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At least 397 records · Page 22

Distribution and Validation of CERES Irradiance Global Data Products Via Web Based Tools

The CERES SYN1deg product provides climate quality 3-hourly globally gridded and temporally complete maps of top of atmosphere, in atmosphere, and surface fluxes. This product requires efficient release to the public and validation to maintain quality assurance. The CERES team developed web-tools for the distribution of both the global gridded products and grid boxes that contain long term validation sites that maintain high quality flux observations at the Earth's surface. These are found at: http://ceres.larc.nasa.gov/order_data.php. In this poster we explore the various tools available to users to sub-set, download, and validate using surface observations the SYN1Deg and Surface-EBAF products. We also analyze differences found in long-term records from well-maintained land surface sites such as the ARM central facility and high quality buoy radiometers, which due to their isolated nature cannot be maintained in a similar manner to their land based counterparts.

Rutan, David↗

Large-Scale High-Resolution Coastal Mangrove Forests Mapping Across West Africa With Machine Learning Ensemble and Satellite Big Data

Coastal mangrove forests provide important ecosystem goods and services, including carbon sequestration, biodiversity conservation, and hazard mitigation. However, they are being destroyed at an alarming rate by human activities. To characterize mangrove forest changes, evaluate their impacts, and support relevant protection and restoration decision making, accurate and up-to-date mangrove extent mapping at large spatial scales is essential. Available large-scale mangrove extent data products use a single machine learning method commonly with 30 m Landsat imagery, and significant inconsistencies remain among these data products. With huge amounts of satellite data involved and the heterogeneity of land surface characteristics across large geographic areas, finding the most suitable method for large-scale high-resolution mangrove mapping is a challenge. The objective of this study is to evaluate the performance of a machine learning ensemble for mangrove forest mapping at 20 m spatial resolution across West Africa using Sentinel-2 (optical) and Sentinel-1 (radar) imagery. The machine learning ensemble integrates three commonly used machine learning methods in land cover and land use mapping, including Random Forest (RF), Gradient Boosting Machine (GBM), and Neural Network (NN). The cloud-based big geospatial data processing platform Google Earth Engine (GEE) was used for pre-processing Sentinel-2 and Sentinel-1 data. Extensive validation has demonstrated that the machine learning ensemble can generate mangrove extent maps at high accuracies for all study regions in West Africa (92%–99% Producer’s Accuracy, 98%–100% User’s Accuracy, 95%–99% Overall Accuracy). This is the first-time that mangrove extent has been mapped at a 20 m spatial resolution across West Africa. The machine learning ensemble has the potential to be applied to other regions of the world and is therefore capable of producing high-resolution mangrove extent maps at global scales periodically.

coastal environment↗

Elemental and lattice-parameter mapping of binary oxide superlattices of (LaNiO 3 ) 4 /(LaMnO 3 ) 2 at atomic resolution

We construct the elemental distribution and lattice strain maps from the measured atomic column positions in a (LaNiO3)(4)/(LaMnO3)(2) superlattice over a large field of view. The correlation between the distribution of B-cations and the lattice parameter in the form of Vegard's law is validated using atomic resolution energy dispersive x-ray spectroscopy (EDS). The maps show negligible Mn intermixing in the LaNiO3 layer, while Ni intermixing in the LaMnO3 layer improves away from the substrate interface to 9.5 atomic% from the 8th period onwards, indicating that the superlattice interfacial sharpness is established as the distance from the substrate increases. The maps allow an observation of the compositional defects of the B-sites, which is not possible by Z-contrast alone. Thus, this study demonstrates a promising approach for atomic scale correlative study of lattice strain and composition, and a method for the calibration of atomic resolution EDS maps.

composition↗

Mapping structural heterogeneity at the nanoscale with scanning nano-structure electron microscopy (SNEM)

