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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 397 records · Page 22
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Collective Energy Transport of Excitons in Two-dimensional Materials

Electronic thermal transport and thermoelectric measurements are pursued in this project to obtain unique insights into the unusual collective energy transport behaviors in two-dimensional (2D) heterostructures. Electronic thermal transport and thermoelectric measurements are essential techniques for characterizing bulk superconductors by probing the heat-carrying quasi-particles. Thermoelectric and electronic thermal transport measurements are expanded in this work beyond bulk systems to probe interactions among electrons, holes, and phonons in 2D heterostructures. In one experiment, a microbridge platform is advanced to demonstrate field-effect resistive-thermometry measurements of the electronic thermal conductivity of graphene heterostructures. Together with first principles theoretical calculations and analytical models, the experimental results suggest that tunable electron coupling with flexural phonons provides a knob to control quantum matters in graphene heterostructures with broken reflection symmetry. In another experiment, the Seebeck coefficient (S) is measured to probe interlayer interactions in electron-hole bilayers that are predicted to give rise to the emergence of a variety of correlated states. As a measure of the entropy, the measured S reveals the signature of electric injection of interlayer excitons in transition metal dichalcogenide (TMD) structures.

36 MATERIALS SCIENCE↗
DOE OSTI2023

MRT 7365: Power flow physics and key physics phenomena

The Z accelerator at Sandia National Laboratories conducts z-pinch experiments at 26 MA in support of DOE missions in stockpile stewardship, dynamic materials, fusion, and other basic sciences. Increasing the current delivered to the z-pinch would extend our reach in each of these disciplines. To achieve increases in current and accelerator efficiency, a fraction of Z’s shots are set aside for research into transmission-line power flow. These shots, with supporting simulations and theory, are incorporated into this Advanced Diagnostics milestone report. The efficiency of Z is reduced as some portion of the total current is shunted across the transmission-line gaps prior to the load. This is referred to as “current loss”. Electrode plasmas have long been implicated in this process, so the bulk of dedicated power-flow experiments are designed to measure the plasma environment. The experimental analyses are enhanced by simulations conducted using realistic hardware and Z voltage pulses. In the same way that diagnostics are continually being improved for sensitivity and resolution, the modeling capability is continually being improved to provide faster and more realistic simulations. The specifics of the experimental hardware, diagnostics, simulations, and algorithm developments are provided in this report. The combined analysis of simulation and data confirms that electrode plasmas have the most detrimental impact on current delivery. Experiments over the last three years have tested the theoretical current-loss mechanisms of enhanced ion current, plasma gap closure, and Hall-related current. These mechanisms are not mutually exclusive and may be coincident in the final feed as well as in upstream transmission lines. The final-feed geometries tested here, however, observe lower-density plasmas without dominant ion currents which is consistent with a Hall-related current. The picture of plasma formation and transport formed from experiment and simulation is informing hardware designs being fielded on Z now and being proposed for the Next-Generation Pulsed Power (NGPP) facility. In this picture, the strong magnetic fields that heat the electrodes above particle emission thresholds also confine the charged particles near the surface. Some portion of the plasmas thus formed is transported into the transmission-line gap under the force of the electric field, with aid from plasma instabilities. The gap plasmas are then transported towards the load by a cross-field drift, where they accumulate and contribute to a likely Hall-related cross-gap current. The achievements in experimental execution, model validation, and physical analysis presented in this report set the stage for continued progress in power flow and load diagnostics on Z. The planned shot schedule for Z and Mykonos will provide data for extrapolation to higher current to ensure the predicted performance and efficiency of a NGPP facility.

