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NASA NTRS2018

An Overview of the TROPICS NASA Earth Venture Mission

The Time-Resolved Observations of Precipitation structure and storm Intensity with a Constellation of Smallsats (TROPICS) mission was selected by NASA as part of the Earth Venture-Instrument (EVI-3) program. The overarching goal for TROPICS is to provide nearly all-weather observations of 3D temperature and humidity, as well as cloud ice and precipitation horizontal structure, at high temporal resolution to conduct high-value science investigations of tropical cyclones. TROPICS will provide rapid-refresh microwave measurements (median refresh rate better than 60 min for the baseline mission) which can be used to observe the thermodynamics of the troposphere and precipitation structure for storm systems at the mesoscale and synoptic scale over the entire storm life cycle. TROPICS comprises six Cube-Sats in three low-Earth orbital planes. Each CubeSat will host a high-performance radiometer to provide temperature profiles using seven channels near the 118.75 GHz oxygen absorption line, water vapour profiles using three channels near the 183 GHz water vapour absorption line, imagery in a single channel near 90 GHz for precipitation measurements (when combined with higher-resolution water vapour channels), and a single channel near 205 GHz which is more sensitive to precipitation-sized ice particles. This observing system offers an unprecedented combination of horizontal and temporal resolution to measure environmental and inner-core conditions for tropical cyclones on a nearly global scale and is a major leap forward in the temporal resolution of several key parameters needed for assimilation into advanced data assimilation systems capable of utilizing rapid-update radiance or retrieval data.Launch readiness is currently projected for late 2019.

TROPICS↗

NASA NTRS1986

Electron-cyclotron maser emission during flares: Emission in various modes and temporal variations

Absorption of radiation at the electron-cyclotron frequency, OMEGA sub e, generated by the electron-cyclotron maser instability was proposed as a possible mechanism for transporting energy and heating of the corona during flares. Radiation from the same instability but at harmonics of OMEGA sub e is believed to be the source of solar microwave spike bursts. The actual mode and frequency of the dominant emission from the maser instability is shown to be dependent on: (1) the plasma temperature, (2) the form of the energetic electron distribution, and (3) on the ratio of the plasma frequency omega sub p to OMEGA sub e. As a result, the emission along a flux tube can vary, with emission at harmonics being favored in regions where omega sub p/OMEGA sub e approx. equal to or greater than 1. Changes in the plasma density and temperature in the source region associated with the flare can also cause the characteristics of the emission to change in time.

Winglee, R. M.↗

NASA NTRS2014

Angular and Polarization Response of Multimode Sensors with Resistive-Grid Absorbers

High sensitivity receiver systems with near ideal polarization sensitivity are highly desirable for development of millimeter and sub-millimeter radio astronomy. Multimoded bolometers provide a unique solution to achieve such sensitivity, for which hundreds of single-mode sensors would otherwise be required. The primary concern in employing such multimoded sensors for polarimetery is the control of the polarization systematics. In this paper, we examine the angular- and polarization- dependent absorption pattern of a thin resistive grid or membrane, which models an absorber used for a multimoded bolometer. The result shows that a freestanding thin resistive absorber with a surface resistivity of eta/2, where eta is the impedance of free space, attains a beam pattern with equal E- and H-plane responses, leading to zero cross polarization. For a resistive-grid absorber, the condition is met when a pair of grids is positioned orthogonal to each other and both have a resistivity of eta/2. When a reflective backshort termination is employed to improve absorption efficiency, the cross-polar level can be suppressed below −30 dB if acceptance angle of the sensor is limited to < or approx. 60deg. The small cross-polar systematics have even-parity patterns and do not contaminate the measurements of odd-parity polarization patterns, for which many of recent instruments for cosmic microwave background are designed. Underlying symmetry that suppresses these cross-polar systematics is discussed in detail. The estimates and formalism provided in this paper offer key tools in the design consideration of the instruments using the multimoded polarimeters.