Here, in this work, we explore the use of scanning electron diffraction (also known as 4D-STEM) coupled with electron atomic pair distribution function analysis (ePDF) to understand the local order (structure and chemistry) as a function of position in a complex multicomponent system, a hot rolled, Ni-encapsulated, Zr 65 Cu 17.5 Ni 10 Al 7.5 bulk metallic glass (BMG), with a spatial resolution of 3 nm. We show that it is possible to gain insight into the chemistry and chemical clustering/ordering tendency in different regions of the sample, including in the vicinity of nano-scale crystallites that are identified from virtual dark field images and in heavily deformed regions at the edge of the BMG. In addition to simpler analysis, unsupervised machine learning was used to extract partial PDFs from the material, modeled as a quasi-binary alloy, and map them in space. These maps allowed key insights not only into the local average composition, as validated by EELS, but also a unique insight into chemical short-range ordering tendencies in different regions of the sample during formation. The experiments are straightforward and rapid and, unlike spectroscopic measurements, don’t require energy filters on the instrument. We spatially map different quantities of interest (QoI’s), defined as scalars that can be computed directly from positions and widths of ePDF peaks or parameters refined from fits to the patterns. We developed a flexible and rapid data reduction and analysis software framework that allows experimenters to rapidly explore images of the sample on the basis of different QoI’s. The power and flexibility of this approach are explored and described in detail. Because of the fact that we are getting spatially resolved images of the nanoscale structure obtained from ePDFs we call this approach scanning nano-structure electron microscopy (SNEM), and we believe that it will be powerful and useful extension of current 4D-STEM methods.

36 MATERIALS SCIENCE↗

Coarse-Grained Simulations for the Characterization and Optimization of Hybrid Protein–DNA Nanostructures

We present here the combination of experimental and computational modeling tools for the design and characterization of protein–DNA hybrid nanostructures. Our work incorporates several features in the design of these nanostructures: (1) modeling of the protein–DNA linker identity and length; (2) optimizing the design of protein–DNA cages to account for mechanical stresses; (3) probing the incorporation efficiency of protein–DNA conjugates into DNA nanostructures. The modeling tools were experimentally validated using structural characterization methods like cryo-TEM and AFM. Our method can be used for fitting low-resolution electron density maps when structural insights cannot be deciphered from experiments, as well as enable in-silico validation of nanostructured systems before their experimental realization. Finally, these tools will facilitate the design of complex hybrid protein–DNA nanostructures that seamlessly integrate the two different biomolecules.

59 BASIC BIOLOGICAL SCIENCES↗

Model Calibration vs. Physics-guided Coverage Mapping: Case Study - Pressure Drop Calculations

This work deals with a fundamental question in model validation: given a body of available experiments and an envisaged domain of nuclear reactor operating conditions (referred to as the reactor application), how can one develop a quantitative approach that measures the portion of the prior uncertainties of the reactor application that is covered by the available experiments? Coverage here means that the uncertainties of the reactor application are originating from and behaving in exactly the same way as those observed at the experimental conditions. This approach is valuable as it provides a scientifically defendable criterion by which experimentally measured biases can be credibly extrapolated (i.e., mapped) to biases for the reactor applications. This work focuses on the application of a new methodology, referred to as physics-guided coverage mapping (PCM), to the estimation of hydraulic pressure losses in reactor pipes. PCM provides a generic, calibration-free approach to the mapping of experimental biases by relying on high fidelity physics simulation and information theoretic measure how much of the application domain is covered by the experiments. The idea is to employ the physics models to establish a joint probability distribution that relates the application and the available body of experiments. An information-theoretic measure, referred to as the mutual information, is used to calculate a quantitative metric that measures the inter-dependence between the application and the experiment. A virtual experiment is employed to demonstrate the application of PCM, wherein the pressure drop is calculated for both the experiment and the application using two different flow conditions, i.e., laminar and turbulent, and the experimental values are simulated. All parameters introducing uncertainties, such as geometry, friction factor formulas and their associated parameters are also incorporated. The results obtained with PCM are compared to a conventional calibration-based approach. This work show that the proposed approach can circumvent a number of challenges that face calibration-based methods, such as nonlinearity, ill-posedness and error compensation in high dimensional models with many parameters. This work focus primarily in this summary on parameter uncertainties and how they can be treated using PCM. In a separate summary, discuss performance of PCM under the presence of modeling uncertainties. This simple study has shown that calibration techniques for very simple situations cannot correctly scale the measurements from the experimental to the application domain. It is our view that is occurs primarily due the phenomenon of error compensation where on artificially changes the value of selected parameters to account for all sources of uncertainties. The situation gets more complicated when one calibrates multiple parameters where now the problem could potentially have an infinite number of ways by which the errors can be compensated. (authors)

