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DOE OSTI2024

Non-volatile magnon transport in a single domain multiferroic

Antiferromagnets have attracted significant attention in the field of magnonics, as promising candidates for ultralow-energy carriers for information transfer for future computing. The role of crystalline orientation distribution on magnon transport has received very little attention. In multiferroics such as BiFeO 3 the coupling between antiferromagnetic and polar order imposes yet another boundary condition on spin transport. Thus, understanding the fundamentals of spin transport in such systems requires a single domain, a single crystal. We show that through Lanthanum (La) substitution, a single ferroelectric domain can be engineered with a stable, single-variant spin cycloid, controllable by an electric field. The spin transport in such a single domain displays a strong anisotropy, arising from the underlying spin cycloid lattice. Our work shows a pathway to understanding the fundamental origins of magnon transport in such a single domain multiferroic.

30 DIRECT ENERGY CONVERSION↗

DOE OSTI2021

Realization of semiconducting layered multiferroic heterojunctions via asymmetrical magnetoelectric coupling

Two-dimensional (2D) semiconducting multiferroics that can effectively couple magnetic and polarization (P) orders have great interest for both fundamental research and technological applications in nanoscale, which are, however, rare in nature. In this work, we propose a general mechanism to realize semiconducting 2D multiferroics via van der Waals (vdW) heterojunction engineering, as demonstrated in a typical heterostructure consisting of magnetic bilayer CrI 3 (bi-CrI 3 ) and ferroelectric monolayer In 2 Se 3 . Interestingly, the novel indirect orbital coupling between Se 4p and Cr 3d orbitals, intermediated by the interfacial I 5p orbitals, is switchable in the opposite P configurations, resulting in an unexpected mechanism of strong asymmetrical magnetoelectric coupling. Therefore, along with the noticeable ferroelectric energy barrier induced by In 2 Se 3 , the realization of opposite magnetic orders in opposite P configurations can eventually result in the novel multiferroicity in bi– CrI 3 /In 2 Se 3 . Finally, we demonstrate that our mechanism can generally be applied to design other vdW multiferroics even with tunable layer thickness.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

DOE OSTI2026

Janus skyrmion: Interfacial quasiparticle with two-faced helicity

Janus particles are functional particles with at least two surfaces showing asymmetric properties. Here, we show at the interface between two magnetic regions with different antisymmetric exchange interactions, an alternative species of two-dimensional topological quasiparticles can emerge, in which different helicity structures can coexist. We name such an interfacial quasiparticle a “Janus skyrmion,” in analogy to the Janus particle. As the Janus skyrmion shows helicity asymmetry, its size could vary with both the in-plane and out-of-plane magnetic fields. A vertical spin current could drive the Janus skyrmion into one-dimensional motion along the interface without showing the skyrmion Hall effect, at a speed which depends on both the in-plane spin-polarization direction and current density. Thermal fluctuations could also lead to one-dimensional random walk of a Brownian Janus skyrmion. This work uncovers unique dynamics intrinsic to interfacial quasiparticles with exotic helicity, which may be realized in interface-engineered magnetic layers.

36 MATERIALS SCIENCE↗

DOE OSTI2025

High Optical-to-X-Ray Polarization Ratio Reveals Compton Scattering in BL Lacertae’s Jet

Blazars, supermassive black hole systems with highly relativistic jets aligned with the line of sight, are the most powerful long-lived emitters of electromagnetic emission in the Universe. We report here on a radio-to-gamma-ray multiwavelength campaign on the blazar BL Lacertae with unprecedented polarimetric coverage from radio to X-ray wavelengths. The observations caught an extraordinary event on 2023 November 10–18, when the degree of linear polarization of optical synchrotron radiation reached a record value of 47.5%. In stark contrast, the Imaging X-ray Polarimetry Explorer found that the X-ray (Compton scattering or hadron-induced) emission was polarized at less than 7.4% (3 σ confidence level). We argue here that this observational result rules out a hadronic origin of the high-energy emission and strongly favors a leptonic (Compton scattering) origin, thereby breaking the degeneracy between hadronic and leptonic emission models for BL Lacertae and demonstrating the power of multiwavelength polarimetry to address this question. Furthermore, the multiwavelength flux and polarization variability, featuring an extremely prominent rise and decay of the optical polarization degree, is interpreted for the first time by the relaxation of a magnetic “spring” embedded in the newly injected plasma. This suggests that the plasma jet can maintain a predominant toroidal magnetic field component parsecs away from the central engine.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2022

