues formed by the UV photolysis of ices simulating interstellar and cometary environments (H2O, CO, CO2, CH3OH, NH3, etc.). Although the presence of amino acids in the interstellar medium (ISM) is still under debate, experiments and the detection of amino acids in meteorites both support a scenario in which prebiotic molecules could be of extraterrestrial origin, before they are delivered to planets by comets, asteroids, and interplanetary dust particles. Nucleobases, the informational subunits of DNA and RNA, have also been detected in meteorites, although they have not yet been observed in the ISM. Thus, these molecules constitute another family of prebiotic compounds that can possibly form via abiotical processes in astrophysical environments. Nucleobases are nitrogen-bearing cyclic aromatic species with various functional groups attached, which are divided into two classes: pyrimidines (uracil, cytosine, and thymine) and purines (adenine and guanine). In this work, we study how UV irradiation affects pyrimidine mixed in interstellar ice analogs (H2O, NH3, CH3OH). In particular, we show that the UV irradiation of H2O:pyrimidine mixtures leads to the production of oxidized compounds including uracil, and show that both uracil and cytosine are formed upon irradiation of H2O:NH3:pyrimidine mixtures. We also study the photostability of pyrimidine and its photoproducts formed during these experiments.

Nuevo, Michel↗
NASA NTRS2000

Paleoproterozoic snowball earth: extreme climatic and geochemical global change and its biological consequences

Geological, geophysical, and geochemical data support a theory that Earth experienced several intervals of intense, global glaciation ("snowball Earth" conditions) during Precambrian time. This snowball model predicts that postglacial, greenhouse-induced warming would lead to the deposition of banded iron formations and cap carbonates. Although global glaciation would have drastically curtailed biological productivity, melting of the oceanic ice would also have induced a cyanobacterial bloom, leading to an oxygen spike in the euphotic zone and to the oxidative precipitation of iron and manganese. A Paleoproterozoic snowball Earth at 2.4 Giga-annum before present (Ga) immediately precedes the Kalahari Manganese Field in southern Africa, suggesting that this rapid and massive change in global climate was responsible for its deposition. As large quantities of O(2) are needed to precipitate this Mn, photosystem II and oxygen radical protection mechanisms must have evolved before 2.4 Ga. This geochemical event may have triggered a compensatory evolutionary branching in the Fe/Mn superoxide dismutase enzyme, providing a Paleoproterozoic calibration point for studies of molecular evolution.

Earth (Planet)↗
NASA NTRS1981

On the structure and composition of Uranus and Neptune

A series of models is presented of Uranus and Neptune in which the relative amounts of (1) rock, (2) ices, and (3) hydrogen and helium are allowed to vary. By fitting the density and the gravitational quadrupole moment, the model composition can be determined. Because of the ambiguity in the rotation periods of these planets, several possible models are presented and discussed.

Podolak, M.↗
NASA NTRS1999

Origin, Bulk Chemical Composition and Physical Structure of the Galilean Satellites of Jupiter: A Post-Galileo Analysis

The origin of Jupiter and the Galilean satellite system is examined in the light of the new data that has been obtained by the NASA Galileo Project. In particular, special attention is given to a theory of satellite origin which was put forward at the start of the Galileo Mission and on the basis of which several predictions have now been proven successful. These predictions concern the chemical composition of Jupiter's atmosphere and the physical structure of the satellites. According to the proposed theory of satellite origin, each of the Galilean satellites formed by chemical condensation and gravitational accumulation of solid grains within a concentric family of orbiting gas rings. These rings were cast off equatorially by the rotating proto-Jovian cloud (PJC which contracted gravitationally to form Jupiter some 4 1/2 billion years ago. The PJC formed from the gas and grains left over from the gas ring that had been shed at Jupiter's orbit by the contracting proto-solar cloud (PSC Supersonic turbulent convection provides the means for shedding discrete gas rings. The temperatures T (sub n) of the system of gas rings shed by the PSC and PJC vary with their respective mean orbital radii R (sub n) (n = 0, 1,2,...) according as T (sub n) proportional to R (sub n) (exp -0.9). If the planet Mercury condenses at 1640 K, so accounting for the high density of that planet via a process of chemical fractionation between iron and silicates, then T (sub n) at Jupiter's orbit is 158 K. Only 35% of the water vapour condenses out. Thus fractionation between rock and ice, together with an enhancement in the abundance of solids relative to gas which takes place through gravitational sedimentation of solids onto the mean orbit of the gas ring, ensures nearly equal proportions of rock and ice in each of Ganymede and Callisto. Io and Europa condense above the H20 ice point and consist solely of hydrated rock (h-rock). The Ganymedan condensate consists of h-rock and H20 ice. For Callisto, NH3 ice makes up -5% of the condensate mass next to h-rock (approximately 50%) and H2O ice (approximately 45%). Detailed thermal and structural models for each of Europa, Ganymede and Callisto are constructed on the basis of the above initial bulk chemical compositions. For Europa (E), a predicted 2-zone model consisting of a dehydrated rock core of mass 0.912 M (sub E) and a 150 km thick frozen mantle of salty H2O yields a moment-of-inertia coefficient which matches the Galileo Orbiter gravity measurement. For Ganymede (G), a 3-zone model possessing an inner core of solid FeS and mass approximately 0.116 M (sub G), and an outer H2O ice mantle of mass approximately 0.502 M (sub G) is needed to explain the gravity data. Ganymede's native magnetic field was formed by thermoremanent magnetization of Fe3O4. A new Callisto (C) model is proposed consisting of a core of mass 0.826 M (sub C) containing a uniform mixture of h-rock (60% by mass) and H2O and NH3 ices, and capped by a mantle of pure ice. This model may have the capacity to yield a thin layer of liquid NH3 (raised dot) 2H2O at the core boundary, in line with Galileo's discovery of an induced magnetic field.

Prentice, A. J. R.↗