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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22

Nonlinear viscoelastic response of silicone additively manufactured direct ink write (DIW) foams under repetitive compression

To investigate dynamic fatigue behavior of foam in military protective applications, such as helmets, additively manufactured (AM) foams were compressively strained into the plateau region using a reduced design of experiments. A simple power law was found to govern the decline in dynamic stiffness (complex modulus) as the foams underwent the purchase order requirement of 10,000 cycles of small deformation in the plateau region. This rate of decline was newly found to correlate with the degree of nonlinearity in the material’s deformation, quantified using total harmonic distortion. Materials with low nonlinearity exhibited relatively stable stiffness across cycles, while those with high nonlinearity experienced greater losses. The observed nonlinearity depended on both applied stress and strain rate. A strong linear correlation (R 2 = 0.78) was identified between second-order nonlinearity and the time-dependent stiffness response. Two lattice structures were examined: face-centered tetragonal (FCT) and simple cubic (SC). The SC material exhibited higher total harmonic distortion (5%) and lower stiffness retention than the FCT (2%). In conclusion, these results suggest that for cyclic compression applications in a wide variety of industries such as packaging, personal protective equipment, or aerospace, selecting materials with lower stress and greater structural uniformity can enhance the stability of dynamic performance.

42 ENGINEERING↗

Atomic Oxygen Impacts on Materials International Space Station Experiment (MISSE)-16 flight Samples

A variety of materials consisting of polyimides, polyethylene terephthalates (PETs), fiber reinforced polymers, and polyhedral oligomeric silsesquioxanes (POSS) were on the exterior of the International Space Station (ISS) as part of Materials International Space Station Experiment (MISSE)-16. Samples on the side of the ISS pointing in the direction of the spacecraft’s motion (the ram direction) were observed for effects due to atomic oxygen (AO). The erosion yield of select materials from MISSE-16 is reported, as well as their variation in surface roughness due to AO erosion. Trade names and trademarks are used in this paper for identification only. Their usage does not constitute an official endorsement, either expressed or implied, by the National Aeronautics and Space Administration.

Samuel A Westrick↗

Updating the Building Science Advisor (BSA): A Tool to Assist in the Design of Durable Building Envelopes

Predicting the moisture durability of building envelope components remains challenging due to multiple influencing factors, including material selection, assembly positioning, local climate conditions, air tightness, interior environment, and construction quality. Building codes increasingly emphasize energy efficiency through enhanced insulation and tighter envelopes but offer limited guidance on moisture durability considerations. Consequently, builders face uncertainty, particularly as new materials and assemblies enter the market.The Building Science Advisor (BSA) is a free, web-based expert system developed to address these challenges by providing actionable insights into the moisture durability and energy efficiency of both new and retrofit wall designs. Recently updated, we are now providing version 3.0 of the tool. BSA features significant user interface improvements, enhancing navigation and user interaction through a refreshed, intuitive design. Additionally, the tool incorporates a newly developed database containing pre-simulated wall assembly cases, significantly reducing response times and improving the accuracy of moisture durability assessments. Furthermore, the updated BSA includes moisture content as a performance criterion, providing users with a more comprehensive understanding of moisture-related durability risks. These enhancements enable rapid, reliable assessments tailored to specific climate zones and local building practices. BSA continues to offer targeted guidance on wall retrofit scenarios and delivers access to an expanded library of location-specific building science resources.This paper describes these key updates, highlighting the enhanced features, expanded capabilities, and overall improvements to user experience and educational content. The paper includes a demonstration that illustrates how the revised BSA effectively supports practitioners in designing durable, energy-efficient building envelope assemblies.

