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At least 397 records · Page 22

Melt Inclusions in Zircon: A Window to Understanding the Structure and Evolution of the Magmatic System Beneath the Laguna del Maule Volcanic Field

Explosive silicic eruptions pose a significant threat to society, yet the development and destabilization of the underlying silicic magmatic systems are still controversial. Zircons provide simultaneous information on the trace element composition and age of silicic magmatic systems, while melt inclusions in quartz and plagioclase yield important constraints on their volatile content as well as storage depth. Melt inclusions in zircons (MIZs) combine these data from a single mineral grain, recording the age, storage depth, temperature, and composition of magmas, and thus provide unique constraints on the structure and evolution of silicic magmatic systems. We studied MIZs from the Laguna del Maule (LdM) volcanic field in the southern Andes that is among the most active Pleistocene-Holocene rhyolitic volcanic centers worldwide and a potentially hazardous system displaying inflation rates in excess of 25 cm/yr. The host zircon ages suggest that the LdM MIZ record extends to ~30 kyr before eruption, in contrast to the melt inclusions in LdM plagioclase and quartz crystals that formed only decades to centuries before eruption. The major element compositions of MIZs are minimally affected by post-entrapment crystallization, and agree well with the LdM rhyolitic whole rock data. The more evolved major element composition of rle MIZs than rdm MIZs, suggests a long-term deeper connection of the rdm crystal mush to a more primitive magma body than that of the rle. The evidence of slow H diffusion observed in MIZs suggest that their H 2 O contents are not significantly affected by diffusion of H through the host zircon. The storage depths of 1.1 to 2.8 kbars recorded by the H 2 O contents of rdm and rle MIZs are consistent with the optimal emplacement window (2.0 ± 0.5 kbar) of silicic magma reservoir growth, storage, and eruptibility based on thermomechanical modeling (Huber et al. 2019).

Kei Shimizu↗

Integrated back to back barrier-N-N(+) varactor diode tripler using a split-waveguide block

The back-to-back barrier-N-N(+) (bbBNN) varactor is a nonlinear device being developed for frequency multiplier applications above 100 GHz. Its symmetrical C-V characteristic, low series resistance, freedom from external bias and suitability to planarization make it an ideal choice for high frequency, low power, odd harmonic generation. In this paper, the performance of a 220-GHz waveguide tripler using, for the first time, a planar GaAs bbBNN device integrated on a quartz microstrip circuit is presented. A new split-waveguide block design has been employed to provide the proper embedding impedances to the device at the input and third harmonic output frequencies. A flange-to-flange tripling efficiency of 7% has been obtained at 220 GHz with an output power in excess of 700 mu W. This is believed to be the highest conversion efficiency yet reported for a tripler with an integrated device at this frequency. Theoretical calculations indicate that substantial improvement is possible with modest changes to the device and circuit parameters.

QUARTZ MICROSTRIP CIRCUITS↗

Carbonate deposition during the late Proterozoic Era: an example from Spitsbergen

Carbonate sediments reflect the physico-chemical and biological circumstances of their formation; thus, features of limestones and dolomites may provide insights into both environmental and evolutionary change through geological time. The Upper Proterozoic (approx 800-700 Ma) Akademikerbreen Group, Spitsbergen, comprises 2000 m of carbonates, with only minor intercalations of quartz arenite and shale. Although Proterozoic carbonates are often seen as predominantly dolomitic, the Akademikerbreen Group is about 45 percent limestone. Stromatolites are conspicuous in outcrop but constitute only 25 percent of the total section. Micrites and coarser intraclastic carbonates derived mainly from micritric precursors comprise 60 percent of the group, while oolites make up the remaining 15 percent. Distinctive sedimentary features of the group include giant (up to 16 mm) ooids, very early diagenetic calcite nodules and cements, micrites containing subaqueous shrinkage cracks filled with equant microspar cement, and strong 13C enrichment in both carbonates and co-occurring organic matter. The principal features of Akademikerbreen carbonates are widely distributed in coeval successions. However, these rocks appear to differ from older limestones and dolomites in their relative abundance of grainstones and, perhaps, micrites, as well as their paucity of tufa-like laminates and columnar or coniform stromatolites that preserve petrographic evidence of in situ precipitation as a dominant means of carbonate accretion. Upper Proterozoic carbonates also differ from Paleozoic accumulations, but the transition is not abrupt. Most changes accompanying the Proterozoic/Phanerozoic transition can be interpreted in terms of the consequences rather than the causes of metazoan and metaphyte evolution, including the evolution of biomineralization. Carbonate sedimentology reinforces data from other sources which indicate the last 200 to 300 Ma of the Proterozoic Eon was a distinctive interval of Earth history.