43 PARTICLE ACCELERATORS↗
DOE OSTI2026

Distinguishability of Radially Directed Energy and Particle Flux in the TJ-II Heliac: Controlling Transport by Feedback-Phasing Experiments

This project supported a U.S. contribution to the TJ-II stellarator research program focused on distinguishing radially directed particle transport from energy transport in magnetized fusion plasmas. The motivating physics issue is that turbulent particle flux and turbulent heat or energy flux are not necessarily locked together: changes in density, electron temperature, plasma potential, and electric-field fluctuations can produce different phase relationships and therefore different radial fluxes. Resolving these relationships is important for understanding improved-confinement behavior, transport-barrier-like regimes, and the broader ability to predict and control confinement in stellarators and related toroidal devices.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2026

An Approach for Simulating Transport of Nonspherical, Sublimating Particles in Rarefied Gas Flows via the Direct Simulation Monte Carlo Method

This paper extends the particle Green’s function approach of Gallis et al. [Phys. Fluids 13, 3482–3492 (2001)] to compute the force and heat transfer on nonspherical, sublimating particles in rarefied gas flows. Green’s functions are derived for rods and plates, which are representative of ice particle shapes, and a numerical procedure is developed for computing the Green’s functions for a general discretized convex shape. Additionally, a sublimation model is developed to simulate the evolution of ice particles in rarefied gas flows. These models are implemented in a direct simulation Monte Carlo code and demonstrated for the case of ice-particle-laden hypersonic flow over a ramp.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Numerical Investigation of the characteristics of pressurized biomass-oxy-combustion

As a second generation of oxy-fuel combustion technologies, pressurized oxy-combustion has a potential to improve the process efficiency and economy. With the modern decarbonization needs, biomass combustion is considered to be nearly CO2 neutral, and thus co-firing biomass with coal in an oxy-combustion process can achieve a negative CO2 balance. The size of the biomass fuel particles is a key parameter in an entrained flow combustor because large biomass particles, exceeding some threshold size, may only partially be burnt due to the restrictions on the heat transport, thereby diminishing the combustion efficiency. While such a threshold particle size has been scrutinized at an atmospheric pressure, the present study extends the analysis to elevated pressures. Specifically, two scenarios were set up, for experimental-scale and full-scale pressurized oxy-combustors, with the threshold sizes of biomass particles appearing 0.5 mm and 5 mm, respectively, without temperature gradient in biomass particles. With temperature gradient, the parametric study included the particles in the range from 0.15 mm to 5 mm. It is shown that the thermal-thin model is applicable to spherical biomass particles not exceeding 0.15 mm. The impact of the heating rate on biomass particle devolatilization was also investigated and the biomass devolatilization could happen in less than 1 second; the same amount of heat energy could induce different volatile release rates.

Li, Lei↗
DOE OSTI2020

Magneto-structural and induction heating properties of MFe2O4 (M?=?Co, Mn, Zn) MNPs for magnetic particle hyperthermia application

The thermal decomposition approach was used for the synthesis of MFe2O4 magnetic nanoparticles (MNPs) by substituting M as Co, Mn, and Zn. The obtained MNPs were characterized for magneto-structural properties using X-Ray diffraction patterns, FTIR, Raman and Mossbauer spectroscopy techniques which confirm the formation of phase pure cubic spinel ferrite with space group Fd3m and five Raman active modes. The size, morphology, and compositional analysis was performed using HRTEM and EDX where the size of MNPs was found to be less than 10 nm that attains superparamagnetism. The magnetic hyperthermia performance of obtained MNPs was evaluated by induction heating experiments at magnetic field range 13.3 to 26.7 kAm-1. The specific absorption rate (SAR) and intrinsic loss power (ILP) values were determined at different magnetic fields within the human tolerable range and correlated with magneto-structural properties to evaluate its potential for possible magnetic particle hyperthermia therapy.