High sensitivity receiver systems↗

DOE OSTI2025

Examples of X-Ray Characterization Techniques in Energy Storage Research

Lithium-ion batteries have revolutionized the portable electronics and transportation sectors. Their performance is often critically dependent on the crystal structures of the anode and cathode electrode materials, which must enable the transport and reversible storage of lithium ions into and out of the lattice. Because lithium is a low-Z element, characterization of materials for lithium-ion batteries can be particularly challenging. Regardless, X-ray techniques enable analysis of material structures to better understand how battery materials perform and degrade, particularly when combined with other materials characterization and electrochemical characterization techniques. While X-ray techniques are most often used in battery research for phase identification of crystal structures, X-ray characterization techniques are also used for a wide variety of other purposes. I will discuss several examples from my research with various collaborators on several projects that highlight the impact that X-ray characterization techniques can have on battery research. The first example will focus on low-temperature microwave-assisted solvothermal synthesis of vanadium-doped LiFePO4 cathode materials for lithium-ion batteries. (1,2) Through a combination of electrochemical and materials characterization, we determined that low temperature synthesis resulted in metastable phases that enabled incorporation of higher dopant levels than resulting from high-temperature synthesis of thermodynamically stable phases. Rietveld refinement of X-ray diffraction data enabled understanding of how lattice parameters changed with doping levels and synthesis temperature. X-ray absorption near edge spectroscopy enabled understanding of the vanadium and iron oxidation states to confirm how vacancies in the structure caused by doping were charge compensated. This was important to understand because the literature suggests doping can improve LiFePO4 electrical conductivity, which improves battery charge and discharge rates. The second example will focus on understanding residual strain in lithium metal anodes. Lithium-ion batteries typically use graphite anodes, but the charge-storage capacity can be theoretically improved ~10x by using lithium metal as the anode material instead. However, lithium anodes suffer from growth of high-aspect-ratio features, such as dendrites, that can pierce nanoporous polymer separators and lead to short circuits and fires. External pressure is commonly applied to cells to enable better morphological control. We hypothesized that applied pressure may promote strain and possibly work hardening during electrochemical cycling, which motivated us to look for evidence of residual strain in lithium metal cycled under applied pressure using X-ray diffraction and sin2(..psi..) analysis. We found that lithium electrodeposited under high pressure exhibited in-plane compressive strain and that that lithium electrodeposited under low pressure did not. (3) The residual strain that accompanies electrodeposition under high pressure may lead to work hardening, which may explain how a soft metal like lithium can puncture separators and why higher pressure does not always decrease short circuits. (4-6) References: 1) Harrison, K. L.; Manthiram, A. Microwave-Assisted Solvothermal Synthesis and Characterization of Metastable LiFe1- x (VO) x PO4 Cathodes. Inorganic chemistry 2011, 50(8), 3613-3620. 2) Harrison, K. L.; Bridges, C. A.; Paranthaman, M. P.; Segre, C. U.; Katsoudas, J.; Maroni, V. A.; Idrobo, J. C.; Goodenough, J. B.; Manthiram, A. Temperature Dependence of Aliovalent-Vanadium Doping in LiFePO4 Cathodes. Chemistry of Materials 2013, 25(5), 768-781. 3) Rodriguez, M. A.; Harrison, K. L.; Goriparti, S.; Griego, J. J.; Boyce, B. L.; Perdue, B. R. Use of a Be-Dome Holder for Texture and Strain Characterization of Li Metal Thin Films via Sin2 (..psi..) Methodology. Powder Diffraction 2020, 35(2), 89-97. 4) Jungjohann, K. L.; Gannon, R. N.; Goriparti, S.; Randolph, S. J.; Merrill, L. C.; Johnson, D. C.; Zavadil, K. R.; Harris, S. J.; Harrison, K. L. Cryogenic Laser Ablation Reveals Short-Circuit Mechanism in Lithium Metal Batteries. ACS Energy Letters 2021, 6(6), 2138-2144. 5) Harrison, K. L.; Merrill, L. C.; Long, D. M.; Randolph, S. J.; Goriparti, S.; Christian, J.; Warren, B.; Roberts, S. A.; Harris, S. J.; Perry, D. L. Cryogenic Electron Microscopy Reveals That Applied Pressure Promotes Short Circuits in Li Batteries. Iscience 2021, 24(12). 6) Harrison, K. L.; Goriparti, S.; Merrill, L. C.; Long, D. M.; Warren, B.; Roberts, S. A.; Perdue, B. R.; Casias, Z.; Cuillier, P.; Boyce, B. L. Effects of Applied Interfacial Pressure on Li-Metal Cycling Performance and Morphology in 4 M LiFSI in DME. ACS Applied Materials & Interfaces 2021, 13(27), 31668-31679.