Diamond Mott Polarimeter

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42 ENGINEERING↗

DOE OSTI2023

Strain Anisotropy Driven Spontaneous Formation of Nanoscrolls from 2D Janus Layers

2D Janus transition metal dichalcogenides (TMDs) have attracted attention due to their emergent properties arising from broken mirror symmetry and self‐driven polarization fields. While it has been proposed that their vdW superlattices hold the key to achieving superior properties in piezoelectricity and photovoltaic, available synthesis has ultimately limited their realization. Here, in this study, the first packed vdW nanoscrolls made from Janus TMDs through a simple one‐drop solution technique are reported. The results, including ab initio simulations, show that the Bohr radius difference between the top sulfur and the bottom selenium atoms within Janus ${M^S_{Se}}$ (M = Mo, W) results in a permanent compressive surface strain that acts as a nanoscroll formation catalyst after small liquid interaction. Unlike classical 2D layers, the surface strain in Janus TMDs can be engineered from compressive to tensile by placing larger Bohr radius atoms on top (${M_S^{Se}}$) to yield inverted C scrolls. Detailed microscopy studies offer the first insights into their morphology and readily formed Moiré lattices. In contrast, spectroscopy and FETs studies establish their excitonic and device properties and highlight significant differences compared to 2D flat Janus TMDs. These results introduce the first polar Janus TMD nanoscrolls and introduce inherent strain‐driven scrolling dynamics as a catalyst to create superlattices.

36 MATERIALS SCIENCE↗

DOE OSTI2025

Experiment of Sea Breeze Convection, Aerosols, Precipitation, and Environment (ESCAPE)

Convective clouds play an important role in Earth’s climate system and are a known source of extreme weather. Gaps in our understanding of convective vertical motions, microphysics, and precipitation across a full range of aerosol and meteorological regimes continue to limit our ability to predict the occurrence and intensity of these cloud systems. To improve predictability, the National Science Foundation (NSF) sponsored a large field experiment entitled “Experiment of Sea Breeze Convection, Aerosols, Precipitation, and Environment (ESCAPE).” ESCAPE took place between 30 May and 30 September 2022 in the vicinity of Houston, Texas, because this area frequently experiences isolated deep convection that interacts with the region’s mesoscale circulations and its range of aerosol conditions. ESCAPE focused on collecting observations of isolated deep convection through innovative sampling and developing novel analysis techniques. This included the deployment of two research aircraft, the National Research Council of Canada Convair-580 and the Stratton Park Engineering Company Learjet, which combined conducted 24 research flights from 30 May to 17 June. On the ground, three mobile X-band radars and one mobile Doppler lidar truck equipped with soundings were deployed from 30 May to 28 June. From 1 August to 30 September 2022, a dual-polarization C-band radar was deployed and operated using a novel, multisensor agile adaptive sampling strategy to track the entire life cycle of isolated convective clouds. Analysis of the ESCAPE observations has already yielded preliminary findings on how aerosols and environmental conditions impact the convective life cycle.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2024

Influence of chemical strains on the electrocaloric response, polarization morphology, tetragonality, and negative-capacitance effect of ferroelectric core-shell nanorods and nanowires

Using Landau-Ginzburg-Devonshire (LGD) approach, we proposed the analytical description of the influence of chemical strains on spontaneous polarization and the electrocaloric response in ferroelectric core-shell nanorods. We postulate that the nanorod core presents a defect-free single-crystalline ferroelectric material, and elastic defects are accumulated in the ultrathin shell, where they can induce tensile or compressive chemical strains. Finite-element modeling (FEM) based on the LGD approach reveals transitions of domain-structure morphology induced by chemical strains in the Ba Ti O 3 nanorods. Namely, tensile chemical strains induce and support the single-domain state in the central part of the nanorod, while the curled domain structures appear near the unscreened or partially screened ends of the rod. The vortexlike domains propagate toward the central part of the rod and fill it entirely, when the rod is covered by a shell with compressive chemical strains above some critical value. The critical value depends on the nanorod sizes, aspect ratio, and screening conditions at its ends. Both analytical theory and FEM predict that the tensile chemical strains in the shell increase the nanorod polarization, lattice tetragonality, and electrocaloric response well above the values corresponding to the bulk material. The physical reason for the increase is strong electrostriction coupling between the mismatch-type elastic strains induced in the core by chemical strains in the shell. Comparison with earlier XRD data confirmed an increase of the tetragonality ratio in tensile Ba Ti O 3 nanorods compared to the bulk material. Obtained analytical expressions, which are suitable for the description of strain-induced changes in a wide range of multiaxial ferroelectric core-shell nanorods and nanowires, can be useful for strain engineering of advanced ferroelectric nanomaterials for energy storage, harvesting, electrocaloric applications, and negative capacitance elements. Published by the American Physical Society 2024