42 ENGINEERING↗

Machine-Learning-Based Predictive Modeling of Glass Transition Temperatures: A Case of Polyhydroxyalkanoate Homopolymers and Copolymers

Polyhydroxyalkanoate-based polymers—being ecofriendly, biosynthesizable, and economically viable and possessing a broad range of tunable properties—are currently being actively pursued as promising alternatives for petroleum-based plastics. The vast chemical complexity accessible within this class of polymers gives rise to challenges in the rational discovery of novel polymer chemistries for specific applications. Here, the burgeoning field of polymer informatics addresses this challenge via providing tools and strategies for accelerated property prediction and materials design via surrogate machine-learning models built on reliable past data. In this contribution, we use glass transition temperature T g as an example target property to demonstrate promise of the data-enabled route to accelerated learning of accurate structure–property mappings in PHA-based polymers. Our analysis uses a data set of experimentally measured T g values, polymer molecular weights, and a polydispersity index for PHA-based homo- and copolymers that was carefully assembled from the literature. A fingerprinting scheme that captures key properties based on topology, shape, and charge/polarity of specific chemical units or motifs forming the polymer backbone was devised to numerically represent the polymers. A validated statistical learning model is then developed to allow for a mapping of the polymer fingerprints onto the property space in a physically meaningful and reliable manner. Once developed, the model can not only rapidly predict the property of new PHA polymers but also provide uncertainties underlying the predictions. The model is further combined with an evolutionary-algorithm-based search strategy to efficiently identify multicomponent polymer compositions with a prespecified T g . While the present contribution is focused specifically on T g , the surrogate model development approach put forward here is general and can, in principle, be extended to a range of other properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

On the completeness of contraction map proof method for holographic entropy inequalities

The contraction map proof method is the commonly used method to prove holographic entropy inequalities. Existence of a contraction map corresponding to a holographic entropy inequality is a sufficient condition for its validity. But is it also necessary? In this note, we answer that question in affirmative for all linear holographic entropy inequalities with rational coefficients. We show that the pre-image of a non-contraction map is not a hypercube, but a proper cubical subgraph, and show that this manifests as alterations to the geodesic structure in the bulk, which leads to the violation of inequalities by holographic geometries obeying the RT formula.

97 MATHEMATICS AND COMPUTING↗

A cloud-free MODIS snow cover dataset for the contiguous United States from 2000 to 2017

This article presents a cloud-free snow cover dataset with a daily temporal resolution and 0.05° spatial resolution from March 2000 to February 2017 over the contiguous United States (CONUS). The dataset was developed by completely removing clouds from the original NASA’s Moderate Resolution Imaging Spectroradiometer (MODIS) Snow Cover Area product (MOD10C1) through a series of spatiotemporal filters followed by the Variational Interpolation (VI) algorithm; the filters and VI algorithm were evaluated using bootstrapping test. The dataset was validated over the period with the Landsat 7 ETM+ snow cover maps in the Seattle, Minneapolis, Rocky Mountains, and Sierra Nevada regions. The resulting cloud-free snow cover captured accurately dynamic changes of snow throughout the period in terms of Probability of Detection (POD) and False Alarm Ratio (FAR) with average values of 0.955 and 0.179 for POD and FAR, respectively. The dataset provides continuous inputs of snow cover area for hydrologic studies for almost two decades. The VI algorithm can be applied in other regions given that a proper validation can be performed.

54 ENVIRONMENTAL SCIENCES↗

Southern Hemisphere Polar Infrared Radiation Experiment (SHIRE) Field Campaign Report