batteries↗

NASA NTRS1990

Thermal analysis of a strongback structure for a high-frequency microwave antenna concept in geosynchronous orbit

The effects of the geosynchronous thermal environment on the performance of a tetrahedral truss strongback structure for a high-frequency microwave antenna concept for earth science monitoring have been studied. Two orbit conditions (an equinox orbit with a 72-minute eclipse and a solstice orbit with no eclipse) and a range of thermal control approaches were investigated under steady state and transient conditions. The thermal control approaches included aluminum surface coatings with high and low solar-absorptivity-to-infrared-emissivity ratios, multi-layer insulation, a sun shield, and various truss element materials. The effects of both earth shadowing and shadowing by the antenna reflector on temperatures were also examined. Temperatures and corresponding structural distortion results are presented.

Farmer, Jeffery T.↗

NASA NTRS1991

Satellite passive-microwave observations and the distribution of net surface accumulation in the interior of Greenland

The rate of net accumulation at the surface and its distribution in ice sheet areas bounded by the dry snow line may be approximated by a determination of either firn external emissivity or various other emissivity terms. A compilation of mean annual brightness temperature for the Greenland ice sheet based on Nimbus-5 Electrically Scanning Microwave Radiometer (19 GHz) data is used to approximate the distribution of the accumulation rate in the area bounded by the dry snow line, applying a simple conversion involving a polynomial function. This is compared with a compilation produced elsewhere using Nimbus-6 SCAMS (31 GHz) data, applying a complex conversion involving the temperature dependence of the absorption coefficient, and with the latest compilation based on surface measurements of the accumulation rate. The findings indicate that in Greenland, the use of polynomial functions to convert for net surface accumulation is a reliable and simple method for estimating both the rate of accumulation and its distribution in areas where there is no melting at the surface.

Giovinetto, M. B.↗

NASA NTRS1996

SSM/I Rain Retrievals Within a Unified All-Weather Ocean Algorithm

A new method for the physical retrieval of rain rates from satellite microwave radiometers is presented and compared to two other rainfall climatologies derived from satellites. The method is part of a unified ocean parameter retrieval algorithm that is based on the fundamental principles of radiative transfer. The algorithm simultaneously finds near-surface wind speed W, columnar water vapor V, columnar cloud liquid water L, rain rate R, and effective radiating temperature T(sub U) for the upwelling radiation. The performance of the algorithm in the absence of rain is discussed in Wentz, and this paper focuses on the rain component of the algorithm. A particular strength of the unified algorithm is its ability to 'orthogonalize' the retrievals so that there is minimum cross-talk between the retrieved parameters. For example, comparisons of the retrieved water vapor with radiosonde observations show that there is very little correlation between the water vapor retrieval error and rain rate. For rain rates from 1 to 15 mm/h, the rms difference between the retrieved water vapor and the radiosonde value is 5 mm. A novel feature of the rain retrieval method is a beamfilling correction that is based upon the ratio of the retrieved liquid water absorption coefficients at 37 GHz and 19.35 GHz. This ratio decreases by about 40% when heavy and light rain co-exist within the SSM/I footprint as compared to the case of uniform rain. This correction has the effect of increasing the rain rate when the spectral ratio of the absorption coefficients is small. Even with this beamfilling correction, tropical rainfall is still unrealistically low when the freezing level in the tropics (approx. 5 km) is used to specify the rain layer thickness. We restore realism by reducing the assumed averaged tropical rain layer thickness to 3 km, thereby accounting for the existence of warm rain processes in which the rain layer does not extend to the freezing level. Global rain rates are produced for the 1991 through 1994 period from observations taken by microwave radiometers (SSM/I) that are aboard two polar-orbiting satellites. We find that approximately 6% of the SSM/I observations detect measurable rain rates (R greater than 0.2 mm/h). Zonal averages of the rain rates show the peak at the intertropical convergence zone (ITCZ) is quite narrow in meridional extent and varies from about 7 mm/day in the winter to a maximum 11 mm/day in the summer. Very low precipitation rates (less than 0.3 mm/day) are observed in those areas of subsidence influenced by the large semipermanent anticyclones. In general, these features are similar to those reported in previously published rain climatologies. However, significant differences do exists between our rain rates and those produced by Spencer. These differences seem to be related to non-precipitating cloud water.