36 MATERIALS SCIENCE↗

DOE OSTI2025

Electrical Energy Storage by Poly(ionic Liquids)

Abstract Manipulating van der Waals (vdW) and ionic interactions in polymers enable energy storage and formations of active or passive components of electrical circuits. The energy storage is achieved by electrically activating ion pairs containing polymers, which create ergotropically favorable non‐equilibrium gradient states. Molecular‐level events responsible for this behavior involve concurrent ion pairs' polarization‐depolarization gradients and conformational changes of aliphatic tails that collectively contribute to lowering local disorder states. Manipulating ionic and vdW interactions stabilizes polarized anion‐cation pairs, thus maintaining electrical energy storage for extended periods. These transparent and easily moldable materials require no multilayered assemblies, and their functional features depend upon polarization conditions and ionic‐vdW interactions, making them applicable in energy storage and other devices transcending classical time intricacy limits.

Liu, Jiahui [Department of Materials Science and E↗

DOE OSTI2025

Electrical Energy Storage by Poly(ionic Liquids)

Liu, Jiahui [Department of Materials Science and E↗

DOE OSTI2024

Changes in environmental and engineered conditions alter the plasma membrane lipidome of fractured shale bacteria

ABSTRACT Microorganisms that persist in fractured shale reservoirs cause several problems including secreting foul gases and forming biofilms. Current biocontrol measures often fail due to limited knowledge of their in situ activities. The plasma membrane protects the cell, mediates many of its critical functions, and responds to intracellular cues and ecological perturbations through physicochemical modifications. As such, it provides valuable insight into the physiological adaptation of microorganisms in disturbed environmental systems. Here, we (i) demonstrate how changes in salinity and hydraulic retention time (HRT) influence the plasma membrane intact polar lipid (IPL) chemistry of model bacterium, Halanaerobium congolense WG10, and mixed microbial consortia enriched from shale-produced fluids and (ii) elucidate adjustments in membrane IPL chemistry during biofilm growth relative to planktonic cells. We incubated H. congolense WG10 in chemostats under three salinities (7%, 13%, and 20% NaCl), operated under three HRTs (19.2, 24, and 48 h), and in drip flow biofilm reactors under the same salinity gradients. Also, mixed microbial consortia in produced fluids were enriched in triplicate chemostat vessels under three HRTs (19.2, 24, and 72 h) and biofilm reactors. Lipids were analyzed by ultra high performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). Our results show that phosphatidylglycerols, cardiolipins, and phosphatidylethanolamines were predominantly enriched in planktonic H. congolense WG10 cells grown at hypersalinity (20%) compared to optimum (13%). In addition, several zwitterionic phosphatidylcholines and phosphatidylethanolamines were higher in abundance during biofilm growth. These observations suggest that microbial adaptation and biofilm formation in fractured shale are enabled by strategic plasma membrane IPL chemistry adjustments. IMPORTANCE Microorganisms inadvertently introduced into the shale reservoir during fracturing face multiple stressors including brine-level salinities and starvation. However, some anaerobic halotolerant bacteria adapt and persist for long periods of time. They produce hydrogen sulfide, which sours the reservoir and corrodes engineering infrastructure. In addition, they form biofilms on rock matrices, which decrease shale permeability and clog fracture networks. These reduce well productivity and increase extraction costs. Under stress, microbes remodel their plasma membrane to optimize its roles in protection and mediating cellular processes such as signaling, transport, and energy metabolism. Hence, by observing changes in the membrane lipidome of model shale bacteria, Halanaerobium congolense WG10, and mixed consortia enriched from produced fluids under varying subsurface conditions and growth modes, we provide insight that advances our knowledge of the fractured shale biosystem. We also offer data-driven recommendations for improving biocontrol efficacy and the efficiency of energy recovery from unconventional formations.