An extended-range atmospheric emitted radiance interferometer (AERI) instrument to be deployed to Scott Base (78 S, 166 E) in McMurdo Sound, Antarctica for the purpose of synergizing with the National Aeronautics and Space Administration (NASA) Polar Radiant Energy in the Far-InfraRed Experiment (PREFIRE) satellite mission (https://prefire.ssec.wisc.edu/), examining the closure of atmospheric thermal emission, and providing validation for PREFIRE. The PREFIRE mission is the first satellite mission to map Earth’s spectrally resolved thermal emission, from 5 to 50 microns, over seasonal to annual timescales. These new observations represent the beginning of an intensive examination of the nature of thermal emission from Earth (emission from both the surface and atmosphere). A primary requirement of the PREFIRE mission is to provide validation of the retrieved variables. Numerous field sites in the Arctic (such as the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) North Slope of Alaska observatory and Summit Station, Greenland) have existing instrumentation to facilitate validation, leaving an observational gap in Antarctica. Through SHIRE, we propose to establish a temporary, intensive measurement site in Antarctica to ensure that both poles are suitably represented, and benefit from this state-of-the art science. This will also allow Arctic and Antarctic atmospheric radiative states to be compared and contrasted. For SHIRE specifically, we also propose further objectives to examine the spectrally resolved thermal radiative closure of the polar atmosphere and the historical changes in Antarctic radiative forcing, using previous Antarctic field campaigns, such as the ARM West Antarctic Radiation Experiment (AWARE).

54 ENVIRONMENTAL SCIENCES↗

Combined analysis of neutron and photon flux measurements for the Jules Horowitz reactor core mapping

We study the combined analysis of nuclear measurements to improve the knowledge of the irradiation conditions in the experimental locations of the future Jules Horowitz Reactor (JHR). The goal of the present work is to measure more accurately neutron flux, photon flux and nuclear heating in the reactor. In a Material Testing Reactor (MTR), nuclear heating is a crucial parameter to design the experimental devices to be irradiated in harsh nuclear conditions. This parameter drives the temperature of the devices and of the samples. The numerical codes can predict this parameter but in-situ measurements are necessary to reach the expected accuracy. For this reason, one objective of the IN-CORE program [1] is to study the combined measurements of neutron and photon flux and their cross advanced interpretation. It should be reminded that both neutron and photon sensors are not totally selective as their signals are due to neutron and photon interactions. We intend to measure the neutron flux by three different kinds of sensors (Uranium Fission chamber, Plutonium Fission chamber and Self Powered Neutron Detector), the photon flux by two different sensors (Ionization chamber and Self Powered Gamma Detector) and the nuclear heating by two different ones (Differential calorimeter and Gamma Thermometer). For the same parameter, we expect that the use of different kinds of sensors will allow a better estimation of the aimed parameter by mixing different spectrum responses and different neutron and gamma contributions. An experimental test called CARMEN-1 is scheduled in OSIRIS reactor (CEA Saclay - France) at the end of 2011, with the goal to map irradiation locations in the reactor reflector to get a first validation of the analysis model. This article focuses on the sensor selection for CARMEN-1 experiment and to the way to link neutron and photon flux measurements in view to reduce their uncertainties but also to better assess the neutron and photon contributions to nuclear heating. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Validation and Scaling of Soil Moisture in a Semi-Arid Environment: SMAP Validation Experiment 2015 (SMAPVEX15)

The NASA SMAP (Soil Moisture Active Passive) mission conducted the SMAP Validation Experiment 2015 (SMAPVEX15) in order to support the calibration and validation activities of SMAP soil moisture data products. The main goals of the experiment were to address issues regarding the spatial disaggregation methodologies for improvement of soil moisture products and validation of the in situ measurement upscaling techniques. To support these objectives high-resolution soil moisture maps were acquired with the airborne PALS (Passive Active L-band Sensor) instrument over an area in southeast Arizona that includes the Walnut Gulch Experimental Watershed (WGEW), and intensive ground sampling was carried out to augment the permanent in situ instrumentation. The objective of the paper was to establish the correspondence and relationship between the highly heterogeneous spatial distribution of soil moisture on the ground and the coarse resolution radiometer-based soil moisture retrievals of SMAP. The high-resolution mapping conducted with PALS provided the required connection between the in situ measurements and SMAP retrievals. The in situ measurements were used to validate the PALS soil moisture acquired at 1-km resolution. Based on the information from a dense network of rain gauges in the study area, the in situ soil moisture measurements did not capture all the precipitation events accurately. That is, the PALS and SMAP soil moisture estimates responded to precipitation events detected by rain gauges, which were in some cases not detected by the in situ soil moisture sensors. It was also concluded that the spatial distribution of the soil moisture resulted from the relatively small spatial extents of the typical convective storms in this region was not completely captured with the in situ stations. After removing those cases (approximately10 of the observations) the following metrics were obtained: RMSD (root mean square difference) of0.016m3m3 and correlation of 0.83. The PALS soil moisture was also compared to SMAP and in situ soil moisture at the 36-km scale, which is the SMAP grid size for the standard product. PALS and SMAP soil moistures were found to be very similar owing to the close match of the brightness temperature measurements and the use of a common soil moisture retrieval algorithm. Spatial heterogeneity, which was identified using the high-resolution PALS soil moisture and the intensive ground sampling, also contributed to differences between the soil moisture estimates. In general, discrepancies found between the L-band soil moisture estimates and the 5-cm depth in situ measurements require methodologies to mitigate the impact on their interpretations in soil moisture validation and algorithm development. Specifically, the metrics computed for the SMAP radiometer-based soil moisture product over WGEW will include errors resulting from rainfall, particularly during the monsoon season when the spatial distribution of soil moisture is especially heterogeneous.