Salonvaara, Mikael [ORNL] (ORCID:0000000318991554)↗

Status of Understanding for Seal Materials

Material selection for mainshaft face and ring seals, labyrinth seals, accessory gearbox face seals, and lip seals are discussed in light of tribology requirements and a given seal application. Carbon graphite has been found to be one of the best sealing materials and it is widely used in current gas turbine mainshaft and accessory gearbox seals. Its popularity is due to its unique combination of properties which consists of dimensional stability, corrosion resistance, low friction, good self lubricating characteristics, high thermal conductivity and low thermal expansion, the latter two properties combining to provide good thermal shock resistance. A brief description of the seals and the requirements they must meet are discussed to provide insight into the limitations and advantages of the seals in containing the lubricant. A forecast is made of the operational requirements of main shaft and gearbox seals for advanced engines and candidate materials and coatings that may satisfy these advanced engine requirements.

P F Brown↗

Ho:Tm:Lu(3)Al(5)O(12) As An Infrared-Laser Material

Material selected on basis of quantum-mechanical modeling of lasing properties. Ho:Tm:Lu(3)Al(5)O(12) features relatively low thermal occupation of lower laser level because this level higher than corresponding levels of most other available laser materials. In addition, it has reasonably large effective cross section for stimulated emission because of contribution of several transitions around central strong transition. Yet another desirable property is its calculated rate of upconversion is lower than those of other laser materials. Inasmuch as upconversion detracts from efficiency of laser, this lower rate of upconversion is highly desirable.

Barnes, Norman P.↗

Affordable Development Strategy for NEP Nuclear Systems

One nuclear electric propulsion (NEP) reactor systems under consideration is a hydride moderated thermal spectrum reactor fueled by high assay low enriched uranium (HALEU). While such a reactor is expected to yield the lightest HALEU reactor design, its development challenges grow exponentially with increasing mission demands, most notably power output, specific weight of the overall system (which may require operation at temperatures exceeding 1200 K), service lifetime, and human-rated reliability. Two of the greatest cost drivers are full-powered nuclear demonstrations and extensive material development campaigns, so it is important to consider options that can minimize the need for or complexity of such tasks. This paper discusses a structured framework being developed for assessing how NEP design choices, such as materials selection, neutronic features, and heat-removal technologies, can translate into project risk and how project performance goals can be traded with development cost.Reactors operating at high temperatures often require cutting-edge heat transfer technologies and creep-resistant materials. Use of new materials in high temperature reactors brings additional complication beyond those common to any new space materials development campaign. For example, such materials may not possess necessary neutronic cross-sectional or neutronic irradiation data. Similarly, use of new materials may significantly influence core neutronics; in some extreme cases, neutronic reactivity feed-back of certain new materials can vary during their service life as radiation damage impacts the scattering cross-section. In an affordable development approach, high fidelity modeling and simulation tools are used to identify and characterize potential ‘knees-in-the-curves’ in the relationship that exists between the mission characteristics and the project risk. Of particular significance is use of modern uncertainty management and variance reduction methods to perform gap analyses that feed into phenomena identification and ranking tables (PIRT) commonly used to communicate nuclear readiness levels. Model-based measurements techniques are used to design sub-scale experiments as a substitute to minimize orcompletely eliminate the need for nuclear demonstrations.This paper will describe the approach and present preliminary results. It will lay the groundwork for developing a set of metrics that can be broadly characterized as system nuclear readiness levels and advancement degree of difficulty for nuclear systems. Equally importantly, a goal of this paper is to initiate a dialogue among stakeholders on what is the sufficient level of maturity that is required for launching a demonstration unit.

Dasari V Rao↗

Free Surface Phenomena Under Low- and Zero-Gravity Conditions

In a low- or zero-gravity environment the free surface of a liquid can behave in striking, unexpected ways. For example, in a partially filled container, a free surface that is well behaved under terrestrial conditions can rise to an arbitrarily large height or even fail to exist when gravity is absent. An answer is sought to the central mathematical questions: Under what conditions can free surfaces exist and what are their properties? -- and experimental questions of what means can be devised to observe and to measure the surfaces quantitatively. Current activity focuses on material selection and the design of optical diagnostic methods for in-space experiments. These experiments will test mathematical predictions of discontinuous transition from existence to nonexistence of capillary free surfaces in certain geometric configurations under zero gravity conditions. Liquids and container materials suitable for achieving the required contact-angle range and optical properties are being investigated, as well as the effects of contaminants and fluid motion on contact angle. The optical diagnostic technique investigation concerns laser-induced fluorescence, including emphasis on data on acquisition, sources and detectors, reliability, data management, and computer control.