NASA Discipline Number 52-30↗

Modeling Dust Mineralogical Composition: Sensitivity to Soil Mineralogy Atlases and Their Expected Climate Impacts

Soil dust aerosols are a key component of the climate system, as they interact with short- and long-wave radiation, alter cloud formation processes, affect atmospheric chemistry and play a role in biogeochemical cycles by providing nutrient inputs such as iron and phosphorus. The influence of dust on these processes depends on its physicochemical properties, which, far from being homogeneous, are shaped by its regionally varying mineral composition. The relative amount of minerals in dust depends on the source region and shows a large geographical variability. However, many state-of-the-art Earth system models (ESMs), upon which climate analyses and projections rely, still consider dust mineralogy to be invariant. The explicit representation of minerals in ESMs is more hindered by our limited knowledge of the global soil composition along with the resulting size-resolved airborne mineralogy than by computational constraints. In this work we introduce an explicit mineralogy representation within the state-of-the-art Multiscale Online Nonhydrostatic AtmospheRe CHemistry (MONARCH) model. We review and compare two existing soil mineralogy datasets, which remain a source of uncertainty for dust mineralogy modeling and provide an evaluation of multiannual simulations against available mineralogy observations. Soil mineralogy datasets are based on measurements performed after wet sieving, which breaks the aggregates found in the parent soil. Our model predicts the emitted particle size distribution (PSD) in terms of its constituent minerals based on brittle fragmentation theory (BFT), which reconstructs the emitted mineral aggregates destroyed by wet sieving. Our simulations broadly reproduce the most abundant mineral fractions independently of the soil composition data used. Feldspars and calcite are highly sensitive to the soil mineralogy map, mainly due to the different assumptions made in each soil dataset to extrapolate a handful of soil measurements to arid and semi-arid regions worldwide. For the least abundant or more difficult-to-determine minerals, such as iron oxides, uncertainties in soil mineralogy yield differences in annual mean aerosol mass fractions of up to ∼ 100 %. Although BFT restores coarse aggregates including phyllosilicates that usually break during soil analysis, we still identify an overestimation of coarse quartz mass fractions (above 2 µm in diameter). In a dedicated experiment, we estimate the fraction of dust with undetermined composition as given by a soil map, which makes up ∼ 10 % of the emitted dust mass at the global scale and can be regionally larger. Changes in the underlying soil mineralogy impact our estimates of climate-relevant variables, particularly affecting the regional variability of the single-scattering albedo at solar wavelengths or the total iron deposited over oceans. All in all, this assessment represents a baseline for future model experiments including new mineralogical maps constrained by high-quality spaceborne hyperspectral measurements, such as those arising from the NASA Earth Surface Mineral Dust Source Investigation (EMIT) mission.

Soil dust↗

STUDY OF PURIFICATION OF WATER FROM BIOLOGICAL WASTE.

All the recent data accumulated for the recovery of potable water from metabolic waste have been obtained from the accordian pleated self-heating catalyst. Potable water was obtained in the preliminary runs. Optical pyrometer readings of the furnace temperature were obtained through the side wall of the quartz reactor tube. No further conclusions have been made regarding the correlations between the low pH and high flow rate of the original unit.

PURIFICATION↗

THIRTY DAY ENDURANCE TEST OF A 30KW ARC JET ENGINE

Details are presented on a 30-day run of a radiation cooled thermal arc jet engine. The engine performed satisfactorily throughout the test period, maintaining a thrust of 250 grams and a propellant specific impulse greater than 1000 seconds a t an input power level of 30 kilowatts. The resulting propulsive efficiency was greater than 40 percent. Visual examination of the arc discharge through a quartz constrictor indicates that there is a smooth, constant diameter, bright core extending from the cathode completely through the constrictor to the cathode. Photographic observations on the arc discharge, using a red filter, indicate that the center of the column is darker than the outside: and this, in turn, suggests that the maximum core temperature is greater than 20,000°K. Calculations on the energy flow rate through a fully developed laminar column, combined with the experimental observation that the longitudinal energy flux gradient along the column is small, suggest that there may be a region of high volumetric energy release in the vicinity of the cathode tip.

Arc jet↗

Miniature servo accelerometer is force- balanced

Miniature servo accelerometer measures unusually small forces of torques. The pendulous mass of the accelerometer is suspended by fused quartz torsion fibers in an electromagnetically force- balanced environment. It is used in gravity surveys for exploring mineral deposits.

Johnston, A. R.↗

High-speed furnace uses infrared radiation for controlled brazing

Furnace produces controlled heat for brazing and heat treating metals over a wide range of temperatures by using a near-infrared heat source positioned at one focus of an ellipsoidal reflector mounted below a cylindrical quartz chamber. This furnace maintains a pure atmosphere, has rapid heatup and cooldown, and permits visual observation.

Eckles, P. N.↗