Wentz, Frank J.↗

NASA NTRS1974

Microwave and infrared observations of molecular spectra in Comet Kohoutek

Transitions of the possible parent molecules H2O, NH3, CH3OH, and N2O as well as the OH radical were searched for in Comet Kohoutek (1973f) in the frequency range 22.2-25.2 GHz. These molecules were not detected but the upper limits for the optical depth, mean column density, and the production rate are derived for each of the molecules. These results are discussed and compared with the reported detections of HCN and CH3CN emission and OH absorption.

Townes, C. H.↗

NASA NTRS1999

On the Fast Evaluation Method of Temperature and Gas Mixing Ratio Weighting Functions for Remote Sensing of Planetary Atmospheres in Thermal IR and Microwave

Evaluation of weighting functions in the atmospheric remote sensing is usually the most computer-intensive part of the inversion algorithms. We present an analytic approach to computations of temperature and mixing ratio weighting functions that is based on our previous results but the resulting expressions use the intermediate variables that are generated in computations of observable radiances themselves. Upwelling radiances at the given level in the atmosphere and atmospheric transmittances from space to the given level are combined with local values of the total absorption coefficient and its components due to absorption of atmospheric constituents under study. This makes it possible to evaluate the temperature and mixing ratio weighting functions in parallel with evaluation of radiances. This substantially decreases the computer time required for evaluation of weighting functions. Implications for the nadir and limb viewing geometries are discussed.

Ustinov, E. A.↗

NASA NTRS1978

Laserfax

The photo shows an Associated Press technician receiving a photograph prepared by means of a high speed, high resolution facsimile system known as Laserfax, so called because it employs a laser beam to scan the photo being sent. Laser scanning data is converted to electrical signals and transmitted to news bureaus within the Associated Press network via microwave radio or telephone lines. At the other end, another laser sweeps reconverted imagery onto a special, light-sensitive, dry silver paper. The paper is then heat processed to reproduce the photograph. Manufactured by Harris Electronics Systems Inc., Melbourne, Florida, Laserfax incorporates NASA thermal control coating technology developed by Jet Propulsion Laboratory for use on spacecraft antennas; the coatings block absorption of solar radiation which would interfere with the antenna's proper operation. Harris Electronics Systems, originally Radiation, Inc., reused the NASA technology in development of Laserfax. A NASA technical support package provided information about the thermal properties that could be expected of various coatings for the facsimile system's paper rollers; this information served as a design base for the infrared heat source used in developing the photo. Although relatively new, Laserfax is in extensive service. It is manufactured in several models. One of them is the type used by the Associated Press, its news bureaus and affiliated newspapers, radio and television stations. Other models have been sold in large numbers to law enforcement agencies for transmitting high quality fingerprints and identification photos. Laserfax is also in service with the National Weather Service, which converts satellite imagery to weather photographs and relays them to local weather stations, television stations, newspapers and airlines.

Source record↗

NASA NTRS1982

Advanced sensors for spaceborne measurements of the earth's atmosphere

Concepts involved in remote sensing from space are reviewed, together with performance requirements of proposed and planned equipment. Attention is focused on measurements of the troposphere, particularly meteorological variables and chemical species. The principles of absorption, using either passive or active sensors, emission detection, fluorescence measurements, and EM radiation scattering are outlined. The proposed NASA Windsat, using a CO2 laser from the Orbiter or from an 800 km orbit spacecraft to measure low-level wind speeds is described, as are the uses of the AMTS atmospheric sounder instrument for IR atmospheric temperature sensing and a 20-channel microwave radiometer to detect moisture profiles in the water vapor bands. Additionally, a microwave pressure sounder to detect backscattered signals at 60 GHz is outlined, along with lidar pressure and wind speed measurement methods.