Concus, P.↗

High temperature electrical property measurements of ceramics

Emerging applications in energy and aerospace systems require high quality data on the high temperature electrical properties of ceramics, particularly oxides, to guide material selection, design, and modeling. This presentation demonstrates the functionality of a specially designed sample fixture that enables electrical measurements to be conducted up to temperatures as high as 1600°C. Utilizing the mismatch in the coefficient of thermal expansion between two materials, a purely mechanical method for establishing electrical contact in the van der Pauw geometry is used to measure the bulk resistivity of ceramic materials. Measurements conducted on a number of common high temperature materials will be presented, including 20 mol % Gd-doped cerium oxide. Measurements are performed using multiple techniques and compared to literature values finding excellent agreement. The approach described in this work enables the van der Pauw method to be applied to many ceramic materials over a wide range of temperatures and environments.

Cann, David P.↗

Selection process for trade study: Graphite Composite Primary Structure (GCPS)

This TA 2 document describes the selection process that will be used to identify the most suitable structural configuration for an SSTO winged vehicle capable of delivering 25,000 lbs to a 220 nm circular orbit at 51.6 degree inclination. The most suitable unpressurized graphite composite structures and material selections is within this configuration and will be the prototype design for subsequent design and analysis and the basis for the design and fabrication of payload bay, wing, and thrust structure full scale test articles representing segments of the prototype structures. The selection process for this TA 2 trade study is the same as that for the TA 1 trade study. As the trade study progresses additional insight may result in modifications to the selection criteria within this process. Such modifications will result in an update of this document as appropriate.

Greenberg, H. S.↗

Milestone 4: Test plan for Reusable Hydrogen Composite Tank System (RHCTS). Task 3: Composite tank materials

This document is the detailed test plan for the series of tests enumerated in the preceding section. The purpose of this plan is to present the test objectives, test parameters and procedures, expected performance and data analysis plans, criteria for success, test schedules, and related safety provisions and to describe the test articles, test instrumentation, and test facility requirements. Initial testing will be performed to screen four composite materials for suitability for SSTO LH2 tank loads and environmental conditions. The laminates for this testing will be fabricated by fiber placement, which is the manufacturing approach identified as baseline for the tank wall. Even though hand layup will be involved in fabricating many of the internal structural members of the tank, no hand-layup laminates will be evaluated in the screening or subsequent characterization testing. This decision is based on the understanding that mechanical properties measured for hand-layup material should be at least equivalent to properties measured for fiber-placed material, so that the latter should provide no less than a conservative approximation of the former. A single material will be downselected from these screening tests. This material will be subsequently characterized for impact-damage tolerance and durability under conditions of mechanical and thermal cycling, and to establish a preliminary design database to support ongoing analysis. Next, testing will be performed on critical structural elements fabricated from the selected material. Finally, the 8-foot diameter tank article, containing the critical structural features of the full-scale tank, will be fabricated by fiber placement and tested to verify its structural integrity and LH2 containment.

Greenberg, H. S.↗

Design of Transpiration Cooled Thermal Protection Systems

This study explored three approaches for the utilization of transpiration cooling in thermal protection systems. One model uses an impermeable wall with boiling water heat transfer at the backface (Model I). A second model uses a permeable wall with a boiling water backface and additional heat transfer to the water vapor as it flows in channels toward the exposed surface (Model II). The third model also uses a permeable wall, but maintains a boiling condition at the exposed surface of the material (Model III). The governing equations for the models were developed in non-dimensional form and a comprehensive parametric investigation of the effects of the independent variables on the important dependent variables was performed. In addition, detailed analyses were performed for selected materials to evaluate the practical limitations of the results of the parametric study.