SMAPVEX15↗

The halo light-cone catalogues of ABACUSSUMMIT

We describe a method for generating halo catalogues on the light-cone using the AbacusSummit suite of N-body simulations. The main application of these catalogues is the construction of realistic mock galaxy catalogues and weak lensing maps on the sky. Our algorithm associates the haloes from a set of coarsely spaced snapshots with their positions at the time of light-cone crossing by matching halo particles to on-the-fly light-cone particles. It then records the halo and particle information into an easily accessible product, which we call the AbacusSummit halo light-cone catalogues. Our recommended use of this product is in the halo mass regime of M halo > 2.1 x 10 11 M ⊙ h -1 for the base resolution simulations, i.e. haloes containing at least 100 particles, where the interpolated halo properties are most reliable. To test the validity of the obtained catalogues, we perform various visual inspections and consistency checks. In particular, we construct galaxy mock catalogues of emission-line galaxies (ELGs) at z ~ 1 by adopting a modified version of the AbacusHOD script, which builds on the standard halo occupation distribution (HOD) method by including various extensions. We find that the multipoles of the autocorrelation function are consistent with the predictions from the full-box snapshot, implicitly validating our algorithm. In addition, we compute and output CMB convergence maps and find that the auto- and cross-power spectrum agrees with the theoretical prediction at the sub-per-cent level.

79 ASTRONOMY AND ASTROPHYSICS↗

Hot deformation characteristics of AZ80 magnesium alloy: Work hardening effect and processing parameter sensitivities

Isothermal compression experiment of AZ80 magnesium alloy was conducted by Gleeble thermo-mechanical simulator in order to quantitatively investigate the work hardening (WH), strain rate sensitivity (SRS) and temperature sensitivity (TS) during hot processing of magnesium alloys. The WH, SRS and TS were described by Zener-Hollomon parameter (Z) coupling of deformation parameters. The relationships between WH rate and true strain as well as true stress were derived from Kocks-Mecking dislocation model and validated by our measurement data. The slope defined through the linear relationship of WH rate and true stress was only related to the annihilation coefficient Ω. Obvious WH behavior could be exhibited at a higher Z condition. Furthermore, we have identified the correlation between the microstructural evolution including β-Mg17Al12 precipitation and the SRS and TS variations. Intensive dynamic recrystallization and homogeneous distribution of β-Mg17Al12 precipitates resulted in greater SRS coefficient at higher temperature. The deformation heat effect and β-Mg17Al12 precipitate content can be regarded as the major factors determining the TS behavior. At low Z condition, the SRS becomes stronger, in contrast to the variation of TS. The optimum hot processing window was validated based on the established SRS and TS values distribution maps for AZ80 magnesium alloy.