Magnetic nanoparticles, complex-decomposition, mag↗
DOE OSTI2021

Gen 3 Particle Pilot Plant (G3P3) -- High-Temperature Particle System for Concentrating Solar Power (Phases 1 and 2)

The U.S. Department of Energy Solar Energy Technologies Office initiated the Generation 3 Concentrating Solar Power (CSP) program to achieve higher operating temperatures (>700 °C) to enable next-generation CSP high-temperature power cycles such as the supercritical CO 2 (sCO2) Brayton Cycle. Three teams were selected to pursue high-temperature gas, liquid, and solid pathways for the heat-transfer media. Phases 1 and 2, which lasted from 2018 – 2020, consisted of design, modeling, and testing activities to further de-risk each of the technologies and develop a design for construction, commissioning, and operation of a pilot-scale facility in Phase 3 (2021 – 2024). This report summarizes the activities in Phases 1 and 2 for the solid-particle pathway led by Sandia National Laboratories. In Phases 1 and 2, Sandia successfully de-risked key elements of the proposed Gen 3 Particle Pilot Plant (G3P3) by improving the design, operation, and performance of key particle component technologies including the receiver, storage bins, particle-to-sCO2 heat exchanger, particle lift, and data acquisition and controls. Modeling and testing of critical components have led to optimized designs that meet desired performance metrics. Detailed drawings, piping and instrumentation diagrams, and process flow diagrams were generated for the integrated system, and structural analyses of the assembled tower structure were performed to demonstrate compliance with relevant codes and standards. Instrumentation and control systems of key subsystems were also demonstrated. Together with Bridgers & Paxton, Bohannan Huston, and Sandia Facilities, we have completed a 100% G3P3 tower design package with stamped engineering drawings suitable for construction bid in Phase 3.

14 SOLAR ENERGY↗
DOE OSTI2020

Analysis of the inter-species power balance in JET plasmas

Most auxiliary heating methods provide heating to more than one particle species (electrons, ions, impurities) in a fusion plasma. This can lead to substantial temperature differences between species, depending on conditions such as heating power to the different species and collisionality, with temperature differences between species limited by inter-species thermal equipartition and transport. The analysis of the steady-state electron-ion and impurity-ion power balances presented in this paper are used for consistency-checking experimental ion and electron temperature measurements and for inferring the main ion temperature from measured impurity temperatures. As ion temperature measurements by charge exchange spectroscopy (CXS) based on impurity ions have become more difficult and time-consuming since the installation of the ITER-like wall (ILW) with Be and W PFC's, knowing the maximum sustainable temperature difference between ions and electrons, |T i -T e | allows rejecting erroneous measurements. It also obviates the need for an ion temperature measurement, if an electron temperature measurement is available and |T i - T e | cannot be larger than the combined errors of the underlying measurements. A power balance analysis is also required for estimating the errors of the ion and electron heat fluxes prior to any species-resolved transport analysis. The ion-impurity temperature differences are usually found to be small due to strong thermal equipartition between ion species. However, they can approach 10% in JET-ILW low density, high power discharges, such the ones under development for a future JET deuterium–tritium campaign (Joffrin et al 2019 Nucl. Fusion). This has a generally small, but not always negligible effect on the calculation of fusion reaction rates, which depend on main ion temperatures. An important outcome of this analysis is that temperature differences between impurity species are always much smaller than between the impurities and hydrogenic species and can usually be neglected. The article presents two methods for calculating the impurity-to-main ion temperature ratio. Finally, this analysis leads to a method for the reconstruction ion temperature profiles from ion temperature data available at only one or a small number of spatial locations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

System and method for forming material substrate printer

A method is disclosed for manufacturing a part via an additive manufacturing process. A solution is used which has a volatile component within which is suspended particles of a powdered material. The solution is heated until it at least one of begins boiling or is about to begin boiling. The heated solution is then deposited at least at one location on a substrate to help form a layer of the part. The volatile component then evaporates, leaving only the particles of powdered material. The particles are then heated to the melting point. The deposition and heating operations are repeated to successively form a plurality of layers for the part. The evaporation of the volatile component helps to cool the part.

36 MATERIALS SCIENCE↗
DOE OSTI2022

System and method for forming material substrate printer

A method is disclosed for manufacturing a part via an additive manufacturing process. A solution is used which has a volatile component within which is suspended particles of a powdered material. The solution is heated until it at least one of begins boiling or is about to begin boiling. The heated solution is then deposited at least at one location on a substrate to help form a layer of the part. The volatile component then evaporates, leaving only the particles of powdered material. The particles are then heated to the melting point. The deposition and heating operations are repeated to successively form a plurality of layers for the part. The evaporation of the volatile component helps to cool the part.