Callens, E. Eugene, Jr.↗

Study of meteoroid impact craters on various materials (A0138-1)

Interplanetary dust particles (micrometeoroids) are expected to form well-defined craters upon impacting exposed material in space. Studying the frequency and features of these craters will provide data on the mass-flux distribution of micrometeoroids and, to a lesser extent, on the velocity magnitude and direction. This experiment will study impact craters produced by micrometeoroids on selected materials (metals and glasses in the form of thick targets) to obtain valuable technological and scientific data. Specifically, the studies will focus on determining micrometeoroid composition and mass-flux distribution. Analyses will also be made on the distribution of impact velocity vectors.

Mandeville, J. C.↗

Investigation of Metal Oxide/Carbon Nano Material as Anode for High Capacity Lithium-ion Cells

NASA is developing high specific energy and high specific capacity lithium-ion battery (LIB) technology for future NASA missions. Current state-of-art LIBs have issues in terms of safety and thermal stability, and are reaching limits in specific energy capability based on the electrochemical materials selected. For example, the graphite anode has a limited capability to store Li since the theoretical capacity of graphite is 372 mAh/g. To achieve higher specific capacity and energy density, and to improve safety for current LIBs, alternative advanced anode, cathode, and electrolyte materials are pursued under the NASA Advanced Space Power System Project. In this study, the nanostructed metal oxide, such as Fe2O3 on carbon nanotubes (CNT) composite as an LIB anode has been investigated.

battery performance↗

Overview of the MISSE-16 Mission and Preliminary Characterization of Novel Space Weathered Materials

The Materials International Space Station Experiment (MISSE) project is a series of experiments that began in 2001, involving the deployment of external experiment platforms on the International Space Station (ISS). Since then, more than 4,000 materials were tested yielding valuable data and insights into the performance of materials and coatings in the harsh space environment, as well as providing a platform for testing and validating new materials and technologies. The results of the MISSE experiments have contributed to the development of more durable and reliable spacecraft and equipment, as well as improving our understanding of the space environment and its effects on human space exploration. To gain deeper insights into the changes in material properties of both novel and heritage spacecraft materials over the course of a mission, we proposed to enhance the MISSE hardware. This was achieved by integrating a high-resolution camera that can capture both RGB and IR color data, along with an updated illumination scheme. The identical sets of selected materials were mounted on the Zenith, Ram, and Wake faces of the ISS to expose them to predominant vacuum ultraviolet (VUV), atomic oxygen, and high-energy electron conditions. In addition, we exposed flight duplicates of these materials to a simulated space environment, which included sequential exposure to the same irradiation species on the ground. This allowed us to study the effects of space exposure on the materials in a controlled manner and to compare their behavior in both real and simulated space environments. The MISSE-FF flight sample collection comprised different classes of polymers, including polyimides from the Kapton family, manufactured by E.I du Pont de Nemours and Co., Polyethylene terephthalate (PET) materials, liquid crystal polymers, PI/Polyhedral Oligomeric Silsesquioxanes (POSS), and carbon and glass fiber reinforced polymers. The experimental cadence during the MISSE-16 mission (~6 months) included daily images of each sample for the first week, weekly for the next 2 months, and monthly the remaining duration of the mission. This paper will focus on the flight duplicate as well as the postflight optical characterization of novel and heritage materials currently under observation on the MISSE-FF.

Jainisha R Shah↗

Development of Large-Scale Thrust Chambers using Laser Powder Directed Energy Deposition