Hinkley, E. D.↗

DOE OSTI2022

Ac losses in field-cooled type I superconducting cavities

As superconductors are cooled below their critical temperature, stray magnetic flux can become trapped in regions that remain normal. The presence of trapped flux facilitates dissipation of ac current in a superconductor, leading to losses in superconducting elements of microwave devices. In type II superconductors, dissipation is well-understood in terms of the dynamics of vortices hosting a single flux quantum. In contrast, the ac response of type I superconductors with trapped flux has not received much attention. Building on Andreev's early work (Andreev 1967 Sov. Phys. JETP 24 1019), here we show theoretically that the dominant dissipation mechanism is the absorption of the ac field at the exposed surfaces of the normal regions, while the deformation of the superconducting/normal interfaces is unimportant. We use the developed theory to estimate the degradation of the quality factors in field-cooled cavities, and we satisfactorily compare these theoretical estimates to the measured field dependence of the quality factors of two aluminum cavities. We also identify a regime in which the dissipated power depends weakly on the Ginzburg-Landau parameter; this makes it possible to apply our findings to cavities made of other materials, such as niobium.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS2010

Improved Determination of Surface and Atmospheric Temperatures Using Only Shortwave AIRS Channels: The AIRS Version 6 Retrieval Algorithm

AIRS was launched on EOS Aqua on May 4, 2002 together with ASMU-A and HSB to form a next generation polar orbiting infrared and microwave atmosphere sounding system (Pagano et al 2003). The theoretical approach used to analyze AIRS/AMSU/HSB data in the presence of clouds in the AIRS Science Team Version 3 at-launch algorithm, and that used in the Version 4 post-launch algorithm, have been published previously. Significant theoretical and practical improvements have been made in the analysis of AIRS/AMSU data since the Version 4 algorithm. Most of these have already been incorporated in the AIRS Science Team Version 5 algorithm (Susskind et al 2010), now being used operationally at the Goddard DISC. The AIRS Version 5 retrieval algorithm contains three significant improvements over Version 4. Improved physics in Version 5 allowed for use of AIRS clear column radiances (R(sub i)) in the entire 4.3 micron CO2 absorption band in the retrieval of temperature profiles T(p) during both day and night. Tropospheric sounding 15 micron CO2 observations were used primarily in the generation of clear column radiances (R(sub i)) for all channels. This new approach allowed for the generation of accurate Quality Controlled values of R(sub i) and T(p) under more stressing cloud conditions. Secondly, Version 5 contained a new methodology to provide accurate case-by-case error estimates for retrieved geophysical parameters and for channel-by-channel clear column radiances. Thresholds of these error estimates are used in a new approach for Quality Control. Finally, Version 5 contained for the first time an approach to provide AIRS soundings in partially cloudy conditions that does not require use of any microwave data. This new AIRS Only sounding methodology was developed as a backup to AIRS Version 5 should the AMSU-A instrument fail. Susskind et al 2010 shows that Version 5 AIRS Only sounding are only slightly degraded from the AIRS/AMSU soundings, even at large fractional cloud cover.

Susskind, Joel↗

NASA NTRS1971

Microwave emission from the moon

Measurements of the microwave emission from the moon and their interpretation in terms of the thermophysics of that body are reviewed. Variations of the brightness temperatures of the moon during a lunation and during eclipses when combined with infrared and radar measurements yield a precise set of physical parameters for the upper few meters of the lunar soil. These parameters include the density, thermal conductivity, dielectric constant, radio absorption coefficients, and the mean temperature gradiant.