36 MATERIALS SCIENCE↗

Resonating quantum three-coloring wave functions for the kagome quantum antiferromagnet

Motivated by the recent discovery of a macroscopically degenerate exactly solvable point of the spin-1/2 XXZ model for J z /J = –1/2 on the kagome lattice —a result that holds for arbitrary magnetization—we develop an exact mapping between its exact ”quantum three-coloring” wave functions and the characteristic localized and topological magnons. This map, involving ”resonating two-color loops,” is developed to represent exact many-body ground state wave functions for special high magnetizations. Using this map we show that these exact ground state solutions are valid for any J z /J ≥ –1/2. This demonstrates the equivalence of the ground-state wave function of the Ising, Heisenberg, and XY regimes all the way to the J z /J = –1/2 point for these high magnetization sectors. In the hardcore bosonic language, this means that a certain class of exact many-body solutions, previously argued to hold for purely repulsive interactions (J z ≥ 0), actually hold for attractive interactions as well, up to a critical interaction strength. For the case of zero magnetization, where the ground state is not exactly known, we perform density matrix renormalization group calculations. Based on the calculation of the ground state energy and measurement of order parameters, we provide evidence for a lack of any qualitative change in the ground state on finite clusters in the Ising (J z >> J), Heisenberg (J z = J), and XY (J z = 0) regimes, continuing adiabatically to the vicinity of the macroscopically degenerate J z /J = –1/2 point. Furthermore, these findings offer a framework for recent results in the literature and also suggest that the J z /J = –1/2 point is an unconventional quantum critical point whose vicinity may contain the key to resolving the spin-1/2 kagome problem.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

A Measurement Source Authentication Methodology for Power System Cyber Security Enhancement

This letter proposes a spatial signature-based power system measurement source identification and authentication methodology. A mathematical morphology method is used to decompose the power system measurement signals and obtain the intrinsic components, which sparsity trends and roughness values are further derived to establish the time-frequency (TF) sparsity mapping. Then random forest classification is utilized to correlate the correct measurement source for each measurement signal based on the derived TF sparsity mapping. Finally, experiment results using five phasor measurement units has validated the effectiveness of this methodology.

42 ENGINEERING↗

Examining Rail Transportation Route of Crude Oil in the United States Using Crowdsourced Social Media Data

Safety issues associated with transporting crude oil by rail have been a concern since the boom of the U.S. domestic shale oil production in 2012. During the last decade, over 300 crude-oil-by-rail incidents have occurred in the United States. Some of them have caused adverse consequences including fire and hazardous materials leakage. However, only limited information on crude-on-rail routes and their associated risks is available to the public. To this end, this study proposed an unconventional way to reconstruct crude-on-rail routes using geotagged photos harvested from the Flickr website. The proposed method linked the geotagged photos of crude oil trains posted online with national railway networks to identify potential railway segments that those crude oil trains were traveling on. Here, a shortest path-based method was applied to infer the complete crude-on-rail routes, by utilizing the confirmed railway segments as well as their directional information. Validation of the inferred routes was performed using a public map and official crude oil incident data. The results suggested that the inferred routes based on geotagged photos had high coverage, with approximately 96% of the documented crude oil incidents aligned with the reconstructed crude-on-rail network. The inferred crude oil train routes were found to pass through several metropolitan areas of high population density, who were exposed to potential risk. These findings could improve situational awareness for policy makers and transportation planners. In addition, with the inferred routes, this study has established a good foundation for future crude oil train risk-analyses along the rail route.

42 ENGINEERING↗

Laser Scanning System for Pressure and Temperature Paints

Acquiring pressure maps of aerodynamic surfaces is very important for improving and validating the performance of aerospace vehicles. Traditional pressure measurements are taken with pressure taps embedded in the model surface that are connected to transducers. While pressure taps allow highly accurate measurements to be acquired, they do have several drawbacks. Pressure taps do not give good spatial resolution due to the need for individual pressure tubes, compounded by limited space available inside models. Also, building a model proves very costly if taps are needed because of the large amount of labor necessary to drill, connect and test each one. The typical cost to install one tap is about $200. Recently, a new method for measuring pressure on aerodynamic surfaces has been developed utilizing a technology known as pressure sensitive paints (PSP). Using PSP, pressure distributions can be acquired optically with high spatial resolution and simple model preparation. Flow structures can be easily visualized using PSP, but are missed using low spatial resolution arrays of pressure taps. PSP even allows pressure distributions to be found on rotating machinery where previously this has been extremely difficult or even impossible. The goal of this research is to develop a laser scanning system for use with pressure sensitive paints that allows accurate pressure measurements to be obtained on various aerodynamic surfaces ranging from wind tunnel models to high speed jet engine compressor blades.

Sullivan, John↗