03 NATURAL GAS↗

DOE OSTI2022

Self‐Assembled LuFeO 3 /LuFe 2 O 4 Heterostructure with Emergent Ferroic Orderings

Abstract Achieving self‐assembling structures that exhibit emergent properties and functionalities is one of the holy grails in nanotechnology and holds great promise for a wide range of potential applications. Herein, a self‐assembled LuFeO 3 –(1/3)LuFe 2 O 4 –LuFeO 3 heterostructure that consists of two model multiferroics, i.e., hexagonal LuFeO 3 and rhombohedral LuFe 2 O 4 , is reported in single‐layer epitaxial LuFeO 3 thin films. Atomic‐scale electron microscopy investigations reveal the spontaneous organization of ferroelectric polarization in each building block, which forms a series of polar configurations. Specifically, the charge and lattice of neighboring LuFeO 3 and LuFe 2 O 4 blocks are closely coupled with competing degrees of freedom. A combination of the quantitative analysis of atomically resolved images and spectroscopy with theoretical calculations determines how charge‐ordering‐induced polarization accommodates charge naturality across the interfaces to reduce the system energy and unravels the formation mechanism of this heterostructure. The results point to the possibilities of generation and control of multiferroic self‐assembled systems, which may provide a basis for engineering novel materials with emergent properties.

Deng, Shiqing↗

DOE OSTI2022

Origin of giant electric-field-induced strain in faulted alkali niobate films

A large electromechanical response in ferroelectrics is highly desirable for developing high-performance sensors and actuators. Enhanced electromechanical coupling in ferroelectrics is usually obtained at morphotropic phase boundaries requiring stoichiometric control of complex compositions. Recently it was shown that giant piezoelectricity can be obtained in films with nanopillar structures. Here, we elucidate its origin in terms of atomic structure and demonstrate a different system with a greatly enhanced response. This is in non-stoichiometric potassium sodium niobate epitaxial thin films with a high density of self-assembled planar faults. A giant piezoelectric coefficient of ~1900 picometer per volt is demonstrated at 1 kHz, which is almost double the highest ever reported effective piezoelectric response in any existing thin films. The large oxygen octahedral distortions and the coupling between the structural distortion and polarization orientation mediated by charge redistribution at the planar faults enable the giant electric-field-induced strain. Our findings demonstrate an important mechanism for realizing the unprecedentedly giant electromechanical coupling and can be extended to many other material functions by engineering lattice faults in non-stoichiometric compositions.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Achieving giant electrostrain of above 1% in (Bi,Na)TiO 3 -based lead-free piezoelectrics via introducing oxygen-defect composition

Piezoelectric ceramics have been extensively used in actuators, where the magnitude of electrostrain is key indicator for large-stroke actuation applications. Here, we propose an innovative strategy based on defect chemistry to form a defect-engineered morphotropic phase boundary and achieve a giant strain of 1.12% in lead-free Bi 0.5 Na 0.5 TiO 3 (BNT)–based ceramics. The incorporation of the hypothetical perovskite BaAlO 2.5 with nominal oxygen defect into BNT will form strongly polarized directional defect dipoles, leading to a strong pinning effect after aging. The large asymmetrical strain is mainly attributed to two factors: The defect dipoles along crystallographic [001] direction destroy the long-range ordering of the ferroelectric and activate a reversible phase transition while promoting polarization rotation when the dipoles are aligned along the applied electric field. Our results not only demonstrate the potential application of BNT-based materials in low-frequency, large-stroke actuators but also provide a general methodology to achieve large strain.

36 MATERIALS SCIENCE↗

NASA NTRS2019

Evaluation of NOAA-20 VIIRS reflective solar bands calibration performance using vicarious approaches

The newly launched polar-orbiting NOAA-20 satellite is the follow-on mission to the SNPP (Suomi National Polar-orbiting Partnership) satellite. Both satellites are in an afternoon orbit with a close equatorial cross time. The Visible Infrared Imaging Radiometer Suite (VIIRS) is a key sensor onboard NOAA-20 and SNPP. The two VIIRS sensors are within the same engineering design with nearly identical spectral ranges. Its on-board calibration components include a solar diffuser and a solar diffuser stability monitor for the reflective solar bands (RSB), a V-groove blackbody for the thermal emissive bands (TEB), and a space view as background reference. This study evaluates calibration performance of the NOAA-20 VIIRS RSB using the first internally released L1B data product by NASA Land SIPS, which has consistent calibration coefficient look up tables (LUT) throughout the entire mission. Several independent vicarious approaches are used to examine the stability and consistence of reflectance. The first approach is based on a double difference method by comparison with SNPP VIIRS using observations from simultaneous nadir overpasses (SNO) with Aqua MODIS. The second is based on the reflectance trends from 16-day repeatable orbits obtained over the widely used Liby-4 desert site so each data point has the nearly same viewing angles relative to the site. The third approach is to use the frequent overpasses over the Dome C snow site. Results of this study provide NOAA-20 VIIRS post-launch calibration stability performance and radiometric agreement with SNPP for the first 18 months of mission.