Demuth, James A.↗
DOE OSTI2022

Characterization and Understanding of Thermal Transport in Stationary and Moving Particle Beds for Concentrating Solar Power

Concentrating solar power (CSP) coupled with thermal energy storage (TES) is being considered as an appealing solution to deliver stable, dispatchable, and inexpensive electricity generation from renewable solar energy. The heat from the HTF is stored in a TES system that is significantly less expensive and more scalable than electrochemical storage, enabling electricity generation when the sunlight is unavailable. The general concentrating solar thermal technologies are being pushed to higher temperature for higher efficiency and lower cost in a diverse range application in electricity generation (in CSP), industrial heating, and thermochemical fuel productions. Inert and abundant solid particles are becoming increasingly more important for these emerging applications. Heat transfer in both stationary and moving particle beds have been studied for many decades, revealing a great deal of insights on the mechanisms. Yet, there are still several unresolved problems from both fundamental understanding and technological applications points of view. In this Chapter, we will attempt to provide an up-to-date picture of thermal transport in stationary and moving particle beds. In both cases, we will review historical and contemporary developments in the theoretical, computational, and experimental aspects of heat transfer and related behaviors in particle beds. Here, we will discuss both the advancements and limitations of the existing studies and point to future developments towards deeper fundamental understandings and better engineering applications.

14 SOLAR ENERGY↗
DOE OSTI2023

A Laboratory Comparison of a Nephelometer and the Cavity-Attenuated Phase Shift Instrument (CAPS)

The interaction of incoming solar radiation (light) with particulate matter in the atmosphere impacts Earth’s radiation budget and thus is of great importance to climate and climate change. This particulate matter consists of particles, an aerosol referring to the ensemble of these particles. All particles scatter incoming solar radiation, sending some of it back to space and providing a cooling influence on the climate. Some particles additionally absorb incoming solar radiation, causing the particle, and the surrounding atmosphere, to heat, and thus altering atmospheric stability and evaporating water and other substances in the particles, which in turn affect the scattering and absorption of light by the particle.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Optimization of a Packed Particle Magnetocaloric Refrigerator: A Combined Experimental and Theoretical Study

Magnetocaloric refrigeration has strong potential towards achieving high efficiency hydrogen liquefaction. Optimising parameters such as particle size and operating cycles can have a significant impact on liquefaction performance. Here, this work reports on a room temperature magnetocaloric refrigeration prototype designed with helium as the heat transfer fluid and packed particle Gd 0.8875 Ce 0.1025 Si 0.84 Cr 0.19 as the refrigerant. The temperature spans and cooling power with three different particle sizes at two different operating cycles were measured. A maximum temperature span of 16.7 K and a maximum cooling power of 8.6 W·kg –1 were obtained. Reduction of performance in the faster cycle was observed in larger particles due to insufficient thermal diffusion time and its implications for cryogenic temperatures are discussed. A numerical model was developed based on the experimentally observed variation of the temperature span and cooling power with particle size and cycle duration. This model was then used to study the competing effects of viscous dissipation and thermal diffusion for different particle sizes and cycle durations.

08 HYDROGEN↗
DOE OSTI2024

Catalytic Reaction Triggered by Magnetic Induction Heating Mechanistically Distinguishes Itself from the Standard Thermal Reaction

As a recent advancement in chemical engineering, magnetic induction heating (MIH) is utilized to initiate the intended reactions by enabling the self-heating of the ferromagnetic catalyst particles. While MIH can be energy-efficient and industrially scalable, its full potential has been underappreciated in catalysis because of the perception that MIH is merely an alternative heating approach. Unexpectedly, we show that the MIH-triggered reaction could go beyond standard thermal catalysis. Specifically, by probing the representative Pt/Fe 3 O 4 catalysts with CO oxidation in both thermal and MIH modes with consistent temperature profiles and catalyst structures, we found that the MIH mode boosts the reactivity more than 25 times by modifying Pt-FeO x interfacial synergies and promoting facile oxidation of the adsorbed carbonyl species by atomic oxygen. Further, as we preliminarily observed, this beneficial MIH-catalysis can be translational to other thermal reactions, potentially paving the way to launch MIH-catalysis as a distinct reaction category.