Historical manufacturing methods for liquid propulsion combustion chambers have relied on series of tube-walls or slotted channel walls (subsequently brazed or plated) for regenerative cooling paths. Large-scale additive manufacturing techniques offer strong potential to minimize manufacturing lead times and cost for developing liquid propulsion chambers, while maintaining performance metrics of traditionally manufactured hardware. The benefits expand beyond traditional combustion chambers to lesser considered nuclear thermal propulsion chambers where radiation energizes the singular incoming propellant stream instead of an exothermic chemical reaction. While each subset of liquid propulsion chambers reaps similar benefit, the geometric challenges in each design can vary substantially. This manuscript discusses the challenges of large contraction ratio propulsion chambers, bimetallic liners and closeout jackets, and material selection when considering laser powder directed energy deposition. LP-DED presently offers build volumes unattainable by L-PBF systems, required for large diameter thrust chambers. LP-DED typically has faster deposition time and is capable of overhang angles without support material (due to the ability to tilt the build plate and minimize the actual build angle). These benefits come at the cost of feature resolution. Designers and manufacturers should consider the effects of thick-wall features printed parallel to the primary surface versus perpendicular due to distortion. Thick-wall and thin-wall features printed in the same plane can substantially increase build time. Where large-scale L-PBF overlaps in size, there may be limited benefit in the quantity of powder required for the build due to the low capture rate of LP-DED and a case-by-case examination is required.

LP-DED↗

Permeation of niobium through grain boundaries in copper

Low mutual solubility is expected to avert interdiffusion in layered composites of phase-separating metals. However, we show that Nb diffuses through polycrystalline Cu—despite the minimal bulk solubility of these elements—due to short circuit transport of Nb along certain grain boundaries in Cu. Atomistic modeling demonstrates that Nb-permeable Cu grain boundaries exhibit negative enthalpy of mixing of Nb, resulting in an enthalpically-stabilized solution of highly mobile Nb atoms that easily diffuse through the boundary. By contrast, Mo, which also has minimal solubility with Cu, has positive enthalpy of mixing at Nb-permeable Cu grain boundaries and does not diffuse through them. Furthermore, our findings suggest material selection and grain boundary engineering as pathways for designing improved diffusion barriers and thermally stable laminate composites.

36 MATERIALS SCIENCE↗

Characterization of Modern Spacecraft Materials under Space-simulated Environment

External spacecraft materials play an important role in satellite protection from the harsh space environment. Research has shown that the physical, chemical, and optical properties of matter change continuously as a result of exposure to solar radiation and aggressive chemical species produced in Earth’s upper atmosphere. Thorough knowledge of the material properties evolution throughout a planned mission lifetime helps to improve the reliability of spacecraft. Moreover, the establishment of correlation factors between true space exposure and accelerated space weather experiments at ground facilities enables accurate prediction of on-orbit material performance based on laboratory-based testing. The presented work aims to evaluate the radiation effects of low Earth orbit (LEO) environment, namely, exposure to the high-energy electrons, atomic oxygen (AO), and vacuum ultraviolet (VUV), of several modern spacecraft materials. The studied materials represent the “flight duplicates” of samples that will be launched as a part of the Materials International Space Station Experiment Flight Facility (MISSE-FF) mission in 2022. MISSE-FF flight sample collection comprises different classes of polymers, including polyimides from the Kapton family, manufactured by E.I du Pont de Nemours and Co., Polyethylene terephthalate (PET) materials, liquid crystal polymers, PI/Polyhedral Oligomeric Silsesquioxanes (POSS), and carbon and glass fiber reinforced polymers. A sequential exposure approach was undertaken to allow monitoring of degradation induced by each environmental component (electrons, AO, and VUV) separately. Surface morphology, optical, and charge transport properties of selected materials were characterized using different techniques, namely, atomic force and scanning electron microscopy, ultraviolet visible (UV/Vis) transmission, reflectance, Bidirectional Reflectance Distribution Function (BRDF), and surface potential decay measurements.

Elena Plis↗

Summary and review of Materials Special Investigation Group evaluations of hardware from the Long Duration Exposure Facility

Major materials findings obtained during LDEF post-flight investigations over the past three and one-half years are reported. The summary of findings to date includes results for thermal control coatings, thin polymeric films, composites, metals, adhesives, contamination, and environments definitions. Reaction rates of selected materials exposed to atomic oxygen are presented. Results useful for model verification and comparison with ground based facility data are specifically highlighted. Potential areas for future work are described. In conclusion, a rationale for a second long term flight experiment is presented.

Whitaker, Ann F.↗