VIIRS↗

DOE OSTI2026

Plasmonic Hybridization and Near-Field Localization in Gold “Dog Bone” Nanoparticles

Gold nanoparticles with complex anisotropic geometries offer unique opportunities for tailoring plasmonic near-fields beyond the limits of conventional nanorods. Here we combine photon-induced near-field electron microscopy (PINEM) and full-wave simulations to resolve plasmon hybridization and near-field localization in gold dog-bone nanoparticles and their dimers with and without conformal SiO 2 shells. We demonstrate that the dog-bone geometry drives unconventional polarization-dependent field confinement, including pronounced tip-localized near-fields under both longitudinal and transverse excitation. Conformal SiO 2 shells red-shift the plasmon resonances through dielectric screening and prevent charge-transfer coupling in adjacent dimers. Depending on the dimer orientation and excitation polarization, coupled structures exhibit distinct bonding- and antibonding-like hybridized modes as well as interparticle near-field channels. However, weakly interacting dimers retain largely independent particle responses with geometry-governed asymmetries. The close agreement between PINEM measurements and simulations establishes a direct picture of how shape, dielectric environment, and nanoscale coupling together define plasmonic modes in complex anisotropic nanoparticles. These findings provide design principles for engineering localized optical fields in plasmonic nanoscale structures.

hybridization↗

DOE OSTI2022

High-density polarization-induced 2D electron gases in N-polar pseudomorphic undoped GaN/Al 0.85 Ga 0.15 N heterostructures on single-crystal AlN substrates

The polarization difference and band offset between Al(Ga)N and GaN induce two-dimensional (2D) free carriers in Al(Ga)N/GaN heterojunctions without any chemical doping. A high-density 2D electron gas (2DEG), analogous to the recently discovered 2D hole gas in a metal-polar structure, is predicted in a N-polar pseudomorphic GaN/Al(Ga)N heterostructure on unstrained AlN. We report the observation of such 2DEGs in N-polar undoped pseudomorphic GaN/AlGaN heterostructures on single-crystal AlN substrates by molecular beam epitaxy. With a high electron density of ~4.3 ×10 13 /cm 2 that maintains down to cryogenic temperatures and a room temperature electron mobility of ~450 cm 2 /V s, a sheet resistance as low as ~320 Ω/$\Box$ is achieved in a structure with an 8 nm GaN layer. Finally, these results indicate significant potential of AlN platform for future high-power RF electronics based on N-polar III-nitride high electron mobility transistors.

42 ENGINEERING↗

DOE OSTI2026

Design and Construction of a Superconducting “Direct Wind” R&D Magnet for the EIC Interaction Region

Brookhaven National Laboratory (BNL) was chosen to host the international Electron-Ion Collider (EIC), which will collide high energy and highly polarized hadron and electron beams with a center of mass energy up to 140 GeV. The Interaction Region (IR) [1] requires several large aperture, relatively high field superconducting dipole and quadrupole magnets, some of which are very closely spaced.\r\nA value engineering effort is underway as part of the EIC Project to construct and test a Direct Wind magnet [2] (coil comprised of NbTi conductor deposited directly onto a support tube, in this instance tapered, and secured mechanically against Lorentz forces afterwards) to replace two Rutherford cable collared magnets. This magnet exceeds the combination of aperture, number of coil \r\nlayers, and magnetic field, as compared to existing accelerator and R&D Direct Wind magnets to date. Furthermore, construction has been completed using a newly commissioned winding machine, upgraded in anticipation of the upcoming EIC production coil fabrication. Design, analysis, construction issues, lessons learned and accomplishments to date shall be discussed, including the \r\nachieved corrections to multipoles made to successive coil layers based on warm magnetic measurements of preceding layers.

43 PARTICLE ACCELERATORS↗