CO oxidation↗
DOE OSTI2022

NSTX-U theory, modeling and analysis results

Here, the mission of the low aspect ratio spherical tokamak NSTX-U is to advance the physics basis and technical solutions required for optimizing the configuration of next-step steady-state tokamak fusion devices. NSTX-U will ultimately operate at up to 2 MA of plasma current and 1 T toroidal field on axis for 5 s, and has available up to 15 MW of neutral beam injection power at different tangency radii and 6 MW of high harmonic fast wave heating. With these capabilities NSTX-U will develop the physics understanding and control tools to ramp-up and sustain high performance fully non-inductive plasmas with large bootstrap fraction and enhanced confinement enabled via the low aspect ratio, high beta configuration. With its unique capabilities, NSTX-U research also supports ITER and other critical fusion development needs. Super-Alfvénic ions in beam-heated NSTX-U plasmas access energetic particle (EP) parameter space that is relevant for both α-heated conventional and low aspect ratio burning plasmas. NSTX-U can also generate very large target heat fluxes to test conventional and innovative plasma exhaust and plasma facing component solutions. This paper summarizes recent analysis, theory and modelling progress to advance the tokamak physics basis in the areas of macrostability and 3D fields, EP stability and fast ion transport, thermal transport and pedestal structure, boundary and plasma material interaction, RF heating, scenario optimization and real-time control.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Reactor for hydrothermal growth of structured materials

Design, fabrication, and usage of a reactor are presented for synthesis of structured materials from a liquid-phase precursor by heating. The structured materials are particles, membranes or films of micro-porous molecular sieve crystals such as zeolite and meso-porous materials. The precursor solution and structured materials in the reactor are uniformly heated by a planar heater with characteristic heat transfer dimension in the range of 3 mm to 10 cm. A planar heater having width and length at least three times of the characteristic heat transfer dimension provides at least one surface of uniform temperature distribution for heating purposes. Heating is conducted over a temperature range of 20 to 300° C. The planar heater can be heated by electrical power of by thermal fluid.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Overview of T and D–T results in JET with ITER-like wall

In 2021 JET exploited its unique capabilities to operate with T and D–T fuel with an ITER-like Be/W wall (JET-ILW). This second major JET D–T campaign (DTE2), after DTE1 in 1997, represented the culmination of a series of JET enhancements—new fusion diagnostics, new T injection capabilities, refurbishment of the T plant, increased auxiliary heating, in-vessel calibration of 14 MeV neutron yield monitors—as well as significant advances in plasma theory and modelling in the fusion community. DTE2 was complemented by a sequence of isotope physics campaigns encompassing operation in pure tritium at high T-NBI power. Carefully conducted for safe operation with tritium, the new T and D–T experiments used 1 kg of T (vs 100 g in DTE1), yielding the most fusion reactor relevant D–T plasmas to date and expanding our understanding of isotopes and D–T mixture physics. Furthermore, since the JET T and DTE2 campaigns occurred almost 25 years after the last major D–T tokamak experiment, it was also a strategic goal of the European fusion programme to refresh operational experience of a nuclear tokamak to prepare staff for ITER operation. The key physics results of the JET T and DTE2 experiments, carried out within the EUROfusion JET1 work package, are reported in this paper. Progress in the technological exploitation of JET D–T operations, development and validation of nuclear codes, neutronic tools and techniques for ITER operations carried out by EUROfusion (started within the Horizon 2020 Framework Programme and continuing under the Horizon Europe FP) are reported in (Litaudon et al Nucl. Fusion accepted), while JET experience on T and D–T operations is presented in (King et al Nucl. Fusion submitted).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