Muhleman, D. O.↗

NASA NTRS1992

Synthesis and characterization of fine grain diamond films

A fine grain diamond film has been developed by microwave plasma assisted chemical vapor deposition. Various analytical techniques, including Rutherford backscattering, proton recoil analysis, Raman spectroscopy, and X-ray diffraction, were utilized to characterize the diamond films. The grain size of the film was determined from bright and dark field electron micrographs, and found to be 200-1000 A. The films exhibited good optical transmission between 2.5 and 10 microns, with a calculated absorption coefficient of 490/cm. The friction coefficients of this film were found to be 0.035 and 0.030 at dry nitrogen and humid air environments, respectively, and the films had low wear rates.

Wu, Richard L. C.↗

NASA NTRS1992

Coronal Magnetic Structures Observing Campaign. II - Magnetic and plasma properties of a solar active region

Simultaneous soft X-ray, microwave, and photospheric magnetic field observations were taken during the Coronal Magnetic Structures Observing Campaign. The plasma electron temperatures and emission measures determined from the X-ray data are used to predict the intensity and structure of the thermal bremsstrahlung emission at 20 and 6 cm. Comparing these predictions with the microwave observations, it is found that the 20 cm structure is very similar to that expected from the X-rays, but a substantial amount of the 6 cm emission was resolved out. The predicted 20 cm brightness temperatures are higher than the observed, requiring cool absorbing material (not greater than 500,000 K) between the hot X-ray plasma and the observer. The absorption mechanism in the cool plasma at 20 cm is most likely thermal bremsstrahlung, requiring coronal magnetic fields as high as 150 G. 'Coronal Magnetograms', made by extrapolating the photospheric longitudinal field using the Sakurai code, show that appropriate values of the total field are reached at heights of 6000-10,000 km above the photosphere (at many but not all locations).

Schmelz, J. T.↗

NASA NTRS1987

Evolution of the axial electron cyclotron maser instability, with applications to solar microwave spikes

The nonlinear evolution of cyclotron radiation from streaming and gyrating electrons in an external magnetic field is analyzed. The nonlinear dynamics of both the fields and the particles are treated fully relativistically and self-consistently. The model includes a background plasma and electrostatic effects. The analytical and numerical results show that a substantial portion of the beam particle energy can be converted to electromagnetic wave energy at frequencies far above the electron cyclotron frequency. In general, the excited radiation can propagate parallel to the magnetic field and, hence, escape gyrothermal absorption at higher cyclotron harmonics. The high-frequency Doppler-shifted cyclotron instability can have saturation efficiencies far higher than those associated with well-known instabilities of the electron cyclotron maser type. Although the analysis is general, the possibility of using this model to explain the intense radio emission observed from the sun is explored in detail.

Vlahos, Loukas↗

NASA NTRS2011

Surface and Atmospheric Contributions to Passive Microwave Brightness Temperatures for Falling Snow Events

Physically based passive microwave precipitation retrieval algorithms require a set of relationships between satellite -observed brightness temperatures (TBs) and the physical state of the underlying atmosphere and surface. These relationships are nonlinear, such that inversions are ill ]posed especially over variable land surfaces. In order to elucidate these relationships, this work presents a theoretical analysis using TB weighting functions to quantify the percentage influence of the TB resulting from absorption, emission, and/or reflection from the surface, as well as from frozen hydrometeors in clouds, from atmospheric water vapor, and from other contributors. The percentage analysis was also compared to Jacobians. The results are presented for frequencies from 10 to 874 GHz, for individual snow profiles, and for averages over three cloud-resolving model simulations of falling snow. The bulk structure (e.g., ice water path and cloud depth) of the underlying cloud scene was found to affect the resultant TB and percentages, producing different values for blizzard, lake effect, and synoptic snow events. The slant path at a 53 viewing angle increases the hydrometeor contributions relative to nadir viewing channels. Jacobians provide the magnitude and direction of change in the TB values due to a change in the underlying scene; however, the percentage analysis provides detailed information on how that change affected contributions to the TB from the surface, hydrometeors, and water vapor. The TB percentage information presented in this paper provides information about the relative contributions to the TB and supplies key pieces of information required to develop and improve precipitation retrievals over land surfaces.

Skofronick-Jackson, Gail↗